• Title/Summary/Keyword: 에너지 평형 법칙

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Performance Evaluation of Heat Recovery Steam Generator in Combined Cycle Gas Turbine Power Plants Based on First and Second-Law Analysis (복합사이클 발전플랜트 폐열회수 보일러의 열역학 제1법칙 및 제2법칙 해석)

  • In, Jong-Soo
    • Proceedings of the KAIS Fall Conference
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    • 2010.11b
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    • pp.684-687
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    • 2010
  • 본 논문은 복합사이클 발전플랜트의 폐열회수 보일러 최적운전 및 최적설계에 대한 새로운 접근 방법을 도출하기 위해 폐열회수 보일러에서 발생되는 증기로 증기터빈을 구동하는 하부사이클 효율을 검토하였다. 열역학 제1법칙 해석을 통해 하부사이클 에너지 평형을 검토하였고, 열역학 제2법칙을 통해 엑서지 평형을 검토하였다. 하부사이클 효율이 최대가 되는 폐열회수 보일러를 설계하기 위해서는 열역학 제1법칙을 해석할 경우 하부사이클 전체를 해석하여야 함을 알 수 있다. 하지만, 열역학 제2법칙을 통한 엑서지 해석을 행할 경우 하부사이클 효율이 최대가 되는 증발온도와 폐여회수 보일러에서 소모되는 엑서지가 최소가 되는 점이 일치함을 알 수 있었다. 따라서 본 논문을 통해 폐열회수 보일러에서 소모되는 엑서지 해석을 통해 하부사이클 효율이 최대가 되는 폐열회수 보일러 최적화가 가능함을 알 수 있다.

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영광1호기 원자로 냉각재 평균 온도 조정에 따른 터빈 사이클 열성능 변화 분석

  • Choi, Kwang-Hui;Hong, Seung-Yeol;Park, Bu-Seong;Kim, Yu
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05a
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    • pp.532-537
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    • 1996
  • 영광 1호기의 일차계통인 원자로 냉각재 평균온도( $T_{avg}$)를 적정값으로 미세조정하여 운전할 때, 2차계통 주요 운전변수인 주증기압력이 상승하고 터빈출력이 상승함을 발견하여 이에 대한 터빈사이클 열성능 변화를 발전소 전체 열평형 계산에 의해 정량적으로 파악하고, 그 원인을 열역학 2법칙에서의 엔트로피개념을 이용한 유용에너지의 최대값인 엑서지이론을 적용하여 분석하고자하였다. 분석 결과 열평형 계산에서는 전체 열량의 대부분인 63.2%가 복수기에서 손실되는 것으로 나타나는 반면, 열역학 제2법칙의 엑서지를 이용한 분석에서는 비가역손실이 주로 터빈(전체 엑서지의 12.7%)에서 일어나고 그 다음이 복수기(5.7%), 급수가열기(2.1%) 그리고 1,2단 재열기 (1.0%)의 순으로 전체 사이클에서 일어나며, 주증기 압력이 상승할 때 터빈 출력이 상승하는 주원인은 주증기의 유용성(엑서지)이 크게 증가하는 것에 비해 터빈사이클에서의 비가역손실은 적게 증가하기 때문으로 나타났다.다.

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Dynamical phase transition of the one-dimensional Ising model

  • Lee, Jaehak;Noh, Chanwoo;Jung, YounJoon
    • Proceeding of EDISON Challenge
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    • 2017.03a
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    • pp.100-109
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    • 2017
  • 이번 연구에서 우리는 궤적 앙상블을 이용해 1 차원 Ising 모형의 동역학적 상전이를 관측했다. s 앙상블이라고도 불리는 궤적 앙상블은 활성도의 켤레 변수를 도입해 활성도에 편중을 두어 궤적을 추출한 앙상블이다. 평형상태에 있는 1 차원 Ising 모델에서는 외부 자기장이 존재하지 않을 때 상전이가 나타나지 않는다. 하지만 s 앙상블을 통해서 우리는 1 차원 Ising 모형에서 동역학적 상전이가 존재한다는 사실을 발견할 수 있었다. 이동역학적 상전이는 유한 크기 조정 법칙이 잘 적용되며 2 차원 Ising 모형과 같은 보편성 등급을 가진 것을 통해 두 상전이가 서로 연관되어 있다는 것을 알 수 있었다. 또한 열역학적 함수인 에너지와 동역학적 함수인 활성도 사이에 선형관계가 존재하는 점을 통해 동역학적 함수와 열역학적 함수 사이의 관계가 존재하는 것을 확인했다. 마지막으로 또 다른 열역학적인 함수인 자화도에 편중을 두었을 때 동역학적 상전이가 일어나는 임계점이 이동하는 것을 통해 에너지 외의 다른 열역학적 함수도 동역학적 함수와 연관된다는 것을 알아냈다.

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Transition of Turbulent Kinetic Energy Through a Serial Unit of Straight-Duct, Contraction and Free-Jet (상류유동전개부, 수축부 및 자유분사류로 이어지는 유동장에서의 난류에너지 천이에 대한 연구)

  • 한용운;남경덕
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.12
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    • pp.2368-2375
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    • 1992
  • The transition of turbulent kinetic energy(TKE) balance along the centerline of the flow unit, which is composed of straight-duct, contraction and free-jet, has been investigated by the hot-wire anemometry. It is found that the mean turbulent kinetic energy is balanced by the dissipation in the internal flow region ; by the production and the dissipation, through contraction ; and by the dissipation, in initial region(X〈8D) of free-jet. But in the developing region (8D〈X〈20D) it is balanced by all of the three(ie, diffusion, production and dissipation). Finally, in the downstream of free-jet, the mean TKE is balanced again by dissipation like as the beginning. The decay-laws along the centerline are checked in the region of free jet as well as in the straightduct. After the developing region of free-jet also exist the decay-laws, the exponent of the axial turbulence being bigger than of the radial.

Development of a Numerical Simulator for Methane-hydrate Production (메탄 하이드레이트 생산 묘사를 위한 수치도구의 개발)

  • Shin, Hosung
    • Journal of the Korean Geotechnical Society
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    • v.30 no.9
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    • pp.67-75
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    • 2014
  • Methane gas hydrate which is considered energy source for the next generation has an urgent need to develop reliable numerical simulator for coupled THM phenomena in the porous media, to minimize problems arising during the production and optimize production procedures. International collaborations to improve previous numerical codes are in progress, but they still have mismatch in the predicted value and unstable convergence. In this paper, FEM code for fully coupled THM phenomena is developed to analyze methane hydrate dissociation in the porous media. Coupled partial differential equations are derived from four mass balance equations (methane hydrate, soil, water, and hydrate gas), energy balance equation, and force equilibrium equation. Five main variables (displacement, gas saturation, fluid pressure, temperature, and hydrate saturation) are chosen to give higher numerical convergence through trial combinations of variables, and they can analyze the whole region of a phase change in hydrate bearing porous media. The kinetic model is used to predict dissociation of methane hydrate. Developed THM FEM code is applied to the comparative study on a Masuda's laboratory experiment for the hydrate production, and verified for the stability and convergence.

Formulation of Fully Coupled THM Behavior in Unsaturated Soil (불포화지반에 대한 열-수리-역학 거동의 수식화)

  • Shin, Ho-Sung
    • Journal of the Korean Geotechnical Society
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    • v.27 no.3
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    • pp.75-83
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    • 2011
  • Emerging issues related with fully coupled Thermo-Hydro-Mechanical (THM) behavior of unsaturated soil demand the development of a numerical tool in diverse geo-mechanical and geo-environmental areas. This paper presents general governing equations for coupled THM processes in unsaturated porous media. Coupled partial differential equations are derived from three mass balances equations (solid, water, and air), energy balance equation, and force equilibrium equation. With Galerkin formulation and time integration of these governing equations, finite element code is developed to find nonlinear solution of four main variables (displacement-u, gas pressure-$P_g$), liquid pressure-$P_1$), and temperature-T) using Newton's iterative scheme. Three cases of numerical simulations are conducted and discussed: one-dimensional drainage experiments (u-$P_g-P_1$), thermal consolidation (u-$P_1$-T), and effect of pile on surrounding soil due to surface temperature variation (u-$P_1$-T).

Optimal Design Method of the Cooling Channel for Manufacturing the Hot Stamped Component with Uniform Strength and Application to V-bending Process (균일 강도 핫스템핑 부품의 제조를 위한 냉각채널 최적 설계 및 V-벤딩 공정에의 적용)

  • Lim, Woo-Seung;Choi, Hong-Seok;Nam, Ki-Ju;Kim, Byung-Min
    • Journal of the Korean Society for Precision Engineering
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    • v.28 no.1
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    • pp.63-72
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    • 2011
  • In recent years, hot-stamped components are more increasingly used in the automotive industry in order to reduce weight and to improve the strength of vehicles. In hot stamping process, blank is hot formed and press hardened in a tool. However, in hot stamping without cooling channel, temperature of the tool increases gradually in mass production thus cannot meet the critical cooling rate to obtain high strength over 1500MPa. Warpage occurs in the hot stamped component due to non-uniform stress state caused by unbalanced cooling. Therefore, tools should be uniformly as well as rapidly cooled down by the coolant which flows through cooling channel. In this paper, optimal design method of cooling channel to obtain uniform and high strength of the component is proposed. Optimized cooling channel is applied to the hot press V-bending process. As a result of measuring strength, hardness and microstructure of the hot formed parts, it is known that the design methodology of cooling channel is effective to the hot stamping process.

Shear Strain Big-Bang of RC Membrane Panel Subjected to Shear (순수전단이 작용하는 RC막판넬의 전단변형률 증폭)

  • Jeong, Je Pyong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.35 no.1
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    • pp.101-110
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    • 2015
  • Recently, nine $1397{\times}1397{\times}178mm$ RC panels were tested under in-plane pure-shear monotonic loading condition using the Panel Element Tester by Hsu (1997, ACI). By combining the equilibrium, compatibility, and the softened stress-strain relationship of concrete in biaxial state, Modern Truss Model (MCFT, RA-STM) are capable of producing the nonlinear analysis of RC membrane panel through the complicated trial-and-error method with double loop. In this paper, an efficient algorithm with one loop is proposed for the refined Mohr compatibility Method based on the strut-tie failure criteria. This algorithm can be speedy calculated to analyze the shear history of RC membrane element using the results of Hsu test. The results indicate that the response of shear deformation energy at Big Bang of shear strain significantly influenced by the principal compressive stress-strain (crushing failure).

Selection of Integrated Concepts Across Science and Humanities Using the Delphi Method (과학과 인문학의 통합개념 선정을 위한 델파이 연구)

  • Kim, Jiyoung;Park, Jieun;Yoon, Heojeong;Park, Eunmi;Bang, Dami
    • Journal of The Korean Association For Science Education
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    • v.34 no.6
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    • pp.549-558
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    • 2014
  • Integrated concepts that are broad enough to embrace facts, principles, laws, and concepts of multiple disciplines could become the core of integrated education. Integrated concept-centered education enables effective and practical learning. In this study, the Delphi Method was implemented targeting experts in science (physics, life science, chemistry, and earth science) and humanities (history, geology, economics, ethics, and politics) to find out the integrated concept that can be used to design the concept-centered integrated education in the Republic of Korea. 124 experts participated in this survey. Delphi survey was conducted for three rounds. In the first round, an open questionnaire was given to experts to collect feasible integrated concepts in each major field. Then, in the second round experts were asked to select integrated concepts that could be used practically in the field of their major. In the third round, the integrated concept with selection frequency over medium value were given. They were asked to evaluate the applicability of integrated concepts by using the Likert-scale questionnaire. Through this process, content validity was analyzed. As a result, five integrated concepts (change, interaction, space-time, energy, and equilibrium) were selected for the inter-science integration. And thirteen integrated concepts (conflict, community, relationship, structure, power, diversity, culture, change, society, interaction, freedom, justice, and equality) were chosen for the inter-humanities integration. Finally, for the science-humanities integration, seven integrated concepts (structure, diversity, change, interaction, cycle, system, and environment) were determined.

Mechanism and Activation Parameters $({\Delta}H^{\neq},\;{\Delta}S^{\neq}$ and ${\Delta}V^{\neq})$ of Electron Transfer Reaction Between $Co^{II}CyDTA\;and\;Fe^{III}$CN Complex Ions (Co(II)-CyDTA와 Fe(III)-CN 착이온간의 전자이동반응에서 활성화파라미터 $({\Delta}H^{\neq},\;{\Delta}S^{\neq}$${\Delta}V^{\neq})$ 와 반응메카니즘)

  • Yu Chul Park;Seong Su Kim
    • Journal of the Korean Chemical Society
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    • v.33 no.3
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    • pp.273-280
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    • 1989
  • The spectra of the $Co^{II}CyDTA$(CyDTA: cyclohexyldiaminetetraacetic acid) complex have been measured in aqueous solution of pH = 6-13.2. The red shift of the spectrum in the more basic solution was ascribed to the transformation of $CoCyDTA^{2-}$ into $CoCyDTA(OH)^{3-}$. The equilibrium constant, $K_{OH} = [CoCyDTA(OH)^{3-}]/[CoCyDTA^{2-}][OH^-]$ was $75M^{-1}$ at $40^{\circ}C$. The electron transfer reactions of $CoCyDTA^{2-}$ and $CoCyDTA(OH)^{3-}$ with $Fe(CN)_6^{3-}$ have been studied using spectrophotometric technique in the range of pH applied to the determination of equilibrium constant. The pseudo first-order rate constants observed ($k_{obs}$) were not changed upto pH = 10.8, but increased with increasing pH in the range of pH = $10.8{\sim}13.0$. The rate law reduced in the range of pH = 6-13 was $k_{obs} = (k_3[CoCyDTA^{2-}] + k_4[CoCyDTA(OH)^{3-}])/(1+K_1[CoCyDTA^{2-}])$. The rate constants of the reactions (3a) and (3b), $k_3$ and $k_4$ respectively have been determined to be 0.529 and $4.500M^{-1}sec^{-1}$ at $40^{\circ}C$. The activation entropies (147{\pm}1.1JK^{-1} mol^{-1}$ at pH = 10.8) and activation volumes $(6.25cm^3mol^{-1}, pH = 10.8)$ increased with increasing pH, while the activation enthalpy (12.44 ${\pm}$ 0.20 kcal/mole) was independent of pH. Using the pH effect on the rate constants, the activation entropies and the activation volumes, the mechanism of the electron transfer reaction for $Co^{II}-Fe^{III}$ system was discussed.

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