• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2003.05a
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• pp.633-638
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• 2003

현재, 각종 산업공정에서 발생하는 부생가스, 도시폐기물, 폐플라스틱, 바이오매스 등의 미활용 에너지원이나 석탄, 폐유 등을 가스화 혹은 열분해 하여 합성가스를 발생시켜 재활용하려는 연구가 활발히 진행하고 있다. 합성가스는 공업적으로 중요한 에너지원 및 화합물을 제조하는 가장 기초적인 반응가스인데, 합성가스를 제조하는 방법 중 가장 잘 알려진 천연가스 개질반응 이외에도 열분해/가스화 반응공정을 통해 제조되기도 한다.(중략)

• Resources Recycling
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• v.23 no.6
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• pp.47-53
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• 2014

Effective treatment and energy conversion technologies are necessary due to the ban of the dumping of organic waste including the sewage sludge. In this study, the kinetics of pyrolysis and combustion were derived in a TGA and thermobalance reactor, which is essential for thermal conversion of sewage sludge to energy. Three steps are shown for the pyrolysis in TGA and the different pre-exponential factors and activation energies are derived depending on the temperature range. Three models of gassolid reaction were applied to the reaction kinetics analysis for the combustion of sewage sludge char and shrinking core model was an appropriated model. Apparent activation energy and pre-exponential factor were evaluated and the effect of oxygen partial pressure was examined.

• Journal of radiological science and technology
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• v.32 no.2
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• pp.205-212
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• 2009

The response correction factor ( h) is a factor to convert the response of the chamber in solid phantom to the response in water. In RW3 solid phantom, the dependency of beam quality and depth for high energy X-rays are known characteristics, however the dependency of field size, SSD, and chamber type are unknown. In this work we have studied the unknown characteristics on the dependency of response correction factor. The farmer type chamber (FC65G) and small chamber (CC13) were used and two beam qualities of 6 and 15 MV were evaluated. The measured response correction factors at the depth of 5 cm and 10 cm were h = 1.015 and 1.021 for 6 MV X-rays, and h = 1.024 and 1.029 for 15 MV X-rays. In conclusion the response correction factor did not depend on the field size and SSD while depending on the beam quality and depth. In the chambers, there are small differences between the two chambers used in this study but we think additional study for more chambers should be required. The results in this study can be used for analyzing the measured values from ionization chamber dosimetry in RW3.

• Journal of the Korean Society of Propulsion Engineers
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• v.26 no.4
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• pp.28-43
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• 2022

To minimize such loss due to aging, research on energetic materials is being actively conducted though, there are difficulties in identifying the comprehensive aging mechanisms as they focused on the respective materials. In this study, thermal and surface analysis were performed on energetic materials composed of metals(W, Ti, and Zr) and KClO₄ oxidizer to solve the blind spots of this aging study. It was newly found that the metals in the hygrothermally aged compounds can cause significant changes in performance. For example, the growth in the thickness of the oxide film on the metals led to an increase in the average value of activation energy(E_α). In addition, the standard deviation of E_α tends to dependent on the type of metal, which is due to the difference in electronegativity.

• Proceedings of the Korea Water Resources Association Conference
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• 2012.05a
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• pp.511-511
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• 2012

강우침식인자는 강우사상(rainfall event)으로 인한 토양침식량을 산정하는 지표(index)로서 일정기간 토양침식의 정도를 산정할 수 있는 범용토양유식공식(Universal Soil Loss Equation)을 구성하고 있는 인자 중 가장 값의 변동성이 크고 동일한 조건에서 토양유실량 산정에 큰 영향을 미치는 인자다. 강우침식인자의 산정은 유량탐사 센서나 강우게이지 자료(pluviograph)로부터 12.7mm이상, 최소 15분간 6.35mm이상의 호우사상을 추출하여 해당하는 호우사상에 대한 강우에너지식에 30분 최대강우강도를 곱한 값의 연평균값을 계산한 것이다(Wischmeier and Smith, 1978). 본 연구에서는 범용토양유실공식(USLE)의 강우침식인 자(R)를 산정하고 지리정보시스템(GIS)을 활용하여 공간적 분포를 나타낼 수 있는 만경강 유역 상류부에 위치한 봉동 수위관측소 유역의 토양침식도를 연도별로 도시하였으며, 2001~2010년까지의 10개년 강우량을 바탕으로 토양침삭량을 산정하였다. 그 결과는 강우량이 많을수록 침식인자가 크게 산정되는 일반적인 결과를 기대 할 수 있지만, 2001~2010년까지 10개년 강우침식인자를 분석한 결과 강우량이 많다하여 침식인자의 변화 값이 크게 반응하는 값보다 강우강도에 의해 침식인자가 크게 반응하는 결과를 보였다. 따라서 강우침식인자는 강우량보다는 강우강도에 좌우됨을 알 수 있었다.

• Journal of the Korean Society of Radiology
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• v.5 no.5
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• pp.261-265
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• 2011

The purpose of this study is to calculate correction factors for energy dependence of a nanoDotdosimeter to measure patient's skin dose in diagnostic radiography. The correction factors were calculated by using the values of mean energy for the RQR standard radiation qualities of IEC publicated by Rosado et al. and the energy response graph of dosimeter relative X-ray on phantom calibration provided by landaur corporation. Results showed the correction factors of 1-1.33 over the tube voltage range of 40-50 kVp. Acquired correction factors are considered to be useful in the clinics for the measurement of accurate skin dose at each tube voltage.

• Proceedings of the Korea Information Processing Society Conference
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• 2001.04b
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• pp.841-844
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• 2001

원자력 발전소의 에너지를 생성하는 원자로의 동특성(Reactor Dynamic Characteristics)은 반응도(Reactivity) 영향인자가 변하여 원자로에 가해지는 외란(disturbances)에 의한 반응도 궤환(feedback)과 부가적으로 변하는 각종 원자로 계통의 설계변수 들에 대한 복잡한 노물리 현상을 통해 결정되며 이러한 현상을 이해하는 것은 원자력 발전소 종사자에게는 무척이나 중요한 일이다. 본 고에서는 가상현실 등 첨단기법을 이용하여 전력연구원에서 개발한 교육지원시스템(VRCATS)의 일환으로 강의실 이론 교육 시에 원격으로 시뮬레이터에 접속하여 각종 반응도 변화를 통한 원자로 노심상태 즉, 노심 내 전체 중성자속분포, 각종 온도 분포를 실시간으로 3 차원으로 보여주며, 시간에 따른 제논, 보론농도 등 반응도 변화 인자 및 총 반응도 변화추이 등을 감시 할 수 있는 컴퓨터 지원 노심설계 및 훈련 시스템(PREMARK) 개발 내용 및 특징을 기술하였다.

• Polymer(Korea)
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• v.38 no.6
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• pp.774-781
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• 2014

Acetylenic or phenylethynyl end-capped polyisoimide oligomers ($M_w$ 2500 g/mol, 5000 g/mol) based upon 4,4'-diamino diphenyl ether (4,4'-ODA)/4,4'-oxydiphthalic anhydride (ODPA) and 4,4'-ODA/3,3',4,4'-benzophenone tetracarboxylic acid dianhydride (BTDA) were synthesized by using 4-ethynylaniline (4-EA) or 4-phenylethynyl phthalic anhydride (4-PEPA) as an end capper. The incorporation of ethynyl groups were confirmed by FTIR spectroscopy. The isomerization temperature was influenced by molecular weight as well as the backbone structure of polyisoimides oligomers. Thus, polyisoimide oligomers with molecular weight of 2500 g/mol was found to be imidized at temperature $10^{\circ}C$ lower than that for the oligomers with molecular weight of 5000 g/mol. The crosslinking reaction of ethynyl groups occurred at a higher temperature than that for the isoimide/imide isomerization reaction. These two reactions were totally or partially overlapped on the DSC thermograms for the polyisoimide oligomer end-capped with 4-EA. Kinetics of thermal imidization and crosslinking reactions for the 4,4'-ODA/ODPA polyisoimide oligomers end-capped with 4-PEPA were investigated by performing dynamic DSC experiments at heating rate of $10^{\circ}C/min$. The activation energy and pre-exponential factors were 141 kJ/mol and $1.45{\times}10^{13}min^{-1}$ for the imidization reaction and 177 kJ/mol and $2.90{\times}10^{13}min^{-1}$ for the crosslinking reaction, respectively.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.547-553
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• 2017

Thermal analysis of three energetic materials used in pyroelectric device was performed using Differential Scanning Calorimetry (DSC). The theoretical method for extracting the reaction rate equation of energetic materials using DSC experimental data is proposed and the reaction rate extraction is performed. The results of the DSC were analyzed by the conversion method such as Friedman. Activation energy and frequency factor according to mass fraction were extracted to complete the reaction rate equation. The extracted reaction rate equation has a form that represents the entire chemical reaction process, not the assumption that the chemical reaction process of the high energy material is a main step in several stages. It has considerable advantages in terms of theoretical and accuracy as compared with the chemical reaction rate form extracted through conventional thermal analysis experiments. Using the derived reaction rate equation, we predicted the performance change of three energetic materials operating on actual storage condition over 20 years.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.1
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• pp.98-108
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• 2006

본 연구에서는 이 단계 연속 바이오 수소/메탄 생산공정의 경제성을 조사하였다. 경제적 관점에서 다양한 수소 및 메탄 발효용 생물반응기를 비교 평가하였다. 이를 바탕으로 포도당으로부터 일 단계 수소발효를 위해 고온 trickling biofilter 반응기 (TBR, $100\;m^3$ 규모)를, 일 단계 반응의 부산물로 생성된 유기산과 알콜류의 이 단계 메탄전환을 위해 고온 upflow anaerobic sludge 반응기 (UASB; $700\;m^3$ 규모)를 선정하였다. 본 이 단계 공정의 수소생산 비용은 $$\;0.26/Nm^3$으로 계산되었고, 이는 고온 TBR 반응기만을 이용한 경우보다 약 30 % 낮았다. 이 단계 공정의 낮은 수소생산 비용은 높은 에너지 회수율과 낮은 슬러지 처리비용에 의한 것이었다. 생물학적 수소 생산공정의 경제성은 탄소원의 종류, 생물반응기의 형태 등 여러 인자에 의해 변경될 수 있으나, 본 연구결과는 향후 연구를 위한 유용한 기준으로 고려될 수 있다.