• Journal of the Korean Society for Marine Environment & Energy
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• v.11 no.3
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• pp.138-149
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• 2008

Rapid accumulation of carbon dioxide in the atmosphere for the past century leads to acidify the surface ocean and contributes to the global warming as it forms acid in the ocean and it is a green house gas. In order to curb the green house gas emissions, in particular carbon dioxide, various multilateral agreements and programs have been established including UN Convention of Climate Change and its Kyoto Protocol for the last decades. Also a number of geo-engineering projects to manipulate the radiation balance of the earth have been proposed both from the science and industrial community worldwide. One of them is ocean fertilization to sequester carbon dioxide from the atmosphere through the photosynthesis of phytoplankton in the sea. Deliberate fertilization of the ocean with iron or nitrogen to large areas of the ocean has been proposed by commercial sector recently. Unfortunately the environmental consequences of the large scale ocean iron fertilization are not known and the current scientific information is still not sufcient to predict. In 2007, the joint meeting of parties of the Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter, 1972 and 1996 Protocol (London Convention/Protocol) has started considering the purposes and circumstances of proposed large-scale ocean iron fertilization operations and examined whether these activities are compatible with the aims of the Convention and Protocol and explore the need, and the potential mechanisms for regulation of such operations. The aim of this paper is to review the current development on the commercial ocean fertilization activities and management regimes in the potential ocean fertilization activities in the territorial sea, exclusive economic zone, and high seas, respectively, and further to have a view on the emerging international management regime to be London Convention/Protocol in conjunction with a support from the United Nations General Assembly through The United Nations Open-ended Informal Consultative Process on Oceans and the Law of the Sea.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.2
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• pp.31-40
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• 2019

In Korea, 51,013 thousand tons of livestock manure was generated in 2018. A total of 46,530 thousand tons, which is 91.2% of the total amount of livestock manure generated, was treated by composting(40,647 thousand tons) or liquid fertilization(5,884 thousand tons) method. At present, the policy of livestock manure treatment in Korea is to make livestock manure into organic fertilizer(compost, liquid fertilizer) and then to applicate it on agricultural land. And this policy is very effective in terms of livestock manure treatment and nutrient recycling. However, considering the steadily declining farmland area for decades, the use of livestock manure compost could be limited in the future. There is also concern that local nutrient overloading, nutrient management regulation, and restrictions on the number of livestock may become serious problem for livestock manure treatment. In addition, there are some opinions that nutrient derived from livestock manure may flow into tributaries of major dams. In recent years, there has been a suspicion that fine dust may be generated from livestock manure compost. In recent years, the use of livestock manure fertilizer has been rapidly increasing, there is a growing demand of the development of new technologies for livestock manure treatment. Especially, cow excretes a larger amount of manure than other livestock, so that the efficiency of development of new technology for cow manure treatment will be high. Therefore, in this study, the combustion characteristics of cow manure pellet were investigated in order to analyzed whether cow manure could be used as source of solid fuel. During the combustion test, the weight loss of the cow manure pellet began to increase when the temperature of the combustion chamber reached $300^{\circ}C$. The ratio of $H_2$, $CH_4$, CO in the pyrolysis gas produced in the pyrolysis process of cow manure pellet were 6.65~11.62%, 0.58~1.54 and 11.47~14.07%, respectively.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.5
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• pp.705-715
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• 2010

The adoption of carbon foot print system is being activated mostly in the developed countries as one of the long-term response towards tightened up regulations and standards on carbon emission in the agricultural sector. The Korean Ministry of Environment excluded the primary agricultural products from the carbon foot print system due to lack of LCI (life cycle inventory) database in agriculture. Therefore, the research on and establishment of LCI database in the agriculture for adoption of carbon foot print system is urgent. Development of LCA (life cycle assessment) methodology for application of LCA to agricultural environment in Korea is also very important. Application of LCA methodology to agricultural environment in Korea is an early stage. Therefore, this study was carried out to find out the effect of lettuce cultivation on agricultural environment by establishing LCA methodology. Data collection of agricultural input and output for establishing LCI was carried out by collecting statistical data and documents on income from agro and livestock products prepared by RDA. LCA methodology for agriculture was reviewed by investigating LCA methodology and LCA applications of foreign countries. Results based on 1 kg of lettuce production showed that inputs including N, P, organic fertilizers, compound fertilizers and crop protectants were the main sources of major emission factor during lettuce cropping process. The amount of inputs considering the amount of active ingredients was required to estimate the actual quantity of the inputs used. Major emissions due to agricultural activities were $N_2O$ (emission to air) and ${NO_3}^-$/${PO_4}^-$ (emission to water) from fertilizers, organic compounds from pesticides and air pollutants from fossil fuel combustion in using agricultural machines. The softwares for LCIA (life cycle impact assessment) and LCA used in Korea are 'PASS' and 'TOTAL' which have been developed by the Ministry of Knowledge Economy and the Ministry of Environment. However, the models used for the softwares are the ones developed in foreign countries. In the future, development of models and optimization of factors for characterization, normalization and weighting suitable to Korean agricultural environment need to be done for more precise LCA analysis in the agricultural area.

• Journal of the Korean earth science society
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• v.43 no.1
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• pp.41-59
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• 2022

In accordance with the enactment of 'the Paris Agreement' in 2015 and 'the Framework Act on Carbon Neutrality and Green Growth for Response to the Climate Crisis' in 2021, each local government has set appropriate reduction target of greenhouse gas to achieve the nationally determined contribution (NDC, the reduction target of 40% compared to 2018) of greenhouse gas (GHG) emissions in 2030. In this study, the current distribution of GHG emissions was analyzed in a time series centered on the Chungbuk region for the period from 1990 to 2018, with the aim of reducing GHG emissions in Chungbuk by 2030 based on the 2030 NDC and scenario. In addition, the prospected reduction by 2030 was estimated considering the projected emissions according to Busines As Usual in order to achieve the target reduction of GHG emissions. Our results showed that GHG emissions in Chungbuk and Korea have been increasing since 1990 owing to population and economic growth. GHG emissions in 2018 in Chungbuk were very low (3.9 %) relative to the national value. Moreover, emissions from fuel combustion, such as cement and lime production, manufacturing and construction industries, and transportation industries, were the main sources. Furthermore, the 2030 target of GHG emission reduction in Chungbuk was set at 40.2% relative to the 2018 value, in accordance with the 2030 NDC and 2050 carbon-zero national scenario. Therefore, when projected emissions were considered, the prospected reduction to achieve the target reduction of GHG emissions was estimated to be 46.8% relative to 2018. The above results highlight the importance of meeting the prospected reduction of GHG emissions through reduction means in each sector to achieve the national and local GHG reduction target. In addition, to achieve the 2030 NDC and 2050 carbon zero, the country and each local government, including Chungbuk, need to estimate projected emissions by year, determine reduction targets and prospect reductions every year, and prepare specific means to reduce GHG emissions.

• Resources Recycling
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• v.17 no.6
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• pp.62-67
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• 2008

Oil shale is a sedimentary rock that contains organic compounds called kerogen that are released as petroleum-like liquids by retorting. In order to evalute oil shale as alternative oil resources, the physical properties of oil shale samples from US and Russia were investigated and Fischer assays were carried out. Thermogravimetric analysis shows that thermal degradation of oil shale consisted of two stage processes, with hydrocarbon release from kerogen followed by $CO_2$ release by carbonate decomposition. Organic compounds in oil shale have an high hydrogen/carbon ratio, and therefore liquid hydrocarbons could be obtained easily. Shale oil yields from Russian and US oil shales by Fischer assay were 12.7% and 18.5%, respectively. The density and boiling point of shale oils are higher than that of Middle East crude oil, indicating that further upgrading processes are necessary for refinery. On the other hands, sulfur contents are relatively low, and the amounts of Vanadium and Nickel are extremely small in shale oil. It was found that paraffins were rich in US shale oil while main components of Russian shale oil were oxygenated hydrocarbons.

• Journal of the Korean Society for Railway
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• v.15 no.4
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• pp.408-412
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• 2012

Recently, new climate change mechanism after 2020 year has been accepted with the parties, and so government is pushing ahead the GHG reduction policies to achieve the effective results. Especially, it is essential to enhance the role of railroad in the public traffic system as well as to develop new cars with high energy efficiency for the GHG reduction of transportation sector. Thus, the calculation method of GHG emission of railroad should be established to manage the emission continuously. In this study, the calculation method of GHG emission of railroad was defined with Tier level considering its emission sources to refer to 2006 IPCC guideline for national GHG inventories. Also, the GHG emission of railroad at Tier 1 level was investigated using the activity data related to the amount of diesel and electricity consumption from 2008 to 2010. As a result, total GHG emission in 2010 was about 2,060 thousands ton CO2e, which have 73% of electricity and 27% of diesel. In future, the plans on the GHG reduction of railroad will be accomplished by the analysis of the detailed trends on the basis of the emission management of Tier 3 level under operating patterns. Therefore, it is important to develop the specific GHG emission factors of railroad in advance.

• JOURNAL OF ELECTRICAL WORLD
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• s.451
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• pp.22-31
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• 2014

온실가스 다량 배출로 인한 지구온난화 현상은 많은 분야에서의 변화를 요구하고 있다. 특히 온실가스 배출의 주원인으로 꼽히고 있는 발전 등 에너지산업 분야의 경우 그 요구는 매우 거세다. 과거에는 경제성장이라는 측면만 고려하면 됐지만, 지금은 기후변화 대응을 위해 환경을 최우선적으로 고려할 것을 주문하고 있기 때문이다. 문제는 현재 전 세계적으로 약 20%에 이르는 인구가 전기 에너지를 사용하지 못하고 있다는 점이다. 즉 향후 에너지를 사용하고자 하는 신규 소비자는 더욱 늘 것이고, 산업의 발전으로 인한 에너지 소비 역시 큰 폭으로 증가할 수밖에 없다. 문제가 굉장히 어렵지만 해결책도 분명 존재한다. 결론적으로 말해 온실가스 배출을 최소화하면서도 에너지 효율은 높인 기술을 개발하면 되는 것이다. 그리고 이미 세계 각국은 청정에너지 기술개발을 위해 다각도의 노력을 펼치고 있는 상황이다. 그렇다면 세계 각국은 미래 에너지시장을 선도할 청정에너지 기술로 어떤 것을 꼽고 있을까. 이 질문에 대한 대답은 지난 5월 서울에서 개최된 '제5차 클린에너지장관회의(CEM, Clean Energy Ministerial)'에서 제시된 바 있다. CEM은 한국, 미국, 영국, 독일, 중국, 일본 등 세계 에너지의 70%를 사용하는 주요 국가의 관계 장관들이 모여 클린에너지 공급 확대와 에너지효율 향상을 위한 구체적 액션플랜을 논의하는 자리다. 2010년 미국에서 첫 회의가 열렸고 아랍에미리트, 영국, 인도에 이어 한국은 5번째로 CEM을 개최했다. 특히 이번 CEM에서는 회원국들의 의견을 모아 10대 청정에너지 혁신기술을 최초로 선정, 발표했다. CEM은 "향후 10년 간 에너지 시장의 변화를 선도할 유망 기술을 선정한 것으로 IEA 등 국제기구와 주요국 기술 로드맵을 기준으로 해 23개 회원국 회람을 거쳐 최종 확정하게 됐다"고 배경을 설명했다. 이번에 선정된 10대 청정에너지 혁신기술은 ${\triangle}$초고압직류송전 ${\triangle}$에너지저장장치 ${\triangle}$바이오연료 ${\triangle}$마이크로 그리드 ${\triangle}$탄소포집 및 저장 ${\triangle}$초고효율 태양광 발전 ${\triangle}$해상풍력 ${\triangle}$신재생에너지 하이브리드시스템 ${\triangle}$빅데이터 에너지관리시스템 ${\triangle}$지열 시스템이다. 이와 관련해 산업통상자원부 윤상직 장관은 "이번에 선정된 10개의 기술은 최근의 기술적 정책적 추세가 잘 반영된 결과"라고 평가했다. 특히 윤 장관은 "중앙집중형 공급원에서 분산형 전원으로의 변화, 에너지 효율향상의 중요성, ICT와 융 복합 추세 등 우리나라의 상황에서 시사하는 바가 크다"며 "현재 수립하고 있는 '제3차 국가에너지기술 개발계획'에 이러한 기술적 추세를 반영하겠다"는 의사를 표명했다. 향후 10년 간 에너지시장의 변화를 선도할 10대 청정에너지 유망기술을 자세히 소개한다.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.06a
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• pp.147-157
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• 2004

The production of $^{14}C$ occurs in the Moderator(MOD), Primary Heat Transport System (PHTS), Annulus Gas System(AGS) and Fuel in the CANDU reactor. Among the four systems, The MOD system is the largest contributor to $^{14}C$ production(approximately 94.8%). $^{14}C$ is distributed of $^{14}CO_2$, $H_2^{14}CO_3$, $H^{14}{CO_3}^-$ and $^{14}{CO_3}^{2-}$ species as a function of the pH of water. Of these species, $H_2^{14}CO_3$ and $H^{14}{CO_3}^-$ form are predominant because the pH of MOD system is ＞ 5. In this paper, adsorption-desorption characteristics of bicarbonate ion (${HCO_3}^-$) by IRN 150 resin was investigated. ${HCO_3}^-$ ion existed in neutral condition(app. pH 7)was reacted with ion exchange resin (IRN-150) and saturated with it. Then $NaNO_3$ and $Na_3PO_4$ solutions selected as extraction materials were used to make an investigation into feasibility of ${HCO_3}^-$ extraction from resin saturated with ${HCO_3}^-$. Desorption of $CO^{2+}$ and $Cs^+$ ion by $Na^+$ ion was not occurred, and desorption of ${HCO_3}^-$ ion by ${NO_3}^-$ and ${PO_4}^{3-}$ was occurred slowly. Also, the status of ion exchange which is used in Wolsong NPPs and generation of spent resin yearly were surveyed.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.1
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• pp.53-59
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• 2015

Combustion characteristics for co-firing of biomass (Walnut Shell) as blending fuel in coal fired boiler have investigated using thermogravimetric analyser (TGA) and drop tube reactor (DTR). The results show that devolatilization and char combustion for WS occurs at lower temperature than those of existing coals and has lower activation energy value, which is resulting in higher reactivity. When the WS is blended with coal, TGA results show linear profiles depending on blending ratio for each fuel. However, DTR results exist the non-additive phenomena for blending of WS. As blending ratio of WS increase, the UBC decrease at BBR 5%, but the UBC rather increase from BBR 10% due to oxygen deficiency formed from rapid combustion of WS. This paper propose that fuel lean condition by oxygen rich lead to higher blending ratio of biomass by solving the oxygen deficiency condition.

• Applied Chemistry for Engineering
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• v.26 no.2
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• pp.205-209
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• 2015

CCU (Carbon Capture & Utilization) has a potential technology for the reduction and usage of carbon dioxide which is greenhouse gas emitting from a fossil fuel buring. To decompose the carbon dioxide, a three phase gliding arc plasma-catalytic reactor was designed and manufactured. Experiments of carbon dioxide reduction was performed by varying the gas flow rate with feeding the $CO_2$ only as well as the input power, the catalyst type and steam supply with respect to the injection of the mixture of $CO_2$ and $CH_4$. The $CO_2$ decomposition rate was 7.9% and the energy efficiency was $0.0013L/min{\cdot}W$ at a $CO_2$ flow rate of 12 L/min only. Carbon monoxide and oxygen was generated in accordance with the destruction of carbon dioxide. When the injection ratio of $CH_4/CO_2$ reached 1.29, the $CO_2$ destruction and $CH_4$ conversion rates were 37.8% and 56.6% respectively at a power supply of 0.76 kW. During the installation of $NiO/Al_2O_3$ catalyst bed, the $CO_2$ destruction and $CH_4$ conversion rates were 11.5% and 9.9% respectively. The steam supply parameter do not have any significant effects on the carbon dioxide decomposition.