• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.08a
• /
• pp.210.1-210.1
• /
• 2013

ZnO는 태양전지의 투명전극 및 윈도우 물질로 그 동안 광범위하게 사용되어 왔다. 하지만 태양광의 효율 증가를 위하여서는 가시광 영역뿐만 아니라 자외선 및 적외선 영역을 이용할 필요가 있다. 또한 금속 산화물 반도체 나노 입자는 크기를 조절하여 흡수하는 태양광의 파장 영역을 조절할 수 있고 이를 이용하여 이종구조를 사지는 고효율의 태양전지를 구현할 수 있다. 본 연구에서는 3.4 eV의 에너지 밴드갭을 가지는 ZnO박막내에 밴드갭을 조절 할 수 있는 금속 산화물 나노입자를 삽입하여 광학적, 전기적 특성을 연구하였다. ZnO 박막을 증착하기 전 유리 및 사파이어 기판에 스퍼터를 사용하여 Pt금속전극을 형성한 이후, ZnO 박막을 $1{\times}10^{-10}$ Torr의 기본 진공도를 유지하는 초고진공 스퍼터를 사용하여 100 nm 두께로 증착 하였다. 금속 산화물 나노 입자를 제작 하기 위하여, ZnO 박막에 열증착 장비(thermal evaporator)를 사용하여 In 나노 입자를 10 nm 이하의 크기로 제작 하였다. 그 상부에 초고진공 스퍼터 와 열증착 장비를 사용하여 ZnO 박막 및 In 나노 입자를 순차적으로 증착하여 수백 nm 두께의 ZnO 박막을 제작한다. ZnO 박막 내부에 형성된 In 양자점은 ZnO 증착공정 중에 산화되어 $In_2O_3$ 의 산화물 나노 입자로 형성되며, 내부의 구조는 투과전자 현미경을 사용하여 확인 하였다. 제작된 금속 산화물 나노입자가 포함된 ZnO 박막의 광학적 특성을 photoluminescence, UV-Vis spectroscopy, ellipsometry를 통하여 확인 하였으며, solar simulator와 전류-전압 특정 장비를 사용하여 전기적 특성을 분석 하였다.

• Korean Journal of Optics and Photonics
• /
• v.14 no.3
• /
• pp.266-271
• /
• 2003

The reflectance spectrum of optical films thicker than a few microns shows an intensity oscillation due to interference. Since the spectral period of the oscillation is inversely related to film thickness, the thickness of an optical film can be determined from the spectral frequency of the oscillation. For rapid data processing, the spectral frequency is obtained by use of a Fast Fourier Transformation technique. The conventional method of applying a Fast Fourier Transformation to the reflectance spectrum versus photon energy is modified so as to clear the ambiguity in choosing the proper effective refractive index value and to prevent the broadening of the Fourier transformed peak due to the refractive index dispersion. This technique of modified Fast Fourier Transformation is suggested by the authors for the first time to their knowledge. From the analysis of the calculated reflectance spectrum of a 30-${\mu}{\textrm}{m}$-thick dielectric film. it is shown to improve the accuracy in determining film thickness by a great amount. The improved accuracy of the modified Fast Fourier Transformation is also confirmed from the analysis of the reflectance spectra of a sample with 80-${\mu}{\textrm}{m}$-thick cover layer and 13-${\mu}{\textrm}{m}$-thick spacer layer on a PC substrate.

• Membrane Journal
• /
• v.28 no.6
• /
• pp.388-394
• /
• 2018

Carbon nanotube (CNT) based membranes are promising candidates for separation membranes by showing high water transport rate and ion rejection rate according to their radii. The ion selectivity is an important factor to discover the full potential of CNT membranes, and it is affected by the functionalization of CNTs. With multivalent/size ion mixtures, the ion selectivity is affected by not only ion-functional groups interaction but also ion-ion interactions and ion size exclusion in a complex manner. In this study, molecular dynamics simulations are performed to study the ion selectivity of functionalized carbon nanotubes when multivalent/size ions are contained. The permeation energy barriers are calculated by plotting potential of mean force profiles, and various factors, such as CNT size and partial charges, affecting ion selectivity are investigated. The results presented here will be useful for designing CNT membranes for ion separation, biomimetic ion channels, etc.

• Journal of Korean Society of Coastal and Ocean Engineers
• /
• v.32 no.6
• /
• pp.420-433
• /
• 2020

In order to increase the stability of existing breakwater, new caissons are installed on the back or the front of existing caissons. It is very important to evaluate wave force and wave run-up according to the change of porosity among caissons and the energy loss due to separation effects. In this study, we use the eigenfunction expansion method with Darcy's law, which describes the flow of a fluid through a porous plate, to analyze the characteristics of wave on circular breakwater of double array for various porous coefficients. To verify the numerical method, the comparison between present results and Sankarbabu et al. (2008) is made. The wave force and the wave run-up acting on each dual cylindrical caisson are calculated for various parameters by considering the energy loss and the change of porosity.

• Membrane Journal
• /
• v.31 no.1
• /
• pp.1-15
• /
• 2021

The membrane-based CO2 capture is a fast-growing branch in gas separating field. Ionic liquid assisted mixed matrix membrane (MMM), which consists of organic fillers with dispersed ionic liquid, shows high potentiality as a candidate for CO2 separation medium. In MMM, various kinds of ionic liquid and inorganic filler are incorporated into polymer to enhance gas separating performance. Especially, the strong interaction between ionic liquid and organic filler gives huge influence on enhancing the separating performance by increasing affinity, selectivity and adsorption of CO2 into the framework. Also the mechanical properties of metal organic framework are positively tuned by input of ionic liquid to improve CO2 permeability and selectivity. In this review, study of various combinations of ionic liquid and metal organic framework (MOF) in the polymeric membrane for carbon dioxide separation is discussed.

• Membrane Journal
• /
• v.32 no.2
• /
• pp.83-90
• /
• 2022

Wastewater from refineries and petroleum plant lead to severe environmental pollution. There are various existing processes applied for oily water treatment, but membrane-based technology is one of the most efficient methods. Polymeric membranes prepared from organic materials for the separation of oil in water often face chronic problem of membrane fouling. Inorganic membranes are considered to be more efficient due to longer lifetime than organic membranes. Zeolite membranes have better chemical stability and long-term recyclability. The presence of hydrophilicity enhances the water flux of membrane. Ceramic membranes prepared from zeolites are another efficient class of inorganic membranes applied for oil water separation. This review is focused on oily wastewater separation based on zeolite membrane which classified into two categories, i) neat zeolite and ii) zeolite composites with other materials.

• Resources Recycling
• /
• v.31 no.5
• /
• pp.3-19
• /
• 2022

Electro-membrane technology is a process for separating and purifying substances in aqueous solution by electric energy using an ion exchange membrane with selective permeability, such as electrodialysis (ED) and bipolar electrodialysis (BMED). Electro-membrane technology is attracting attention as an environmental friendly technology because it does not generate by-products during the process and the recovered base or acid can be reused during the process. In this paper, we investigate the principles of ED and BMED technologies and various characteristics and problems according to the cell configuration. In particular, by investigating and analyzing research cases related to the treatment of waste sodium sulfate (Na₂SO₄), which is generated in large amounts during the metal recovery process.

• Membrane Journal
• /
• v.32 no.5
• /
• pp.336-347
• /
• 2022

Reverse electrodialysis (RED) is one of the promising eco-friendly renewable energy technologies which can generate electricity from the concentration difference between seawater and freshwater by using ion-exchange membranes as a diaphragm. The ion-exchange membrane is a key component that determines the performance of RED, and must satisfy requirements such as low electrical resistance, high permselectivity, excellent durability, and low manufacturing cost. In this study, pore-filled anion-exchange membranes were fabricated using porous polymer substrates having various thicknesses and porosity, and the effects of ion-exchange polymer composition and membrane thickness on the power generation performance of RED were investigated. When the electrical resistance of the ion-exchange membrane is sufficiently low, it can be confirmed that the RED power generation performance is mainly influenced by the apparent permselectivity of the membrane. In addition, it was confirmed that the apparent permselectivity of the membranes can be improved through IEC, crosslinking degree, membrane thickness, surface modification, etc., and the optimum condition must be found in consideration of the trade-off relationship with electrical resistance.

• Journal of Adhesion and Interface
• /
• v.24 no.2
• /
• pp.54-59
• /
• 2023

Silver nanowire-based transparent electrodes are very attractive as a next-generation flexible and transparent electrode that can replace ITO-based flexible electrodes because they have excellent conductivity, transmittance and mechanical flexibility. However, weak understanding of the silver nanowire solution for the fabrication of silver nanowire-based transparent electrodes often cause abnormal operation of the electrical device or peeling problem of the electrode films when applied to electronic devices. Here, we studied a Hydroxypropyl Methylcellulose (HPMC) adhesion promoter, which is one of the additives for silver nanowire solution, to improve the understanding of silver nanowire solution. In detail, it is characterized how the HPMC changes the properties of silver nanowire solution and silver nanowire film, which is fabricated with silver nanowire solution including the HPMC adhesion promoter. As the characteristics of solution, polar surface tension and dispersive surface tension were measured. As the film characteristics, surface energy, surface morphology, silver nanowire density, and sheet resistance were analyzed.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2021.06a
• /
• pp.279-279
• /
• 2021

위성영상정보는 센서의 종류, 취득, 분석, 재난과 위성영상 특성 매칭 등의 제약으로 재난 상황에서 제한적으로 사용되었다. 일반적으로 인공위성의 종류는 탑재한 센서의 정보제공 능력 범위에 따라 분류 가능하며 이에 따라 대상 범위가 결정된다. 본 연구에서는 재난의 예측, 탐지, 사후처리를 위한 위성자료의 취득과 활용을 위해 다양한 위성과 탑재된 센서의 궤도, 공간 해상도, 파장대 등의 특성에 대하여 분석하고 재난유형별로 최적 위성영상을 선정하였다. 행정안전부에서는 재난과 재해의 유형을 자연재난(10종)과 사회재난(27종)으로 분류하였다. 위성영상 활용이 가능한 재난 유형은 가시적으로 확인이 가능한 자연재난에 해당하며 그 중 태풍, 홍수, 가뭄, 산불 등 총 4종의 재난유형별로 가용한 최적의 위성영상을 분석하였다. 재난관측에 사용 가능한 대표적인 탑재체의 종류는 극궤도 지구관측 위성에서 광학과 SAR로 구분할 수 있다. 각 기본 특성에 따라 제공되는 정보의 종류가 분류되며 광학 센서는 태양복사 및 지구복사에너지 파장 영역 중 가시광선-근적외선-단파적외선-열적외선 파장대 영역의 분광 정보를 제공할 수 있는 다중 밴드들로 구성된다. 지표의 특정 대상이나 물질을 탐지하고 변화를 감지·분석하는데 유용하여 홍수, 태풍, 지진 등 자연 및 사회 재난·재해 관측에 유용하게 이용된다. SAR 센서는 장파장의 전자기파를 방출한 후 돌아오는 신호를 활용하여 대상에 대한 정보를 획득한다. 대기의 효과 및 요소를 투과하는 주파수 대역별 장파장 밴드 정보를 활용하여 고해상도의 대상 표면, 위치, 형태 등의 정보를 측량 및 관측하므로 중·광역 지역에 제약 없이 영상정보를 획득할 수 있어 산사태, 홍수, 지진, 등의 재난 모니터링에 유용하다. 이러한 다종 위성별 센서들의 특징(공간 해상도, 파장대별 밴드 특성, 관측폭, 재방문 주기 등)들을 분석하여 재난유형별로 가용한 무료/상용 지구관측위성을 분류한 결과 태풍에는 광역관측, 정지궤도 위성, 홍수에는 광학 및 SAR 고해상도 위성, 가뭄은 광역관측, 다분광 광학 위성 그리고 산불에는 정지궤도, 광학, SAR 위성이 적합함을 알 수 있다.