• Applied Chemistry for Engineering
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• v.31 no.5
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• pp.453-466
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• 2020

As the demand for eco-friendly energy increases to overcome the energy shortage and environmental pollution crisis, hydrogen economy has been proposed as a potential solution. Accordingly, an economical and efficient hydrogen production is considered to be an essential industrial process. Research on applying hydrogen separation membranes for H₂/CO₂ separation to the production of highly concentrated hydrogen by purifying H₂ and capturing CO₂ simultaneously from synthetic gas produced by gasification is in progress nowadays. In high temperature environments, the membrane separation process using glassy polymeric membrane with H₂ selectivity has the potential for CO₂ capture performance, and is an energy and cost effective system since polybenzimicazole (PBI)-based separators show excellent chemical and mechanical stability under high-temperature operation conditions. Thus, the development of high-performance PBI hydrogen separators has been rapidly progressing in recent years. This overview focuses on the recent developments of PBI-based membranes including structure modified, cross-linked, blended and carbonized membranes for applications to the industrial hydrogen separation process.

• Fire Science and Engineering
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• v.24 no.3
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• pp.131-138
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• 2010

Experimental and numerical studies were conducted to investigate the thermal and chemical characteristics of heptane fires in a full-scale ISO 9705 room. Representative fire conditions were considered for over-ventilated fire (OVF) and under-ventilated fire (UVF). Fuel flow rate and doorway width were changed to create OVF and UVF conditions. Detailed comparisons of temperature and species concentrations between experimental and numerical data were presented in order to validate the predictive performance of FDS (Fire Dynamic Simulator). The OVF and UVF were explicitly characterized with distributions of temperature and product formation measured in the upper layer, as well as combustion efficiency and global equivalence ratio. It was shown that the numerical results provided a quantitatively realistic prediction of the experimental results observed in the OVF conditions. For the UVF, the numerically predicted temperature showed reasonable agreement with the measured temperature. The predicted steady-state volume fractions of $O_2$, $CO_2$, CO and THC also agreed quantitatively with the experimental data. Although there were some limitations to predict accurately the transient behavior in terms of CO production/consumption in the UVF condition, it was concluded that the current FDS was very useful tool to predict the fire characteristics inside the compartment for the OVF and UVF.

• Fire Science and Engineering
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• v.29 no.2
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• pp.25-32
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• 2015

The improved thermal stability and anti-oxidation properties of lyocell fiber were studied based on flame retardant treatment by using $Na_3PO_4$ solution. The optimized conditions of flame retardant treatment were studied on various concentrations of $Na_3PO_4$ and the mechanism was proposed through experimental results of thermal stability and anti-oxidation. The integral procedural decomposition temperature (IPDT), limiting oxygen index (LOI) and activation energy ($E_a$) increased 30, 160% respectively via flame retardant treatment. It is noted that thermal stability and anti-oxidation improved based on char and carbon layer formation by dehydrogenation and dissociation of C-C bond resulting the hindrance of oxygen and heat energy into polymer resin. The optimized conditions for efficient flame retardant property of lyocell fiber were provided using $Na_3PO_4$ solution and the mechanism was also studied based on experimental results such as initial decomposition temperature (IDT), IPDT, LOI and $E_a$.

• Journal of the Korean Institute of Gas
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• v.20 no.6
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• pp.43-49
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• 2016

In this paper, purpose of study is emissions characteristics according to effects of heating value variations of CNG fuel in a dual-fuel engine fueled by diesel and natural gas. For heating value variation of CNG fuel, nitrogen gas was mixed with pure CNG fuel. So the higher heating value was changed from $10,400kcal/Nm^3$ to $9,400kcal/Nm^3$. Under one condition of CNG substitution rate was fixed at 80%, diesel fuel was injected at a fixed injection timing of 16 CAD BTDC and fuel pressure was also fixed at 110 MPa. The condition of tested engine was 1800 rpm and 500Nm. Emissions were sampled in exhaust pipe was located at downstream turbocharger. As a result, emissions characteristics were checked in heating value variations of CNG fuel with mixed nitrogen gas THC, $CH_4$ and CO emissions decreased and NOx and $CO_2$ increased.

• Journal of the Korean Institute of Gas
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• v.19 no.2
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• pp.29-36
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• 2015

This study is an 1-D numerical study prior to modification of diesel engine for power plants to natural gas/diesel dual fuel engine using GT-Power with 1.5MW diesel engine for power generation. Natural gas injector was installed to intake manifold for dual fuel engine model. Effects on engine performance and characteristics were investigated when dual fuel is used in unmodified diesel engine. The analysis was done under 5 conditions from 0% to 40% of mixing rate on 720RPM engine speed. As a result of research, the engine performance was decreased as increasing ratio of natural gas. Engine brake power was decreased by 18.4% under 40% mixing rate condition. To clarify the reason, effects of injection timing and period were evaluated with DOE method. Considering this result, optimization was done for these parameters. Also, comparison between performances of dual fueled engine and diesel engine was made after optimizing the timing of injection by DOE method. As a result, engine brake power was decreased by 8.55% under mixing rate 40% condition showing 12.5% improvement.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.10
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• pp.725-731
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• 2016

This study numerically investigates the thermal performance of a 2.0-kW butane-based combustion heating system for an electric vehicle under cold conditions. The system is used for cabin space heating and coolant-based battery thermal management. ANSYS CFX 17 software was used for parametric analysis. The mass flow rates of cold air and coolant were varied, and their effects were compared. The numerical results were validated with theoretical studies, which showed an error of 0.15%. As the outside air mass flow rates were increased to 0.005, 0.01, and 0.015 kg/s, the cabin supply air temperature decreased continuously while the coolant outlet temperature increased. When the coolant mass flow rates were increased to 0.005, 0.01 and 0.015 kg/s, the air temperature increased while the coolant outlet temperatures decreased. The optimal mass flow rates are discussed in a consideration of the requirements for high cabin heating capacity and efficient battery thermal management.

• Journal of the Korean Institute of Gas
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• v.25 no.4
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• pp.36-42
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• 2021

When the landfill gas generated at the landfill site is released into the atmosphere, methane gas with a high global warming potential is emitted, which adversely affects climate change. When methane contained in landfill gas is used as fuel for internal combustion engines and burned to generate electricity, it is emitted into the atmosphere in the form of carbon dioxide, which can contribute to lowering the global warming potential. Therefore, in order to use the landfill gas as fuel for power generation using an internal combustion engine, it is important to increase the thermal efficiency of the engine. Thus, it is necessary to use a fuel supply system in which gas is injected using an electronically controlled injector at an intake port for each cylinder rather than a fuel supply technology using the conventional mixer technology. In order to use the electronically controlled gas injection method, it is important to accurately measure the mass flow rate according to the conditions of using landfill gas. For this, a study was conducted to measure the injection amount and calculate them in order for the intake port gas injection of landfill gas.

• Journal of the Korean Geosynthetics Society
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• v.18 no.2
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• pp.37-44
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• 2019

The compressive strength of the soil stabilizer in the deep mixing method (DMM) depends on kinds of soil, particle size distribution, and water content. Because of this, Laboratory test has to perform to estimate the unit weight of binder to confirm the satisfaction of the design strength. In this study, uniaxial compression strength was measured by mixing the soil stabilizers developed in the previous study with clay in Busan, Yeosu, and Incheon area. And the strength enhancement effect was evaluated comparing with blast furnace slag cement (BFSC). Also, the relationship between the unit content of binder and uniaxial compressive strength was investigated in order to easily calculate the unit weight of binder required to ensure the stability of the ground at the field. As the results of the analysis, the relationship between the unit content of binder and the uniaxial compressive strength are ${\gamma}_B=(108.93+0.0284q_u){\pm}35$ when W/B is 70%, and ${\gamma}_B=(122.93+0.0270q_u){\pm}40$ when W/B is 80%.

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.4
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• pp.468-475
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• 2019

An end-line flame arrester allows free venting in combination with flame protection for vertical vent applications. End-line flame arresters are employed in various fields, especially in shipping. In flame arresters, springs are essential parts because the spring load and the spring's elasticity determine the hood opening moment. In addition, the spring has to work under a high-temperature condition because of the burning gas flame. Therefore, it is necessary to analyze the mechanical load and elasticity of the spring when the flame starts to appear. Based on simulations of the working process of a specific end-line flame arrester, a thermal and structural analysis of the spring is performed. A three-dimensional model of a burned spring is built using computational fluid dynamics (CFD) simulation. Results of the CFD analysis are input into a finite element method simulation to analyze the spring structure. The research team focused on three cases of spring loads: 43, 93, and 56 kg, correspondingly, at 150 mm of spring deflection. Consequently, the spring load was reduced by 10 kg after 5 min under a $1,000^{\circ}C$ heat condition. The simulation results can be used to predict and estimate the spring's load and elasticity at the burning time variation. Moreover, the obtained outcome can provide the industry with references to optimize the design of the spring as well as that of the flame arrester.

• Korean Journal of Heritage: History & Science
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• v.48 no.1
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• pp.148-165
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• 2015

Iron was one of the most influential factors for formation and development of ancient countries. The diffusion of ironware had increased agricultural productivity and brought about military technical revolution. Needless to say, the rise and fall of the countries depended on the possession of stable iron production. Raw materials and fuels are the key factors for mass production of iron and a transportation route is essential to supply the goods. Jungwon area satisfies the three factors. There are many iron manufacture sites such as Jincheon Seokjang-ri Gusan-ri, and Chunju Chilgeum-dong Tangeumdae earthen ramparts in the Jungwon area. In order to study the ancient iron manufacture technique, reconstitution experiment was carried out using restored furnace which was made based on the Jincheon Seokjang-ri B-23 furnace. Some notable results were identified with the experiment as in the followings. Firstly, a roasting process has a connection with the decrease of hardness of the iron ore. Secondly, melting of the blast pipe as well as the formation of product within the furnace had a crucial effect on the cessation of the experiment. Thirdly, reduced iron in various locations within the furnace prove that there was enough reducing environment during the working. Not only melting point but also properties of iron can vary depending on the carbon contents. For the reason, formation of approximate environment in which iron can react to the chalcoal is the most important factor in terms of iron manufacture.