• Elastomers and Composites
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• v.47 no.4
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• pp.318-328
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• 2012

In this study, the one-component curable polyurethane resin was manufactured using blocked isocyanate and hybrid technology. To prepare the one-component curable hybrid polyurethane, silica hybrids including hydroxyl group was synthesized, and the size, shape and distribution of hybrid particle in polyurethane resin were confirmed. Then the dissociation property, mechanical property and molding property of blocked isocyanate were investigated. The dissociation property of blocked isocyanate in one-component curable polyurethane became better as the heating temperature and treatment time increased. The synthesized silica hybrid had spherical appearance and size of 23~27 nm in diameter, and it was observed that the hybrid particles were homogeneously distributed in polyurethane structure. In the case of hybrid polyurethane, the mechanical property, anti-abrasion and thermal property were higher than those of general polyurethane, and it was observed that the mechanical property was maintained when the plasticizer was introduced.

• Journal of Korea Water Resources Association
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• v.41 no.4
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• pp.379-394
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• 2008

Recently, extreme precipitation events beyond design capacity of hydraulic system have been occurred and this is the causes of failure of hydraulic structure for flood prevention and of severe flood damage. Therefore it is very important to understand temporal and spatial characteristics of extreme precipitation events as well as expected changes in extreme precipitation events and distributional characteristics during design period under future climate change. In this paper, climate change scenarios were used to assess the impacts of future climate change on extreme precipitation. Furthermore, analysis of future extreme precipitation characteristics and I-D-F analysis were carried out. This study used SRES B2 greenhouse gas scenario and YONU CGCM to simulate climatic conditions from 2031 to 2050 and statistical downscaling method was applied to establish weather data from each of observation sites operated by the Korean Meteorological Administration. Then quantile mapping of bias correction methods was carried out by comparing the simulated data with observations for bias correction. In addition Modified Bartlett Lewis Rectangular Pulse(MBLRP) model (Onof and Wheater, 1993; Onof 2000) and adjust method were applied to transform daily precipitation time series data into hourly time series data. Finally, rainfall intensity, duration, and frequency were calculated to draw I-D-F curve. Although there are 66 observation sites in Korea, we consider here the results from only Seoul, Daegu, Jeonju, and Gwangju sites in this paper. From the results we found that the rainfall intensity will be increased and the bigger intensity will be occurred for longer rainfall duration when we compare the climate conditions of 2030s with present conditions.

• Journal of the Mineralogical Society of Korea
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• v.17 no.1
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• pp.99-114
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• 2004

Mineralogical characteristics of fracture-filling minerals from deep borehole in the Yuseong area were studied for the radioactive waste disposal project. There are many fracture zones in the deep drill holes of the Yuseong granite, which was locally affected by the hydrothermal alteration. According to the results of hole rock analysis of drill core samples, $SiO_2$ contents are distinctly decreased, whereas $Al_2$$O_3$ and CaO contents and L.O.I. values are increased in the -90 m∼-130 m and -230 m∼-250 m zone, which is related to the formations of filling minerals. Fracture-filling minerals mainly consist of zeolite minerals (laumontite and heulandite), calcite, illite ($2M_1$ and 1Md polytypes), chlorite, epidote and kaolinite. The relative frequency of occurrence among the fracture-filling minerals is calcite zeolite mineral > illite > epidote chlorite kaolinite. Judging from the SEM observation and EPMA analysis, there is no systematic change in the texture and chemical composition of the fracture-filling minerals with depth. In the study area, low temperature hydrothermal alteration was overlapped with water-rock interactions for a long geological time through the fracture zone developed in the granite body. Therefore the further study on the origin and paragenesis of the fracture-filling minerals are required.

• Journal of the Korean Association of Geographic Information Studies
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• v.22 no.2
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• pp.133-151
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• 2019

This study aims to analyze cold air characteristics in the watershed areas and to suggest strategies for utilizing them in urban ventilation corridor plans. For this purpose, the Jungnangcheon watershed and Uijeongbu-si in the northern part of Gyeonggi province, and Anyangcheon watershed as well as Yangjaecheon Tancheon watershed and Gwacheon-si in the southern part were selected as study areas. We used KALM (Kaltluftabflussmodell), a cold air simulation model developed in Germany and identified both the cold air flow and the height of cold air layer generated during 6 hours at night. Uijeongbu City is located on the main stream of the Jungnangcheon watershed, and the local cold air from the southern outskirts is an important part of Uijeongbu-si's overall ventilation corridor planning. In addition, the cold air generated in the vicinity of Mt. Sapae flows into the central business district near the city hall and plays a major role in regulating the thermal environment of the city. But, the cold air flows in the eastern part of Uijeongbu-si was not smoothly. The cold air flow generated in the east of Gwanak Mountain and in the west of Cheonggye Mountain was the most active in the northern part of Gwacheon-si. This flow is also a major ventilation corridor in Anyangcheon watershed as well as Yangjaecheon Tancheon watershed. But, the southern part where the cold air flow is not smooth is planed to be developed as 'Gwacheon Knowledge Information Town Public Housing District', so rapid development is expected in the future. Hence, it is suggested that an additional ventilation corridor plan should be established based on the detailed local wind flow analysis.

• Korean Journal of Heritage: History & Science
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• v.56 no.3
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• pp.158-171
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• 2023

Pottery filled with organic materials was excavated from the G-2 building site of Yongjangseong Fortress, Jingo, a relic of the Goryeo Dynasty. In this study, the characteristics of organic material were confirmed by a scientific analysis of organic material in pottery found at the palace in Yongjangseong, Jindo. In addition, it was intended to review the analysis method to identify the natural resin and to secure characteristic components(biomarkers) for each natural resin and use them as basic data in the future. The organic materials in the pottery were analyzed using attenuated total reflectance Fourier-transformed infrared spectroscopy(ATR-FTIR) and gas chromatography mass spectrometry(GC-MS). The infrared spectral characteristics were estimated to be natural resin, and biomarkers of organic materials were identified as sesquiterpene-based compounds(C₁₅H₂₄, MW 204) and derivatives. The lacquer(T.vemicifluum) is composed mainly of alkenes, alkanes, and catechol. Pine resin(P.densiflora), on the other hand, is primarily composed of diterpenoid(abietic acid, pimaric acid) and Whangchil(yellow lacquer) is identified to have sesquiterpenes(such as selinene, muurolene, calamenene) as its main components. So, the organic material in the pottery can be identified as Whangchil by comparing their compounds with modern resin materials from Dendropanax. morbifera that correspond with the results. Whangchil, which is exuded from the Dendropanax. morbifera, has been used as a natural coating materials since ancient times, and it has been confirmed that the characteristic components are well preserved even 700 years later. It can be assumed that the interior Whangchil was stored not for use as a coating, but rather for ritual purposes when the building was constructed, because the pottery was found near the cornerstone. Furthermore, based on simplified sample preparation using pyrolysis-gas chromatography mass spectrometry(Py-GC-MS), the thermal decomposition products were found to be similar to the characteristic components, suggesting that this method can be applied to the identification of natural resins used in historic artifacts.

• Journal of the Korean Applied Science and Technology
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• v.32 no.1
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• pp.48-55
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• 2015

IMO to issue some restricted maritime legislation for reducing the adverse environmental impacts arising from such ship exhaust emissions. According to the IMO policy, every ship entering the Baltic SECAs has to equip the gas cleaning scrubber. The discharged waste solution by gas cleaning scrubber contains many types of salts, which to recover some valuable materials before disposal. This study try to achieve valuable salts including AN and AS throughout a few process such as selective organic solvents salting out, low temperature extraction and thermal evaporation. Amongst them, Thermal evaporation with repetition extraction using inorganic solvent was the most optimum to purify the extracted AN. This valuable salt was evaluated by Elemental analysis and Differential scanning calorimetry.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.81-81
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• 2009

최근 휴대폰, 노트북 등과 같은 소형 멀티미디어 기기의 사용이 증가함에 따라 전자 패키징 산업은 경박단소화를 요구하고 있습니다. 더불어 전기적 신호의 손실을 줄이기 위해 전기, 전자산업체에서는 가볍고 굴곡성이 우수한 연성인쇄회로기판(Flexible Printed Circuit Board, FPCB)과 가격이 싸고 신뢰성이 입증된 경성인쇄회로기판(Rigid Printed Circuit Board, RPCB)의 전극간 접합에 많은 관심을 보이고 있습니다. 기존에 연성인쇄회로기판과 경성인쇄회로기판을 접합하는 방식으로는 connector를 이용한 체결법이 사용되고 있지만 완성품의 부피가 커지고 자동화 공정이 힘들며 I/O 개수가 제한적이어서 신호전달에 취약한 단점이 있습니다. 또한, 최근 FPCB를 RPCB에 접합하는데 interconnection으로 이방성 도전 필름(Anisotropic conductive film, ACF) 또는 비전도성 필름(Non-conductive film)이 널리 사용되고 있습니다. 하지만 필름의 가격이 비싸고, 낮은 전기 전도도를 보이며, 신뢰성 특성이 낮다는 단점을 가지고 있습니다. 본 실험에서는 기존의 connector 방식과 접착 필름을 이용한 방식을 대체하기 위하여 솔더를 interlayer로 이용하여 열과 압력으로 접합하는 방법에 대하여 연구하였습니다. 실험에 사용된 솔더의 조성은 Sn-3.0Ag-0.5Cu (in wt%)이고, RPCB와 FPCB의 표면처리는 ENIG로 하였습니다. 접합 온도와 접합 시간에 따라 최적의 접합 조건을 도출하고자 하였고, 접합된 시편을 가지고 신뢰성 테스트를 진행하였습니다. $85^{\circ}C$/85% 고온고습 시험과 고온 방치 시험을 통하여 접합부의 신뢰성을 테스트 하였고, 90도 Peel test로 기계적 접합 강도를 측정하였고, 파괴 단면을 Scanning Electron Microscopy (SEM), Energy-dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS)로 분석하였습니다.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.368-368
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• 2012

무기물 나노입자를 포함하는 유기물/무기물 나노복합체는 플렉시블 전자 소자에 적용이 가능하기 때문에 차세대 비휘발성 메모리 소자에 대한 응용연구가 활발히 진행되고 있다. 본 논문에서는 $CuInS_2$ (CIS)/ZnS 코어-쉘 나노 입자를 포함한 poly(N-vinylcarbazole) (PVK) 고분자 박막을 기억 매체로 사용하는 유기 쌍안정성 소자(organic bistable devices, OBD) 메모리 소자를 제작하고 전기적 성질에 대하여 관찰하고 전하 수송 메카니즘에 대하여 규명하였다. 화학적 방법으로 형성한 CIS/ZnS 코어-쉘 나노 입자와 PVK를 toluene 용매에 녹인 후 초음파 교반기를 사용하여 나노 복합 소재를 형성하였다. 하부 전극으로 indium-tin-oxide (ITO)가 증착되어 있는 유리 기판 위에 나노 복합 소재를 스핀코팅 방법으로 도포한 후 열을 가해 잔류 용매를 제거하였다. CIS/ZnS 코어-쉘 나노 입자가 분산되어 있는 PVK 나노 복합 소재로 구성된 박막위에 상부 전극으로 Al을 열증착하여 메모리 소자를 제작하였다. 전류-전압 (I-V) 측정 결과에서 저전압에서는 전도도가 낮은 OFF 상태를 유지하다 어느 특정 양의 전압에서 전도도가 갑자기 증가하여 높은 전도도의 ON 상태로 전이되는 쌍안정성이 관찰되었다. 전류의 ON/OFF 비율은 약 $10^3$이며 역방향 바이어스를 가해주었을 때 특정 음의 전압에서 전도도가 ON 상태에서 OFF 상태로 전환되는 전형적인 OBD 메모리 소자의 I-V 특성을 나타났다. 메모리 전하 수송 메커니즘 분석 결과 쓰기 과정은 thermionic emission (TE), space-charge-limited-current (SCLS) 모델과 지우기 과정은 Fowler-Nordheim (FN) 터널링 모델로 설명이 되었다. 제작된 소자에 대해 기억 시간 측정 결과는 ON과 OFF 상태의 전류가 장시간에도 변화가 거의 없는 소자의 안정성을 보여주었다. 이 실험 결과는 CIS/ZnS 코어-쉘 나노 입자가 분산되어 있는 PVK 나노 복합 소재를 사용하여 안정성을 가진 OBD 메모리 소자를 제작할 수 있음을 보여주고 있다.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.26 no.2
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• pp.77-83
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• 2020

A series of foamed plastic sheets containing biomass (as HMR container) were developed via different foaming process temperatures, and their density, porosity, WVTR, and pore morphology were evaluated. Thermal stability of samples during re-heating the food in oven, change in morphology, density, porosity, and WVTR were investigated using a simulated thermal shock process according to MIL-STD-883E assay. As such, the pore size of samples was generally increased with increasing temperature of the foaming process. It can be explained that as foaming temperature increased, the viscosity of molten resins and the repulsive force against pore expansion decreased. In addition, an increase in the thermal shock cycle reduced the pore size and WVTR, while density increased because high temperature treatment that softened the sheet matrix was followed by a low temperature incubation, which contracted the matrix, thereby changing the physical and morphological properties of samples. However, an insignificant change in density was observed and WVTR tended to be decreased, indicating that as-prepared foamed plastic sheets could be used as a high thermal stable container for HMR application. Therefore, it found that the properties of newly developed HMR containers containing biomass were dependent on the foaming process temperature. Moreover, to better understanding of these newly developed containers, further investigations dealing with foaming process temperature based on various food items and cooking conditions are needed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.3
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• pp.638-644
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• 2019

In this study, the fluid flow and heat transfer characteristics within sandwich panels are investigated using computational fluid dynamics. Within the sandwich panels having periodic cellular cores, air can freely move inside the core section so that the structure is able to perform multi-functional roles such as simultaneous load bearing and heat dissipation. Thus, there needs to examine the thermal and flow analysis with respect to design variables and various conditions. In this regard, ANSYS Fluent was utilized to explore the flow and heat transfer within the pyramidal truss sandwich structures by varying the truss angle and inlet velocity. Without the entry effect in the first unitcell, the constant rate of pressure and the constant rate of Nusselt number was observed. As a result, it was demonstrated that Nusselt number increases and friction factor decreases as the inlet velocity increases. Moreover, the rate of Nusselt number and friction factor was appreciable in the range of V=1-5m/s due to the transition from laminar to turbulent flow. Regarding the effect of design variable, the variation of truss angle did not significantly influence the characteristics.