• Journal of Korean Society of Environmental Engineers
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• v.36 no.4
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• pp.231-236
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• 2014

Sawdust, produced as an wood by-product, is usable biomass as liquid fuels if decomposed to monomer unit, because the chemical structure are similar to high octane materials found in gasoline. In this study, parameters of thermochemical degradation by acetone-solvolysis reaction of sawdust such as the effect of reaction temperature, reaction time and type of solvent on conversion yield and degradation products were investigated. The liquid products by acetone-solvolysis from sawdust produced various kind of ketone, phenol and furan compounds. The optimum sawdust conversion was observed to be 88.7% at $350^{\circ}C$, 40min. Combustion heating value of liquid products from thermochemical conversion processes was as high as 7,824 cal/g. The energy yield and mass yield in acetone-solvolysis of sawdust was 60.8% and 36.4 g-oil/100g-sawdust after 40 min of reaction at $350^{\circ}C$, respectively. The major components of the acetone-solvolysis products, that could be used as liquid fuel, were 4-methyl-3-pentene-2-one, 1,3,5-trimethylbezene, 2,6-dimethyl-2,5-heptadiene-4-one, 3-methyl-2-cyclopenten-1-one as ketone compounds.

• Journal of Adhesion and Interface
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• v.18 no.3
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• pp.109-117
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• 2017

Poly(N-vinyl carbazole) (PVK) homopolymer, poly(4-vinylpyridine) (PVP) homopolymer, and PVK-b-PVP block copolymer were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization and the polymers were used to prepare non-aqueous graphene dispersions with four different solvents, ethanol, N-methyl-2-pyrrolidone (NMP), dichloromethane (DCM), and tetrahydrofuran (THF). $^1H-$ and $^{13}C-NMR$ spectroscopy, size exclusion chromatography (SEC), and differential scanning calorimetry (DSC) were carried out to confirm the chemical structure of the polymers. Stability of graphene dispersions was measured by on-line turbidity measurement. Time-dependent Turbiscan Stability Index (TSI) values were interpreted in terms of surface tension (${\sigma}$) and solubility parameter (${\delta}$) among solvents, polymers, and graphene. It was confirmed that the solubilities of polymer and surface tension between solvent and graphene affected the dispersion stability of graphene. PVK-b-PVP block copolymer could effectively maintain the low TSI values of graphene dispersions in ethanol and THF, which have been known as poor solvents for graphene dispersions. It can also be noted that DCM shows good dispersion stability comparable to NMP, which has been known as the best solvent for graphene dispersion.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.3
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• pp.135-141
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• 2013

Mechanical alloying was carried out to produce $CrSi_2$ thermoelectric compound using a mixture of elemental $Cr_{33}Si_{67}$ powders. An optimal milling and heat treatment conditions to obtain the single phase of $CrSi_2$ compound with fine microstructure were investigated by X-ray diffraction and differential scanning calorimetry measurement. $CrSi_2$ intermetallic compound with a grain size of 70 nm could be obtained by MA of $Cr_{33}Si_{67}$ powders for 70 hours and subsequently annealed at $650^{\circ}C$. Consolidation of the MA powders was performed in a spark plasma sintering (SPS) machine using graphite dies at $600{\sim}1000^{\circ}C$ under 60 MPa. The shrinkage of MA samples during SPS consolidation process increased gradually with increasing temperature up to $1000^{\circ}C$ and relatively significant at about $600^{\circ}C$. We tend to believe that these behaviors are deeply related to form a $CrSi_2$ compound during heating process, as can be realized from the DSC measurement. Electrical conductivity and Seebeck coefficient of sintered bodies were measured up to $900^{\circ}C$. Seebeck coefficient and power factor of $Cr_{33}Si_{67}$ compact prepared by MA and SPS at $1000^{\circ}C$ showed the maximum value of $125{\mu}V/K$ at $400^{\circ}C$ and $4.3{\times}10^{-4}W/mK^2$ at $350^{\circ}C$, respectively.

• Clean Technology
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• v.17 no.2
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• pp.156-165
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• 2011

The process for bioethanol production from lignocellulosic biomass was studied through process simulation using PRO/II. Process integration was conducted with concentrated acid pretreatment, hydrolysis process, SMB (simulated moving bed chromatography) process and pervaporation process. Energy consumption could be minimized by the heat recovery process. In addition, material and energy balance were calculated based on the results from the simulation and literature data. A net production yield of 4.07 kg-biomass and energy consumption value of 3,572 kcal per 1 kg ethanol were calculated, which is indicating that 26% yield increase and 30% energy saving compared to the bioethanol production process with dilute-acid hydrolysis (SRI report). In order to make it possible, sugar conversion yield of cellulose and hemi-cellulose is to be reached up to 90% and fermentation of xylose needs to be developed. In order to reduce the energy consumption up to 30%, the concentration of acid solution after being separated by 5MB should exceed 20%. If acid/sugar separation by SMB process is to be practical, the bioethanol process designed in this study can be commercially feasible.

• Journal of Korean Home Economics Education Association
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• v.17 no.3 s.37
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• pp.35-52
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• 2005

To assess the food habits, the nutrient intakes and diet quality of high school students living in Chuncheon area. a dietary survey using a questionnaire and 24hr recall method was conducted with 318 subjects. $30.8\%$ of the subjects often skipped breakfast and $28.0\%$ had snacks over once per day. Mean daily energy intake was $1740\pm712kca1\;with\;61.1\%$ of energy supplied by carbohydrate, $16.0\%$ by protein and $23.1\%$ by fat. As well as insufficiencies in calcium and iron intakes, the bioavailability of calcium and iron consumed is considered to be low because most of them came from plant origins. For calcium, iron and riboflavin, the proportions of subjects with intake levels less than $75\%$ of RDA were all over $68\%$. The mean adequacy ratio(MAR), an index of overall dietary quality was 0.79 for males and 0.78 for females. The indexes of nutritional quality(INQ) were over 1 for most nutrients except 3 nutrients: 0.67 of calcium, 0.82 of iron, 0.90 of riboflavin. Nutrient intake levels less than $75\%$ of RDA may be appropriate as a criteria for insufficiency of nutrient intakes. Based on these results, it is evident that some of high school students in Chuncheon area did not consume enough nutrients, especially calcium, iron and riboflavin.

• Culinary science and hospitality research
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• v.16 no.5
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• pp.164-177
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• 2010

This study examines die causal relationships among motivation to eat out, servicescape, customer satisfaction and repurchase intention in Seoul metropolitan area by conducting a survey to herbal food restaurant customers from January 20, 2010 to February 26, 2010. A total of 600 copies were distributed, and 522 copies were collected. Among them, except for 29 copies which were inadequate for analysis, 493 copies were analyzed by a factor analysis and reliability analysis using SPSS 12.0, and die research hypotheses were verified with a canonical correlation analysis and regression analysis. The results are as follows. First, there are relatively high correlations between such motivation for herbal food as the prevention of diseases, eco-friendly food, recipes, food calories and servicescape of functionality, safety, cleanliness, and accessibility. Second, die result of the multiple regression analysis between servicescape of herbal food and customer satisfaction shows that safety, cleanliness, and accessibility have significant effects on customer satisfaction. Third, customer satisfaction with herbal food has a positive effect on repurchase intention. Accordingly, useful suggestions are provided on the basis of these results.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.17 no.3
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• pp.121-127
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• 2007

We have applied mechanical alloying (MA) to get $Mg_2Si$ thermoelectric material with nano-sized grains. An optimal milling and heat treatment conditions to obtain the single phase of $Mg_2Si$ compound with fine microstructure were investigated by X-ray diffraction and differential scanning calorimetry (DSC) measurement. The $Mg_{66.7}Si_{33.3}$ MA samples ball-milled for $20{\sim}180\;hrs$ exhibit two broad exothermic heat releases around $220^{\circ}C$ and $570^{\circ}C$. On the other hand, MA sample ball-milled far 260 hrs exhibits only a sharp exothermic peak at $230^{\circ}C$ Single phase Mg2Si powder can be obtained by MA of $Mg_{66.7}Si_{33.3}$ mixture for 60 hours and subsequently heated up to $620^{\circ}C$. Sintering of the MA powders was performed in a spark plasma sintering (SPS) machine using graphite dies at $800{\sim}900^{\circ}C$ under 50 MPa. The shrinkage of sintering sample during SPS was significant at about $200^{\circ}C$. All compact bodies have a high relative density above 94% with metallic glare on the surface.

• Applied Chemistry for Engineering
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• v.26 no.6
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• pp.698-705
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• 2015

Two series of symmetric dimesogenic compounds containing a butylene or 1-methylbutylene spacer as a flexible group were synthesized. The mesogenic groups of synthesized compounds consist of an azobenzene group with a terminal substituent. Chemical structures as well as, thermal, mesomorphic, and photochemical properties of the synthesized compounds were investigated using FT-IR, $^1H-NMR$, differential scanning calorimetry (DSC), polarizing optical microscopy (POM), and UV-visible spectrometry. P-H, P-F, and $P-OC_6H_{13}$ showed monotropic liquid crystal phases, whereas the others showed enantiotropic liquid crystal phases. Compounds with butylene group as a flexible spacer exhibited wider mesophase temperature ranges and higher thermal transition temperatures than compounds containing a 1-methylbutylene group. Compounds with a high absolute value of the Hammett substituent constant exhibited high thermal transition temperatures and improved stability in the liquid crystal phase. Furthermore, in the absence or presence of UV light illumination, terminal substituents of the azomesogenic group were important factors in deciding the maximum absorbance wavelength (${\lambda}_{max}$) and the rate of photoisomerization (K).

• Fire Science and Engineering
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• v.15 no.1
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• pp.16-22
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• 2001

Thermal properties of PP and LLDPE dusts from chemical plant and their risks of coexisting with oxidizer were investigated by a pressure vessel. The thermal decomposition of PP and LLDPE dusts with temperature using DSC and the weight loss with temperature using TGA were also investigated to find the thermal hazard of PP and LLDPE dusts. Using the pressure vessel which can estimate ignition and explosion of PP and LLDPE dusts coexisting with oxidizer, a series of bursting of a rupture disc, experiments has been conducted by varying the orifice diameters the weight ratio of the sample coexisting with oxidizers and the species of oxidizer. And fire gases was measured by gas analyser ($ECOM-A^+$). According to the results of the thermal analysis of PP and LLDPE dusts, the decomposition temperature range of PP and LLDPE dusts was 200 to 350 and 300 to $500^{\circ}c$, respectively. The risk of PP and LLDPE dusts coexisting with oxidizer was increased as the orifice diameter was decreased. On the other hand, it was increased as the weight ratio of the sample to the oxidizer were increased. In addition, the risk of PP and LLDPE dusts coexisting with oxidizer was affected by the decomposition temperature of the sample and oxidizer. It is found that the risk of fire becomes high when the decomposition temperature of the sample is about same as that of oxidizer. Also, the fire gases was occurred carbon monoxide and carbon dioxide. The amount of carbon monoxide generated was found to be much higher in PP decomposition than in LLDPE due to incomplete combustion of PP which has high content of carbon in chemical compound.

• Korean Journal of Food Science and Technology
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• v.52 no.1
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• pp.31-39
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• 2020

The effects of heat-moisture treatment (HMT) on the functional properties of high amylose rice starches (HARSes) purified from Korean rice varieties (A-type Goami and Singil and B-type Dodamssal and Goami2) were investigated. HMT was accomplished with moisture contents of 18 and 27% and heated at 100℃ for 16 h. While the amylose content, swelling power and solubility decreased after HMT, the water binding capacity and resistant starch (RS) content increased with increasing moisture content after HMT. The X-ray diffraction patterns of all HARSes did not change after HMT, but a decrease in the intensity of peak at 2θ=5° was observed in B-type HMT HARSes. While the starch granules aggregated after HMT, their shape and size remained unchanged. B-type HARSes exhibited higher gelatinization temperatures and lower pasting viscosities than A-type HARSes following HMT. The results, thus, suggest that while the crystalline intensity of B-type Dodamssal and Goami2 rice starches did not change after HMT, the RS content, water binding capacity, and pasting temperatures of all HARSes increased with increasing moisture content after HMT.