• 제목/요약/키워드: 연소배기특성

검색결과 402건 처리시간 0.026초

SCR 촉매에 포함된 조촉매 영향 (Effect of Containing Promoter on SCR Catalysts)

  • 서충길
    • 한국산학기술학회논문지
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    • 제19권9호
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    • pp.474-481
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    • 2018
  • 친환경자동차의 보급 확대를 위한 정책수립과 기술개발이 지속적으로 이루어지고 있는 실정이나 아직까지도 내연기관이 차지하는 비중은 약 95% 차지하고 있다. 화석연료를 기반으로 하는 내연기관의 엄격한 배기가스규제를 충족시키기 위해 자동차와 선박용 후처리장치의 비중이 점차로 증가하고 있다. 디젤엔진은 이산화탄소 배출량이 적고 강력한 파워와 연료의 경제성을 가지고 있으며, 상용차뿐만 아니라 승용차에서도 시장의 수요가 증가하고 있다. 디젤 연료 특성으로 인하여 질소산화물은 국부적인 고온연소 영역에서 생성되며, 입자상물질은 확산연소 영역에서 생성된다. 희박한 LNT(질소산화물 흡장촉매)와 urea-SCR(선택적인촉매환원장치)는 디젤엔진에서 질소산화물을 저감시키기 위한 후처리장치로 개발되어져왔다. 이 연구는 가혹해지고 있는 배기가스 규제 대응을 위해 선택적인촉매환원장치의 촉매에 포함됨 조촉매의 영향을 파악하는 것이다. 망간-선택적인촉매환원장치의 질소산화물 저감 성능이 가장 우수하였으며, 망간 이온과 Zeolyst의 Al과의 이온교환이 잘 되었고, 활성화 에너지가 낮아 반응 속도가 빨라짐에 따라 질소산화물 저감 성능이 향상되었다. 7Cu-15Ba/78Zeolyst SCR 촉매의 질소산화물 저감 성능은 200도에서 32%, 500도에서 30%를 나타내며 가장 높은 성능을 나타내었고, 조촉매로 첨가된 산화바륨의 질소산화물의 흡장 물질이 Cu-SCR 촉매에 잘 분산되어 있고 Cu-SCR 촉매의 환원 반응과 더불어 산화바륨의 추가적인 질소산화물 저감 성능이 영향을 끼쳤기 때문이다. 7Cu-15Ba/Zeolyst SCR 촉매는 3종 촉매 중 열적 열화에서 내구성이 강하였다. 열적 열화에 따른 동종 성분 산화구리가 이동하여 응집되는데, 산화바륨이 주촉매 산화구리 입자의 응집을 감소시켰기 때문이다.

시설농업난방 경유대체유로서 폐타이어오일의 연소 특성 (Combustion Qualities of Waste Tire Oil as Substituting Light Oil for Greenhouse Heating)

  • 김영중;유영선;강금춘;이건중;윤진하
    • Journal of Biosystems Engineering
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    • 제25권6호
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    • pp.481-488
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    • 2000
  • This study was initiated in order to find alternative fuel substituting for light oil the most common fuel for heating greenhouse. The tire oil used in this research was produced by pyrolysis process, one of the final products besides steel string and carbon black in which waste tires as a form of chopped pieces broken by shredding machine are heated up to 200~30$0^{\circ}C$ with maximum restraining of oxygen supply. In order to justify light oil equivalent qualities in tire oil combustion characteristics were defined in the way of comparing kinetic viscosities in the wide range of temperature flame sizes and exhaust gas components in the various combustion conditions. We found that kinetic viscosity of tire oil was lower than light oil by 1 to 2 cSt in the temperature range showing better flowing mobility in the fuel line of the burner and no significant difference in flame size between the two oils in the all combustion treatments. However much more NO and SO$_2$ were detected from the exhaust gases of tire oil than light oil combustions. In fact tire oil contains more nitrogen and total sulfur, by 25 times and 40 times respectively than light oil according to the composition analysis. Tolerable limit for SO$_2$discharge amount defined by the national air pollution standards is under 540ppm so tire oil combustion satisfies the requirement though. It is desirable if sulfur and nitrogen filtering process shall be added in the tire oil production line. Except the exhaust gas components all greenhouse heating qualities of tire oil including hot air temperature are very identical to those of light oil.

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화학반응수치해석을 이용한 HCCI기관의 예혼합기의 성층화성이 연소시의 압력 상승률에 미치는 영향 (Numerical Analysis of Effect of Inhomogeneous Pre-mixture on Pressure Rise Rate in HCCI Engine by Using Multizone Chemical Kinetics)

  • 임옥택
    • 대한기계학회논문집B
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    • 제34권5호
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    • pp.449-456
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    • 2010
  • HCCI 엔진은 고효율, 저공해를 실현할 수 있는 차세대 내연기관이다. 그러나 HCCI 엔진이 상용화되기 위해서는 몇 가지 문제점들이 해결되어야 한다. 그 중에서 가장 큰 문제점은 과도한 압력 상승률이 노킹을 발생시키기 때문에 운전영역이 제한되는 것이다. 이번 연구의 목적은 HCCI 엔진에서 압력상승률 저감을 위하여 온도 성층화와 농도 성층화 효과를 조사하는 것이다. 그리고 Multi-zone 모델을 이용한 화학반응 수치해석을 통하여 연소 및 배기가스 특성에 미치는 영향을 알아보았다. 수치해석에서 2 단계 열발생을 가지는 DME와 1단계 열발생을 가지는 메탄을 사용하였다.

EGR 제어를 통한 디젤 및 바이오디젤의 저온연소 특성 비교 (Comparisons of Low Temperature Combustion Characteristics between Diesel and Biodiesel According to EGR control)

  • 이용규;장재훈;이선엽;오승묵
    • 한국분무공학회지
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    • 제16권3호
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    • pp.119-125
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    • 2011
  • Due to the oxygen contents in biodiesel, application of the fuel to compression ignition engines has significant advantages in terms of lowering PM formation in the combustion chamber. In recent days, considerable studies have been performed to extend the low temperature combustion regime in diesel engines by applying biodiesel fuel. In this work, low temperature combustion characteristics of biodiesel blends in dilution controlled regime were investigated at a fixed engine operating condition in a single cylinder diesel engine, and the comparisons of engine performances and emission characteristics between biodiesel and conventional diesel fuel were carried out. Results show that low temperature combustion can be achieved at $O_2$ concentration of around 7~8% for both biodiesel and diesel fuels. Especially, by use of biodiesel, noticeable reduction (maximum 50% of smoke was observed at low and middle loads compared to conventional diesel fuel. In addition, THC(total hydrocarbon) and CO(Carbon monoxide) emissions decreased by substantial amounts for biodiesel fuel. Results also indicate that even though about 10% loss of engine power as well as 14% increase of fuel consumption rate was observed due to lower LHV(lower heating value) of biodiesel, thermal efficiencies for biodiesel fuel were slightly elevated because of power recovery phenomenon.

순산소 연소 배출 입자 제거용 건식 전기집진장치 운전 특성 (Operational Characteristics of a Dry Electrostatic Precipitator for Removal of Particles from Oxy Fuel Combustion)

  • 김학준;한방우;오원석;황규동;김용진;홍정희
    • 대한기계학회논문집B
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    • 제34권1호
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    • pp.27-34
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    • 2010
  • 본 연구에서는 순환방식의 1000 CMH급 전기집진장치 성능평가 시스템 구축하여, 대용량 순산소 연소 장치 없이 순산소 연소가스 모사 조건(고농도 $CO_2$ 조건)에서 엣지-평판형 전기집진장치를 방전극 형상, 집진판 간격, 유입속도, 가스조성 및 분진 입경에 따라 성능을 평가하였다. $CO_2$ 70% 조건에서 3 종 방전극에 대해 성능 비교를 한 결과, 방전극 편 면적이 넓은 방전극이 상대적으로 높은 포집효율을 나타내었다. 또한 유입속도가 감소할수록, 분진 입경이 증가할수록, 집진판 간격이 좁을수록 분진 집진 효율이 증가하였으나, $CO_2$ 농도가 증가할수록 효율이 감소하였다. 그러므로 $CO_2$ 농도가 높을 것으로 예상되는 순산소 연소 등 배기가스 조건에 적용되는 전기집진장치를 설계할 경우, 기존과 동일한 단위 가스 체적 당 코로나 전력 조건에서 집진장치 내부 유속을 줄이거나 집진판 간격을 좁히는 설계변화가 요구되며, 방전극의 경우 방전편 면적이 넓으면서 코로나 전류가 높은 방전극이 적용되야 할 것으로 판단된다.

분사시기 및 분사각 변화에 따른 HCCI 엔진의 혼합기 분포 및 연소특성에 관한 연구 (A Study on the Characteristics of Mixture Formation and Combustion in HCCI Engine according to the Various Injection Angles and Timings)

  • 김형민;류재덕;이기형
    • 한국자동차공학회논문집
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    • 제14권4호
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    • pp.20-25
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    • 2006
  • Recently, there has been an interest in premixed diesel engines as it has the potential of achieving a more homogeneous and leaner mixture close to TDC compared to conventional diesel engines. Early studies are shown that in a HCCI(Homogeneous Charge Compression Ignition) engine, the fuel injection timing and injection angle affects the mixture formations. Thus the purpose of this study was to investigate relationship of combustion and mixture formations according to injection timing and injection angle in a common rail direct injection type HCCI engine using a early injection method called the PCCI(Premixed Charge Compression Ignition). From this study, we found that the fuel. injection timing and injection angle affect the mixture formations and in turn affects combustion in the PCCI engine.

가솔린 엔진의 밸브타이밍 변화가 부분부하 조건에서 잔류가스량 및 연소특성에 미치는 영향 (Effect of Value Timing on Residual Gas Fraction and Combustion Characteristics at Part Load Condition in an SI Engine)

  • 김철수;송해박;이종화;유재석;조한승
    • 한국자동차공학회논문집
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    • 제8권4호
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    • pp.26-33
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    • 2000
  • In-cylinde flow and mixture formation are key contributors to both idle stability and combustion stability at part load condition in SI engine. The real time measurements of air-fuel ration and in- cylinder residual gas fraction are particularly important to obtain a better understanding of the mechanisms for combustion and emissions especially during cold start and throttle transient condition. This paper reports the cycle resolved measurements of residual gas fraction and equivalence ration near speak plug with value timing change and their effects on combustion characteristics at part load. The results showed that the effect of intake value opening on the residual gas fraction was smaller than that of exhaust valve closing because of the decreases of exhaust gas reverse flow from exhaust port. The variation of equivalence ratio near spark plug increased with the increase of value overlap and it closely related with heat release rate and combustion stability

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Kerosene (Coal Oil)을 사용한 스파크점화기관의 연소실헤드 온도 변화에 따른 엔진 성능 및 배기 특성에 관한 연구 (A Study on the Performance and Emission Characteristics According to the Coolant Temperature of Combustion Chamber Head of Spark Ignition Engine Fuelled with Kerosene (Coal Oil))

  • 한성빈;정연종
    • 한국수소및신에너지학회논문집
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    • 제28권1호
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    • pp.92-97
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    • 2017
  • Kerosene (Coal oil) is a particularly attractive fuel because it is widely used to power jet engines of aircraft as jet fuel and some rocket engine. This paper describes the performance and emission characteristics according to the collant temperature of combustion chamber head of spark ignition engine fuelled with kerosene. As a result, the following knowledge is obtained. As the collant temperature of combustion chamber head is decreased, torque, volumetric efficiency and brake specific fuel consumption have been increased. When coolant temperature of combustion chamber lower, THC emission increased but CO and $NO_x$ emission decreased.

바이오디젤유(미강유 에스테르)를 이용한 농업용 디젤기관의 연소 특성 (The Combustion Characteristics of Agricultural Diesel Engine using Biodiesel Fuel(Ester of Rice Bran Oil))

  • 유경현;윤용진;오영택
    • 대한기계학회논문집B
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    • 제27권2호
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    • pp.181-187
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    • 2003
  • Biodiesel fuel as an alternative fuel for diesel engine has a great possibility to solve the problems such as air pollution. It is a domestically produced, renewable fuel that can be manufactured from vegetable oils, used vegetable oils, or animal fats. In this study, the usability of biodiesel fuel derived from rice bran oil as an alternative fuel for diesel engines was investigated in agricultural diesel engine. Emissions were characterized with neat biodiesel fuel and with a blend of biodiesel fuel and conventional diesel fuel. Since the biodiesel fuel includes oxygen of about 11%, it could influence the combustion process strongly. So, the use of biodiesel fuel resulted in lower emissions of carbon monoxide, carbon dioxide, and smoke emissions without any increase of oxides of nitrogen. It is concluded that biodiesel fuel can be utilized effectively as a renewable and an environmentally Innocuous fuel for diesel engine.

LPG/DME 혼합연료를 사용하는 직접분사식 디젤 엔진의 부분부하 성능 및 배기특성에 관한 연구 (Performance and Emission Characteristics of a DI Diesel Engine Operated with LPG/DME Blended Fuel)

  • 이석환;오승묵;최영;조준호;차경옥
    • 한국자동차공학회논문집
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    • 제17권5호
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    • pp.53-60
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    • 2009
  • In this study, LPG-blended DME fuel was experimentally investigated in CI(compression ignition) engine. In particular, performance, emissions characteristics (including hydrocarbon, CO, and NOx emissions), and combustion stability of engine fueled with LPG-blended DME fuel were examined. The extent of LPG fuel in the blended fuel was 0-40 wt%. Results showed that stable engine operation was possible in a wide range of engine loads on DME blended with maximum 30% of LPG by mass in a CI engine. Considering the results of the engine power output and exhaust emissions, blended fuel up to 30% of LPG by mass can be used as an alternative to diesel in a CI engine. LPG blended DME fuel is expected to have potential for enlarging the DME market.