• Title/Summary/Keyword: 액상폐기물

Search Result 61, Processing Time 0.022 seconds

Characteristics of Acetaldehyde Decomposition over Heat Treated Cobalt Phthalocyanine Catalysts (열처리 조건에 따른 코발트 프탈로시아닌 촉매상에서 아세트알데히드 분해 특성)

  • 서성규;윤형선;김대중
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2003.11a
    • /
    • pp.489-490
    • /
    • 2003
  • 아세트알데히드는 석유화학관련시설에서 많이 배출되는 것으로 알려져 있으며, 환경부 고시(제2001-36호)에 이를 포함한 37개 VOC 규제제품 및 물질로 명시되어 있다. 또한, 현재의 8개 악취물질에도 포함되어 있어 강력히 규제하고 있는 물질이다. 아세트알데히드의 주요 특성으로서 최소감지농도는 0.21ppm, LEL(Lower Explosive Limit)은 4%로 반응성이 매우 크며, 액상 및 증기상에서 가연성이 매우 큰 물질이다. 이러한 물질을 처리하기 위해 직접연소법과 촉매연소법을 이용하여 처리하고 있으나, 직접연소법을 이용하는 소각로의 경우 산업폐기물을 소각하는 과정에서 아세트알데히드가 배출되고 있어 아세트알데히드의 주 배출원 이며 고온처리로 인한 비용부담의 단점이 있다. (중략)

  • PDF

$^{137}Cs$ and $^{90}Sr$ Sorption of Kaolinite (배올리나이트의 $^{137}Cs$$^{90}Sr$ 흡착특성)

  • 정찬호;조영환;박상원;김수진
    • Journal of the Mineralogical Society of Korea
    • /
    • v.7 no.2
    • /
    • pp.91-96
    • /
    • 1994
  • 중.저준위 방사성 폐기물의 대표적인 핵종인 137Cs, 90Sr에 대한 캐올리나이트의 흡착특성을 수용액의 이온강도와 pH의 영양하에서 알아보았다. 흡착실험은 회분식으로 하였고, 사용한 수용액은 NaCl, CaCl2, MgSO4, KCL 각각을 10-1, 10-2, 10-3, 10-4 mole/$\ell$로 하였다. 수용액광물 평형상태의 pH를 4.5, 7.0, 10.5로 조절하였다. 실험결과 캐올리나이트의 Cs, Sr 흡착은 이온강도와 pH에 상당한 영향을 받으며, Sr 흡차에 양이온들의 경쟁은 Ca2+ Mg2+>K+>Na+ 순을 보이고, Cs의 경우에는 K+>Ca2+ Mg2+>Na+의 순을 보인다. 이는 수용액상에서 이온들의 수호에너지와 관련되며, 광물입자와 이온들의 물구조변환특성에 의해 설명된다. Cs과 Sr 사이에 흡착우선성은 산성 내지 약알카리에서는 Cs이 Sr보다 흡착이 잘 되나, 강알칼리성 환경에서는 Sr이 Cs보다 흡착이 잘 되는 pH 의존성을 보였다. 수용액의 pH가 증가함에 따라 핵종의 흡착량이 증가하는데, 이는 캐올리나이트의 흡착자리인 실라놀과 알루미놀에 의한 제타전위가 pH에 의존함과 잘 일치한다.

  • PDF

The Primary Research on oil Conversion Technology of biomass by Pyrolysis (열분해에 의한 바이오매스의 유류자원화 기술에 관한 기초 연구)

  • Chio, Hyuk-Jin;Yoo, Sun-Kyoung;Oh, Sang-Woo;Lee, Seung-Guk;Lee, Seung-Hoon
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.10 no.2
    • /
    • pp.112-117
    • /
    • 2007
  • This study aims to develop an alternative energy like oil made from marine organic waste by marine products waste, spent fishing nets. There are already many commercial examples and case studies based on the petroleum industry-refuse plastic or refuse tire, however, it is rare that a research developing alternative energy from food waste and organic waste. Therefore, this study investigated the oil made from thermal decomposition under the high temperature and high pressure condition, and examined the possibility for commercial use by testing its own characteristics. A bio-oil from thermal decomposition at $250^{\circ}C$ and 40 atm was hard to remove impurities because of its high viscosity, showed lower caloric value than heavy oil, and generated various gases which were not appropriate for the use of fuel. It is noticeable that thermal decomposition was occurred at $250{\pm}5^{\circ}C$ using steam pressure, which much lower compared to the existing method of thermal decomposition, more than $500^{\circ}C$. Since the high viscosity of bio-oil, it is necessary a further study to use as liquid fuel.

  • PDF

Removal Characteristics of Mixed Heavy Metals from Aqueous Solution by Recycled Aggregate as Construction Waste (건설폐기물인 순환골재를 이용한 수용액상에서의 혼합 중금속 제거 특성)

  • Shin, Woo-Seok;Kim, Young-Kee
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.16 no.2
    • /
    • pp.115-120
    • /
    • 2013
  • This study examined the removal rate of mixed heavy metals from aqueous solution using recycled aggregate. The recycled aggregate is favorable for the absorbent because it contains about 95% (CaO, $SiO_2$, $Al_2O_3$ and $Fe_2O_3$), which are major ingredient of adsorbent for heavy metal. The kinetic data presented that the slow course of adsorption follows the Pseudo first and second order models. The equilibrium data were well fitted by the Langmuir model and showed the affinity order: $Cu^{2+}$ > $Pb^{2+}$ > $$Zn^{2+}{\simeq_-}Ni^{2+}$$ > $Cd^{2+}$. The results also showed that adsorption rate slightly increased with increasing pH from 6 to 10. Moreover, this trend is similar to results obtained as function of loading amount of recycled aggregate. Meanwhile, an unit adsorption rate was slightly decreased. From these results, it was concluded that the absorbents can be successfully used the removal of the heavy metals from the aqueous solutions.

Waste Minimization Technology Trends in Semiconductor Industries (반도체 제조 공정에서의 환경 유해성 배출물 절감 기술 동향)

  • Lee, Hyunjoo;Yi, Jongheop
    • Clean Technology
    • /
    • v.4 no.1
    • /
    • pp.6-23
    • /
    • 1998
  • Recently, semiconductor industry has grown rapidly because of the large demand for electronic devices and equipment. The semiconductor industries have also played an important role on the economic growth in Korea. As the environmental regulations become strict, the proper environmental management and the well-developed waste minimization technologies in semiconductor industries are two of urgent problems to be solved. The semiconductor manufacturing process consists of a series of continuous chemical processes, such as cleaning, oxidation, diffusion, photolithography, etching and film deposition. During the processes, various environmentally hazardous wastes are produced. The wastes may be classified as wastewater, gaseous pollutants, and solid wastes. For waste minimization, the substitution of raw materials and process optimization techniques are used, while the selective destruction technologies of toxic chemicals contained in the wastes have been reported. Also, new technologies have been developed for source reduction and waste reduction, such as reduction of toxic chemical use and substitution of hazardous liquids with gaseous reactants or solvent.

  • PDF

Study on Reutilization with Aerobic Microbes of Organic Food Waste Leachates (호기성 미생물을 이용한 음폐수의 처리 및 자원화에 관한 연구)

  • Kang, Bo-Mi;Hwang, Hyeon-Uk;Kim, Ji-Hoon;Yang, Yong-Woon;Kim, Young-Ju
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.33 no.1
    • /
    • pp.54-59
    • /
    • 2011
  • This test established the bioavailability and sample input by mixing the maintaining the microbial machine parts and food waste leachates in weight of 2:1 as advanced experiment, maintaining the constant temperature, agitating and observing its weight and property change for 60 hours. And, I injected daily the established microbial machine parts and food waste leachates rate, maintained the temperature in the reactor with $55{\sim}65^{\circ}C$, and agitated with constant speed. I studied the recycling possibility of food waste leachates by extracting the sample after 24 hours, verifying its characteristics, and repeating the food waste leachates input and sample extraction for about 40 days. Considering all about the results of this study, I saw that 87.32% of food waste leachates was reduced, and the solid of bluebug or food included in the food waste leachates was decomposed within 24 hrs. pH for 43 days after 9 days of stabilization period was maintained from 3.7~3.9 and the ignition loss from 88.67~87.3%, and the quantity of organic matter from 77.6~80.88%. With the similar result daily maintained, it is considered to progress more the minimization by inputting the future food waste leachates. C/N rate satisfies the less than 25 that is the composting basis within 8 days, maintaining between 13~15, with 2% of salt not exceeded, it is able to recycle as the compost of food waste leachates as based on the composting with no extracted heavy metal content.

From food wastes into useful probiotics: Development of Lactic acid bacteria as useful probiotics for animal feed without antibiotics using food waste (음식물류폐기물의 자원화를 위한 항세균 활성 유산균의 개발)

  • Seo, Jeong-Yong;Song, In-Geun;Lee, Dae-Gyu;Lee, Ki-Young;Kim, Young-Jun
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.14 no.2
    • /
    • pp.112-120
    • /
    • 2006
  • For the conversion of food waste into a good recycling material such as animal feed without antibiotics, thirteen lactic acid bacteria, which can be used as good probiotics for animal feed, were isolated from the intestine and feces in pigs. All isolates showed strong tolerance to high salt (4% of NaCl), acid(pH4.0), and bile juice (0.8% of oxgall). The growth rate was best at $37^{\circ}C$ in all strains. Among the isolates, Lactobacillus plantarum CJY-22, L. brevis CJY-42, L. arizonensis CJY-3, and Pediococcus sp. CJY-41 showed higher and broader spectrum of antimicrobial activities against six different pathogens such as Salmonella, typhimurium. L. plantarum CJY-22 has also grown well at $25^{\circ}C$, making this strain as an appropriate candidate for the fermentation of food waste at room temperature, thus conducting the fermentation process cost-effectively.

  • PDF

Dynamic Behavior of Offshore Waste Landfill Revetment with Geosynthethic-Soil Interface (토목섬유 접촉면을 포함한 해상 폐기물처분장 호안구조물의 동적 거동)

  • Kwak, Chang Won;Oh, Myoung Hak;Park, Inn Joon;Jang, Dong In
    • Journal of the Korean Geotechnical Society
    • /
    • v.33 no.12
    • /
    • pp.141-150
    • /
    • 2017
  • Geosynthetics are generally utilized to restrain the leakage of leachate and other contaminants during the construction of offshore waste landfill. Therefore, geosynthetic-soil interface is formed inevitably. In this study, 2 dimensional numerical analysis is performed to assess the dynamic behaviour of the offshore waste landfill including geosynthetic-soil interface. Offshore waste landfill can be divided into rubble mound revetment and retaining wall types and analyzed on each type. Effective stress analysis is conducted to consider the variation of pore water pressure and axial force and shear displacement of the interface are compared based on the characteristics of seismic frequency. Consequently, retaining wall type demonstrates more stable behavior against liquefaction potential and favorable forces and shear displacement.

Effect of Reaction Temperature Program on Thermal Degradation of Low-quality Pyrolytic Oil for Bench-scale Continuous Reaction System (벤치 규모 연속반응시스템에서 저급 열분해유 분해반응에 대한 반응온도 프로그램의 영향)

  • Lee, Kyong-Hwan;Nam, Ki-Yun
    • Clean Technology
    • /
    • v.15 no.3
    • /
    • pp.186-193
    • /
    • 2009
  • The characteristics of product materials obtained from thermal degradation of low-qualify pyrolytic oil were investigated in this study. The reactants were produced by pyrolysis of mixed plastic waste with film type in a commercial rotary kiln reaction system. The properties of reactants were measured by elemental analysis, calorimetry analysis and SIMDIST analyst. The result of degradation experiments with different reaction temperature programs was discussed through product yields, cumulative yields and production rates of oil products. The multi-step reaction temperature program resulted in higher yields of product oils and lower yields of residues than one-step reaction temperature program. The product characteristics such as production yield and the rate of oil products etc. were influenced by reaction temperature program in the continuous thermal degradation.

Relationship between Compressive Strength and Dynamic Modulus of Elasticity in the Cement Based Solid Product for Consolidating Disposal of Medium-Low Level Radioactive Waste (중·저준위 방사성 폐기물 처리용 시멘트 고화체의 압축강도와 동탄성계수의 관계)

  • Kim, Jin-Man;Jeong, Ji-Yong;Choi, Ji-Ho;Shin, Sang-Chul
    • Journal of the Korea Concrete Institute
    • /
    • v.25 no.3
    • /
    • pp.321-329
    • /
    • 2013
  • Recently, the medium-low level radioactive waste from nuclear power plant must be transported from temporary storage to the final repository. Medium-low level radioactive waste, which is composed mainly of the liquid ion exchange resin, has been consolidated with cementitious material in the plastic or iron container. Since cementitious material is brittle, it would generate cracks by impact load during transportation, signifying leakage of radioactive ray. In order to design the safety transporting equipment, there is a need to check the compressive strength of the current waste. However, because it is impossible to measure strength by direct method due to leakage of radioactive ray, we will estimate the strength indirectly by the dynamic modulus of elasticity. Therefore, it must be identified the relationship between of strength and dynamic modulus of elasticity. According to the waste acceptance criteria, the compressive strength of cement based solid is defined as more than 3.44 MPa (500 psi). Compressive strength of the present solid is likely to be significantly higher than this baseline because of continuous hydration of cement during long period. On this background, we have tried to produce the specimens of the 28 day's compressive strength of 3 to 30 MPa having the same material composition as the solid product for the medium-low level radioactive waste, and analyze the relationship between the strength and the dynamic modulus of elasticity. By controling the addition rates of AE agent, we made the mixture containing the ion exchange resin and showing the target compressive strength (3~30 MPa). The dynamic modulus of elasticity of this mixtures is 4.1~10.2 GPa, about 20 GPa lower in the equivalent compressive strength level than that of ordinary concrete, and increasing the discrepancy according to increase strength. The compressive strength and the dynamic modulus of elasticity show the liner relationship.