• Title/Summary/Keyword: 양의 인자분석법

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Investigation on the optical, structural and electrical properties of the RF sputtered layers obtained from CuInSe2 single precursors (CuInSe2 단일전구체에서 스퍼터링된 박막의 광학적, 구조적 및 전기적 특성평가)

  • Jeong, Chaehwan;Kim, Saerok;Kim, Jinhyeok;Kim, Kwangbok
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.78.2-78.2
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    • 2010
  • Cu(In,Ga)Se2 (CIGS)박막태양전지는 간단한구조와 가격경쟁력 및 고효율화 가능성에 대한 기대감에 의해 많은 연구가 수행되어오고 있다. 특히 높은 흡수계수와 적절한 밴드갭, 큰 결정크기와 같은 물질의 특성들이 장점으로 작용하고 있기 때문이다. 또한 CIGS박막태양전지는 다른 태양전지에 비해 광열화가 적다는 장점도 가지고 있다. CIGS 박막은 CuInSe2내의 In 사이트에 Ga을 도핑함으로서 형성이 되는데 그때의 밴드갭은 약 1.4eV이며 이를 형성하기 위해 많은 방법들이 제안되고 있는데, CIGS박막 형성 시 가장 중요시 여겨야 될 인자는 구성원소로부터 최적화된 조성비를 찾는 것이다. 이러한 관점에서 볼때 evaporation법이나 sputtering법같은 진공방식의 공정법이 비진공방식에 비해 최적의 조성비를 찾는 것이 수월할 것으로 생각된다. selenization을 하기전에, 동시증착이나 다층박막형성을 통해 Cu-In-Se의 조합이 일반적으로 이루어진다. 어떤방법이든 Se의 부가적인 공급이 이루어지는데 시작 전구체의 조합에서 그 해법을 제시하는 것에 대한 논의가 많이 부족한 현실로서, CuInSe2의 단일전구체에 의한 박막형성과 특성평가에 대해 구체적인 논의가 필요하다. 본 실험에서는 Cu-In-Se 전구체를 CuInSe2 단일 타겟에서부터 RF 마그네트론 스퍼터링법을 이용하여 박막증착을 하여 Se의 Rapid Thermal Process(RTA)법을 통해 Se이 순차적으로 공급되었다. 이때 형성되는 박막의 태양전지 흡수층 적용을 위한 광학적, 전기적 및 구조적에 대한 논의된다. Soda lime glass(SLG)와 Corning 1737 유리를 기판으로 하여 아세톤-에탄올을 이용, 초음파세척을 실시하였다. 스퍼터 공정을 하기전에 흡착된 물분자를 제거하기 위하여 약 30분간 $120^{\circ}C$로 열을 가해주었으며, 공정을 위한 총 아르곤 가스의 양은 약 50sccm이며 이때의 공정압력은 20mtorr로 고정하였다. 우선 RF power와 기판온도에 따른 단일전구체 형성을 관찰하기 위하여 각각 30~80W, RT~$400^{\circ}C$로 변화를 주어 박막을 형성한 후 모든 sample에 대하여 $500^{\circ}C$분위기에 effusion cell을 이용하여 Se 분위기에서 결정화를 실시하였다. 샘플의 두께는 Surface profiler로 측정하였고 단면은 전자주사현미경으로 관찰되었다. 동시에 SEM이미지를 통하여 morphology와 grain size 및 EDX를 통하여 조성분석을 하였다. 밴드갭, 투과율 및 흡수계수는 UV-VIS-NIR분광분석법을 통하여 수행되었으며, 전기적 특성분석을 위해 4-point-probe와 Hall effect측정을 수행하였다. 공정변수에 따른 단일타겟으로 얻어 결정화된 CuInSe2박막의 자세한 결과와 논의에 대하여 발표한다.

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Increased Matrix Metalloproteinase-9 and Tissue Inhibitor of Metalloproteinase-1 Levels in the Cerebrospinal Fluid from Children with Aseptic Meningitis (무균성 뇌수막염 소아에서 뇌척수액내 Matrix Metalloproteinase(MMP)-9과 Tissue Inhibitor of Metalloproteinase(TIMP)-1의 증가)

  • Yang, Ju Hee;Park, Min Hyuk;Shim, Jung-Yeon;Jung, Hye Lim;Park, Moon Soo;Keum, Dong Hyuck
    • Clinical and Experimental Pediatrics
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    • v.46 no.6
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    • pp.548-553
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    • 2003
  • Purpose : Matrix metalloproteinase(MMP)-9 is known to breakdown the blood-brain barrier by degrading the extracellular matrix of the subendothelial basement membrane in meningitis. Tissue inhibitor of metalloproteinase(TIMP)-1, a known inhibitor of MMP-9, has been postulated to inhibit the proteolytic activity of MMP-9 by bindng to MMP-9, but their interaction has not been fully understood yet. So far, there have been some reports on the relationship of MMP-9 and TIMP-1 in bacterial meningitis, but few reports in viral meningitis. Furthermore, there has been no report on this in Korea. We investigated the concentrations of MMP-9 and TIMP-1 in cerebrospinal fluid (CSF) and serum of patients with viral meningitis and control subjects, and evaluated their relationship with other clinical parameters of meningitis. Methods : CSF and blood were obtained from 25 subjects with viral meningitis and 14 control subjects. After centrifugation, supernatants were stored at $-20^{\circ}C$ and we assayed concentrations of MMP-9 and TIMP-1 by the sandwich ELISA method. Results : Concentrations of CSF MMP-9 and TIMP-1 were significantly elevated in patients with viral meningitis, when compared with those in control subjects. Their serum levels showed no differences between the two groups. MMP-9 levels were closely correlated with TIMP-1 levels in the CSF($r_s=0.42$, P<0.05). CSF MMP-9/TIMP-1 ratios were significantly higher in patients with viral meningitis than those in the control subjects(P<0.05). Both CSF MMP-9 and TIMP-1 levels positively correlated with CSF total leukocyte counts($r_s=0.43$, P<0.05, $r_s=0.48$, P<0.05). TIMP-1 levels positively correlated with total protein concentrations in the CSF($r_s=0.43$, P<0.05). Conclusion : MMP-9 and TIMP-1 may play an important role in the breakdown and maintenance of BBB in viral meningitis, respectively.

Factors Associated with Renal Scar in Children with Vesicoureteral Reflux (방광 요관 역류가 있는 소아에서 신반흔 형성과 관련된 인자들)

  • Kim Kyoung Hee;Jang Sung Hee;Lee Dae-Yeol
    • Childhood Kidney Diseases
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    • v.5 no.1
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    • pp.43-50
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    • 2001
  • Purpose : The urinary tract infection associated with vesicoureteral reflux(VUR) in children may result in serious complications such as renal scarring, hypertension, proteinuria and end stage renal disease. The purpose of this study was to evaluate the factors affecting renal scar such as age, gender, grade of VUR, and ACE gene polymorphism, and body growth in the patients with and those without renal scar associated with VUR Methods : During the period from January 1994 to July 2000, We had 93 children with urinary tract infection associated with VUR who were admitted to the Department of pediatrics of Chonbuk National University Hospital. The patients were divided into two groups according to follow up 99mTc-DMSA renal scan; patients with renal scar group and those with non-scar group. We analyzed and compared the factors associated with renal scarring between the two groups. Results : There were no significant difference in gender, causative organism, ACE gene polymorphism, height and weight at diagnosis between renal scar group and non-scar group. Fifty four patients were in renal scar group and forty seven of them had VUR. The age at diagnosis was significantly higher in renal scar group (2.48${\pm}$2.64yr) than in non renal scar group (1.26${\pm}$1.83yr). Especially, the infants who were less than 1 year of age with VUR developed relatively more renal scar compared with infants older than 1 tear of age. The incidence of renal scarring showed a direct correlation with the severity of VUR. Conclusion : The factors affecting renal scar formation were age at diagnosis, presence and grade of VUR, but the other factors such as gender, causative organism, ACE gene polymorphism were not associated with renal scarring. Therefore, further evaluation about uropathogenic E coli and foflow up study about body growth associated with severity of renal scar would be necessary. (J. Korean Soc Pediatr Nephrol 5 : 43- 50, 2001)

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Production of Total Reducing Sugar and Levulinic Acid from Brown Macro-algae Sargassum fulvellum (거대 갈조류 모자반으로부터 환원당과 레불린산의 생산)

  • Jeong, Gwi-Taek
    • Microbiology and Biotechnology Letters
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    • v.42 no.2
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    • pp.177-183
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    • 2014
  • Recently, many biofuels and chemicals converted from renewable resources have been introduced into chemical industries. Sargassum fulvellum is a brown macro-algae, which is found on the seashores of Korea and Japan. In this work, the production of total reducing sugar and levulinic acid from S. fulvellum, using dilute-acid catalyzed hydrothermal hydrolysis and statistical methodology, was investigated. As a result, 15.28 g/l total reducing sugar was obtained under the optimized conditions of $160.1^{\circ}C$, 1.0% sulfuric acid, in 20.2 min. Furthermore, 2.65 g/l levulinic acid was obtained at $189.5^{\circ}C$, 2.93% sulfuric acid, in 48.8 min.

Clinical Characteristics of Intensive Care Unit Patients with Carbapenem Resistant Acinetobacter Baumannii Isolated from Sputum (객담에서 Carbapenem 내성 Acinetobacter baumannii가 동정된 중환자실 환자의 임상적 특징)

  • Lee, Sung Won;Jo, Heui Sug;Kim, Woo Jin
    • Tuberculosis and Respiratory Diseases
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    • v.60 no.2
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    • pp.228-234
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    • 2006
  • Background : Acinetobacter baumannii is an important pathogen associated with nosocomial infections in intensive care units, and is responsible for nosocomial pneumonia, UTI, bacteremia, etc. The main concern is that this pathogen is often resistant to many antimicrobial agents, particularly to carbapenem. This study compared the clinical those of ICU admitted patients with the carbapenem resistant A. baumannii isolated from the sputum with characteristics of patients with carbapenem sensitive A. baumannii. Methods : A total of 49 patients with A. baumannii from a sputum culture who were admitted to the ICU from January to December 2003 were enrolled in this study. This study evaluated the demographic variables, mortality, APACHE II score, comorbidity, antibiotics used, hospital and ICU stay, Clinical Pulmonary Infection Score, and mechanical ventilation. A retrospective analysis was made by a review of the patients' medical records. Results : Carbapenem sensitive and resistant A. baumannii was isolated from 23 patients and 26 patients respectively. Univariate analysis revealed renal disease, the use of carbapenem and aminoglycoside to be statistically significant factors for carbapenem resistance. Multivariate analysis revealed carbapenem use(p=0.024; OR, 8.17; CI 1.32 to 50.68) to be positively associated with carbapenem resistance, and aminoglycoside use(p=0.026; OR, 0.18; CI, 0.04 to 0.82) to be negatively associated with carbapenem resistance. There was no significant difference in mortality between the carbapenem sensitive and resistant group(30 vs 42%. P=0.39). Conclusion : The occurrence of carbapenem resistant A. baumannii is positively associated with carbapenem use and negatively associated with aminoglycoside use. Carbapenem resistance in the sputum culture did not affect the mortality rate.

Studies of Specific Foods to Absolute Intake and Between-Person-Variance in Various Nutrients Intake (농촌거주 청소년의 식이조사에서 나타난 영양소의 주된 공급식품과 변이식품의 양상)

  • 김영옥
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.6
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    • pp.892-900
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    • 1995
  • Dietary data of 538 middle school students have been analysed to identify the contribution of specific foods to absolute intake and between-person-variance in nutrient consumption. The 24-hour-dietary-recall method had been used to collect the data required. Contribution of specific foods, in terms of ranking order for both absolute intake and between-person-variance have been observed. Ranking order of food for absolute intake was given based on the percen of contribution whereas the ranking order of foods for between-person-variance was given based on the percent of contribution whereas the ranking order of foods for between-person-variance was given based on a coefficient fo variation. As a result, for most of the nutrients(except cholesterol), the ranking order of foods for the between-person-variance was quite different from that of absolute intake. The results indicate that to identify between-person-variance of nutrient intake in an epidemiology study, foods with a high ranking in between-person-variance should be included in developing the food frequency questionnaires rather than foods which showed a high ranking in absolute intake.

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The Factors Affecting Accurate Quantitaion of Proteinuria Using Sp ot Urine Protein/Creatinine Ratio in Children (소아 단백뇨 검사에 있어서 단회뇨 단백 크레아티닌 비에 영향을 미치는 요인)

  • Jung, Ji-Mi;Kwon, Eun-Ji;Chung, Woo-Yeong
    • Childhood Kidney Diseases
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    • v.12 no.2
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    • pp.150-156
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    • 2008
  • Purpose : Many results have reported a correlation between the spot urine protein/creatinine ratio(P/C ratio) and 24-hour urinary protein(24UP) amount. This study was designed to evaluated correlation between 24UP amounts and P/C ratio in children and to find the factors that affect this correlation. Methods : 210 patients who visited the Department of Pediatrics in Busan Paik Hospital from september 2003 to december 2007 were included in this study. All the patients were divided into I, II, III/A, B, C group[I:24UP(mg/$m^2$/day)]<100, II: 100$\leq$24UP<1,000, III: 24UP$\geq$1,000, A: Cr excretion(mg/kg)<15, B: 15$\leq$Cr excretion<25, C: Cr excretion$\geq$25)]. Pearson correlation analysis was performed between 24UP and P/C ratio to evaluate the relationship. We defined fractional difference between 24UP and P/C ratio, and then performed multiple regression analysis. Results : There was a strong positive linear correlation between 24UP and P/C ratio in all patients, and the correlation was also good in each group. The factors affecting accurate quantitation of proteinuria using spot urine P/C ratio was creatinine excretion. Conclusion : Spot urine P/C ratio is a useful test to predict proteinuria roughly. Therefore, we expect that urine P/C ratio can be used as parameter instead of 24UP, if we set cutoff value of P/C ratio considered to creatinine excretion according to age and sex in large pediatric population.

Construction of Three Dimensional Soil Cadmium Pollution Map Using Geotechnical Information DB System (국토지반정보시스템을 이용한 3차원 토양오염지도 구축)

  • Hwang, Dae Young;Kang, In Joon;Jang, Yong Gu;Kim, Soo Kyum
    • Journal of Korean Society for Geospatial Information Science
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    • v.24 no.4
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    • pp.13-19
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    • 2016
  • This study presented the build-up of three-dimensional soil pollution map for precise analysis. To do this, survey on the existing pollutant region on Dongnae-gu, Busan that is the study subject, showed that it tended to produce 0.72 clusters. So, this study suggested to investigate center of $1km{\times}1km $ grid and, as the results of comparing the pollution map that input pollution figure values based on the actually investigation point showed precise results. And, it divided the standard of pollution into 5 levels in surface and underground space and the map was built up using IDW interpolation against the amount of polluted substance. The pollution of ground surface, flow of polluted substance, coefficient of permeability and ground water level that are 504 geotechnical informations were selected as the influential parameters in pollution analysis of underground space, and it calculated that to 0~20 points by dividing the characteristics. It enables the build-up of pollution map of ground surface-underground with depth that considers the characteristics of soil layers and it is considered that it is possible to analyze the general infiltration. And, it was considered that it enables more accurate forecast about influential analysis per depth and pollution of underground water.

Imputation of missing precipitation data using machine learning algorithms (머신러닝 알고리즘을 이용한 결측 강우 데이터 추정에 관한 연구)

  • Heechan Han
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.320-320
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    • 2023
  • 강우 데이터는 수문기상, 환경, 농업, 자연재해, 그리고 수자원 시스템 분야에서 가장 필수적인 기본 요소 중 하나이다. 또한 강우 데이터는 수문학적 분석에서 활용되는 필수 입력 자료 중 하나로 관측 데이터의 품질에 따라 수문 모형을 이용한 모의 결과물의 정확도가 결정된다고 할 수 있다. 따라서, 강우 관측소별로 강우 데이터의 품질을 어떻게 관리하느냐에 따라 수문 모형의 활용 범위 및 수자원 관리의 효율성이 결정될 수 있다. 강우의 시공간적 변동성은 수 많은 인자들과 직간접적으로 연계되어 있기 때문에 미계측 강우 자료에 대해 직접 관측이 아닌 수치 모형을 이용하여 강우의 발생과 강우량을 산정하는 것은 매우 복잡한 과제 중 하나이다. 현재 국내에서 운용되고 있는 강우 관측소의 경우에도 미계측 된 강우 데이터가 존재함으로써 강우 데이터의 활용에 제한이 생기는 경우가 있다. 따라서, 이러한 미계측 데이터의 추정 및 보완은 보다 효과적인 수재해 방지, 수자원 관리를 위한 필수 과제 중 하나이다. 일반적으로, 미계측 강우를 산정하기 위해서 Kriging, Thiessen, 등우선법, 그리고 역거리 관측법 등 다양한 수문학적 방법들이 적용되고 있다. 이러한 방법들은 산악효과나 강우 관측소의 분포 상태 등을 고려하지 못하기 때문에 측정하는 지역에 따라 강우 추정 오차가 커질 수 있다는 한계가 있다. 최근에는 데이터 관측 시스템과 빅데이터 기술의 발전과 활용 가능한 데이터의 양이 증가함에 따라 머신러닝을 활용한 사례가 증가하고 있다. 머신러닝은 데이터 사이의 관계를 기반으로 분류, 회귀, 그리고 예측 문제에 주로 사용되는 기법 중 하나이다. 따라서, 본 연구에서는 광주광역시 지역에 위치한 주요 강우 관측 지점들을 대상으로 미계측 된 시강우 데이터를 추정 및 복원하고자 한다. 여기서 데이터 추정 기술이란 미계측 강우의 발생 유무 및 강우량을 추정할 수 있는 기술을 의미한다. 이를 위해 대표적인 머신러닝 알고리즘인 인공신경망(Artificial Neural Network) 및 랜덤포레스트(Random Forest)를 적용하였다.

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Introduction of Denitrification Method for Nitrogen and Oxygen Stable Isotopes (δ15N-NO3 and δ18O-NO3) in Nitrate and Case Study for Tracing Nitrogen Source (탈질미생물을 이용한 질산성 질소의 산소 및 질소 동위원소 분석법 소개)

  • Lim, Bo-La;Kim, Min-Seob;Yoon, Suk-Hee;Park, Jaeseon;Park, Hyunwoo;Chung, Hyen-Mi;Choi, Jong-Woo
    • Korean Journal of Ecology and Environment
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    • v.50 no.4
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    • pp.459-469
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    • 2017
  • Nitrogen (N) loading from domestic, agricultural and industrial sources can lead to excessive growth of macrophytes or phytoplankton in aquatic environment. Many studies have used stable isotope ratios to identify anthropogenic nitrogen in aquatic systems as a useful method for studying nitrogen cycle. In this study to evaluate the precision and accuracy of denitrification bacteria method (Pseudomonas chlororaphis ssp. Aureofaciens ($ATCC^{(R)}$ 13985)), three reference (IAEA-NO-3 (Potassium nitrate $KNO_3$), USGS34 (Potassium nitrate $KNO_3$), USGS35 (Sodium nitrate $KNO_3$)) were analyzed 5 times repeatedly. Measured the ${\delta}^{15}N-NO_3$ and ${\delta}^{18}O-NO_3$ values of IAEA-NO-3, USGS 34 and USGS35 were ${\delta}^{15}N:4.7{\pm}0.1$${\delta}^{18}O:25.6{\pm}0.5$‰, ${\delta}^{15}N:-1.8{\pm}0.1$${\delta}^{18}O:-27.8{\pm}0.4$‰, and ${\delta}^{15}N:2.7{\pm}0.2$${\delta}^{18}O:57.5{\pm}0.7$‰, respectively, which are within recommended values of analytical uncertainties. Also, we investigated isotope values of potential nitrogen source (soil, synthetic fertilizer and organic-animal manures) and temporal patterns of ${\delta}^{15}N-NO_3$ and ${\delta}^{18}O-NO_3$ values in river samples during from May to December. ${\delta}^{15}N-NO_3$ and ${\delta}^{18}O-NO_3$ values are enriched in December suggesting that organic-animal manures should be one of the main N sources in those areas. The current study clarifies the reliability of denitrification bacteria method and the usefulness of stable isotopic techniques to trace the anthropogenic nitrogen source in freshwater ecosystem.