• Title/Summary/Keyword: 에너지 정의

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Determination of Quantum well Thickness of ZnO-ZnMgO core-shell Cylindrical Heterostructures by Interband Optical Transitions

  • Sin, Yong-Ho;No, Seung-Jeong;Kim, Yong-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.208-208
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    • 2013
  • ZnO는 직접천이형 반도체로 약 3.37 eV의 넓은 에너지 band-gap과 60 meV의 비교적 큰 엑시톤 결합 에너지를 가지고 있다. 또한 단결정 성장 가능과 투명성 등 많은 장점들로 인하여 GaN와 대체할 자외선 또는 청색 발광소자나 ITO를 대체할 투명전극 같은 광범위한 광전소자로 큰 주목을 받으며 연구되어 왔다. 이러한 ZnO는 다양한 물질들의 첨가를 통해 인위적으로 특성변화가 가능한데 Mg, Be, Cd 첨가를 통한 에너지 밴드갭의 확장과 수축, Al 첨가를 통한 전기전도성의 증가 등이 그 예이다. 최근에는 밴드갭 조절을 이용한 ZnO-ZnMgO와 같은 이종접합구조가 광소자 등의 응용을 목적으로 많은 연구가 이루어지고 있다. 더불어 나노선이나 나노막대 같은 1차원 구조를 갖는 ZnO 계열 반도체의 연구는 현재 큰 이슈가 되고 있는 나노 크기의 소자 개발에 매우 큰 적용 가능성을 가지고 있다. 우리는 수열합성법을 이용하여 hexagonal ZnO 나노막대를 성장하고 그 표면에 core-shell 형태의 $ZnO-Zn_{1-x}Mg_xO$ (x=0.084) 양자우물을 원자층증착법으로 증착하였다. 본 연구에서는 만들어진 ZnO 나노막대와 ZnO-ZnMgO 나노막대, core-shell ZnO-ZnMgO 양자우물 sample들의 저온(5 K) Photoluminescence 측정을 통하여 광학적 band 구조를 분석하였다. 실험적으로 의도된 양자우물 두께와 다른 실제 형성된 양자무물의 두께를 알아내기 위하여 2차원 hexagonal 양자우물 band 구조에서 self-consistent nonlinear Poisson-Schr$\"{o}$dinger 방정식 계산과 컴퓨터 시뮬레이션을 이용하였으며, 이 방법으로 계산된 값과 실험값의 비교를 통하여 실제 형성된 양자우물의 두께를 정량적으로 유출할 수 있었다.

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Material Life Cycle Assessment of Mg-CaO-10 wt.% MWCNT Hydrogen Storage Composites (수소저장용 Mg-CaO-10 wt.% MWCNT 복합체의 물질 전과정 평가)

  • HAN, JEONG-HEUM;LEE, YOUNG-HWAN;YU, JAE-SEON;HONG, TAE-WHAN
    • Journal of Hydrogen and New Energy
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    • v.30 no.3
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    • pp.220-226
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    • 2019
  • Magnesium hydride has a high hydrogen storage capacity (7.6 wt.%), and is cheap and lightweight, thus advantageous as a hydrogen storage alloy. However, Mg-based hydrides undergo hydrogenation/dehydrogenation at high temperature and pressure due to their thermodynamic stability and high oxidation reactivity. MWCNTs exhibit prominent catalytic effect on the hydrogen storage properties of $MgH_2$, weakening the interaction between Mg and H atoms and reducing the activation energy for nucleation of the metal phase by co-milling Mg with carbon nanotubes. Therefore, it is suggested that combining transition metals with carbon nanotubes as mixed dopants has a significant catalytic effect on the hydrogen storage properties of $MgH_2$. In this study, Material life cycle evaluation was performed to analyze the environmental impact characteristics of Mg-CaO-10 wt.% MWCNTs composites manufacturing process. The software of material life cycle assessment (MLCA) was Gabi 6. Through this, environmental impact assessment was performed for each process.

The Effects of Green Marketing Activities of New Energy Vehicle Companies on Purchase Intention: Focused on the Mediating Effects of Environmental Involvement (신에너지 자동차 기업의 그린마케팅 활동이 구매의도에 미치는 영향: 환경관여도의 매개효과를 중심으로)

  • Lyu, Yang;Jin, Chunhua
    • Journal of Digital Convergence
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    • v.20 no.5
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    • pp.93-98
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    • 2022
  • This research emphasized that the importance of green marketing activities elements such as green product, green price, green place, and green promotion. Moreover, it focused on verifying the effects of these four elements on purchase intention through environmental involvement. To verify this, an empirical analysis was conducted on Chinese consumers who have experienced or are considering purchasing a new energy vehicle. The research results are as follows. First, all four elements of green marketing activities improve environmental involvement. Second, environmental involvement was found to increase the level of purchase intention. Third, environmental involvement has a partial mediating effects in the relationship between the four elements of green marketing activities and purchase intention. Finally, the limitations of this study and future research directions were discussed.

The industrial trends of GaN substrates on the power electronic semiconductors (전력반도체용 GaN 기판 산업동향)

  • Lee, Hee Ae;Park, Jae Hwa;Lee, Joo Hyung;Park, Cheol Woo;Kang, Hyo Sang;In, Jun Hyeong;Shim, Kwang Bo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.4
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    • pp.159-165
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    • 2018
  • The demand on use of GaN single crystal substrates for high efficient and environment - friended high power electronic semiconductor has be increased. The industrial business trend on GaN substrate along with its research activities has been reviewed through the recent scientific and technical in formations on the basic of Yole report (2013). The research on the GaN single crystal substrate has been performed continuously for the purpose of the high quality and larger diameter, but its market has not been activated yet.

Optimal Soft Decision for Cooperative Spectrum Sensing in Cognitive Radio Systems (무선 인지 시스템에서 협력 스펙트럼 센싱을 위한 최적화된 연판정 방식)

  • Lee, So-Young;Kim, Jin-Young
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.4
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    • pp.423-429
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    • 2011
  • Cooperative spectrum sensing is proposed to overcome some problem such as multipath fading and shadowing and to improve spectrum sensing performance. There are different combining methods for cooperative spectrum sensing: hard decision method and soft decision method. In this paper, we analysis the performance of cooperative spectrum sensing with distance based weight that is kind of a soft decision rule for cognitive radio(CR) systems and CR systems sense the spectrum of the licensed user by using a energy detection method. Threshold is determined in accordance with the constant false alarm rate(CFAR) algorithm for energy detection. The signal of licensed user is OFDM signal and the wireless channel between a licensed user and CR systems is modeled as Gaussian channel. From the simulation results, the cooperative spectrum sensing with distance based weight combining(DWC) and equal gain combing(EGC) methods shows higher spectrum sensing performance than single spectrum sensing does. And the detection probability performance with the DWC is higher than that with the EGC.

Nuclear Magnetic Resonance Study of 23Na in NaMgCl3 Single Crystal (NaMgCl3 단결정 내의 23Na 원자핵에 대한 핵 자기 공명 연구)

  • Yeom, Tae Ho
    • Journal of the Korean Magnetics Society
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    • v.25 no.6
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    • pp.185-188
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    • 2015
  • We have investigated nuclear magnetic resonance of $^{23}Na$ nucleus in $NaMgCl_3$ single crystal in the temperature range 200 K~410 K using FT-NMR spectrometer. The spin-lattice relaxation times $T_1$ of $^{23}Na$ nucleus residing at cubic symmetry in the host crystal was measured as a function of temperature. The $T_1$ of $^{23}Na$ nucleus decreased with increasing temperature. The nuclear spin-lattice relaxation rate $1/T_1$ of $^{23}Na$ in $NaMgCl_3$ single crystal was proportional to the temperature T. This behavior is explained with the characteristic feature of the direct process between the nuclear spins and single phonon, $1/T_1$ being proportional to the absolute temperature. The activation energy calculated was $E_a=4.82J/mol$.

Oxidation of Ash Free Coal from Lignite and Anthracite Coals in a Molten Carbonate Fuel Cell (갈탄과 무연탄으로부터의 초청정석탄 제조 및 용융탄산염형 연료전지에서의 산화거동연구)

  • LEE, SANGWOO;KIM, YUJEONG;KIM, TAEKYUN;LEE, KIJEONG;LEE, CHOONGGON
    • Journal of Hydrogen and New Energy
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    • v.27 no.1
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    • pp.63-70
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    • 2016
  • In this study, ash free coals(AFCs) were produced with lignite and anthracite coals in a microwave. The AFCs were analyzed with proximate analysis, fourier transform infrared spectrometry (FTIR), X-ray diffraction analysis, and thermogravimetric analysis (TGA). The extraction yields of the AFCs were 16.4 wt%, 7.6 wt% at lignite and anthracite coal, respectively. The chemical and physical properties of the AFCs were similar regardless of the original coal types. Oxidation behavior of the AFCs was investigated by supplying a mixture of 3g of AFC and 3g of electrolyte into the coin-type molten carbonate fuel cell (MCFC). For the evaluation of AFC fuel performance, electrochemical analysis of the steady-state polarization and step-chronopotentiometry were conducted based on the standard hydrogen fuel (69 mol% $H_2$, 17 mol% $CO_2$, 14 mol% $H_2O$). The AFCs showed similar electrochemical oxidation behaviors regardless of the original coal types. The overvoltage of the AFCs was larger than the hydrogen fuel, although OCV of the AFCs was higher.

Limit State Assessment of SCH80 3-inch Steel Pipe Elbows Using Moment-Deformation Angle Relationship (모멘트-변형각의 관계를 이용한 SCH80 3인치 강재배관엘보의 한계상태 평가)

  • Kim, Sung-Wan;Yun, Da-Woon;Cheung, Jin-Hwan;Kim, Seong-Do
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.3
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    • pp.122-129
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    • 2020
  • To conduct probabilistic seismic fragility analysis for nuclear power plants, it is very important to define the failure modes and criteria that can represent actual serious accidents. The seismic design criteria for piping systems, however, cannot fully reflect serious accidents because they are based on plastic collapse and cannot express leakage, which is the actual limit state. Therefore, it is necessary to clearly define the limit state for reliable probabilistic seismic fragility analysis. Therefore, in this study, the limit state of the SCH80 3-inch steel pipe elbow, the vulnerable part of piping systems, was defined as leakage, and the in-plane cyclic loading test was conducted. Moreover, an attempt was made to quantify the failure criteria for the steel pipe elbow using the damage index, which was based on the dissipated energy that used the moment-deformation angle relationship.

Parametric Study on Earthquake Responses of Soil-structure Interaction System by Substructure Method (부분구조법에 의한 지반-구조물상호작용시스템의 지진응답 매개변수 연구)

  • 박형기;조양희
    • Journal of the Earthquake Engineering Society of Korea
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    • v.2 no.1
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    • pp.1-10
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    • 1998
  • In the dynamic soil-structure interaction(SSI) analysis, numerous uncertain parameters are involved. They include the uncertainties in the definition of input motions, modeling of soil-structure interaction systems. analysis techniques, etc. This paper presents the results of parametric studies of the seismic responses of a reactor containment structure built on the viscoelastic layered soil. Among the numerous parameter, this study concentrates on the effects of definition point of the input motion, embedment of structure to the base soil, thickness of the top soil layer, and rigidity of the base soil. The substructure method using frequency independent impedances is adopted. The method is based on the mode superposition method in time domain using the composite modal damping values of th SSI system computed from the ratio of dissipated energy to the strain energy for each model. From the study results, the sensitivity of each parameter on the earthquake responses has been suggested for the practical application of the substructure method of SSI analysis.

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Microstructural Evolution of $BaTiO_3$ Ceramics during the Cubin-Hexagonal Phase Transformation ($BaTiO_3$ 요업체에서 Cubic-Hexagonal 상전이에 따른 미세조직 변화)

  • 이태헌;이정아
    • Journal of the Korean Ceramic Society
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    • v.33 no.4
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    • pp.448-454
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    • 1996
  • The microstructural evolution of BaTiO3 ceramics during cubic-hexagonal phase transformation was investiga-ted. In the case of phase transformation from cubic to hexagonal BaTiO3 the hexagonal phase nucleated at the surface region of specimen. On the other hand in the case of that from hexgonal phase to cubic, cubic phase was initiated at the center region of specimen. And fast grain growth and irregular grain boundary shape could be also observed during these transformation processes. Besides low densified hexagonal BaTiO3 specimen was made with low forming pressure. The phase transformation of these specimens toward cubic phase was relatively retarded comparing with dense hexagonal BaTiO3 specimens. was made low forming pressure.. The phase transformation of these specimens toward cubic phase was relatively retarded comparing with dense hexagonal BaTiO3 specimens. These results were explained that hexagonal BaTiO3 had lowder surface energy than cubic phase.

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