• Polymer Science and Technology
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• v.15 no.3
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• pp.296-302
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• 2004

최근 분자들의 자기조립 현상을 나노-바이오 소자 개발에 응용하는 연구가 활발히 진행되고 있으며, 이러한 응용을 위한 대표적인 자기조립체로는 양친성 계면활성제, 블록공증합체, 콜로이드와 초분자체를 들 수 있다. 대부분의 콜로이드가 구형 모양으로 vander Waals interaction에 의하여 3-D결정 (crystal) 형태의 자기조립구조를 형성하는 반면에, 콜로이드를 제외한 대부분의 자기조립체는 적정 조건에서 액정 (liquid crystals), 결정 (crystal) 및 무정형 (amorphous)을 형성한다. 적용하고자 하는 응용의 범위와 재료의 특성에 따라서 각 상태 (phase)를 이용할 수 있으나, 액정상을 이용하는 것과 결정상을 이용하는 경우가 대부분이다. (중략)

• 전기의세계
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• v.38 no.10
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• pp.4-12
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• 1989

최근에는 전자 장치가 소형화, 경량화되는 추세이다. 이러한 전자 장치와 인간의 접속 방법으로 표시기(display)가 사용된다. 표시 기술은 표1에 나타난 것처럼 CRT, PDP, LCD, ECD, 기타 등으로 구별할 수 있다. 그중에서 LCD(Liquid Crystal Display)는 낮은 전력 소모, 낮은 구동 전압, 소형, 경량, gray scale 기능, 저가격 등의 장점이 있기 때문에 많은 연구가 수행되고 있다. 액정 지시기는 외부 전장에 의한 분자의 배열이 이루어져, 빛을 선별 투과 혹은 반사시켜 빛의 세기를 조절하는 특성을 이용하여 정보 전달 기능을 갖는다. LCD는 시계, 전자계산기, TV, 컴퓨터 단말기 등에 이용된다. LCD에 사용되는 액정은 구조적 특성에 따라서 semetic, cholestic, nematic액적으로 분류된다. 그런데 nematic액정이 분자 재배열에 필요한 반응 시간이 가장 빠르기 때문에 많이 사용된다.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.44 no.2
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• pp.183-190
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• 2024

An environmentally-friendly nanocoating method that effectively adds flame retardant(FR) and gas shielding properties to combustible polymeric construction materials such as flexible polyurethane (PU) foam was studied. Naturally-driven two-dimensional(2D) nanomaterials such as graphene oxide (GO) can exhibit liquid crystalline (LC) properties in aqueous solutions, enabling uniform coatings on the various substrates including 3D-porous foams. LC phase-assisted coating serves as 3D-scaffold, facilitating the introduction of small molecules having antioxidant capabilities such as dopamine which is to form uniformly stacked FR coating. Additionally, the structural characteristics of the 2D-materials can effectively hinder the migration of toxic gases and flammable substances in the gas phase generated during combustion. This LC phase flame retardant coating technology could be a new approach to provide environmentally friendly and effective flame retardant and gas barrier properties to various types of polymeric materials.

• The Korean Journal of Rheology
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• v.3 no.1
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• pp.68-75
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• 1991

상업적으로 많이 이용되는 폴리에틸렌테레프탈레이트(PET)에 액정중합체(LCP)인 열방성 폴리에스터를 첨가하여 유변학적 특성을 조사하고 전단속도와 혼합비에 따른 LCP domain의 형태 변화를 고찰하였다. 모체고분자 내 구형과 타원형을 이루는 LCP domain들 은 신장력에 의해 피브릴 구조의 변형되고 이 피브릴은 흐름방향으로 배향되어 용융체에 윤 활제와 같은 역할을 함으로써 용융점도의 감소를 보이는데 특히 높은 전단속도 영역에서 LCP가 30wt%까지 첨가될수록 큰 폭으로 감소하였다. 주사식 현미경(SEM)의 관찰로부터 LCP domain의 피브릴구조를 확인할 수 있었고 또한 LCP domain의 형태 변화가 용융점도 가 감소에 직접 관계됨을 확인할 수 있었다.

• Applied Chemistry for Engineering
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• v.26 no.3
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• pp.280-286
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• 2015

Two series of unsymmetric dimesogenic compounds containing a butylene or pentamethylene group as the flexible spacer were synthesized and their thermal and mesomorphic properties were studied. Mesogenic groups of the synthesized compounds consisted of a cholesteryl and an azobenzene group with lateral substituent. Chemical structures and mesomorphic properties of the synthesized compounds were investigated by FT-IR, $^1H$-NMR, differential scanning calorimeter (DSC), and polarizing optical microscope (POM). All synthesized compounds, apart from $D5-OCH_3$, showed enantiotropic liquid crystal phases. Compounds having an even number of carbon atoms in the flexible spacer exhibited wide mesophase temperature ranges and high isotropic transition temperatures. Regarding the effect of lateral substituents, compounds with bulky substituents exhibited decreased mesophase temperature ranges and isotropic transition temperatures, while those with polar substituents showed the increased thermal stability of the smectic phase.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.39 no.4
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• pp.10-18
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• 2002

This paper reports a methodology for calculating distribution of the director in an In-plane switching liquid crystal cell by a numerical technique. To calculate distribution of the director, we developed a three dimensional finite element method (FEM) and calculated the distribution of electric potential and electric field in the liquid crystal cell. We have considered the free-energy density composed of electric potential and strain energy in the bulk of liquid crystal cell and calculated the switching property of liquid crystal cell by the Ericksen-Leslie equation and the Laplace equation We generated 1,859 nodes and 8,640 elements for IPS mode cell with 24${\mu}{\textrm}{m}$$\times$12${\mu}{\textrm}{m}$$\times$4.5${\mu}{\textrm}{m}$ and performed transient analysis until 16ms. As a result, horizontal electric field occurred at cell region except liquid crystal region above electrodes and the disclination occured on electrodes.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.17 no.3
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• pp.146-154
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• 2024

In this paper, we present a convenient liquid crystal (LC) molecular alignment method using brush hairs as an alternative to the rubbing process in the LC display industry. Titanium strontium yttrium zirconium oxide (TiSrYZrO) solution was prepared using a sol-gel process, and the TiSrYZrO alignment film production and LC molecular alignment were integrated through a one-step brush coating process. As the curing temperature increased, the LC molecule alignment of the LC cell improved, and the formation of a physical surface anisotropic structure due to the shear stress caused by the movement of the brush hairs on the coating surface led to uniform alignment of the LC molecules. Uniform and homogeneous LC molecular alignment was confirmed through polarizing optical microscopy and pretilt angle measurement. Through thermal oxidation using X-ray photoelectron spectroscopy, the TiSrYZrO thin film well formed of metal oxide was confirmed and verified to have excellent optical transparency. From these results, it is expected that a convenient LC molecular alignment method using brush hairs as an alternative to the rubbing process will be a viable next-generation technology.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.04b
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• pp.136-140
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• 2002

투과형 광 시야각 모드의 하나인 Fringe Field Switching (FFS) mode를 반사형 액정 디스플레이소자로 응용하여 전기 광학적 특성을 컴퓨터 시늉 하였다. FFS mode는 액정이 수평으로 균일하게 유지되면서 구동하므로, 시야각에 따른 굴절률 변화 역시 균일하게 유지된다. 이러한 특성 때문에 반사형 FFS mode는 부가적인 위상필름을 쓰지 않고, 액정층과 편광판 1매 만으로도 일정한 수준의 반사형 디스플레이 특성을 얻을 수 있다. 컴퓨터 시늉을 통해 1매 편광판과 액정층, 반사판으로 구성된 Normally Black모드의 셀 구조를 취하고, 셀 간격을 일정하게 유지하면서 액정의 ${\Delta}n$을 변화시켜 특성을 구하는 방식으로 수행하여, 입사광의 파장이 550nm일때 최적의 셀 위상차값으로 $d{\Delta}n$인 $0.1365{\mu}m$를 얻었다. 입사광원을 $0^{\circ}C$로 하고 편광판 투과율이 41%였을 때 정면 반사율은 on시 33.6%, off시 0.14%로 명암대비가 233:1이었다. 특히 시야각은 극각 $60^{\circ}C$이내의 전 방향에서 명암 대비비가 5이상의 특성을 보였다.

• Korean Journal of Optics and Photonics
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• v.12 no.3
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• pp.235-239
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• 2001

In this paper, we propose an optical configuration of a reflective AFLC display mode using a half-wave AFLC cell in which inplane tilt angle is $22.5^{\circ}C$. To check the validity of our design, we fabricate a reflective half-wave AFLC cell of which the in-plane tilt angle is $24.9^{\circ}C$, and measure viewing angle and visible spectra characteristics. In the results, the half-wave AFLC cell in the reflective configuration exhibits wide viewing-angle as well as high brightness and contrast. trast.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.30 no.2
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• pp.279-294
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• 2004

This study described about a liquid crystalline technology that is used in cosmetics industry. Various intermediate phases may exist between solid and liquid. At high surfactant concentration, several liquid crystalline phases can be made to have formed. Although molecular arrangement with crystallization is not regular, it is known that more relative regular state is liquid crystalline or meso-phase than liquid phase. Usually, it described in detail about manufacturing method that explained about a kind of liquid crystalline technology in cosmetics, a new liquid crystalline technology, and makes liquid crystalline. Specialty, it introduced about kind of special an emulsifier to form liquid crystalline. There were hydrogenated lecithin, ceramide, dipalmitoylhydroxyproline, DEA-cetyl phosphate, Gemini-surfactant in representative raw material to form liquid crystalline. Liquid crystalline extent that used polarization microscope to observe formation, and appears best from 400times, 600times, 1,000times well appeared. Also, droplet particle size that liquid crystal is made best 1.0-10.0$\mu\textrm{m}$ be. General emulsion more than superior result that measures the skin moisturizing effect to take advantage of liquid crystalline technology of vitamin was seen. As presence at a clinical result, wave and general emulsion more than superior result (more than 20%) that measures skin moisturizing effect about liquid crystalline of vitamin B$\_$5/ were seen (ANOMA t-test, p<0.05)