• Title/Summary/Keyword: 에너지 정의

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Optimization and Elucidation of Esterification between Adipic Acid and 1,4-Butane Diol (Adipic acid와 1,4-butane diol의 에스테르화 반응 최적화 및 반응기작 규명)

  • Chung, Suk-Jin;Park, Soo-Nam
    • Korean Journal of Food Science and Technology
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    • v.35 no.3
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    • pp.399-404
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    • 2003
  • Aliphatic polyester, especially poly(butylene adipate)(PBA), is quite biodegradable and one of the most promising polymer materials to be commercialized. Bis(4-hydroxybutyl) adipate (BHBA) formation stage is the first principal process in the production of PBA from adipic acid (AA) and 1,4-butane diol (BD). In this study, we investigated for the effective production of Bis(4-hydroxybutyl) adipate (BHBA), effects of molar ratio of adipic acid (AA) to 1,4-butane diol (BD), catalyst (tetrabutyl titanate, TBT) concentration, and temperature on the reaction rate of esterification between AA and BD were investigated. Initial reaction rate of the esterification decreased with increasing molar ratio of AA to BD and reaction temperature, whereas reaction constant increased with increase in catalyst-concentration. Activation energy values for catalyzed and uncatalyzed esterifications were 198.5 and 94.8 kJ/mol, respectively.

Optimization of Biodiesel Production from Rapeseed Oil Using Response Surface Methodology (반응표면분석법을 이용한 유채유로부터 바이오디젤 생산의 최적화)

  • Jeong, Gwi-Taek;Yang, Hee-Seung;Park, Seok-Hwan;Park, Don-Hee
    • KSBB Journal
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    • v.22 no.4
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    • pp.222-227
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    • 2007
  • Biodiesel (fatty acid methyl esters) have used to as substitutes for petro-diesel by mixed-form with petro-diesel. In several processes of biodiesel production, alkali-catalyst transesterification produced to biodiesel of high contents with short reaction time. In this study, we investigate the optimal condition of alkali-catalyst transesterification of rapeseed oil produced at Jeju island in Korea using response surface methodology. The optimal condition of biodiesel production is reaction temperature 59.7$^{\circ}C$, catalyst amount 1.18%, oil to methanol molar ratio 1:8.75, and reaction time 5.18 min. At that reaction condition, the fatty acid methyl ester contents of product are above 97%. Our results may provide useful information with regard to the development of more economic and efficient biodiesel production system.

Optimization of Chlorella saccharophila Cultivation and Useful Materials Production (Chlorella saccharophila 배양 최적화 및 유용물질의 생산)

  • Kim, A-Ram;Park, Mi-Ra;Kim, Hyo Seon;Kim, Sung-Koo;Jeong, Gwi-Taek
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.74-79
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    • 2017
  • In this study, the optimization of several factors for Chlorella saccharophila cultivation was investigated. The studied factors were medium type, culture type, inoculum size, sugar/nitrogen source type and concentrations. As a result, the optimized conditions for C. saccharophila cultivation were found to be the best at 3% (v/v) inoculum, 30 g/L glucose and 0.95 g/L $NaNO_3$ under mixotrophic culture. Under the optimized condition, the content of oil was high at 12 day, whereas, the amount of biomass and chlorophyll were high at 10 day.

A Power Plane Using the Hybrid-Cell EBG Structure for the Suppression of GBN/SSN (GBN/SSN 억제를 위한 이종 셀 EBG 구조를 갖는 전원면)

  • Kim, Dong-Yeop;Joo, Sung-Ho;Lee, Hai-Young
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.18 no.2 s.117
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    • pp.206-212
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    • 2007
  • In this paper, a novel power/ground plane using the hybrid-cell electromagnetic band-gap(EBG) structure is proposed for the wide-band suppression of the ground bound noise(GBN) or simultaneous switching noise(SSN). The -30 dB stopband of the proposed structure starts from a few hundred MHz where the GBN/SSN energy is dominant. The distinctive features of this new structure are the thin spiral strip line and hybrid-cells. They realize the enhanced inductance and the shorter period of the EBG lattice. As a result, the lower cut-off frequency and bandwidth of the -30 dB stopband becomes lower and wider, respectively. In addition, the proposed structure has smaller number of resonance modes between power/ground planes and performs a low EMI behavior compared with the reference board.

Effect of ZrO2 Addition on the Microstructure and Electrical Properties of Ni-Mn Oxide NTC Thermistors (Ni-Mn 산화물 NTC 서미스터의 미세구조와 전기적 특성에 미치는 ZrO2첨가의 효과)

  • 박경순;방대영;윤성진;최병현
    • Journal of the Korean Ceramic Society
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    • v.40 no.1
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    • pp.11-17
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    • 2003
  • The effect of$ZrO_2$addition on the microstructure and electrical properties of Ni-Mn oxide NTC thermistors was studied. Major phases present in the sintered bodies of $Ni_{1.0}Mn_{2-x}Zr_xO_4$ were the solid solutions of Ni-Mn-Zr oxides with a cubic spinel structure and the $ZrO_2$ with a tetragonal structure. The $ZrO_2$ was formed by the partial decomposition or incomplete formation of the Ni-Mn-Zr oxides during sintering. With increasing the amount of added $ZrO_2$, the $ZrO_2$ phase increased. The relationship between log resistivity (log p) and the reciprocal of absolute temperature (1/T) of the NTC thermistors prepared was linear, indicative of NTC characteristics. The resistivity, B constant and activation energy of the thermistors increased with increasing $ZrO_2$ content.

Strength Analysis of Double Bottom Structures in Stranding by Idealized Structural Unit Method (이상화(理想化) 구조요소법(構造要素法)에 의한 좌초시(坐礁時) 이중저(二重底) 구조(構造)의 손상 및 강도(强度) 해석(解析))

  • Jeom-K. Paik;Chang-Y. Kim
    • Journal of the Society of Naval Architects of Korea
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    • v.28 no.1
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    • pp.125-138
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    • 1991
  • In this paper, an efficient method for the analysis of damage and strength of double bottom structure in stranding is described by using idealized structural unit method. Also a procedure for the determination of the effective double bottom height which is required in order to protect the inner-bottom plate is proposed. In the comparison between the present solution and he existing experimental and numerical results in stranding, its observed that the present method gives reasonable results requiring very shorts computiong times. The present method is then applied to the double bottom structure of 40K product oil carrier which is designed by the double skin design concept as an example. By performing the series of analysis, the influence of vertical member space, plate thickness and double bottom height on the energy absorption capacity of the double bottom structure in stranding is investigated. Also the minimum double bottom height with varying each design variable Is calculated based on the above result.

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Evaluation of Indoor Environment Characteristics through Field Measurement in Large-sized Discount Stores (현장측정을 통한 대형 할인매장의 실내환경 평가)

  • Park Byung-Yoon;Jung Yong-Ho;Ham Heung Don;Sohn Jang-Yeul
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.9
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    • pp.863-872
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    • 2005
  • It is important to control indoor environment for influence on health and comfort of occupants in large-sized discount stores. On the other hand large-sized discount stores have a large number of visitors, vestibules, open spaces, high energy consumption and increasing of outside air intake. This study aims to offer the design data of building services system that can save energy and control environment through field measurement selecting two large-sized discount stores. Indoor environment factors such as temperature, relative humidity, air velocity and concentrations of $CO_2$, CO gas and TSP were measured and evaluated. In each case of $CO_2$, and CO gas, its maximum values were 2,800 ppm and 20 ppm. So proper strategy for the indoor air quality is indispensable in this type of building. Dry bulb temperature varies from $18^{\circ}C$ to $28^{\circ}C$ according to a measuring point and time. From this results, it is inferred these buildings had excessive equipment capacity. In terms of economical and environmental points, these data will be utilized to the design of HVAC system of retail facilities.

Selection of Ventilation Rate and Filter for a Residential Housing in View of Indoor Particle Concentration (공동주택의 적정 환기량 및 필터의 선정 - 실내입자농도를 중심으로 -)

  • Noh, Kwang-Chul;Jung, Yee-Kyeong;Hwang, Jung-Ho
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.517-522
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    • 2008
  • Ventilation rate and filter were selected to simultaneously satisfy indoor air quality and minimize energy consumption in residential housing. The concentrations of indoor particles were calculated using an adapted mass balance model for various ventilation airflow rates. To satisfy the guidelines for indoor concentrations of particles, the minimum ventilation rates of 1.0/h, 0.6/h and 0.4/h were required for MERV11, MERV13 and MERV14, respectively. And the fan power consumptions induced by ducts, a heat exchanger and a filter were calculated for various ventilation airflow rates. The increase in the ventilation rate caused a dramatic increase in the power consumption, but the filter performance did not have much of an effect on the fan power for ventilation airflow rates lower than 0.4/h. The use of the ventilation filter of MERV 14 was suggested at a ventilation rate of 0.4/h when the fan power consumptions were considered in addition to the indoor concentrations of particles and $CO_2$. The use of the MERV14 filter at a ventilation rate of 0.6/h could be more effective than the additional use of an indoor air cleaner when the residential housing unit was ventilated.

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LHCP phosphorylation and Chlorophyll-Fluorescence Quenching of PSII in Ginseng Thylakoid Members (인삼 틸라코이드에서 광계II의 LHCP 인산화와 형광 Quenching)

  • 양덕조;김명원
    • Journal of Ginseng Research
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    • v.16 no.2
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    • pp.124-128
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    • 1992
  • Vsing the phosphorylated thylakoid membrane induced by 5-35kLux of light intensities, we investigated the chlorophyll nuorescence quenching of PSII and the phosphorylation of LHCPII i in relation to the chlorophyll-bleaching of Panax ginseng C.A. Meyer. In the Presence of DCMU, both of the fluorescence yield of non-phosphorylated thylakoid and the rate of fluorescence quencing dependent on the Phosphorylation were high p. ginseng more then Glyine max L. And at the high light F intensity (above 25 kLux) the fluorescence quenching rate of p. ginseng compared with that of G. max reached nearly to 2 times. The LHCPII of P. ginseng was composed of 3 major Polypeptides (24.5, 26 and 27kD) and 3 minor polypeptides (24, 25.3 and 28.3kD) in the region of 24-29kD and differed, from G. max in both of the number and quantity of polypeptides. Among these polypeptides, the phosphorylated polypeptide dependent on the light intensity was 24kD in P. ginseng.

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An Analysis of Consumption Patterns of High-Caffeinated Energy Drinks and Adverse Effects by Surveys from Students at Middle and High Schools in Korea (국내 중고등학생들의 고카페인 에너지음료 소비패턴 및 부작용에 대한 분석)

  • Yang, Young-Mo;Huh, Wan;Jeong, Eun;Lee, Jae-Joon;Choi, Eun Joo
    • YAKHAK HOEJI
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    • v.58 no.6
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    • pp.387-396
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    • 2014
  • High Caffeinated Energy Drink (HCED) consumption among adolescents has been exponentially increasing. The intake of HCED may cause various side effects. However, studies regarding intake of HCED in adolescents have been rarely implemented in Korea. The purpose of this study was to investigate HCED consumption patterns among adolescents and prevalence of adverse effects from HCED consumption and to compare them between middle and high school students. The self-reported questionnaire with 31 questions was used to evaluate HCED consumption patterns and adverse effects. Among 792 students, 455 who had drunken HCED were included in the analysis. Nine (4.0%) Middle School Students (MSSs) and 11 (4.8%) High School Students (HSSs) responded that they did not know HCED, and 188 (83.6%) MSSs and 221 (96.1%) HSSs had heard that HCED contains high amount of caffeine. Seventy-four (36.8%) MSSs drank their first HCEDs from curiosity and 63 (31.3%) MSSs to stay awake while studying. However, 134 (61.2%) HSSs consumed their first HCEDs to keep awake while studying, and 57 (26.0%) HSSs from curiosity. Twenty-eight (12.5%) MSSs and 46 (20.3%) HSSs had increase in heart rate, 52 (23.2%) MSSs and 83 (36.4%) HSSs insomnia, and 8 (3.6%) MSSs and 18 (7.9%) HSSs hand and facial tremor. As shown in this study, HCED consumption among adolescents in Korea was high. Thus, Korean government should continuously focus its efforts to educate not only children and adolescents but also their parents for HCEDs in order to increase parents' awareness of HCEDs and conduct education regarding HCED intake at home above all.