• Title/Summary/Keyword: 에너지 성능 평가

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Synthesis and Characteristic Evaluation of Downward Conversion Phosphor for Improving Solar Cell Performance (태양전지 성능향상을 위한 하향변환 형광체의 합성 및 특성평가)

  • Jae-Ho Kim;Ga-Ram Kim;Jin-To Choi;Soo-Jong Kim
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.5
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    • pp.523-528
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    • 2023
  • The applicability as a material to improve solar cell performance was reviewed by synthesizing a phosphor that emits red wavelengths by a liquid synthesis method using a metal salt aqueous solution and a polymer medium as a starting material. An aqueous solution was prepared using nitrate of metals such as Ca, Zn, Al, and Eu, and a precursor impregnated with starch, a natural polymer, was sintered to synthesize CaZnAlO:Eu phosphor powder. The surface structure and composition analysis of the synthesized CaZnAlO:Eu phosphor powder were analyzed by scanning electron microscope(SEM) and energy-dispersed X-ray spectroscopy(EDS). The crystal structure of CaZnAlO:Eu phosphor particles was analyzed by an X-ray diffraction analyzer (XRD). As a result of measuring the photoluminescence(PL) characteristics of the phosphor, it was confirmed that a red phosphor with a light emitting wavelength of 650-780nm was successfully synthesized. According to SEM and EDS analysis, the synthesized Ca14Zn6Al9.93O35:Eu3+0.07 phosphor powder has a uniform particle size, and Eu ions used as an activator are present. The synthesized CZA:Eu3+ phosphor can be used as a material that can increase the light absorption efficiency of the solar cell by converting ultraviolet or visible light down conversion into a wavelength in the near-infrared region.

Monovalent Ion Selective Anion-Exchange Membranes for Reverse Electrodialysis Application (역전기투석 응용을 위한 1가 이온 선택성 음이온교환막)

  • Ji-Hyeon Lee;Moon-Sung Kang
    • Membrane Journal
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    • v.34 no.1
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    • pp.58-69
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    • 2024
  • Reverse electrodialysis (RED) is an electro-membrane process employing ion-exchange membranes (IEMs) that can harvest electric energy from the concentration difference between seawater and river water. Multivalent ions contained in seawater and river water bind strongly to the fixed charge groups of the IEM, causing high resistance and reducing open-circuit voltage and power density through uphill transport. In this study, a pore-filled anion-exchange membrane (PFAEM) with excellent monovalent ion selectivity and electrochemical properties was fabricated and characterized for RED application. The monovalent ion selectivity of the prepared membrane was 3.65, which was superior to a commercial membrane (ASE, Astom Corp.) with a selectivity of 1.27 under the same conditions. Additionally, the prepared membrane showed excellent electrochemical properties, including low electrical resistance compared to ASE. As a result of evaluating RED performance under seawater of 0.459 M NaCl/0.0510 M Na2SO4 and river water of 0.0153 M NaCl/0.0017 M Na2SO4, the maximum power density of 1.80 W/m2 was obtained by applying the prepared membrane, which is a 40.6% improved output performance compared to the ASE membrane.

Anaerobic digestion technology for biogas production using organic waste (유기성폐기물의 혐기성 소화에 의한 바이오가스 생산 기술)

  • Kim, Hyoung-Gun;Lee, Dae-Sung;Jang, Hae-Nam;Chung, Tai-Hak
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.3
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    • pp.50-59
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    • 2010
  • A pilot-scale test for production of biogas was conducted in an specially designed anaerobic digester (KH-ABC) in which the highly concentrated organic waste (food-waste and piggery-manure) was treated. The effect of inhibitive material to the reaction on anaerobic digestion and the feasibility of digested fluid for the liquefied fertilizer were investigated. The production rate of biogas, the concentration of methane($CH_4$) in biogas, and the digesting rate of volatile solid(VS) were analyzed in the variance of the operating conditions ; the influent rate, the mixture ratio of food waste and piggery manure, and the hydraulic retention time(HRT), etc. The production rate of biogas increased from 1.2 to $2.0kg-VS/m^3{\cdot}d$ with the organic loading rate(OLR). The most suitable operating conditions were recorded at $6m^3/day$ of an influent rate, 2:3 of the raw material mixture ratio(food waste : piggery manure) and 25 days of HRT, respectively. Under those conditions, the production rate of biogas, the concentration of methane($CH_4$) in biogas and the digesting rate of volatile solid(VS) were $220m^3/day$, 64%, and 70%, respectively. The concentration of inhibitive materials was below toxic standard and the anaerobic digested fluid(raw material mixture ratio of 3:7) could meet the condition of the liquefied fertilizer.

Use of Numerical Simulation for Water Area Observation by Microwave Radar (마이크로웨이브 레이더를 이용한 수역관측에 있어서의 수치 시뮬레이션 이용)

  • Yoshida, Takero;Rheem, Chang-Kyu
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.3
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    • pp.208-218
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    • 2012
  • Numerical simulation technique has been developed to calculate microwave backscattering from water surface. The simulation plays a role of a substitute for experiments. Validation of the simulation was shown by comparing with experimental results. Water area observations by microwave radar have been simulated to evaluate algorithms and systems. Furthermore, the simulation can be used to understand microwave scattering mechanism on the water surface. The simulation has applied to the various methods for water area observations, and the utilizations of the simulation are introduced in this paper. In the case of fixed radar, we show following examples, 1. Radar image with a pulse Doppler radar, 2. Effect of microwave irradiation width and 3. River observation (Water level observation). In addition, another application (4.Synthetic aperture radar image) is also described. The details of the applications are as follows. 1. Radar image with a pulse Doppler radar: A new system for the sea surface observation is suggested by the simulation. A pulse Doppler radar is assumed to obtain radar images that display amplitude and frequency modulation of backscattered microwaves. The simulation results show that the radar images of the frequency modulation is useful to measure sea surface waves. 2. Effect of microwave irradiation width: It is reported (Rheem[2008]) that microwave irradiation width on the sea surface affects Doppler spectra measured by a CW (Continuous wave) Doppler radar. Therefore the relation between the microwave irradiation width and the Doppler spectra is evaluated numerically. We have shown the suitable condition for wave height estimation by a Doppler radar. 3. River observation (Water level observation): We have also evaluated algorithms to estimate water current and water level of river. The same algorithms to estimate sea surface current and sea surface level are applied to the river observation. The simulation is conducted to confirm the accuracy of the river observation by using a pulse Doppler radar. 4. Synthetic aperture radar (SAR) image: SAR images are helpful to observe the global sea surface. However, imaging mechanisms are complicated and validation of analytical algorithms by SAR images is quite difficult. In order to deal with the problems, SAR images in oceanic scenes are simulated.

Priority Decision of Small Hydropower Development using Spatial Multi-Criteria Decision Making (공간 다기준의사결정을 활용한 소수력 개발의 우선순위 결정)

  • Kim, Gil-Ho;Yi, Choong-Sung;Yeo, Gyu-Dong;Shim, Myung-Pil
    • Journal of Korea Water Resources Association
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    • v.42 no.12
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    • pp.1029-1038
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    • 2009
  • Recently, it is expected that small hydropower (SHP) could potentially provide sufficient amounts of alternative energy in Korea where there is an abundance of potential sites and where social efforts are being made to reduce the emissions of green house gases. In the past, the resources survey for SHP development has been carried out using onsite surveys and paper maps, which incurred a great deal of time and cost. Furthermore, the tools for decision making such as determining development priorities or evaluating feasibility have been considered only economic aspect and focused on the performance characteristics of power generation. However, as the concept of sustainable development has been being advanced in recent years, especially focused on human-social, environmental and ecological in addition to economical sector; the consideration of these multiple criteria has become essential for sustainable SHP development. This study aims to propose the spatial multi-criteria decision making (MCDM) methodology for determining priorities among a number of locations on the planning stage of SHP development using AHP and GIS. The proposed methodology is applied for determining development priorities among the SHP locations in Cho River basin and this study presents the detailed spatial information data and the results of development priorities. As a fundamental work, this study will be beneficial to the future activation of SHP development and will help the decision making in evaluating the feasibility of SHP development.

RF Magnetron Sputtering 및 Evaporation을 이용하여 증착한 CdTe 박막의 물성평가

  • Kim, Min-Je;Jo, Sang-Hyeon;Song, Pung-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.345-345
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    • 2012
  • 최근 의료산업에서는 고해상도 및 동영상 구현이 가능한 직접 방식의 X-선 검측센서에서 X-ray 흡수효율이 좋은 반도체 센서(CdTe, CdZnTe 등)와 성숙된 기술, 집적효율이 뛰어난 CMOS 공정을 이용한 제품을 출시하여 대면적화 및 고집적화가 가능하게 되어 응용분야가 점차 확대되고 있는 추세이다. 하지만 이 역시 고 성능의 X-선 동영상 구현을 위해서는 고 해상도 문제, 검출효율 문제, 대면적화의 어려움이 있다. 기존의 X-선 광 도전층의 증착은 증착 속도와 박막 품질에서 우수한 Evaporation 법이 사용되고 있다. 한편, 대면적에 균일한 박막형성이 가능하기 때문에 양산성에서 우월성을 가지는 sputtering법의 경우, 밀도가 높은 소결체 타겟의 제조가 힘들뿐만 아니라 증착 속도가 낮아 장시간 증착 시 낮은 소결밀도로 인한 타겟 Particle 영향으로 인해서 대 면적에 고품질의 박막을 형성하기가 어렵다. 하지만 최근 소결체 타겟 제조기술 발달과 함께, 대면적화와 장시간 증착에 대한 어려움이 해결되고 있어 sputtering 법을 이용한 고품질 박막 제조 기술의 연구가 시급한 실정이다. 본 연구에서는 $50{\times}50$ mm 크기의 non-alkali 유리기판(Corning E2000) 위에 Evaporation과 RF magnetron sputtering을 사용하여 다양한 기판온도 (RT, 100, 200, 300, $350^{\circ}C$)에서 $1{\mu}m$의 두께로 CdTe 박막을 증착하였다. RF magnetron sputtering의 경우 CdTe 단일 타겟(50:50 at%)을 사용하였으며 Base pressure는 약 $5{\times}10^{-6}$ Torr 이하까지 배기하였고, Working pressure는 약 $7.5{\times}10^{-3}$ Torr에서 증착하였다. 시편과 기판 사이의 거리는 70 mm이며 RF 파워는 150 W로 유지하였다. CdTe 박막의 미세구조는 X-ray diffraction (XRD, BRUKER GADDS) 및 Field Emission Scanning Electron Microscopy (FE-SEM, Hitachi)를 사용하여 측정하였다. 또한, 조건별 박막의 조성은 Energy Dispersive X-ray Spectroscopy (EDS, Horiba, 7395-H)을 사용하여 평가하였다. X-선 동영상 장치의 구현을 위해서는 CdTe 다결정 박막의 높은 흡수효율, 전하수집효율 및 SNR (Signal to Noise Ratio) 등의 물성이 요구된다. 이러한 물성을 나타내기 위해서는 CdTe 박막의 높은 결정성이 중요하다. Evaporation과 RF magnetron sputtering로 제작된 CdTe 박막은 공정 온도가 증가함에 따라 기판상에 도달하는 스퍼터 원자의 에너지 증가로 인해서 결정립이 성장한 것을 확인할 수 있었다. 따라서 CdTe 박막이 직접변환방식 고감도 X-ray 검출기 광도 전층 역할을 수행할 수 있을 것으로 기대된다.

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Simulation of Asymmetric Fuel Thermal Behavior Using 3D Gap Conductance Model (3 차원 간극 열전도도 모델을 이용한 핵연료봉의 열적 비대칭 거동 해석)

  • Kang, Chang Hak;Lee, Sung Uk;Yang, Dong Yol;Kim, Hyo Chan;Yang, Yong Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.3
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    • pp.249-257
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    • 2015
  • A fuel assembly consists of fuel rods composed of pellets (UO2) and a cladding tube (Zircaloy). The role of the fuel rods in the reactor is to generate heat by nuclear fission, as well as to retain fission products during operation. A simulation method using a computer program was used to evaluate the safety of the nuclear fuel rods. This computer program has been called the fuel performance code. In the analysis of a light water reactor fuel rod, the gap conductance, which depended on the distance between the pellets and cladding tube, mainly influenced the thermomechanical behavior of the fuel rod. In this work, a 3D gap element was proposed to simulate the thermo-mechanical behavior of the nuclear fuel rod, considering the gap conductance. To implement the proposed 3D gap element, a 3D thermo-mechanical module was also developed using FORTRAN90. The asymmetric characteristics of the nuclear fuel rod, such as the MPS (missing pellet surface) and eccentricity, were simulated to evaluate the proposed 3D gap element.

Inelastic Behavior of Post-tensioned Wide Beam System with different Reinforcement ratios within Column core (포스트텐션을 도입한 넓은 보에서 기둥 폭 내부에 배근된 보강재의 정착비에 따른 비탄성 거동 평가)

  • Choi Yun-Cheul;Lim Jae-Hyung;Moon Jeong-Ho;Lee Li-Hyung;Kwon Ki-Hyuk
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.85-94
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    • 2005
  • Post-tensioned Precast concrete System(PPS) consists of U-shaped precast wide beams and concrete column. The continuity of beam-column joint is provided with floor concrete cast on the PC shell beam and post-tensioning. The purpose of this paper is to evaluate the response of PPS interior beam-column joint subjected to cyclic lateral loading. To this end, an experimental investigation was performed with three half-scale specimens of interior connection. The design parameters are the amount of beam reinforcement placed inside the joint core. The test results showed that cracks were distributed well without my significant degradation of strength and ductility. Also, it was found that the prestressing may affect to alter the torsional crack angle. And the specimens sufficiently resist up to limiting drift ratio of 0.035 in accordance with the provisional by ACl of acceptance criteria for concrete special moment frames.

Biotechnology for the Mitigation of Methane Emission from Landfills (매립지의 메탄 배출 저감을 위한 생물공학기술)

  • Cho, Kyung-Suk;Ryu, Hee-Wook
    • Microbiology and Biotechnology Letters
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    • v.37 no.4
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    • pp.293-305
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    • 2009
  • Methane, as a greenhouse gas, is some 21~25 times more detrimental to the environmental than carbon dioxide. Landfills generally constitute the most important anthropogenic source, and methane emission from landfill was estimated as 35~73 Tg per year. Biological approaches using biocover (open system) and biofilter (closed system) can be a promising solution for older and/or smaller landfills where the methane production is too low for energy recovery or flaring and installation of a gas extraction system is inefficient. Methanotrophic bacteria, utilizing methane as a sole carbon and energy source, are responsible for the aerobic degradation (oxidation) of methane in the biological systems. Many bench-scale studies have demonstrated a high oxidation capacity in diverse filter bed materials such as soil, compost, earthworm cast and etc. Compost had been most often employed in the biological systems, and the methane oxidation rates in compost biocovers/boifilters ranged from 50 to $700\;g-CH_4\;m^{-2}\;d^{-1}$. Some preliminary field trials have showed the suitability of biocovers/biofilters for practical application and their satisfactory performance in mitigation methane emissions. Since the reduction of landfill methane emissions has been linked to carbon credits and trading schemes, the verified quantification of mitigated emissions through biocovers/biofilters is very important. Therefore, the assessment of in situ biocovers/biofilters performance should be standardized, and the reliable quantification methods of methane reduction is necessary.

A Study on the Validity of the Prediction of Binaural Parameters by 5 Channel Microphone System (5채널 마이크로폰 시스템을 활용한 공간감 지표 예측의 타당성에 관한 연구)

  • Jang Jae-Hee;Oh Yang-Ki;Jeong Dae-Up;Jeong Hyok
    • The Journal of the Acoustical Society of Korea
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    • v.24 no.2
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    • pp.103-110
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    • 2005
  • Providing adequate amount of spatial impression for spaciousness) has been known to be one of the most important design considerations for the good acoustics of rooms for music. and the measurement, of room acoustics using parameters. such as LEF and IACC, forms an essential part of such evaluation. However. it is unavoidable to use different transducers (figure of eight microphones. head and torso) for the measurement of each parameter and it tends to make the measurement procedure complicated. The Present work tried to provide a simpler way to measure these binaural room acoustic parameters including monaural ones with a single measurement system using both spatial information collected through a 5-channel microphone and a trained neural network. A computer simulation program, CATT-Acoustic V7.2. which allowed us to obtain exactly the same spatial information as a 5-channel microphone was used. since it requires quite a large amount of data for practical training of a neural network. Since each reflection has different energy. delay and direction, energy should be integrated properly. the concept of ray tracing method was applied inversely in this work. Also applying weightings according to the delay times was considered in this work. Finally, predicted results were compared with the measured data md their correlations were analyzed and discussed.