• Korean Journal of Materials Research
• /
• v.7 no.7
• /
• pp.608-617
• /
• 1997

전자빔 용해법에 의해 고순도 티타늄잉고트 및 버튼시편을 제조하였다. 이들 중 18개의 금속불순물을 GDMS(Glow Discharge Mass Spectrometry)로 그리고 탄소, 질소, 산소의 함량을 고온연소법으로 측정한 후 이들과 전기비저항, 경도와의 관계를 조사하였다. 99%와 99.6%스폰지를 용해한 경우 대부분의금속불순물들이 대폭 감소하는 큰 휘발 정련효과가 나타났으며 비금속불순물들의 경우는 장비의 진공상태에 따라 큰 영향을 받으며 정련효과를 기대할 수 없었다. 금속 불순물중 철은 가장 제거하기 어려운 원소로 밝혀졌으며 이는 원료 스폰기중에서 철이 주불순물이기 때문이며 추가적인 예비정련이 필요한 것으로 나타났다. 상온 및 액체질소온도에서의 전기비저항은 가스불순물의 량이 증가함에 따라 직선적으로 증가하였으며 이들의 저항비($\rho$$_{RT}$ /$\rho$$_{N2}$)는 가스불순물의 총량이 1,000ppm이하의 경우 불순물량이 감소함에 따라 급격하게 저하하였으며 이 이상인 경우 완만하게 감소하였다. 이들의 경도는 가스불순물의 량이 증가하였으며 산소당량의 평방근에 비례하는 것으로 나타났다.다.

• Journal of the Korean Chemical Society
• /
• v.54 no.5
• /
• pp.533-540
• /
• 2010

An activated carbon was tested for its ability to remove transition metal ions from aqueous solutions. Physical, chemical and liquid-phase adsorption characterizations of the carbon were done following standard procedures. Studies on the removal of Ni(II), Cu(II) and Fe(III) ions were attempted by varying adsorbate dose, pH of the metal ion solution and time in batch mode. The equilibrium adsorption data were fitted with Freundlich and Langmuir and the isotherm constants were evaluated, equilibrium time of the different three metal ions were determined. pH was found to have a significant role to play in the adsorption. The processes were endothermic and the thermodynamic parameters were evaluated. Desorption studies indicate that ion-exchange mechanism is operating.

• Journal of the Korean Chemical Society
• /
• v.43 no.2
• /
• pp.167-171
• /
• 1999

An investigation of the interaction of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Pb(II) and Ag(I) with two N,N'-dibenzylated nitrogen-oxygen mixed donor macrocyclic ligands, has been carried out. Tle log K values for the respective complexes in 95% methanol have been determined potentiometrically. Both ligands have formed stable complex with only Cu(II) and Ag(I) ion. Transport measurements in a bulk liquid membrane system exhibited a very high selectivity of Ag(I) ion over the other metal ions used.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.7 no.4
• /
• pp.73-79
• /
• 2003

The tensile strength test and the analysis for the section of brazing were performed in the cases of materials used for combustion chamber of regeneratively cooled liquid rocket engine. BNi-2 and BNi-7 based on nickel were used for brazing as filler metal. The properties of material and filler metal were analyzed by tensile strength test and metal microscope for 12 specimens. The tensile-strength of brazing for chrome-copper alloy and other kinds of alloy was higher than that of chrome-zirconium-copper alloy and other kinds of alloy The tensile strength in the case of BNi-2 as filler metal was higher than that of BNi-7 because the wetting property of BNi-2 was better than that of BNi-7.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.08a
• /
• pp.129-129
• /
• 2011

냉음극 변압기 전원 소스를 이용하여 저진공에서 플라즈마를 발생시키는 시스템을 개발하였다. 또한 이 장치를 이용하여 도핑된 산화막 증착 기술을 연구하였다. 이 때 도핑 전구체는 액체 소스였으며 이를 기화시켜 사용하였다. 특히 p 타입이 도핑된 이산화규소 박막 증착을 상온에서 실시하였다. 공정 압력은 400~1,000 mT였으며, 전압은 약 1,100~2,100 V 범위에서 조절하였다. 증착된 박막은 박막 두께와 홀 측정을 실시하였다. 홀 측정을 위한 인듐 금속 접합을 400 C에서 실시하였다. 결과를 요약하면, 플라즈마 공정 압력이 400에서 1,000 mTorr로 증가함에 따라 박막 증착 속도는 약 240~440 ${\AA}$/min이었다. 또한 증착된 p-SiO2의 벌크 농도는 같은 압력 증가에 따라 약 $1.2{\times}10^{19}$에서 $6.5{\times}10^{18}/cm^3$으로 절반 정도 감소하였다. 그에 따라 도핑된 산화막의 비저항은 $~1.4{\times}10^{-3}$에서 $2.5{\times}10^{-3}{\Omega}{\cdot}cm$로 증가하였다. 홀 이동도는 약 380~400 $cm^2/V{\cdot}s$를 유지하였다. 또한 전압이 1,100 에서 2,100 V로 증가함에 따라 산화막의 증착 속도는 약 330에서 410 ${\AA}$/min으로 증가하였다. 그러나 전압이 증가해도 벌크 농도는 약 8,9~$6.6{\times}10^{18}/cm^3$의 범위였다. 보다 자세한 결과는 발표를 통해 설명할 것이다.

• Current Industrial and Technological Trends in Aerospace
• /
• v.9 no.1
• /
• pp.139-149
• /
• 2011

The combustion chamber and nozzle of a liquid rocket engine need thermal protection against the high temperature combustion gas. The nozzle extension of a high-altitude engine also has to be compatible with high temperature environment and several kinds of cooling methods including gas film cooling, ablative cooling and radiative cooling are used. Especially for an upper-stage nozzle extension having a large expansion ratio, the weight impact on the launcher performance is crucial and it necessitated the development of light-weight refractory material. The present survey on the nozzle extension materials employed in the liquid rocket engines of USA, Russia and European Union has revealed a trend that the heavier metals like stainless steels and titanium alloys are being substituted with light weight carbon fiber or ceramic matrix composite materials.

• Proceedings of the KSME Conference
• /
• 2007.05b
• /
• pp.2678-2683
• /
• 2007

The interaction between metal molecules and liquid metal molecules was modeled in the molecular scale and simulated by the molecular dynamics method in order to understand behaviors of the cluster on metallic surface in collision process. Lennard-Jones potential had been used as intermolecular potential, and only attraction 때 d repulsion had been used for the behavior of the cluster on the metal surface. As results, the behavior of the cluster was so much influenced by the cluster of liquid metal temperature and function of molecules forces, such as attraction and repulsion, in the collision progress. These results of simulation will be the foundation for the micro fabrication manufacturing by using spray application technology.

• 한국연소학회:학술대회논문집
• /
• 2014.11a
• /
• pp.161-164
• /
• 2014

The feasibility of a molten metal as a bed material of a pyrolysis system was investigated. The molten metal has various advantages such as high thermal conductivity, wide operating range and low viscosity. Tin was selected since its physical characteristics are suitable for the purpose. As a results, it was found that pyrolytic oil yield and reaction rate were significantly enhanced with the molten Tin. In addition, oxygen component of the product oil was decreased due to Tin oxidation.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.1 no.2
• /
• pp.113-124
• /
• 1977

By spplying the ultrasomic wave to the solidifing liquid metal, grain sizes of the ingot are refined and the structures are homogenized. One of the reason is the enhancement of nucleation by ultrasonic vibration. According to the reports on this subject, the uncleating conditions are formed by the increse of melting point which is produced by the high pressure due to caviation. In this paper we study whether the caviations are the orgin of the nucleation and analized whether the nucleating conditions are formed by the increase of melting point or not and also compared the analytical result with the experim nt. We analized the pressure change induced by cllaphsing of cavity and the motion of cavith in oscillating pressure field. And we further analized the variation of melting point with pressure change.

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.06a
• /
• pp.247-250
• /
• 2009

Sodium heat pipe for high-temperature solar thermal application was manufactured and tested for transient and steady-state operations. Total length of the heat pipe was 650 mm and the outer diameter was 12.7 mm. Thermal performance was compared experimentally for two different cooling methods of the forced and the natural convection cooling in the heat pipe condenser. During the experiment, the maximum temperature was about 1300K, and different cooling methods were applied to the condenser region to charge the operating temperature. The effective thermal conductivity and the thermal resistance were investigated as a function of heat flux, heat transport length, and operating temperature.