• Title/Summary/Keyword: 액화기술

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업계동향 - 충전소 비상발전기 보유 관련 기준 개정 안내

  • 한국LP가스공업협회
    • LP가스
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    • v.23 no.4
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    • pp.24-25
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    • 2011
  • 현행 LPG충전소는 액화석유가스 충전시설의 시설기준 및 기술기준(액법 시행규칙 별표 3, 16항 및 KGS CODE 331~334)에 따라 비상발전기를 무조건 보유해오고 있었으나, 우리협회는 지식경제부 및 한국가스안전공사 등에 지속적 건의를 통해 관련규정 "비상전력설비 설치기준(KGS CODE)"을 개정(2011.07.27 시행)하여 비상발전기를 선택적으로 보유할 수 있도록 하였으니 충전소 운영에 참고하시기 바랍니다.

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Trend and Subject in Welding Technique of LNG Aboceground Storage Tank (지상식 LNG 탱크의 용접기술 현황과 향후 동향)

  • Kouzuki, Haruya;Ogawa, Tsuneshi
    • Journal of Welding and Joining
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    • v.13 no.3
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    • pp.18-33
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    • 1995
  • 천연가스는 지구상에서 비교적 광범위하게 생산되며 구미 등에서는 대부분 pipe line으로 소비지까지 운송하여 사용하고 있지만 일본 등에서는 액화 천연가스 (LNG)로 저장, 수송하여 사용하고 있다. LNG 저장탱크는 생산측의 액화기지와 사용측 의 수입기지에 설치되며 지금까지 약 240기가 건설되어 있다. 종래 탱크 1기의 용량 은 대부분 6 - 8만m$^{3}$ 규모였지만, 토지의 유효이용 등으로 대형화되고 있으며, 또 지상식에서는 PC(Prestressed Concrete)의 방파제를 외부탱크에 근접시켜 외부탱크 와 일체화시킨 PC LNG 탱크가 개발.설계되었다. 일본에서는 이미 이 방식으로 세계 최대규모인 14만m$^{3}$ 탱크가 건조되어 가동 중이다. LNG의 주성분은 메탄이고 비등점은 -161.5.deg.C로 극저온이다. 이러한 저온에서도 취화되지 않고 사용할 수 있는 재료는 9%Ni강, Al 합금, 스테인레스강 및 Invar 등이 있지만, 탱크의 대형화에 따라 가공성, 용접성 및 경제성을 고려하여 요즈음은 9%Ni강이 주로 사용되고 있다. 한편 9%Ni강용 용접재료는 고Ni계 합금 및 모재와 동일한 성분계의 공금계가 있지만 지금까지 고 Ni계 합급이 주로 사용되고 있다. 본 내용에서는 9%Ni강을 사용한 지상식 평지원통형 LNG 탱크를 예로 들어 탱크의 개요 및 용접재료, 용접시공 등을 포함한 용접기술에 대해서 개괄적으로 설명하고자 한다.

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Effect of Temperatures to Crude Oil Productions with Rapeseed Straw on Application of Hydro-thermal Liquefaction Technology (Hydro-thermal Liquefaction Technology적용 시 유채대를 이용한 Crude oil생산에 미치는 반응온도의 영향)

  • Shin, JoungDu;Hong, Seung-Gil;Kwon, Soon-Ik;Park, Woo-Kyun;Park, SangWon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.1
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    • pp.104-109
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    • 2010
  • Hydro-thermal liquefaction technology for rapeseed straws was investigated the biomass conversion rate with different catalysts and reaction temperatures. NaOH and KOH were used for catalysts, and the reaction temperature were ranged from 180 to $320^{\circ}C$ at every $20^{\circ}C$ of intervals for 10 minutes. The reaction was carried out in a 5,000 mL liquefaction system with dispenser and external electrical furnace. Raw materials (160g), 2,000 mL of distilled water and 10% (wt/wt) of catalyst to plant residue were fed into the reactor. It was observed that the maximum crude oil yield was about 36% at temperature range, $260{\sim}280^{\circ}C$ with KOH and at $300^{\circ}C$ with NaOH, respectively. It was observed that the more calorific values of crude oil, the higher reaction temperature with KOH, but it had the reverse pattern in NaOH.

Steam Reforming of Hydrothermal Liquefaction Liquid from Macro Algae over Ni-K2TixOy Catalysts (Ni-K2TixOy 촉매를 이용한 해조류 유래 수열 액화 원료의 수증기 개질 반응 연구)

  • Park, Yong Beom;Lim, Hankwon;Woo, Hee-Chul
    • Clean Technology
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    • v.23 no.1
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    • pp.104-112
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    • 2017
  • Hydrogen production via steam reforming of liquefaction liquid from marine algae over hydrothermal liquefaction was carried out at 873 ~ 1073 K with a commercial catalyst and Ni based $K_2Ti_xO_y$ added catalysts. Liquefaction liquid obtained by hydrothermal liquefaction (503 K, 2 h) was used as a reactant and comparison studies for catalytic activity over different catalysts (FCR-4-02, $Ni/K_2Ti_xO_y-Al_2O_3$, $Ni/K_2Ti_xO_y-SiO_2$, $Ni/K_2Ti_xO_y-ZrO_2/CeO_2$ and Ni/$K_2Ti_xO_y$-MgO), reaction temperature were performed. Experimental results showed Ni/$K_2Ti_xO_y$ based catalysts ($Ni/K_2Ti_xO_y-Al_2O_3$, $Ni/K_2Ti_xO_y-SiO_2$, Ni/$K_2Ti_xO_y-ZrO_2$/ $CeO_2$ and Ni/$K_2Ti_xO_y$-MgO) have a higher activity than commercial catalyst (FCR-4-02) and In particular, a product composition was different depending on support materials. An acidic support ($Al_2O_3$) and a basic support (MgO) led to a higher selectivity for CO while a neutral support ($SiO_2$) and a reducing support ($ZrO_2/CeO_2$) resulted in a higher $CO_2$ selectivity due to water gas shift reaction.

Hydrogen Production by Steam Reforming of Liquefied Natural Gas (LNG) over Nickel Catalyst Supported on Surfactant-templated Mesoporous Alumina (계면활성제를 이용하여 제조된 중형기공성 알루미나 담체에 담지된 니켈촉매 상에서 액화천연가스(LNG)의 수증기개질반응에 의한 수소 제조)

  • Seo, Jeong-Gil;Youn, Min-Hye;Song, In-Kyu
    • Clean Technology
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    • v.15 no.1
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    • pp.47-53
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    • 2009
  • Mesoporous aluminas (A-C, A-A, and A-N) were prepared by a templating method using cationic(C), anionic(A), and non-ionic(N) surfactant as a structure-directing agent, respectively. Nickel catalysts supported on mesoporous alumina (Ni/A-C, Ni/A-A, and Ni/A-N) were then prepared by an impregnation method, and were applied to hydrogen production by steam reforming of liquefied natural gas (LNG). Regardless of surfactant type, nickel species were finely dispersed on the surface of mesoporous alumina in the calcined catalysts. It was revealed that interaction between nickel species and support in the reduced catalysts was strongly dependent on the identity of surfactant. LNG conversion and $H_2$ composition in dry gas increased in the order of Ni/A-C < Ni/A-A < Ni/A-N. It was found that catalytic performance increased with increasing nickel surface area in the reduced catalyst. Among the catalyst tested, Ni/A-N catalyst with the highest nickel surface area showed the best catalytic performance.

Numerical Study on the Characteristics of Butane Fuels (부탄 연료의 연소 특성에 관한 수치해석적 연구)

  • Choi, Sul-Ki;Baik, Doo-Sung;Lee, Jong-Sun
    • Proceedings of the KAIS Fall Conference
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    • 2009.12a
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    • pp.897-899
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    • 2009
  • 본 연구는 수치해석 코드를 사용하여 액화석유가스의 연소 특성을 파악하고자 한다. 시뮬레이션은 Chemkin 코드를 적용하여 정적연소와 같은 조건에서 모델링되었다. 특히 연소 현상을 파악하기 위해서 당량비를 변화시켰다. 이러한 연구는 LPG 연료를 사용하는 압축착화 디젤엔진의 기초적인 연구에 도움을 줄 것이다.

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Compressed Natural Gas Bus & Liquefied Petroleum Gas Vehicle (압축천연가스(CNG)버스와 액화석유가스(LPG)자동차)

  • 윤재건
    • Journal of the Korean Professional Engineers Association
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    • v.34 no.3
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    • pp.28-32
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    • 2001
  • Using the CNG(compressed natural gas) and LPG(liquified petroleum gas) as the automotive fuel will be expanded because of their clean effect to the environmental air qualify. But these programs of gas using expansion would have a difficulty due to public consideration of gas utilities as a big hazard. The Ministry of Environment has an ambitious plan to substitute more than 25,000 buses with CNG and ensure more than 200 CNG refueling stations as well by the year of 2007. However, it is very difficult to establish new CNG and LPG refueling stations because of expanded safety distance than ever before by several major explosion accidents.

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Performance Analysis of Direct Expansion and Organic Rankine Cycle for a LNG Cold Power Generation System (LNG냉열발전시스템에 있어서 직접팽창 및 유기랭킨사이클의 운전성능평가)

  • Cho, Eun-Bi;Jeong, Moon;Hwang, In-Ju;Kang, Choon-Hyoung
    • Transactions of the KSME C: Technology and Education
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    • v.3 no.1
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    • pp.55-62
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    • 2015
  • The liquefaction to produce LNG (liquefied natural gas) is the only practical way for mass transportation of natural gas across oceans, which accompanies considerable energy consumption in LNG plants. Power generation is one of the effective utilization ways of LNG cold energy which evolves during the vaporization process of LNG with sea water. In this work, performance analysis of two cold energy generation processes, direct expansion and organic Rankine cycles, were carried out by using Aspen HYSYS simulation. The results show that the performance of the organic Rankine cycle is superior to the direct expansion.

Investigation of ground condition charges due to cryogenic conditions in an underground LNG storage plant (지하 LNG 저장 시험장에서 극저온 환경에 의한 지반상태 변화의 규명)

  • Yi Myeong-Jong;Kim Jung-Ho;Park Sam-Gyu;Son Jeong-Sul
    • Geophysics and Geophysical Exploration
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    • v.8 no.1
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    • pp.67-72
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    • 2005
  • To investigate the feasibility of a new concept of storing Liquefied Natural Gas (LNG) in a lined hard rock cavern, and to develop essential technologies for constructing underground LNG storage facilities, a small pilot plant storing liquid nitrogen (LN2) has been constructed at the Korea Institute of Geoscience and Mineral Resources (KIGAM). The LN2 stored in the cavern will subject the host rock around the cavern to very low temperatures, which is expected to cause the development of an ice ring and the change of ground condition around the storage cavern. To investigate and monitor changes in ground conditions at this pilot plant site, geophysical, hydrogeological, and rock mechanical investigations were carried out. In particular, geophysical methods including borehole radar and three-dimensional (3D) resistivity surveys were used to identify and monitor the development of an ice ring, and other possible changes in ground conditions resulting from the very low temperature of LN2 in the storage tank. We acquired 3D resistivity data before and after storing the LN2, and the results were compared. From the 3D images obtained during the three phases of the resistivity monitoring survey, we delineated zones of distinct resistivity changes that are closely related to the storage of LN2. In these results, we observed a decrease in resistivity at the eastern part of the storage cavern. Comparing the hydrogeological data and Joint patterns around the storage cavern, we interpret this change in resistivity to result from changes in the groundwater flow pattern. Freezing of the host rock by the very low temperature of LN2 causes a drastic change in the hydrogeological conditions and groundwater flow patterns in this pilot plant.

Characteristics of $SF_6$ Gas Recycling Processes ($SF_6$가스 회수 공정들의 특성 연구)

  • Cho, Hoon;Woo, Dae-Sik;Choi, Yu-Mi;Han, Myung-Wan
    • Clean Technology
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    • v.17 no.4
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    • pp.329-335
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    • 2011
  • $SF_6$ gas is well known as a global warming gas. Global warming potential of $SF_6$ gas is 22,000 times higher than that of $CO_2$. Recycling of $SF_6$ gas is an essential technology for the sake of the environment and the economy. The recovery processes of $SF_6$ gas studied in this work were liquefaction, distillation, and crystallization processes because these processes were thought to be easily carried to the fields for recycling waste $SF_6$ gas. The processes were simulated and optimized using Aspen plus. The optimization problems were formulated to minimize energy consumption with satisfying product specification and desired recovery. The performance of the processes was compared based on the optimization results. Effects of major process variables on the recovery performance were investigated and optimal operation guide for changing product specification and product recovery was provided.