• Defense and Technology
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• no.9 s.163
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• pp.46-50
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• 1992

고온, 고압의 추진제 연소가스로부터 노즐 구조물을 보호하기 위해 사용되는 열 차폐용 삭마성 내열재료(ablative material)의 종류와 재료선정을 위한 시험방법, 설계 및 제작기법, 성능평가 기준 등에 관한 연구동향을 검토하고 본 연구팀의 연구결과를 제시하였습니다 고체추진제 연소 환경하에서의 노즐 보호재료로서는 고분자계 삭마성 내열재가 주로 사용되는데, 이 ablative material에는 여러 종류가 있으나 높은 heat flux와 빠른 mass flow에 대한 내열을 위해서는 페놀, 폴리이미드 등 열경화성 수지인 charring material이 모재로 주로 사용되며 강도향상을 위해서 탄소, 실리카, 석면, 유리등의 강화섬유가 보강재로 사용됩니다 현재는 모재로서 고분자계 수지외에도 세라믹과 같은 무기재료, 금속재료등과 강화섬유를 조합하여 내열성과 강도가 향상된 재료를 개발하는 연구도 진행되고 있습니다

• The Korean Journal of Rheology
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• v.11 no.1
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• pp.9-17
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• 1999

Viscoelastic characteristics of cured phenolic resin/carbon fiber composite materials were investigated through glass transition and degradation reaction processes in the high temperature region up to $400^{\circ}C$. A typical glass transition of the cross-linked thermoset polymer was followed by irreversible degradation reactions, which were exhibited by the increasing storage modulus and loss modulus peak. A degradation master curve was constructed by using the vertical and horizontal shift factors, both of which complied well with the Arrhenius equation in light of the kinetic expression of degradation rate constants. Using an analogy to the Havriliak-Negami equation in dielectric relaxation phenomena, a viscoelastic modeling methodology was developed to characterize the frequency- and temperature-dependent complex moduli of the degrading thermoset polymer composite systems. The temperature-dependent relaxation time of the degrading composites was determined in a continuous fashion and showed a minimum relaxation time between the glass transition and degradation reaction regions. The capability of the developed modeling methodology was demonstrated by describing the complex behavior of the viscoelastic complex moduli of reacting phenolic resin composite systems.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.04a
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• pp.116-119
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• 2000

본 연구에서는 온도의 상승에 의하여 부피가 팽창하는 열팽창 고무 치공구의 팽창 특성을 이용하여 열경화성 복합재료를 경화하고 압축하는 과정을 실험과 모델링을 통하여 해석하였으며, 열가소성 복합재료의 함침공정을 연구하였다. 열팽창 고무치공구가 사용되는 닫힌계와 열린계에서 예상되는 압력을 이론적으로 유도하였고, 경화가 수반되는 과정에 있어서는 실험을 통하여 열팽창치공구와 프리프레그가 나타내는 압력을 측정하였다. 온도가 상승하고 경화가 수반되는 경우에 등속도 압축실험에 의하여 얻어지는 응력-변형율 곡선은 비선형점탄성 특성을 보여주었는데, 본 연구에서는 Maxwell모델을 KWW(Kohlrausch-Williame-Watts)식으로 변형시킨 모델식을 이용하여 이를 매우 정확하게 표현할 수 있었다. 또한 고무치공구를 이용하여 열가소성 수지의 복합재료 성형공정을 실험하였고, 중성자 레디오그래피 촬영을 통하여 기공의 분포를 관찰하였다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.4
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• pp.76-85
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• 2019

Recently, various investigation of vegetable oil which is extracted from natural resources is being progressed because of its low cost and environmental aspect. However, double bonds in vegetable oil should be substituted to other high reactive functional group due to its low reactivity for synthesizing bio-polymeric materials. ${\alpha}$-eleostearic acid, which is consist of conjugated triene, is the main component of tung oil, and the conjugated triene allows tung oil to have higher reactivity than other vegetable oil. In this study, tung oil is copolymerized with styrene and divinylbenzene to make thermoset resin without any substitution of functional group. Thermal and mechanical properties are measured to investigate the effects of the composition of each monomer on the synthesized thermoset resin. The result shows that the products have only one Tg, which means the synthesized thermoset resins are homogeneous in molecular level. Mechanical properties show that tung oil act as soft segment in the copolymer and make more elastic product. On the other hand, divinylbenzene acts as hard segment and makes more brittle product.

• Composites Research
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• v.30 no.1
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• pp.1-6
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• 2017

Epoxy resin (EP) is one of the most famous thermoset materials. In general, because EP has three-dimensional random network, it possesses thermal properties like a typical heat insulator. Recently, there has been increasing interest in controlling the network structure for making new functionality from EP. Indeed, the new modified EP represented as liquid crystalline epoxy (LCE) is spotlighted as an enabling technology for producing novel functionalities, which cannot be obtained from the conventional EPs, by replacing the random network structure to oriented one. In this paper, we review current progress in the field of LCEs and their application for the highly thermal conductive composite materials.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2012.03a
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• pp.74-74
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• 2012

섬유 프리프레그(Prepreg)는 강화섬유를 수지에 함침하여 B-stage로 만든 복합재료의 중간성형재료이다. 최종적으로 프리프레그를 금형에 적층하여 가열 가압하여 수지를 경화함으로써 최종제품이 완성된다. 본 연구에서는 직물형 프리프레그를 사용하였는데, 사용되는 직물형태로는 복합재료 성형공정에서 형태안정성이 우수한 평직물과 능직물이 주로 사용된다. 직물형 프리프레그를 사용한 복합재료는 작업성과 형태안정성이 우수하면서 내충격특성이 우수하여 오토바이용 헬멧, 방탄용 헬멧 등에 주로 사용된다. 프리프레그에 요구되는 주요 특성중 하나는 Tack성으로서, 성형 과정에서 프리프레그를 여러 장 적층할 때 적층된 층 간에 미끄러지지 않으면서 잘 고정되어 적층 작업을 원활하게 하는 역할을 한다. Tack성은 수지의 B-stage 경화 후의 점성 거동에 따라 변화될 수 있는 것으로 표면의 끈끈함의 정도로서 알 수 있다. Tack성은 온도에 민감하여 측정 시에 일정한 온도의 유지가 중요하다. 이러한 온도에 대한 민감성 때문에 프리프레그의 저장시 저온에서 저장하는 것이 원칙인데, 상온에 있을 경우 시간경과에 따른 Tack성 변화가 크게 나타나게 된다. 따라서 본 연구에서는 아라미드 섬유와 열경화성수지를 이용하여 프리프레그를 제조하고 이를 상온상태에서 보관 시 일정시간 경과에 따른 Tack성 변화를 알아보고자 하였다.

• Polymer(Korea)
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• v.27 no.5
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• pp.493-501
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• 2003

Poly(methyl methacrylate) (PMMA) particles, denture base resin, were synthesized by suspension polymerization through control of polymerization conditions (stabilizer concentration, co-monomer concentration, and the agitation speed) and evaluated changes in molecular weight and particle size. We also investigated their mechanical properties of compression-molded samples which were from synthesized polymer powder mixed with methyl methacrylate (MMA) solution. under the condition of volumetric ratio as 2:1(PMMA powder and MMA solution). The results shows that the mechanical properties were mainly affected by particle size over 100 ${\mu}$m (in particle size) and by molecular weight under 100 ${\mu}$m (in particle size). From these results, we concluded that the most appropriate particle size of PMMA powder for heat-cured denture base resins is around 100 ${\mu}$m. and its molecular weight is around 300000 (M$\sub$n/).

• Elastomers and Composites
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• v.43 no.2
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• pp.113-123
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• 2008

Epoxy resins are thermoset polymers that exhibit good adhesion, creep resistance, heat resistance, and chemical resistance. These polymers, however, give poor resistance to crack propagation and low impact strength. In this study, epoxy/carboxyl-terminated butadiene acrylonitrile (CTBN) and epoxy/amine-terminated butadiene acrylonitrile (ATBN) composites were prepared with different ratio of CTBN and ATBN to improve low impact strength of epoxy resin. The impact strength of epoxy/elastomeric composites shows high values with increasting nonpolar surface free energy while the tensile strength and the glass transition are decreased. The highest surface free energy, impact strength observed when 15 phr CTBN and 15 phr ATBN added, respectively. It can be concluded that as liquid rubber to improve impact strength of epoxy resin, ATBN is more preferable to CTBN.

• Polymer(Korea)
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• v.26 no.6
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• pp.718-727
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• 2002

In this work, an Ar+ beam was irradiated on carbon fiber surfaces to improve the interfacial shear strength (IFSS) of the resulting composites using an ion assisted reaction (IAR) method h single fiber pull-out test was executed to investigate the basic characteristics of the single Carbon fiber/matrix interface. Based on Greszczuk's geometrical model, the debonding force for pull-out of the fiber from the resins was discussed with the applied ion beam energy as a result, it was known that an ion beam treatment produced the functional groups on fiber surface and etching lines along the fiber axis direction, resulting in increasing the adhesion forces between fibers and matrix, which caused the improvement of the IFSS in a composite system. And, it was also found that the maximum IFSS was shown at 0.8 keV ion beam energy in this system.

• Journal of the Microelectronics and Packaging Society
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• v.6 no.4
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• pp.15-22
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• 1999

Generally, many equipments and a long lead time ale required to manufacture the build-up multilayer board through various processes such as etching, plating, drilling etc. Wet process is suitable for mass production, however it is not adequate for manufacturing prototype in developing stage. In this study, a silk screen printing technology is introduced to make a prototype build-up multilayer board. As for the material photo/thermal curable resin and conductive paste are used for forming dielectric and conductor. And conductive paste fills vias for interconnecting each layer, and also is used for circuit patterning by silk screen technology. Finally, the basic concept and the possibility of build-up multilayer board prototype is proposed and verified as a powerful approach, compared with the conventional processes.