• Title/Summary/Keyword: 액체약

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Influence of Reaction Temperature on Bio-oil Production from Rice Straw by the Pyrolysis (볏짚으로부터 바이오오일 생산에 대한 열분해 반응온도의 영향)

  • Kang Bo-Sung;Park Young-Kwon;Kim Joo-Sik
    • Resources Recycling
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    • v.15 no.1 s.69
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    • pp.12-19
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    • 2006
  • Rice straw is one or the main renewable energy sources in Korea. Bio-oil is produced from rice straw with a lab-scale equipment mainly with a fluidized bed and a char removal system. It was investigated how the reaction temperature affected the production of bio-oil and the efficiency of a char removal system. To elucidate how the temperature depended on the production of bio-oil, experiments were conducted at $466^{\circ}C,\;504^{\circ}C\;and\;579^{\circ}C$, respectively. The mass balance was established in each experiment, and the produced gas and oil were analyzed with the aid of GCs and a GC-MS system. The char removal system is composed of a cyclone and a hot filter. Tn the experiments, we observed that the production of bio-oil was decreased with temperature, and the bio-oil contained very useful chemicals.

Influence of Reaction Temperature on the Pyrolytic Product of Rice Straw by Fast Pyrolysis using a Fluidized Bed (볏짚의 급속 열분해 생성물에 대한 반응온도의 영향)

  • Kang, Bo-Sung;Park, Young-Kwon;Kim, Joo-Sik
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.10a
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    • pp.47-58
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    • 2005
  • Rice straw is one of the main renewable energy sources in Korea, and bio-oil is produced from rice straw with a lab. scale plant equipped mainly with a fluidized bed and a char removal system. We investigated how the reaction temperature affected the production of bio-oil and the efficiency of a char removal system. To elucidate how the temperature depended on the production of bio-oil, experiment were conducted between $450^{\circ}C\;and\;600^{\circ}C$ with a feed rate of about 300g/h. The mass balance was established in each experiment, and the produced gas and oil were analyzed with the aid of GCs and a GC-MS system. The char removal system is composed of a cyclone and a hot filter. In the experiments, we observed that the optimum reaction temperature range for the production of bio-oil is between $450^{\circ}C\;and\;500^{\circ}C$.

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Combustion Performance of a Full-scale Liquid Rocket Thrust Chamber Using Kerosene as Coolant (실물형 액체로켓엔진 연소기 케로신냉각 연소시험 성능결과)

  • Han, Yeoung-Min;Kim, Jong-Gyu;Moon, Il-Yoon;Seo, Seong-Hyeon;Choi, Hwan-Seok;Lee, Soo-Yong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.163-168
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    • 2006
  • The combustion performance tests of a 30 tonf-class full-scale combustion chamber performed with kerosene as a coolant were described. The combustion chamber has chamber pressure of 53bara and propellant flow mass rate of 90kg/s. Since it was first firing test for 30tonf-class combustion chamber using kerosene cooling, kerosene coolant mass flow rate of 32kg/s which correspond to 120% of design mass flow rate were performed. Then, the firing test with kerosene mass flow rate of 25kg/s were successfully performed. The test results are described and the results showed that the kerosene cooling performance of this combustion chamber is sufficient and the firing test with regenerative cooling is feasible.

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Simulator Development for Startup Analysis of Staged Combustion Cycle Engine Powerpack (다단연소사이클 엔진 파워팩 시동 해석 시뮬레이터 개발)

  • Lee, Suji;Moon, Insang
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.5
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    • pp.62-70
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    • 2015
  • A liquid rocket engine system can cause rapid pressure and temperature variations during the startup period. Thus the startup analysis is required to reduce time and expense for successful development of liquid rocket engine through the startup prediction. In this study, a startup analysis simulator is developed for a staged combustion cycle engine powerpack. This simulator calculates propellant flow rates using pressure and flow rate balances. In addition, a rotational speed of turbopump is obtained as a function of time by mathematical modeling. A startup analysis result shows that the time to reach a steady-state and a rotational speed at the steady-state are 1.3 sec and 27,500 rpm, respectively. Moreover it can indicate proper startup sequences for stable operation.

고체 수소를 이용한 군용 연료전지 차량

  • 이부윤
    • Journal of the KSME
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    • v.44 no.1
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    • pp.27-27
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    • 2004
  • 미국 국방부 소속 육군차량사업부(National A Automotive Center)는 대체에너지를 이용한 군용 차량 개발을 위해 Michigan 주 Rochester Hills에 위치한 E Energy Conversion Devices(ECD) 사와 일부 기술 개발 에 대한 기술 제휴를 한다고 발표했다. 국방부는 태양전 지와 수소를 연료로 사용하는 대체에너지 차량을 개발하 기 위해 ECD에 1단계 연구에 필요한 연구비를 지원했다. 이번 연구에는 연료전지를사용한차량개발을위해 5 500,$\omega$0달러가 투자되는데, Texaco Ovollic Hydrogen S Systems(TOHC)의 고체 휴대용 수소 연료와 채충천 (refueling) 시스탬이 주요 개발 목표로 설정됐다. ECD의 역할은 최근 개발된 Toyota Prius에 시범 적으로 장착된 저압 고체형 수소 저장 시스템의 기술을 군용 차량에 알맞게 전환시키는 것이다. TOHC와 ECD가 개발한 고체형 수소 보관 시스댐은 고압을 요구하는 연료전지 차량의 수소 저 장 시스템이 갖고 있는 많은 문제점들을 해결할 수 있을 것으로 기대되는 연료전지를 이용한 엔진 개발 중 최신 기술이다. 특히 전투 상황에서 차량이 폭발하기 쉬운 수소 저장 탱크를 장착한 채 전 장으로간다는 것은적에게 노출 될 경우자살과마찬가지인 치명적인 피해를 입을수 있다. 이 프로젝트의 개요를 살펴보면, 수소 저장 시스템은 적어도 약 lOkg의 수소를 적은 용적 내에 낮은 압력에서 안전하게 고체 상태로 저장할 수 있다. 이 고체 저장 용기는 하루에 두 번 1.7kg의 수소를 10분 이내에 재급유할 수 있다. 수소는대부분고압가스형태나저온액체 형태로보관된다. 기체나액체 형태의 수소는 연료전 지에 사용되기에는 적합하지 않은 점이 많다. Ovonie 수소 저장 방법은 수소를 저압 고체 형태 ( (metal hydride)로 보관하는 방법으로, 고압 기체나 저온 액체가 갖고 있는 많은 문제점들을 해결 할수있다. 그림을 참조하면 고체 형태의 수소 보관 방법이 다른 보관 방법에 비교해 단위 체적당 최고 6배 많은수소질량을보관할수 있다. 이 고체 형태의 보관방법은수소가적절한합금과평형 압력 이 상의 환경에 놓일 경우 합금에 홉착되는 현상을 이용하고 있다. 수소를 흡수한 합금은 새로운 특성 을 가진 metal hydride로 변하게 된다. 이 과정 에서 열이 부산물로 발생한다. 반대로 수소를 metal hydride로부터 분리시키기 위해서는 합금을 가열해야 한다.

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Bubble Properties in Bubble Columns with Electrolyte Solutions (전해질용액 기포탑에서 기포특성)

  • Yoo, D.J.;Lim, D.H.;Jeon, J.S.;Yang, S.W.;Kang, Y.
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.543-547
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    • 2016
  • Bubble properties such as size (chord length) and rising velocity were investigated in a bubble column with electrolyte solutions, of which diameter was 0.152m and 2.5m in height, respectively. The size and rising velocity of bubbles were measured by using the dual electrical resistivity probe method. Effects of gas and liquid velocities and ionic strength of liquid phase on the size and rising velocity of bubbles were determined. The bubble size increased with increasing gas velocity but decreased with increasing liquid velocity or ionic strength of liquid phase. The rising velocity of bubbles increased with increasing gas velocity and decreased with increasing ionic strength of liquid phase, however, it showed a slight maximum value with varying liquid velocity. The size and rising velocity of bubbles were well correlated with operating variables.

Dynamic Characteristics of External loop Air-Lift Reactor (외부 순환 공기리프트 반응기의 동특성)

  • 강귀현;김춘영정봉우
    • KSBB Journal
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    • v.7 no.1
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    • pp.59-65
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    • 1992
  • Hydrodynamics and mixing characteristics such as circulation time, mixing time, circulation velocity and axial dispersion coefficient were investigated using highly viscous pseudoplastic solutions of carboxymethyl cellulose(CMC) in an external circulation loop air-lift reactor with 13$\ell$ working volume. The superficial gas velocity was changed from 1.9 to 6.2cm/s and CMC concentration from 0 to 1.0wt%. The theoretical model based on the pressure balance is developed mathematically to predict liquid circulation velocity. Gas hold-up, circulation velocity and axial dispersion coefficient of liquid phase increased with increasing gas velocity and decreased slightly with increasing liquid viscosity. Mixing time and circulation time decreased with increasing gas velocity and increased with increasing liquid viscosity. Experimental data on liquid circulation velocity were in good agreement with the predicted values.

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Optical properties of $Nd^{3+}$ complexes for liquid laser material (액체 레이저의 매질 개발을 목적으로 한 $Nd^{3+}$ 착물의 광학적 특성)

  • 김정호
    • Korean Journal of Optics and Photonics
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    • v.10 no.4
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    • pp.318-322
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    • 1999
  • Perdeuterated hexaflouroacetylacetonato-neodymium [$Nd(HFA-D)_3$] complexes were synthesized by the keto-enol tautomerism reaction of $Nd(HFA-D)_3$ in methanol-d$_4$ in order to reduce the radiationless transition to the ligands. The emission properties of $Nd(HFA-D)_3$ complex were measured in the following anhydrous deuterated organic solvents; $Methanol-d_4$, $Aceton-d_6$, $THE-d_8$ and $DMSO-d_6$, and these properties depended on the coordination ability of solvent molecules. The intensity and lifetime of the emission in dimethysulfoxide (DMSO-$d_6$) were superior to those in other in other deuterated solvents. It was suggested that the anhydrous $DMSO-d_6$might be the most appropriate solvent for the liquid laser material of $Nd(HFA-D)_3$ complex.

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Cultural Characteristics and Scale-up for Submerged Cultivation of Hericium erinaceum Through Air-lift and Jar Fermenter System (Air-lift 및 Jar Fermenter에 의한 Hericium erinaceum 심부배양의 배양특성 및 Scale-up)

  • Jung, Jae-Hyun;Lee, Keun-Eok;Lee, Shin-Young
    • KSBB Journal
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    • v.21 no.2
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    • pp.103-109
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    • 2006
  • For the study of Hericium erinaceum as a useful functional foods and materials, liquid cultivation under two different bioreactors(air-lift fermenter and jar fermenter) which was not studied systematically until now, was conducted as a method of mass cultivation for H. erinaceum. A batch cultivation in an air-lift fermenter and a jar fermenter was examined for enhancing the productivity because of small amounts of mycelial weight and slow growth in case of a liquid culture for H. erinaceum. We found that air lift fermenter system was more effective than jar fermenter for mycelial production of H. erinaceum, and mycelial morphology was a critical factor of the growth. By scale-up and cultivation based on morphological analysis, the conditions for mass production with 30 L and 500 L jar fermenter was 200 and 150 rpm of agitation speed at 1 vvm of aeration rate, respectively, and mycelial dry weight under these conditions was enhanced to about $13{\sim}14g/L$.

Finding Optimal Mass Flow Rate of Liquid Rocket Engine Using Generic Algorithm (유전알고리즘을 이용한 액체로켓엔진 최적 유량 결정)

  • Lee, Sang-Bok;Jang, Jun-Yeoung;Kim, Wan-Jo;Kim, Young-Ho;Roh, Tae-Seoung;Choi, Dong-Whan
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.93-96
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    • 2011
  • A genetic algorithm (GA) has been employed to optimize the major design variables of the liquid rocket engine. Mass flow rate to the main thrust chamber, mass flow rate to the gas generator and chamber pressure have been selected as design variables. The target engine is the open gas generator cycle using the LO2/RP-1 propellant. The objective function of design optimization is to maximize the specific impulse with condition of energy balance between the pump and the turbine. The properties of the combustion chamber have been obtained from CEA2. Pump & turbine efficiencies and properties of the gas generator have been modeled mathematically from reference data. The result shows 3~4% errors for the specific impulse and 2~6% errors for the pump power of the gas generator cycle compared to references.

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