• Title/Summary/Keyword: 액체 밀도

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The Present and the Prospects for Batteries (전지기술의 국내외 연구동향)

  • 이주성
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1999.10a
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    • pp.1-2
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    • 1999
  • 시간과 공간의 구애를 받지 않는 양질의 음성, 화상, 문자정보의 교환을 위한 노력으로 디지털 휴대폰과 휴대용 컴퓨터가 등장하면서 음성과 문자정보의 교환분야에 커다란 진보를 이룩하였다. 그러나 현재는 휴대폰이 음성정보에 문자정보교환이 추가된 상황이기 때문에, 아직도 관련 정보교환기술 및 기기개발이 진행되고 있다. 앞으로 휴대폰과 휴대용 컴퓨터의 기능을 통합하고 화상정보까지 결합된 휴대용 정보기기를 위해서는 전자회로의 집적화 및 통신속도 증대가 필수적이다. 또한 이들 휴대용 정보기기를 구동시키기 위한 전력도 증가될 것으로 예측되기 때문에, 현재 전원으로 사용되는 2차전지보다 에너지 밀도가 더욱 증패된 전지가 요구될 것으로 예상된다. 그리고 내연기관의 배기에 의해 발생되는 환정오염문제를 해결하기 위한 방법중의 일환으로 전기자동차 개발이 진행되고 있으며, 이들 전기자동차에 2차전지를 장착하기 위해서 경제성이 있고, 고속충전이 가능하고, 안전성이 높은 고에너지 밀도의 2차 전지 개발이 요구되고 있다. 현재 2차전지는 음극재료나 양극재료에 따라 낚축전지, 니켈/카드륨(Ni/Cd) 전지, 니켈/수소(Ni/MH) 전지, 라륨 2 차전지등이 있으며, 전극재료의 고유특성에 의해 전위와 애너지 밀도가 결정된다. 특히 리튬 2차전지는 리튬의 낮은 산화환원전위와 분자량으로 인해 에너지 밀도가 높기 때문에 앞에서 언급한 휴대용 전자기기의 구동전원으로 많이 사용되고 있다. 리튬 2차전지는 음극 재료가 금속리튬인 경우는 리튬금속으로, 탄소재료인 경우는 리튬이온이라 하며, 한편으로 전해질이 고체 고분자이거나 혹은 역체 유기용매와 리튬염을 고분자와 혼성시킨 겔(gel)인 경우는 고분자로, 전해짙이 리튬염이 전리되어 있는 유동성 액체일 경우는 고분자를 생략하여 구분하고 있다. 즉 리튬금속 2 차전지(LB), 리튬이온 2 차전지(LIB), 리튬금속 고분자 2차전지(LPB), 리튬 이온 고분자 2차전지(LIPB)로 크게 구분된다. 금속리듐을 음극으로 사용하고 전해질로는 리튬염이 전리되어 있는 액체유기용매 를 사용한 리튬금속 2차전지는, 금속리튬전극이 충방전 과정을 반복하면서, 전리된 리튬이 균일하게 산화환원되지 못하고 표변에서 양극방향으로 성장하는 수지상 (dendrite) 현상으로 인해 안전성 확보에 문게가 있었다. 리튬과 알루미늄 합금형태로 음극에 사용한 동전형 전지는 상용화 되었지만, 이러한 단점을 개선하기 위해 리튬이온이 금속으로 석활되는 환원반응전위보다 높은 전위에서 전극재료가 충전되면서 리튬이온이 저장되고, 방전되면서 배출되는 탄소를 음극재료로, 그리고 리튬이온이 충방 전시 가역적으로 삼입 탈리되는 층상의 리튬금속산화물을 양극으로 구성하고, 엑체 전해질과 다공성 고분자 분리막을 사용한 것이 LIB이다. LIB에서 리튬이온의 이동이 가능한 액체전해질의 가능을 고분자 전해질이 대신함으로서 보다 높은 안정성을 확보 한 전지가 LIPB 이다. 또한 고분자 전해질을 사용한 경우 금속리튬상에서의 수지상 성장이 저하되는 현상이 관찰됨으로서, 이론용량이 3,860mAh/g 에 달하는 리튬금속 혹은 합금을 고분자 전지에서 음극으로 사용하고자 하는 2 차전지가 LPB 이다. 리튬 2차전지는 비록 1989년 액체전해질을 사용한 금속리튬 2차전지의 실패전력을 안고있지만 궁극적으로는 이론적으로 최대의 에너지밀도를 가지고 있는 LPB를 지 향할 것으로 예상되지만 가까운 장래에 실현되기는 어려울 것이다. 따라서 향후의 라튬 2차전지의 전개방향은 현재의 LIB를 고분자 전해질을 채용하는 LIPB로 진행시커면서 저가의 전극재료개발을 지속적으로 추진할 것으로 예상된다. 현재 리튬 2차전지는 소형전지에 국한되고 있지만 전기자동차나 전력저장용으로 이를 대형화시커기 위해서는 열적특성이 우수하고 저가인 전극재료개발이 선행되야하기 때문에, 저가의 탄소재료와 코발트산화물을 대신할 수 있는 철, 망칸 또는 니켈산 화물의 개발이 필요하다.

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Establishment of suspension culture condition for embryogenic callus proliferation and somatic embryo development of Kalopanax septemlobus (음나무 배발생 캘러스의 증식 및 체세포배 발달을 위한 액체 현탁 배양조건 확립)

  • Kim, Sun-Ja;Moon, Heung-Kyu
    • Journal of Plant Biotechnology
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    • v.36 no.1
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    • pp.7-12
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    • 2009
  • This study was conducted to establish the optimal suspension culture system for both the propagation of embryogenic cells (ECs) and the induction of somatic embryos (SEs) of Kalopanax septemlobus. The proliferation rate of ECs was reduced as the inoculum density was increased; the highest rate was obtained when 0.1 g/100 ml of cells was initially inoculated. According to the analysis of cell growth pattern and cell growth cycle (G1, Sand G2/M), the cell growth started in 5 days culture initiation, grew rapidly until 15 days and then decreased gradually. Distinctive changes of the cell growth cycle by the culture periods was also observed; the growth cycle was doubled from initial 5.6% to 11.7% of S stage in 5 days culture and then reached in stable stages again. Therefore, the results indicated that a 15-day-cycle was the optimal culture period for the propagation of the ECs through the suspension culture. Furthermore, the cell inoculum density was also important for the induction of SE; more than 65% of SEs at the torpedo stage was induced by using the low level of cell inoculum (0.5 g/L), while the higher inoculum densities were rapidly reduced the proportion of SEs at that stage. Although the higher inoculum density delayed the development of SE, it did not affect the proportion of SEs at the globular and heart stage. In conclusion, this study showed that the suspension culture of the Kalopanax septemlobus ECs through the control of inoculum density was an efficient way for both the propagation of ECs and the induction of SEs, suggesting that the development of this system might help to reduce the culture period for the somatic embryo production.

An Evaluation of Numerical Schemes in a RANS-based Simulation for Gaseous Hydrogen/Liquid Oxygen Flames at Supercritical Pressure (초임계 압력하의 기체수소-액체산소 화염에 대한 난류모델을 이용한 해석에서 수치기법 평가)

  • Kim, Won Hyun;Park, Tae Seon
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.3
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    • pp.21-29
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    • 2013
  • Turbulent flow and thermal fields of gaseous hydrogen/liquid oxygen flames at supercritical pressure are investigated by turbulence models. The modified Soave-Redlich-Kwong (SRK) EOS is implemented into the flamelet model to realize real-fluid combustions. For supercritical fluid flows, the modified pressure-velocity-density coupling are introduced. Based on the algorithm, the relative performance of six convection schemes and the predictions of four turbulence models are compared. The selected turbulence models are needed to be modified to consider various characteristics of real-fluid combustions.

Spray Characteristics of Effervescent Swirl Injectors for Variable Thrust (가변추력을 위한 기체주입식 와류형 분사기의 분무특성)

  • Lee, Wongu;Hwang, Donghyun;Ahn, Kyubok;Yoon, Youngbin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.2
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    • pp.1-12
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    • 2019
  • A fundamental study on a gas injection variable thrust method for thrust throttling in a liquid rocket engine was conducted. The gas injection variable thrust has the advantage of not only being able to control the thrust with a simple structure but it also increases the atomization performance through the injection pressure drop that increases in direct proportion to the density reduction. In this study, spray characteristics such as spray instability, spray pattern, spray angle, and breakup length based on changes in the liquid mass flow rate and amount of injected gas were investigated using effervescent swirl injectors.

Physical and Thermodynamic Properties of Imidazolium Ionic Liquids (이미다졸계 이온성 액체의 물성)

  • Oh, Sooyeoun;Kang, Jeong Won;Park, Byung Heung;Kim, Ki-Sub
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.708-712
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    • 2012
  • Ionic liquids (ILs) existing as liquid state at room temperature are composed of a immense heterocyclic cation and inorganic anion which is smaller than cation's size. Thus, the species of cation and anion as well as the length of alkyl group on the cation have influence on their physical properties. Their outstanding properties such as non-volatility, thermal stability and wide range of electrochemical stability make these materials excellent candidates for green solvent which can substitute the conventional organic solvents. In this study, ILs based on imidazolium cation have been synthesized such as 1-butyl-3-methylimidazolium bromide ([BMIM][Br]), 1-butyl-3-methylimidazolium chloride ([BMIM] [Cl]), 1-butyl-3-methylimidazolium iodide ([BMIM][I]), and 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][$BF_4$]). The density, viscosity, refractive index, heat capacity and ionic conductivity of [BMIM][Br], [BMIM][I], and [BMIM] [$BF_4$] were measured over range of temperature of 293.2 to 323.2 K. The density and refractive index values of [BMIM][I] were the highest among three ILs and the viscosity values of [BMIM][Br] were the highest among three ILs. The heat capacities [BMIM][$BF_4$] were higher than those of [BMIM][Br]. The ionic conductivities of [BMIM][$BF_4$] were higher than those of [BMIM][I].

Measurement of Liquid Density using Tuning Fork (튜닝포크를 이용한 액체밀도의 계측)

  • Kim, Choong-Hyun;Lee, Yong-Bok;Lee, Sung-Chul
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.1
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    • pp.86-91
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    • 2007
  • A sensor using quartz toning fork is presented for measuring liquid density. It consists of a PZT plate as an actuator for piezoelectric excitation and a quartz tuning fork as a sensor for resonant frequency detection. The resonant frequency is determined from the sensing voltage measured in tuning fork when the excitation frequencies of PZT actuator are swept around the resonant frequencies of tuning fork. The resonant frequency determined the liquid density. The density values of three kinds of organic solvents are measured and compared with the standard values. The experimental results are in agreement with the standard values and the maximum standard deviation is less than 9%.

Performance Comparison of Correlations of the Saturated Liquid Densities for Pure Substances (순수물질에 대한 포화액체밀도 상관식의 성능비교)

  • Lee, Kyoung-Youl;Park, Kyoung-Kuhn
    • Proceedings of the SAREK Conference
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    • 2005.11a
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    • pp.373-379
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    • 2005
  • A few correlation equations of the saturated liquid density are reviewed and a new equation is proposed. Performance of each equation is examined using the data listed in the ASHRAE table for 22 pure substance refrigerants. The new four-parameter equation yields an average absolute deviation of 0.03% for 22 refrigerants. Performance of the new four-parameter equation is found to be equivalent to those of the existing equations such as Hou-Martin equation(0.03%) and Iglesias-Silva-Hall equation(0.08%).

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Analysis of rapid estimation of cement fineness using hydrometer and water bottle (액체밀도계 및 생수병을 이용한 시멘트 분말도 신속 추정 가능성 분석)

  • Lee, Jae-Jin;Han, Jun-Hui;Hyun, Seong-Yong;Kim, Yeong-Tae;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.85-86
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    • 2018
  • In this study, we previously conducted a quick evaluation of cement powder map using mesiline and hydrometer. The experiment also confirmed the possibility of rapid quality evaluation of cement powder. In this study, further studies have been conducted to apply speed and cost more economical than conventional methods, and the possibility of applying this research is to be analyzed. The result of the experiment was 500 mL of a bottled water bottle with a solid edge for measurement convenience, and the hydrometer was determined to be B type. In addition, density values of each other by powder during the same time period are considered to be measurable, indicating large differences.

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Numerical Study for Kerosene Surrogate Model in Supercritical Swirl Injector (초임계 스월 인젝터에서의 케로신 Surrogate 모델에 대한 수치적 연구)

  • Kim, Kuk-Jin;Heo, Jun-Young;Sung, Hong-Gye
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.19-23
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    • 2010
  • Injection characteristics of a kerosene swirl injector of liquid rocket engine operating at supercritical environment have been investigated. Kerosene surrogate models are proposed to model the kerosene properties. Turbulent numerical model is based on large eddy simulation and contains Soave modification of Redlich-Kwong equation of state and Chung's model. Numerical analysis results at supercritical environment are compared with the one at transcritical condition. Differences of density and viscosity are analyzed at both liquid film and core gas in the swirl injector.

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Analysis of Influence Factors in Fineness Rapid Evaluation Blast Furnace Slag Powder by Hydrometer (액체밀도계에 의한 고로슬래그 미분말 분말도 신속평가에서의 영향인자 분석)

  • Moon, Byeong-Yong;Kim, Min-Sang;Lee, Jea-Hyeon;Joo, Eun-Hui;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.167-168
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    • 2017
  • In this research, the blast-furnace slag powder using the hydrometer also attempted to analysis the influence factor due to the temperature change of water and sample, and the number of upside down turns at the time of rapid evaluation. As a result, the influence of the number of turn was not large, but was the temperature of the water and sample are greatly affected.

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