• Proceedings of the Korean Geotechical Society Conference
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• 2010.09a
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• pp.1253-1257
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• 2010

그라우팅은 건설공사에서 지반의 갈라진 틈이나 공동, 공극 등에 적절한 충전재를 압력을 이용하여 주입하는 것으로, 굴착공사 시 누수방지와 불안정한 지반의 보강을 위하여 광범위하게 사용되고 있다. 가장 많이 사용되고 있는 그라우팅 주입재의 재료로는 물유리계를 주재료로 사용하는 약액주입공법이 많이 사용되어지고 있다. 기존의 물유리계 재료를 사용할 경우 발생하는 용출현상 및 강도저하를 보완하기 위하여 가소성을 부과한 무기질계 재료ECG(Eco Clean Grouting)를 사용하여, 강도 및 내구성이 우수하고 주입재의 용출 현상이 발생하지 않아 환경오염 문제가 거의 없는 영구적인 차수 및 보강에 적합한지와 친환경적 특성을 확인한다. 본 연구는 가소성 무기질계 재료인 ECG(Eco Clean Grouting)재료를 사용하여 현재 많이 사용되는 재료인 물유리계 재료로 일축압축강도, 체적변화, 내구성 평가, 투수시험, 어독성 시험, 용탈시험등을 수행하여 비교 분석 하였다. 일축압축 시험결과 재령 28일 강도는 ECG가 물유리재료에 비해 크게 발현되었고, 내화학성시험 결과 ECG의 길이변화율이 거의 없는 것으로 내화학성에서 강점을 보였다.

• Journal of Korean Tunnelling and Underground Space Association
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• v.12 no.1
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• pp.75-85
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• 2010

The focus of this study is to evaluate the field applicability of the newly developed inorganic thixotropic-grout in various ways. In order to do this, the volume stability and the permeability of the inorganic thixotropic-grout have been measured and compared to the existing silica type grouts. In addition, the filling capability of the grout into the tail void has been evaluated through both an experiment with a miniature tail-void filling equipment and a test filling at the shield TBM construction site. The volume loss of the inorganic thixotropic-grout after a 14 day-curing under the atmosphere condition was appeared to be minimal. The excellent waterproofing ability of the inorganic thixotropic-grout was confirmed through a permeability test. The toxicity of the inorganic thixotropic-grout has been evaluated through a toxicity test of aquatic fishes (KS M 0111) and the pH value of the liquid eluviated from inorganic thixotropic-grout was measured as an average of 8.0 and a fatality rate of goldfish after 96 hours was 10% or so. The existence of harmful heavy metals in the liquid eluviated from the inorganic thixotropic-grout has been also examined through an atomic absorption spectroscopy (AAS) test. Any of harmful heavy metals were not detected and the detected level of $Cr^{6+}$ and Cd was far below the standard. Based on both an experiment with a miniature tail-void filling equipment and a test filling at the shield TBM construction site, the filling ability of inorganic thixotropic-grout into the tail void was proved to be excellent.

• Korean Journal of Environmental Agriculture
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• v.4 no.2
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• pp.118-125
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• 1985

To establish an evaluation system of aquatic toxicity of chemicals at no-effect level, flow through and early life stage toxicity test were performed on a freshwater fish, the medaka (Oryzias latipes). The characteristics of medaka as a bioassay organism for the chronic toxicity test were discussed. Maximum acceptable toxicant concentration(MATC) of butachlor for the madaka in soft water was estimated using survival, growth, and reproduction as indicators of toxic effects. During a 3-month period, the fry of medaka were exposed to butachor concentrations ranging from 0.16 to 0.0l mg/liter and the DO concentration, temperature, and pH in the exposure chamber were measured to check the test condition. The highest concentration showed slight decrease of growth rate in medaka and reduced hatchability of spawning egg. Survival, growth, and reproductive success of adults in butachlor concentration of 0.04 and 0.01 mg/liter were not different from those of the control. The MATC was estimated to be between 0.04 and 0.16 mg/liter for medaka.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.1
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• pp.115-122
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• 2018

In order to conduct the "A Study on Experiment for Improvement of Water Quality in Concrete Block Using illite and $TiO_2$ Powder", as a result of the preliminary mortar experiment, water quality purification characteristic test, pollution-resistance test, fish poison test, and the related KS-equivalent tests after manufacturing the actual concrete block, the following conclusion were deduced. As a result of the concrete block functional evaluation equivalent to KS, all the conditions showed higher compressive strength. Even though increase of absorption rate, according to illite replacement in vesicular structure, was expected as a problem, it was replaced after mixing with Titanium dioxide, and then Titanium dioxide was settled in large pores of illite so there was no problem in absorption rate.

• Journal of the Korean Geotechnical Society
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• v.17 no.6
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• pp.47-51
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• 2001

There are two strategies to cope with the troubles in landfill site after closure. The first method is active in a way that the wastes are dug up and the recyclable materials are reutilized, meanwhile the materials not recyclable are incinerated in order to minimize the volume of residues to be disposed of. The second method is rather passive and defensive in a way that the source of contamination, that is, buried wastes are not treated. Instead, the transport of leaking leachate and gases generated from the wastes are intercepted and controlled. In this study, as a passive way of the efficient leachate blocking process, applicabilities of geocrete and soluble sodium silicate as a substitute to control leachate leaking from landfill sidewall were investigated. In case of compression test, the strength of mixture I (Geocrete:Sodium silicate=1:3.9 v/v) and mixture II (Geocrete:Sodium silicate=1:2.5 v/v), even after 7 days' curing was higher than the minimum allowance to tolerate the loading(5 kg/$\textrm{cm}^2$). Soaking in the acid fur 4 days and 7 days respectively, the compressive strength of the specimens reduced seriously. The toxicity of geocrete is not detected through the bioassay test, once it was mixed with sodium silicate and the complex was formed. The hydraulic conductivity of the mixtures even after 7 days' curing was lower than the threshold limit $(1.0\times10_{-7}cm/s)$.

• The Korean Journal of Pesticide Science
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• v.17 no.4
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• pp.343-349
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• 2013

Environment-friendly agro-materials tend to be preferred to chemical insecticides recently. For this reason, many studies are conducted to develop environment-friendly insecticides containing natural materials. The purpose of this study was to assess ecotoxicity for pepper extract and cassia oil (11.5+46%, A), pepper extract and cassia oil (23+34%, B), and pepper extract and lavender oil (40+10%, C). They are expected to prevent from pests especially diamondback moth, and can be used for agro-materials. Their formulation was emusifiable concentration (EC). Target species used to assess acute toxicity were aquatic invertebrate (Daphina magna), fish (Cyprinus carpio), honeybee (Apis mellifera L.) and earthworm (Eisenia fetida). The $EC_{50}$ value of A, B, and C to aquatic invertebrate were 0.46, 1.9, 0.25 mg $L^{-1}$ respectively and these values were moderately toxic according to standard of USEPA. In case of acute toxicity test to fish, the $LC_{50}$ of A, B, and C were 1.9, 2.9, 3.8 mg $L^{-1}$ respectively. A was category II in acute toxicity of fish and not acceptable to evaluation criteria of environment-friendly agro-materials. B and C were category III and acceptable. Acute contact and oral toxicity test to honeybee were conducted and the $LD_{50}$ of A, B, and C were > 100 ${\mu}g$ a.i. $bee^{-1}$ in both of tests. It indicated they were low toxic to honeybee. In case of acute toxicity test to earthworm, $LC_{50}$ of A, B, and C were 695, 988, and 564 mg $kg^{-1}$. In conclusion, pepper extract+cassia oil 57% EC and pepper extract+lavender oil 50% EC were expected to be used for environment-friendly insecticide materials with low risk against ecosystem and contribute to developing environment-friendly agro-materials.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1998.11a
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• pp.156-161
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• 1998

As grouting materials for ground improvement, silicate materials such as water glass, silica-sol and so forth are used worldwide. However, they may pollute underground water. In this study, fish poison test(Korean standard industrial code KS M 0111) which estimates toxicity for fish is applied to evaluate the toxic effect by grouting materials. From the test result of the sample made of LW, LC50(Median Lethal Concentration) reaches within 24 hours. In case of the silica-sol, it does not even in 96 hours. Therefore, we can conclude that the sililca-sol grouting method is more free from the danger of underground water pollution. From the result that the mortality of fish under the condition of pH 8.6 is 0% within 96 hours, the groundwater can be saved by controlling pH below 8.6 for the grouting in the field.

• Journal of the Korean Geotechnical Society
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• v.32 no.3
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• pp.29-37
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• 2016

SSG (self-healing smart grouting) method, which is developed recently, has the characteristics such as an improvement of durability and waterproofing, prevention of leaching and pollution. In this study, we performed several tests such as gel-time measurement, uniaxial compression test, permeability test, fish poison test and chemical resistance test to compare the engineering properties of SSG with the other chemical grouting method (LW, SGR). As results of tests, the SSG method has low possibility of groundwater and ground pollution caused by leaching, furthermore, it has advantages like long/short term waterproofing, strength and durability. Therefore the SSG method can be applicable in the fields as an alternative of existing chemical grouting methods with problems.

• Journal of the Korean GEO-environmental Society
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• v.6 no.4
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• pp.65-71
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• 2005

Recently, difficulties in soft ground improvement that caused by effectiveness of the ground improvement, the durability and environmentally friendliness of the injection material come to the fore. This paper studies the field applicability of the SCM in reinforcement and seepage cutoff of the back of an existing continuous wall. SCM uses double rod which imposes heavy pressure($10-100kgf/cm^2$) to disturbed, cut, discharge, and mix the ground. It is observed that a bulb is formed by using cement paste and environmentally friendly injection materials with minimal alkali leaching. Unconfined compression test and fish poison tests are performed. Test results indicate that the method results in higher durability, less leaching through use of the environmentally friendly injection material, and faster mobilization of the strength. In addition, field tests confirm the formation of the bulb and the seepage cutoff wall.

• Journal of the Korean Geosynthetics Society
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• v.20 no.2
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• pp.1-11
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• 2021

In this study, a study related to laboratory and pilot test were performed to use an environmental soil stabilizer developed to induce a hardening reaction similar to that of Ordinary Portland Cement (OPC) by using industrial by-products of blast furnace slag and the combustion ash of a circulating fluidized bed boiler as the main material. For this, specimens were prepared using liquid A of sodium silicate and silica sol, and liquid B of an environmental soil stabilizer (or OPC), and laboratory tests were performed to analyze the strength and environmental characteristics. And pilot test was performed on the aging reservoir, field permeability test and electrical resistivity survey were performed in the field to analyze the applicability. As a result of the laboratory test, the homo-gel compressive strength of the chemical injection material using the environmental soil stabilizer as liquid B was about 2.88 to 3.23 times greater than that of OPC. In addition, the elution amount of most heavy metals was lower than that of OPC, and the survival rate in the fish, acute toxicity test was 100%. Therefore, when judged based on the results of the laboratory test, it was analyzed to be superior to OPC in terms of strength and environment. In the results of the pilot test in the aging reservoir, when the environmental soil stabilizer was reinforced with liquid B of the chemical injection material, the coefficient of permeability in the aging reservoir decreased to 1/50 level. In addition, as a result of the electrical resistivity survey, it was analyzed that the electrical resistivity inside the aging reservoir increased as time passed, the saturation zone disappeared, and the overall reinforcement.