• Title/Summary/Keyword: 열분석적 특성

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Thermoelectric Properties and Crystallization of $(Bi1-xSbx)_2Te_3 $ Thin Films Prepared by Magenetron Sputtering Process (마그네트론 스퍼터링법으로 제조한 $(Bi1-xSbx)_2Te_3 $박막의 결정성과 열전특성)

  • 연대중;오태성
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.62-62
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    • 2000
  • 비접촉식 온도센서는 물체에서 방출하는 적외선 등의 복사신호를 열에너지로 전환하고 이를 다시 전기신호로 2차 에너지 변환하여 온도를 감지하는 센서로 인체 검지를 응용한 다양한 상품 및 교통, 방재, 빌딩 시스템 등의 분야에 널리 응용되고 있다. 비접촉식 적외선 센서는 열에너지를 전기에너지로 변환하는 방법에 따라 양자형과 열형으로 구분되며, 이중 양자형은 광전도나 광기전력 효과 등을 이용하여 감도 및 응답성이 우수하다는 장점을 지니고 있지만, 소자부를 80K 이하 온도로 유지시키는 냉각을 필요로 하므로 대형 제작이 불가피하고 그 용도가 제한적이다. 열형은 냉각이 필요 없고 소형으로 제작가능한 장점을 지니고 있어 써모 파일이나 초전체를 이용한 번용 센서가 보급되고 있다. 그러나 써모파일의 경우 출력되는 전기 신호가 미약하여 감도 및 응답성을 향상하기 위해 구조가 복잡하고, 특히 모터초퍼나 저항을 전압으로 변환시키는 전력기 등이 필요로 하는 단점을 지니고 있다. 따라서 이러한 문제점을 보완하기 위해 열전재료 박막을 이용한 적외선 센서를 개발하려는 노력이 진행중에 있다. 열전박막을 이용한 적외선 센서는 열전재료의 Seebeck 현상을 이용하여 열에너지에서 전기에너지의 변환이 자가발전으로 이루어져 offset과 외부 바이어스를 필요로 하지 않는다. 또한 작은 온도 변화에도 그 감도와 응답성이 높고, 출력신호가 커서 증폭기 등이 불필요한 장점을 지니고 있다. 특히 초전형 센서가 상온에서도 기판에 대한 열 확산을 제어해야 하는 문제점을 갖는 반면, 열전박막형 적외선 센서는 고온에서도 안정된 출력 신호를 얻을 수 있어 그 활용 온도 범위가 크게 확대될 것으로 기대된다. 본 실험에서는 우수한 열전특성을 갖는 (Bi1-xSbx)2Te3 박막을 얻기 위해 열팽창계수가 작고 알칼리 원소가 0.3% 이하로 포함되어 있는 corning glass(# 7059)를 기판으로 사용하였다. 또한 최적의 열전특성을 나타내는 조성을 실험적으로 구하기 위해 (Bi0.2Sbx)2Te3 조성의 합금 타? 위에 Bi2Te3 및 Sb2Te3 chip을 올려놓고 그 면적을 변화시켜 다양한 조성의 열전박막을 증착하였다. 열전박막의 증착시 산화와 오염에 의한 열전특성 변화를 최소화하기 위해 초기진공도를 1$\times$10-6 Torr로 하였으며, Ar 가스를 흘려주어 2$\times$102 Torr 의 증착진공도를 유지하였다. 열전박막을 증착하기 전에 기판을 10분간 200W의 출력으로 RF 처리하였으며, 30$0^{\circ}C$에서 33 /sec의 속도로 (Bi1-xSbx)2Te3 박막을 증착하였다. 이와 같이 제조된 (Bi1-xSbx)2Te3 박막의 미세구조를 SEM으로 관찰하고 EDS로 조성을 분석하였으며, XRD를 이용하여 결정성을 관찰하였다. 또한 (Bi1-xSbx)2Te3 박막의 Seebeeck 계수 및 전기비저항을 측정하고 증착된 박막조성, 결정상, 미세구조와 열전특성간의 상관관계를 고찰하였다.

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The heat transfer characteristics of viscoelastic non-newtonian fluids in the entrance region of circular tube flows (원형관속을 유동하는 점탄성 유체의 입구 영역 열전달 특성에 관한 연구)

  • 엄정섭;황태성;유상신
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.1032-1043
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    • 1989
  • The heat transfer characteristics of the drag reducing polymer solutions are investigated experimentally in the thermal entrance region of circular tube flows. Fluids used in experiments are the aqueous solutions of high molecular polymer, polyacrylamide Separan AP-273 and the range of polymer concentrations is from 20 to 1000 wppm. Two stainless steel tubes with inside diameter 8.5mm(L/D=712) and 10.3mm(L/D=1160) are used for the heat transfer flow loops. The flow loop is set up to measure friction factors and heat transfer coefficients of test sections in two different modes; the recirculating flow system and once-through flow system. The test tubes are heated directly by electricity to apply the constant heat flux boundary conditions to the wall. Three different types of adaptors are used to observe the effects of the upstream flow conditions of the heat transfer test sections. The viscosity and characteristic relaxation time of the test fluids circulating in the flow system are measured by the capillary tube viscometer and falling ball viscometer at regular time intervals. The installed adaptors exhibit slight effect on the entrance heat transfer of Newtonian fluid. However, no noticeable effects are observed for the entrance heat transfer of the drag reducing fluids. The order of magnitude of the thermal entrance lengths of the drag reducing fluids which follow the minimum friction asymptote is much longer than that of Newtonian fluids in turbulent flows. A new dimensionless parameter, the viscoelastic Graetz number, is defined and all the experimental data are recasted in terms of the viscoelastic Graetz number. The local Nusselt number of the viscoelastic fluids is represented as a function of flow behavior index n and the viscoelastic Graetz number. As degradation continues the viscosity and the characteristic relaxation time of the testing fluids decrease. Weissenberg number defined by the relaxation time and D/V appears to be a proper dimensionless parameter in describing degradation effects on heat transfer of the viscoelastic fluids.

Synthesis of TiO2-xNx Using Thermal Plasma and Comparison of Photocatalytic Characteristics (열플라즈마에 의한 TiO2-xNx의 합성 및 광촉매 특성 비교)

  • Kim, Min-Hee;Park, Dong-Wha
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.270-276
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    • 2008
  • $N_2$ doped $TiO_2$ nano-sized powder was prepared using a DC arc plasma jet and investigated with XRD, BET, SEM, TEM, and photo-catalytic decomposition. Recently the research interest about the nano-sized $TiO_2$ powder has been increased to improve its photo-catalytic activity for the removal of environmental pollutants. Nitrogen gas, reacting gas, and titanium tetrachloride ($TiCl_4$) were used as the raw materials and injected into the plasma reactor to synthesize the $N_2$ doped $TiO_2$ power. The particle size and XRD peaks of the synthesized powder were analyzed as a function of the flow rate of the nitrogen gas. Also, the characteristics of the photo-catalytic decomposition using the prepared powder were studied. For comparing the photo-catalytic decomposition performance of $TiO_2$ powder with that of $TiO_2$ coating, $TiO_2$ thin films were prepared by the spin coating and the pulsed laser deposition. For the results of the acetaldehyde decomposition, the photo-catalytic activity of $TiO_{2-x}N_x$ powder was higher than that of the pure $TiO_2$ powder in the visible light region. For the methylene blue decomposition, the decomposition efficiency of $TiO_2$ powder was also higher than that of $TiO_2$ film.

Mechanical evaluation of SiC-graphite interface of seed crystal module for growing SiC single crystals (탄화규소 단결정 성장을 위한 종자결정모듈의 탄화규소-흑연 간 접합계면의 기계적 특성 평가)

  • Kang, June-Hyuk;Kim, Yong-Hyeon;Shin, Yun-Ji;Bae, Si-Young;Jang, Yeon-Suk;Lee, Won-Jae;Jeong, Seong-Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.5
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    • pp.212-217
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    • 2022
  • Large thermal stress due to the difference between silicon carbide and graphite's coefficients of thermal expansion could be formed during crystal growing process of silicon carbide (SiC) at high temperature. The large thermal stress could separate the SiC seed crystals from graphite components, which bring about the drop of the seed crystal during crystal growth. However, the bonding properties of SiC seed crystal module has hardly reported so far. In this study, SiC and graphite were bonded using 3 types of bonding agents and a three-point bending tests using a mixed-mode flexure test were conducted for the bonded samples to evaluate the bonding characteristics between SiC and graphite. Raman spectroscopy, X-ray Photoelectron Spectroscopy, and X-ray Computed Tomography were used to analyze the bonding characteristics and the microstructures of the SiC-graphite interfaces bonded with the bonding agents. As results, an excellent bonding agent was chosen to fabricate SiC seed crystal module with 50 mm in diameter. An SiC single crystal with 50 mm in diameter was successfully grown without falling out during top seeded solution growth of SiC at high temperature.

Analyzing Sand Transfer Path by Songdo Beach Using Time Series Analysis (시계열 분석을 통한 송도해안의 해안사구 이동경로 분석)

  • Han, Chung-Mok;Kim, Yong-Suk
    • The Journal of the Korea Contents Association
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    • v.9 no.8
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    • pp.384-391
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    • 2009
  • The coastline area, which was the important to decide the shape of the national land, has the characteristics of changing its shapes and features. We have some trouble to make the appropriate use-plan, because of the huge land to be reclaimed from the sea and developing large and small coast areas. Of them the coastal sand dune plays a definite primary role in the side of tourism and ecology. But there is not enough study for that. Busan Songdo coast is decided as an object of this study. We would analyze transfer path of the coastal sand dune through the time series analysis with RTK-GPS survey for many years. In case of Song do coast, the mean coastline length is approximately 620m, the area is approximately $31,846m^2$. Breakwaters are set up in right and left sides in Song do coast. it can make the sand dune be a minimum. So the coastal sand dune is steadily deposited with a certain beach nourishment of every year. As a result of 7 times survey, both sides of the coastal sand dune are eroded. It turns out it is going ahead over all as the center of the coastal sand dune is deposited.

Analysis of the Disposal Tunnel Spacing and Disposal Pit Pitch for the HLW Repository Design (심지층 처분시설 설계를 위한 처분터널 및 처분공 간격 분석)

  • Lee, Jong-Youl;Kim, Seong-Ki;Kim, Jhin-Wung;Choi, Jong-Won;Hahn, Pil-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.4
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    • pp.349-358
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    • 2005
  • In this study, analysis of the disposal tunnel spacing and disposal pit pitch was carried out, as a factor of the design to estimate the scale and layout of the repository. To do this, based on the reference repository concept and the engineered barrier concept, several cross sections of the disposal tunnel and disposal pit were established. After then, the mechanical and thermal stabilities of the established tunnels were analyzed. Also, an optimized disposal tunnel spacing and the disposal pit pitch reducing the excavation volume was proposed. The results of these analyses can be used in the deep geological repository design. The detailed analyses by the exact site characteristics data to reduce the uncertainty of the site and the modification for the optimization are required.

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Parametric Analysis for the Simultaneous Carbonation and Chloride Ion Penetration in Reinforced Concrete Sections (중성화와 염화물 침투가 동시에 발생하는 철근콘크리트 단면의 매개변수 분석)

  • Zhu, Xingji;Kim, Soye;Kwak, Dong-Woo;Bae, Kyung-Tae;Zi, Goangseup
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.5
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    • pp.66-74
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    • 2016
  • The objective of this study is the investigation of the influence of carbonation on the penetration of chloride ions in reinforced concrete sections for different mix proportions and environmental conditions. A comprehensive numerical model based on the change of the pore structure and the chemical equilibrium was used for this combined action of carbonation and chloride ingress. The empirical formulae of some parameters in this model are estimated according to numerous experimental data. And, a set of data analysis is carried out to simplify the estimation of model variables to reduce the computational cost. A coupled simulation of the transports of carbon dioxide, chloride ions, heat and moisture is carried out. Then, the parametric analysis is given and the numerical results show that the effect of carbonation of the free chloride ingress is significant and depends on the binder types and concrete mix proportion.

A Study on the Reliable Video Transmission Through Source/Channel Combined Optimal Quantizer for EREC Based Bitstream (EREC 기반 비트열을 위한 Source-Channel 결합 최적 양자화기 설계 및 이를 통한 안정적 영상 전송에 관한 연구)

  • 김용구;송진규;최윤식
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.12B
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    • pp.2094-2108
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    • 2000
  • 오류를 수반하는 통신망을 통한 멀티미디어 데이터의 응용은 최근 그 수요가 급증하고 있다. 하지만 그 구현은 많은 문제점들을 야기하는데, 전송된 비디오 데이터에 발생한 오류를 처리하는 문제가 그 중 하나이다. 이는 압축된 비트열에 발생한 오류가 영상의 시-공간 방향으로 심각한 전파 현상을 수반하기 때문이다. 이러한 심각한 오류 전파를 완화하기 위해 본 논문에서는 EREC라 알려진 오류 제한 기법을 적용하고, 적용된 EREC의 오류 전파 특성을 분석하였다. 이를 통해, 압축 부호화된 하나의 기본 블록 (매크로 블록)이 복호시 오류가 생길 확률을 추정하였으며, 추정된 확률의 근사를 통해 양 끝단(전송단과 수신단)에서의 비디오 화질 열화를 예측하였다. 추정 확률의 근사는 매 기본 블록에서 발생된 비트수에 대한 그 기본 블록이 복호시 오류가 생길 확률을 간단한 1차식을 통한 선형 회귀법으로 모델링 되었으며, 따라서 간단한 방법을 통해 양 끝단의 화질 열화를 효과적으로 예측할 수 있었다. 부호화된 비트열이 전송 오류에 보다 강인하게 되도록 하기 위해, 본 논문에서 개발된 화질 열화 모델을 양자화기 선택에 적용함으로써, 새로운 최적 양자화 기법을 제시하였다. 본 논문에서 제안된 최적 양자화 기법은, 기존의 양자기 최적화 기법들과는 달리, 복호단에서의 복원 영상 화질이 주어진 비트율에서 최적이 되도록 양자화를 수행한다. H.263 비디오 압축 규격에 적용한 제안 양자화 기법의 실험 결과를 통해, 제안 기법이 매우 적은 계산상의 부하를 비용으로 객관적 화질은 물론 주관적 화질까지 크게 개선할 수 있음을 확인할 수 있었다.내었다.Lc. lacti ssp. lactis의 젖산과 초산의 생성량은 각각 0.089, 0.003과 0.189, 0.003M이었다. 따라서 corn steep liquor는 L. fermentum와 Lc. lactis ssp, lactis 의 생장을 위해 질소 또는 탄소 공급원으로서 배지에 첨가 될 수 있는 우수한 농업 부산물로 판단되었다.징하며 WLWQ에 적용되는 몇 가지 제약을 관찰하고 이를 일반적인 언어원리로 설명한다. 첫째, XP는 주어로만 해석되는데 그 이유는 XP가 목적어 혹은 부가어 등 다른 기능을 할 경우 생략 부위가 생략의 복원 가능선 원리 (the deletion-up-to recoverability principle)를 위배하기 때문이다. 둘째, WLWQ가 내용 의문문으로만 해석되는데 그 이유는 양의 공리(the maxim of quantity: Grice 1975) 때문이다. 평서문으로 해석될 경우 WP에 들어갈 부분이 XP의 자질의 부분집합에 불과하므로 명제가 아무런 정보제공을 하지 못한다. 반면 의문문 자체는 정보제공을 추구하지 않으므로 앞에서 언급한 양의 공리로부터 자유롭다. 셋째, WLWQ의 XP는 주제어 표지 ‘는/-은’을 취하나 주어표지 ‘가/-이’는 취하지 못한다(XP-는/-은 vs. XP-가/-이). 이는 IP내부 에 비공범주의 존재 여부에 따라 C의 음운형태(PF)가 시성이 정해진다는 가설로 설명하고자 했다. WLWQ에 대한 우리의 논의가 옳다면, 본 논문은 다음과 같은 이론적 함의를 기닌다. 첫째, WLWQ의 존재는 생략에 대한 두 이론 즉 LF 복사 이론과 PF 삭제 이론

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Laser Transmission Welding of Flexible Substrates and Evaluation of the Mechanical Properties (플렉서블 기판의 레이저 투과 용접 및 기계적 특성 평가)

  • Ko, Myeong-Jun;Sohn, Minjeong;Kim, Min-Su;Na, Jeehoo;Ju, Byeong-Kwon;Park, Young-Bae;Lee, Tae-Ik
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.2
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    • pp.113-119
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    • 2022
  • In order to improve the mechanical reliability of next-generation electronic devices including flexible, wearable devices, a high level of mechanical reliability is required at various flexible joints. Organic adhesive materials such as epoxy for bonding existing polymer substrates inevitably have an increase in the thickness of the joint and involve problems of thermodynamic damage due to repeated deformation and high temperature hardening. Therefore, it is required to develop a low-temperature bonding process to minimize the thickness of the joint and prevent thermal damage for flexible bonding. This study developed flexible laser transmission welding (f-LTW) that allows bonding of flexible substrates with flexibility, robustness, and low thermal damage. Carbon nanotube (CNT) is thin-film coated on a flexible substrate to reduce the thickness of the joint, and a local melt bonding process on the surface of a polymer substrate by heating a CNT dispersion beam laser has been developed. The laser process conditions were constructed to minimize the thermal damage of the substrate and the mechanism of forming a CNT junction with the polymer substrate. In addition, lap shear adhesion test, peel test, and repeated bending experiment were conducted to evaluate the strength and flexibility of the flexible bonding joint.

Analysis of Activities in Chemistry Chapters of Middle School Science Textbooks for the 2009 Revised Science Curriculum: Focus on 8 Science Practices (2009 개정 교육과정에 따른 중학교 과학교과서 화학 단원에 포함된 활동 분석: 8가지 과학 실천을 중심으로)

  • Choi, Minji;Choi, Aeran
    • Journal of the Korean Chemical Society
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    • v.60 no.6
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    • pp.436-451
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    • 2016
  • This study analyzed activities in chemistry chapters of middle school science textbooks for the 2009 revised curriculum using 8 science practices. All the activities that students could experience inquiry were analyzed in this study. There were the most activities in 'Molecular motion and change of state' and the least activities in 'Heat and our life' of three textbooks. There were the most science practices in 'Features of substance' in two textbooks, but there were the least science practice in 'Heat and our life' of three textbooks. 'Investigation planning and performing', 'data analyzing and interpreting', and 'explanation composition and problem solution designing' were frequently included, but 'asking questions and defining issues' was not included at all. For 'Investigation planning and performing', 'data analyzing and interpreting', and 'explanation composition and problem solution designing', a variety of achievement goals were targeted while a few goals were frequently targeted. Two to four kinds of science practices were frequently included in an inquiry activity. There were few activity that includes over 5 different kinds of science practice.