• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2017.05a
• /
• pp.643-646
• /
• 2017

In a liquid rocket engine using hydrocarbon fuels, cooling of the combustion chamber wall is necessary to prevent the combustion chamber wall from melting or structurally deforming due to high heat flux. Among the various methods, regenerative cooling, which uses fuel as a coolant and then injects it into the combustion process, has good performance. This study investigated the heat transfer characteristics of kerosene as a coolant by varying the copper cross-sectional area, the flow rate in the channel, and the current applied to the channel. Convective heat transfer occurred rapidly when the cross-sectional area of the copper channel was small and when the kerosene flow velocity was fast.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2017.05a
• /
• pp.991-994
• /
• 2017

In hypersonic aircraft, increase of aerodynamic and engine heat lead thermal load in airframe. It could lead structural change of aircraft's component and malfunctioning. Endothermic fuels are liquid hydrocarbon fuels which are able to absorb the heat load by undergoing endothermic reactions. In this study, we investigated the method of measuring the heat sink of catalyst by using exo-tetrahydrodicyclopentadiene as a fuel in a packed bed flow reactor similar to the actual reaction conditions.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1997.04b
• /
• pp.27-28
• /
• 1997

최근 들어 분리공정의 발달과 산업의 고도화에 따라 기체 및 액체분리의 중요성이 강조되면서 열적, 화학적 그리고 기계적 안정성이 좋으며, 수명이 길고, 세척과 재생이 용이하며, 미생물에 의한 손상이 없는 무기막에 대한 연구가 진행중이다. 무기막은 기공의 크기에 따라 크게 다공성 막과 비다공성 막의 두 종류로 구분된다. 비다공성 금속막은 특정 기체에만 투과성을 가지며, 이때 기체는 용해-확산(solution-diffusion)기구에 의해 금속막을 투과하므로 특정기체에 대한 선택도는 매우 크나 투과도가 매우 작고 가격이 비싼 단점을 가지고 있다. 다공성 막은 기체 투과율이 큰 반면 기체 선택도가 작은 단점을 가지고 있다. 현재 기체분리에 사용되고 있는 무기막은 기공크기가 40${\AA}$ 이상으로 기체 분리가 Kundsen diffusion에 의해 이루어지므로, 기체 투과도는 큰 반면에 기체에 대한 선택도는 그리 크지 않다. 따라서 최근 들어서는 다공성 담체에 기공이 작은 ($d_{pore}<20{\AA}$)박막을 담지시켜 기체의 분리 선택도를 향상시키기 위한 연구가 활발히 이루어지고 있다. 본 연구에서는 유기금속 화학증착법(metal-organic chemical vapor deposition:MOCVD)을 이용하여 수소 선택성을 가지는 $SiO_2/Al_2O_3$ 복합막을 비율별로 제조하여 증착속도를 알아보고, 열과 수분에 노출시켜 박막의 기체투과도 변화를 살펴보았다.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2000.02a
• /
• pp.36-36
• /
• 2000

KSTAR 토카막은 보조가열 장치로 2005년까지 1대(최종적으로는 2대)의 중성입자빔 입사장치(NBI)를 설치하여 장치의 기본 설계값에 도달할 예정이다. KSTAR NBI는 3개의 이온원을 가지고 있으며 총 수소 유입량은 70 Torr.L/s인 반면 고속 중성 입자빔량은 모두 11 Torr.L/s로 기체 배기량은 59 Torr.L/s에 달하고 압력은 장소에 따라 10-5~10-6 Torr로 유지되며 총배기속도가 1~2$\times$106 L인 펌프가 필요하다. 이때 크라이오 펌프(cryopump) 방식이 거의 유일한 해결책이라고 할 수 있다. 크라이오 펌프는 고속 입자빔 수송로의 양편에 각각 설치되는데 총면적 30m2 내외의 극저온 냉각판(cryo-pnael)들과 이를 상온 열복사로부터 보호하기 위한 열차폐(thermal shield) 및 흡기구 배플(baffle), 그리고 적절한 냉각장치로 구성된다. 시운전 단계에서는 15K GM 냉동기와 활성탄이 부착된 냉각판을 사용하는 방식과 4K GM 냉동기로 냉각하는 방식이, 최종 운전단계에서는 3.7K 액체 헬륨을 사용하는 방식이 고려되고 있다. 크라이오 펌프의 구조설계에 앞서 우선 배기속도, 흡？량, 작동압력, 냉각판 온도, 열손실량 등 설계사양을 확정하고 정리하는 일이 진행되고 있다. 또 냉각방식과 상관없이 동일한 개념으로 만들어지는 배플과 열차폐의 최적설계를 위한 몬테카를로 계산과 열전도 계산을 병행하고 있다. 이 곳에서는 KSTAR NBI 장치의 주배기계로서 사용될 크라이오 펌프의 설계방향과 전반적인 구조 및 예상성능 등에 대해 발표하려고 한다.

• Journal of Industrial Technology
• /
• v.39 no.1
• /
• pp.41-45
• /
• 2019

Hydrogen sulfide ($H_2S$) is mainly produced along with methane and hydrocarbons in many gas fields as well as hydrodesulfurization processes of crude oils containing sulfur compounds and the emission of $H_2S$ has a considerable effect on both environmental problem and human health aspects due to formation of, e.g. acid rain and smog. In recent years, ionic liquids (ILs) have been proposed as the most promising solvents for $CO_2$ and hazardous pollutants capture, such as $H_2S$ and sulfur dioxide ($SO_2$). In this work, we demonstrate the use of the predictive COSMO-SAC model for the prediction of Henry's law constant of $H_2S$ in ILs. Furthermore, the method is used to screen for potential IL candidates for $H_2S$ capture from a set of 2,624 ILs formed from 82 cations and 32 anions. The effects of cation on the Henry's law constant of $H_2S$ such as (i) the variation of the alkyl chain length on cation, (ii) the substituent of methyl group ($-CH_3$) for H in C(2) position and (iii) the change of ring structure for cation family are clearly predicted by COSMO-SAC model.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.23 no.3
• /
• pp.76-87
• /
• 2019

A direct connected test was conducted for a supersonic combustor with a cavity-type flame holder. Liquid hydro-carbon fuel was injected in different types of injectors: inclined and aeroramp injectors, for the flow condition of Mach 4 at an altitude of 20 km. The static pressure on the combustor wall along the axis and the total pressure at the exit of combustor were measured to analyze the combustion characteristics at various fuel flow rates.

• Journal of Radiation Protection and Research
• /
• v.39 no.1
• /
• pp.38-45
• /
• 2014

This paper describes the results of assessment of radiological dose resulting from operation of the Daedeok nuclear facilities including the HANARO research reactor, which has been performed to assure whether or not to comply with the regulation standards of the radioactive effluents releases. Based on the meteorological data and the radiation source term, the maximum individual doses were evaluated from 2010 to 2012. The atmospheric dispersion and the deposition factors of gaseous effluents were calculated using the XOQDOQ computer code. ENDOS-G and ENDOS-L code systems were also used for maximum individual dose calculation from gaseous and liquid effluents, respectively. The results were compared with the regulation standards for the radioactive effluents presented by the Nuclear Safety and Security Commission (NSSC). The effective doses and the thyroid doses of the maximum individual were calculated at the maximum exposed point in the Daedeok site, and contributions of exposure pathways to the radiological doses resulting from gaseous and liquid radioactive effluents were evaluated at each facility of the Daedeok site. As a result, the maximum exposed age was analysed to be the child group, and the operation of HANARO research reactor had a major effect more than 90% on the individual doses. The main exposure pathways for gaseous radioactive effluent were from ingestion and inhalation. The effective doses and the thyroid doses were considerably influenced by tritium and iodine, respectively. The gaseous radioactive effluents contributed more than 90% on the total doses, whereas the contributions of the liquid radioactive effluents were relatively low. Consequently, the maximum individual dose due to radioactive effluents from the nuclear facilities within the Daedeok site were less than 3% of the regulation standard over 3 years; therefore, it can be concluded that radioactive effluents from the nuclear facilities were well managed, with the radiation-induced health detriment for residents around the site being negligible.

• Journal of the Korean Society of Food Science and Nutrition
• /
• v.44 no.2
• /
• pp.173-181
• /
• 2015

This study investigated the effects of scopoletin (6-methoxy-7-hydroxycoumarin) supplementation on insulin resistance and the antioxidant defense system in chronic alcohol-fed rats. Rats were fed a Lieber-Decarli liquid diet containing 5% ethanol with or without two doses of scopoletin (0.01 and 0.05 g/L) for 8 weeks. Pair-fed rats received an isocaloric carbohydrate liquid diet. Chronic alcohol did not affect fasting serum glucose levels, although it induced glucose intolerance and hyperinsulinemia compared with the pair-fed group and led to insulin resistance. Both doses of scopoletin similarly improved glucose intolerance, serum insulin level, and insulin resistance. Scopoletin supplementation significantly activated phosphatidyl inositol 3-kinase, which was inhibited by chronic alcohol. Two doses of scopoletin up-regulated hepatic mRNA expression and activity of glucokinase as well as down-regulated mRNA expression and activity of glucose-6-phosphatase compared with the alcohol control group. Both doses of scopoletin significantly reduced cytochrome P450 2E1 activity and elevated aldehyde dehydrogenase 2 activity, resulting in a lower serum acetaldehyde level compared with the alcohol control group. Chronic alcohol suppressed hepatic mRNA expression and activities of antioxidant enzymes such as superoxide dismutase, catalase, and glutathione peroxidase; however, they were reversed by scopoletin supplementation, which reduced hydrogen peroxide and lipid peroxide levels in the liver. These results indicate that dietary scopoletin attenuated chronic alcohol-induced insulin resistance and activated the antioxidant defense system through regulation of hepatic gene expression in glucose and antioxidant metabolism.

• Applied Chemistry for Engineering
• /
• v.29 no.5
• /
• pp.533-540
• /
• 2018

Graphene has been reported to be an excellent lubricant additive that reduces friction and wear when coated on the surface of various materials or when dispersed in lubricants as an atomic thin material with the low surface energy. In this study, alkyl functionalized graphene oxide (FGO) nanosheets for oil-based lubricant additives were prepared by using three types of alkyl chloride chemicals (butyl chloride, octyl chloride, and tetradecyl chloride). The chemical and structural properties of the synthesized FGOs were analyzed by Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscope (SEM), and transmission electron microscope (TEM). The synthesized FGOs were dispersed at 0.02 wt% in PAO-0W40 oil and its tribological characteristics were investigated using a high frequency friction/wear tester. The friction coefficient and the wear track width of poly alpha olefin (PAO) oil added with FGO-14 were tested by a ball-on-disk method, and the measured results were reduced by ~5.88 and ~3.8%, respectively compared with those of the conventional PAO oil. Thus, it was found that the wear resistance of PAO oil was improved. In this study, we demonstrated the successful functionalization of GO as well as the improvement of dispersion stability and tribological characteristics of FGOs based on various alkyl chain lengths.

• Membrane Journal
• /
• v.28 no.3
• /
• pp.214-219
• /
• 2018

In the present study, superflux nickel capillary supports for gas and vapor separation membranes were prepared by a combined process of NIPS and sintering. Nickel capillary precursors were prepared by NIPS process from PSf-Ni-DMAC-PEG400 dope solution and was sintered at various temperatures in $H_2$ atmosphere to reliably produce Ni capillary support. The optimized Ni capillary support has an outer and inner diameters of 722 and $550{\mu}m$, and its thickness was $94{\mu}m$. It has 3-dimensional pore channel network and its porosity and mean pore diameter was 26% and $4{\mu}m$, respectively. Also, its mechanical strength was tested in tensile mode: its fracture load was 2.84 kgf and the fracture elongation was 13%. Finally, its single gas permeance was measured: He, $N_2$, $O_2$, and $CO_2$ permeance was 432,327, 281,119, 264,259, and 193,143 GPU, respectively. The superflux behavior could be explained from viscous flow through the macropores having a diameter of $4{\mu}m$ and narrow thickness. It could be concluded that the superflux behavior of the Ni capillary support was from the 3-D pore channel network and the small thickness.