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Morphology and Swelling Behaviors of PVA/Gelatin Blend Membranes Prepared Under High Electric Field (고전장하에서 제조된 PVA/Gelatin 블렌드막의 구조와 팽윤거동)

  • Huh, Yang-Il;Yun, Hyung-Ku
    • Polymer(Korea)
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    • v.30 no.6
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    • pp.563-567
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    • 2006
  • Poly(vinyl alcohol) (PVA) and gelatin (GEL) blend membranes were prepared by solution casting method under a high electric field. SEM observation of the membrane showed that gelatin rich domains were elongated and oriented to the direction of the applied electric field in PVA matrix. This can be attributed to the electrostatic emulsifying effects due to a reduction in interfacial tension. In addition, it was observed through WAXD and swelling measurements that the degree of crystallinity of membranes increased with applied electric field strength. This may be interpreted to be caused by the orientation effect of GEL domains in the blend membrane, and the self-annealing effect due to some heat generated from high electric field during casting.

A Physical Characteristics and Synthesis of Top Coat Polymeric Dispersion Film by Complex Polyol (복합폴리올 이용한 Top coat용 수분산 고분자 필름의 합성 및 물리적 특성)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.92-99
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    • 2016
  • Polyurethane resin used to leather coat was synthesized by the addition reaction of PPG and PTMG with different mole ratios. Physical characteristics of the synthesized polyurethane resin were measured by the SEM, FT-IR and the UTM. Increasing mole ratio of PTMG having four methylene groups caused the increase of abrasion resistance and tensile strength. The elongation was decreased. As we measured the solvent(toluene) resistance of poly urethane resin, it was found the there were no effect of PTMG mole ratios on the phyhsical properties of the resin. The viscosity was increased by ratio of PTMG mole ratio.

Nano-Kenaf Cellulose Effects on Improved Mechanical Properties of Polypropylene Composite (나노 케냐프 셀룰로오스가 폴리프로필렌 복합소재의 물성 증가에 미치는 영향)

  • Oh, Jeong Seok;Lee, Seong-Hoon;Bumm, Sughun;Kim, Kwang-Jea
    • Polymer(Korea)
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    • v.37 no.5
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    • pp.613-617
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    • 2013
  • The effects of nano size kenaf cellulose fiber on mechanical property of polypropylene (PP) composite were investigated. The addition of nano-kenaf in place of natural kenaf showed higher tensile strength, flexural strength, impact strength, and heat deflection temperature compared to the natural kenaf filled PP composite, while it shows lower melt flow index, elongation%, and flexural modulus. These seemed to be due to the increased surface area of nano-kenaf fiber contacting PP matrix and reduced impurities such as volatile extractives on the fiber surface.

Creep Life Prediction by ISM of Elevated Temperature Materials for Pressure Vessel(II) (압력용기용 고온재료의 ISM에 의한 크리프 수명예측(II))

  • 공유식;김헌경;황성필;김일석;오세규
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2001.05a
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    • pp.307-313
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    • 2001
  • In this Paper, friction welding optimization for 1Cr0.5Mo-STS304($\Phi$14mm), AE applications for the weld quality evaluation and the applications of various life prediction methods such as LMP(Larson-Miller Parameter) and ISM(initial strain method) were investigated : the creep behaviors of those steels and the friction welded joints under static load were examined by ISM combined with LMP at 400, 500, 550 and $600^{\circ}C$, and the relationship between these two kinds of phenomena was studied. The real-time predicting equations of elevated-temperature creep life(fracture time) under any creep stress at any elevated- temperature could be developed by LMP and LMP-ISM, It was confirmed that the life prediction equations by LMP and LMP-ISM are effective only up to 10$^2$hrs and can not be used for long times of 10$^3$-10$^{6}$ hrs, but by ISM it can be used for long times creep prediction of more than 10$^4$hrs with most reliability.

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Study on Creep Life Prediction by Initial Strain Method for Friction Welded Joints of Heat Resisting Steels (내열강 마찰용접재의 ISM에 의한 크리프 수명예측에 관한 연구)

  • 김헌경;김일석;이연탁;공유식;오세규
    • Journal of Ocean Engineering and Technology
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    • v.15 no.2
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    • pp.46-52
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    • 2001
  • In this paper, the real-time prediction of high temperature creep life was carried out for the friction welded joints of dissimilar heat resisting steels (SUH3-SUH35). various life prediction method such as LMP (Larson_miller Parameter) and ISM (initial strain method) were applied. The creep behaviors of those steels and the welds under static load were examined by ISM combined with LMP at 500, 600 and $700^{\circ}C$, and the relationship between these two methods was investigated. A real-time creep lie (tr, hr) prediction equation by initial strain (${\varepsilon}_0$, %) under any creep stress ($\sigma$, MPa) at any high temperature (T, K) was developed as follows: $t_r={\alpha}{\varepsilon}_0^{\beta}{\sigma}^{-1}$ where, ${\phi}=16: {\alpha}=10^{51.412-0.104T+5.375{\times}10^5T^2}$, $ {\beta}=-83.989+0.180T-9.957{\times}10^{-5}T^2,{\phi}=20:$ ${\alpha}=10^{69.910-0.146T+7.744{\times}10^{-5}T^2$, ${\beta}=-51.442+0.105T-5.595{\times}10^{-5}T^2$ for SUH3-SUH35 friction weld of =16mm and 20mm, respectively.

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Characteristics of Connected Speech in ADSD (내전형 연축성 발성장애의 연속 발화 특성)

  • Hwang, Yon-Shin;Kim, Jae-Ok;Choi, Hong-Shik
    • Phonetics and Speech Sciences
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    • v.1 no.1
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    • pp.93-98
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    • 2009
  • The aim of this study was to investigate voice characteristics of adductive spasmodic dysphonia(ADSD) by measuring electroglottal and acoustic examination at the sentence level. The clinical records of 86 ADSD female patients (age group of $20{\sim}50$ years) and the control records of 86 normal females (age group of $20{\sim}40$ years) were recorded by speech studio(Laryngograph Ltd., UK). An independent t-test was used to compare ADSD and normal group. Results were as follows. (1) Fundamental frequency($F_0$) was significantly decreased in ADSD compared with normal group. (2) Irregularity of frequency and closed quotient(CQ) was significantly increased in ADSD compared with normal group. (3) Voiceless duration increased and voiced duration was significantly decreased in ADSD compared with normal group. (4) Fricative duration was increased in ADSD compared with normal group but it wasn't significant. In conclusion, strained, tight and choked voice shows an increase of CQ, tremor voice shows an increase of irregularity of frequency and less feminine voice shows decrease of $F_0$. Increase of voiceless duration and fricative duration and decrease of voiced duration related with diminution speech intelligibility.

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Dynamic Tensile Tests of Steel Sheets for an Auto-body at the Intermediate Strain Rate (중변형률 속도에서의 차체용 강판의 동적 인장실험)

  • Lim, Ji-Ho;Huh, Hoon;Kwon, Soon-Yong;Yoon, Chi-Sang;Park, Sung-Ho
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.456-461
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    • 2004
  • The dynamic behavior of sheet metals must be examined to ensure the impact characteristics of auto-body by a finite element method. An appropriate experimental method has to be developed to acquire the material properties at the intermediate strain rate which is under 500/s in the crash analysis of auto-body. In this paper, tensile tests of various different steel sheets for an auto-body were performed to obtain the dynamic material properties with respect to the strain rate which is ranged from 0.003/sec to 200/sec. A high speed material testing machine was made for tension tests at the intermediate strain rate and the dimensions of specimens that can provide the reasonable results were determined by the finite element analysis. Stress-strain curves were obtained for each steel sheet from the dynamic tensile test and used to deduce the relationship of the yield stress and the elongation to the strain rate. These results are significant not only in the crashworthiness evaluation under car crash but also in the high speed metal forming.

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A Study on The Variation of Penetration According to The Shielding Gas in A1100 Aluminum Welding (A1100 알루미늄 용접에서 실드가스의 종류에 따른 용입부의 변화 연구)

  • Kim, Jin-Su;Kim, Bub-Hun;Kim, Gue-Tae;Park, Yong-Hwan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.2
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    • pp.49-54
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    • 2013
  • Recently welding of aluminum material is actively carried out to make lightweight in the fields of LNG vessels, aircraft, chemical plants, etc. To obtain high strength, hardness and elongation, elements such as manganese, zinc, silicon, etc should be added in aluminum alloy, which has been improved on the mechanical properties like precipitation hardening, age hardening, loosening, corrosion resistance acid resistance. Ar gas is used as a shielding gas of MIG welding for aluminum, also $N_2$, $O_2$, $CO_2$, $H_2$ etc can be added depending on the composition of the alloy. In this study, Ar + $O_2$, Ar, and He were used for welding, hardness, penetration status and changes in composition of penetrated parts were compared and analyzed. This made it possible to know the status and changes of the process in the penetrated parts depending on used gas throughout this study.

A Study on the Moulding Analysis of Automobile Valve Body Mid-plate (자동차 밸브바디 중간플레이트 성형해석에 관한 연구)

  • Jang Hun;Sung Back-Sub;Cha Yong-Hoon;Kim Duck-joong;Lee Youn-sin
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2005.05a
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    • pp.174-179
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    • 2005
  • In the super slow speed die casting process, the casting defects due to melt flow should be controlled in order to obtain sound casting products. The casting defects that are caused by molten metal were cold shut formation, entrapment of air, gas, and inclusion. But the control of casting defects has been based on the experience of the foundry engineers. The calculation of simulation can produce very useful and important results. The calculation data of die casting process condition from the computer simulation by the Z-CAST is made to insure that the liquid metal is injected at the right velocity range and that the filling time is small enough to prevent premature solidification. The parameters of runner shape that affected on the optimized conditions that was calculated with simple equation were investigated. These die casting process control techniques of automobile valve body mid-plate have achieved good agreement with the experimental data of tensile strength, hardness test, and material structure photographies satisfactory results.

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A Study on the Refrigerant Characteristics of the HFC-l52a, and Azeotrope Mixed with $CF_3 I$ (HFC-152a와 HFC-1523에 $CF_3 I$를 혼합한 공비혼합냉매 특성에 관한 연구)

  • 이종인;하옥남;김재열;이연신;권일욱
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.10 no.6
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    • pp.102-108
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    • 2001
  • To prevent green house effect and destruction of an ozone layer, an ozone destruction potential(OBP) must be zero and a refrigerant for low global warming potential(GWP) is needed. HFC-l34a, in which hydrogen is mixed instead of chlorine is a refrigerant used for automobile conditioners and its destruction potential is ecologically zero. However, it is not consid- ered as a perfect substitutive refrigerant as its GWP is high. It is studied refrigerant mixtures in which HFC-l52a and $CF_3 I$ in HFC-l52a with low GWP and zero ODP are mixed by experimentally and concluded as follows: 1) With the variation of speed of compressor outside temperature and flow rate, 7he heat of evaporator and compressor and coefficient of perfor- mance was varied, and influenced the air conditioner. 2) The pressure of evaporator was decreased with increasing the speed of compressor and the pressure of evaporator with the refrigerant HFC-l52a was higher 24% than that of azotrope refrigerant mixed with $CF_3 I$

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