• Electrical & Electronic Materials
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• v.7 no.1
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• pp.32-41
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• 1994

In this study, the TSC spectroscopy has been applied to investigate the influence of structural change due to a process of curing reaction on the electrical properties of epoxy composites cured with acid-anhydride. Five TSC peaks appeared in -160-250[.deg.C]: in the low temperature region below glass transition temperature(T$\_$g/), three relaxation mode peaks due to action of side chains, substitution group or terminal groups have been observed, a peak associated with T$\_$g/, appeared in 110[.deg. C] and p peak due to ionic space charges located in 150[.deg.C]. Each peak was separated into elementary peaks by the partial polarization procedure, and the distribution of activation energy and relaxation time were analized to clearify the origin of each peak. Also, overaboundantly added hardener separated a .betha. peak near 10[.deg. C] into two peaks of .betha.$\_$1/(10.deg. C) and .betha.$\_$2/(20.deg. C) according to increasement of forming field, and the separated hardener was oxidated thermally with increasing surrounding temperatures. The expansion of the free volume need in molecular motion and the reduction of the structural packing density through thermal oxidation process increased TSC between .alpha. peak and .betha. peak and decreased T$\_$g/.

• Magazine of the Korea Concrete Institute
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• v.10 no.5
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• pp.109-115
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• 1998

철근콘크리트 구조물이 과소설계되어 있거나 과다 하중이 작용하게 되면 그 구조물의 구조성능을 파악하여 보수.보강을 시행하게 된다. 최근에 가장 맣이 사용되는 보수.보강 재료로는 특히 휨내력을 보강하는데 탄소섬유를 들 수 있다. 탄소섬유쉬트는 내열성과 내호염성에 있어서 회재가 발생할 경우 보강재료로서 충분한 성능을 가지고 있다. 그러나 이를 접착시키는데 사용되는 에폭시는 유기계 물질로서 화재시 유독가스가 발생하고 내열성능도 30$0^{\circ}C$정도에도 지탱하기 어려워 화재 발생이 가능한 구조물에 사용하기 어렵다. 이 연구에서는 무기계 폴리머 복합재료로 접착된 탄소섬유를 고온(약 800~100$0^{\circ}C$, 1시간)으로 가열한 후 가열된 섬유판의 인장, 휨 전단내력을 검토하여 내열성능을 파악하고 이 섬유쉬트로 보강한 철근콘크리트 부재의 휨 성능을 실험적으로 규명하여 화재의 위험이 있는 구조물에 구조적인 보강재료로 사용이 가능한가를 검토하였다. 연구 결과, 개발된 무기계 폴리머 복합체는 인장강도, 휨강도 및 접착강도가 유기계 접착제와 유사하게 나타났고 800~100$0^{\circ}C$ 정도로 1시간 가열한 이후에도 상온 시험체 휨내력과 전단내력의 63%, 33% 정도를 유지하여 화재의 위험이 있는 부위에도 사용이 가능한 것으로 판단되었다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.04b
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• pp.8-9
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• 2008

In the procedure of the estimation, the short time breakdown characteristics for the epoxy composite specimens, which were made with the variation of hardener and/or filler, were tested firstly. Then the long time voltage-to-time test was implemented. Finally, the long time breakdown voltage of each specimen was estimated with the parameters obtained from the statistical treatment with Weibull distribution. Base on the results, it has been found that the optimal weight ratio of epoxy resin/hardener/filler that has the excellent long time breakdown characteristic was 100/100/65. It was due to the silane treatment which relieves the electric field at the interface between filler and epoxy.

• Electrical & Electronic Materials
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• v.7 no.3
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• pp.187-199
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• 1994

In order to find an effect of structural changes due to variation of addition ratio of anhydride hardener and postcuring herat-treatments upon electrical properties of epoxy composites, the dielectric properties over a frequency range from 30[Hz] to l[MHz] were investigated in the temperature range of 20-180[.deg. C]. From the dielectric properties, the a peaks related with glass-transition phenomena of epoxy network appeared near 130[.deg. C], the conduction loss in high temperature region above 150[.deg. C] due to thermal dissociation of hardener started off with the low frequency side and the .betha. peak concerned with contribution of movable unreacted terminal epoxy groups and curing agents in the glass states concurred with the high-frequency side below 20[.deg. C]. And an effect of an hydride hardener upon structural changes and of postcuring heat treatments upon structural stability in epoxy composites would be explained through the estimation of the distribution of relaxation times and the activation energy for a .alpha. peak according to the WLF equations.

• Korean Journal of Materials Research
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• v.18 no.10
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• pp.542-546
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• 2008

$BaTiO_3$/epoxy composites can be applied as the dielectric materials for embedded capacitors. The effects of the degree of $BaTiO_3$ particle agglomeration on the dielectric properties of $BaTiO_3$/epoxy composites were investigated in the present study. The degree of particle agglomeration was controlled by the milling of the agglomerated particles. The size and content of the agglomerated $BaTiO_3$ particles decreased with an increase in the milling time. The dielectric constants and polarizations of $BaTiO_3$/epoxy composites abruptly decreased with the increase of the milling time. It was concluded that the dielectric constants and polarizations of $BaTiO_3$/epoxy composites decreased as the degree of particle agglomeration decreased. The degree of agglomeration of $BaTiO_3$ particles turned out to be a very influential factor on the dielectric properties of $BaTiO_3$/epoxy composites.

• Journal of the Korean Society of Industry Convergence
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• v.25 no.3
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• pp.461-466
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• 2022

Epoxy resins are widely used in various industrial fields. However, they suffer from brittleness, an issue that must be addressed for further applications. To solve this problem, additional fillers are needed to improve the mechanical and thermal properties of the resins; zirconia is one such filler. However, it has been reported that aggregation may occur in the epoxy composites as the amount of zirconia increases, preventing enhancement of the mechanical strength of the epoxy composites. Herein, to reduce the aggregation, zirconia was well dispersed on halloysite nanotubes (HNTs), which have high thermal and mechanical strength, by a conventional wet impregnation method using zirconyl chloride octahydrate as a precursor. The mechanical and thermal strengths of the epoxy composites with The zirconia impregnated HNTs (Zr/HNT) were investigated. Zr/HNT were characterized by Scanning electron microscope (SEM), transmittance electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy. The thermal strength of the epoxy composites was studied by thermomechanical analysis (TMA) and the mechanical strength of the epoxy composites (flexural strength) was studied by using a universal testing machine (UTM). The mechanical and thermal strengths of the epoxy complex with Zr/HNT were improved compared to those of the epoxy complex with HNT, and also increased as the content of Zr/HNT increased.

• Journal of the Korean Society of Industry Convergence
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• v.27 no.2_2
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• pp.371-375
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• 2024

Epoxy resins are widely used in various fields due to their high adhesion, mechanical strength, and solvent resistance. However, as the volume decreases during the hardening process and the cooling process after hardening, stress is generated and when an external force is applied, the brittle material exhibits destruction behavior. To complement this, research has been conducted using inorganic nanofillers such as halloysite nanotube(HNT). HNT has a nanotube structure with the chemical formula of Al₂Si₂O₅(OH)₄·nH₂O and is a natural sediment of aluminosilicate. It has been used as additive to improve the mechanical properties of epoxy composites with exchange of amine group as a terminal functional group. In order to simplify complicated procedures of common wet method, a dry coating machine was designed and used for amine group exchange in previous research. In this study, they were applied as filler in epoxy composites, and mechanical properties such as tensile strength and flexural strength of composites were examined.

• Clean Technology
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• v.19 no.3
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• pp.300-305
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• 2013

Zinc oxide (ZnO) and reduced graphite oxide (rGO) composites were synthesized and tested as adsorbents for the hydrogen sulfide ($H_2S$) adsorption at mid-to-high (300 to $500^{\circ}C$) temperatures. In order to investigate the critical roles of oxygen containing functional groups, such as hydroxyl, epoxy and carboxyl groups, attached on rGO surface for the $H_2S$ adsorption, various characterization methods (TGA, XRD, FT-IR, SEM and XPS) were conducted. For the reduction process for graphite oxide (GO) to rGO, a microwave irradiation method was used, and it provided a mild reduction environment which can remain substantial amount of oxygen functional groups on rGO surface. Those functional groups were anchoring and holding nano-sized ZnO onto the 2D rGO surface; and it prevented the aggregation effect on the ZnO particles even at high temperature ranges. Therefore, the $H_2S$ adsorption capacity had been increased about 3.5 times than the pure ZnO.

• Journal of the Korean Wood Science and Technology
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• v.27 no.2
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• pp.15-22
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• 1999

Polymeric meterials that are used for noise and vibration damper in wood/polymer/wood sandwich composites, must have a high loss factor(tan ${\delta}$), and at the same time the storage modulus(E) of $5{\times}10^7$ to $10^9$ dyne/$cm^2$ must withstand over a wide temperature and frequency ranges. In this study, the series of epoxy resinlpolyacrylate interpenetrating polymer networks(IPNs) were synthesized by simultaneous polymerization. Their dynamic tensile properties were measured at 110Hz using Rheovibron instrument. Composite damping factor(tan ${\delta}_c$) and dynamic bending modulus($E_c,\;E_^{\prime\prime}c$) of wood/polymer/wood sandwich composites were measured at 110Hz using a Rheovibron in bending mode of vibration. These dynamic tensile studies indicated that cured epoxy resin/polyacrylates IPNs were semicompatible in the sense that both the shifting of T($E^{\prime\prime}_{max}$) or T(tan ${\delta}_{max}$) and the broadening of glass transition temperature range were observed. Especially, the cured Epikote871/P(n-BMA) IPNs of composition 70/30 to 50/50 showed a relatively high tan a and appropriate E' value over a wide temperature range; consequently the tan a e curves of wood/IPNs/wood sandwich composites was broadened over a wide temperature range.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.11
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• pp.5947-5955
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• 2013

This study was intended to estimate the axial deformation of joint between pavement modules in the rapid-constructible modular pavement system, and to investigate the applicability of two-phase composites for a joint material, which was composed of cement paste, epoxy, or polyurethane as a matrix and sand as particles. A case which had supports under the pavement module as well as a case which the module was put on roadbed directly were considered in FEM analysis for the axial deformation. The effect of self-weight, live load, thermal change, and drying shrinkage were estimated and the thermal change was found to cause the largest deformation compared to the others. Deformation capacity of two-phase composites was predicted using the modified shear-lag model. In the analytical results for the elastic modulus and maximum tensile strain with different volume fractions of sand, 20~30 % replacement of sand was revealed to satisfy the required strain capacity with economy when if the width of joint was designed to be 15~20 mm.