• Title/Summary/Keyword: 압력주입

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Cu 함량 변화에 따른 Mo-N-Cu 박막의 특성 및 내마모 특성 평가

  • Choe, Min-Gi;Jo, Seong-U;Gwon, Jeong-Dae;Kim, Jong-Guk;Kim, Do-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.227-227
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    • 2010
  • 동력 전달을 위한 구동 부품에 대한 내마모성 개선을 통한 에너지 효율 및 부품의 수명 향상에 대한 사회적 관심이 급증하고 있다. 특히, 최근에는 자동차용 구동부품에 저마찰 내마모 특성이 우수한 Mo-N-Cu 나노복합체 박막에 대한 연구가 활발하게 진행되고 있다. 본 연구에서는 Mo-N-Cu 나노복합체 박막을 마그네트론 스퍼터링 증착법을 활용하였고, 이때 Mo 및 Cu 타겟을 적용하여 동시에 증착하였다. 진공 챔버의 진공도는 $5{\times}10^{-6}\;Torr$ 이하의 초기 진공도를 확보한 이후, 알곤 및 질소 가스를 주입하여 공정 압력이 5 mTorr 수준이 되도록 하였다. 이때 N2/(Ar+N2) = 0.5를 유지하였다. Mo-N-Cu 박막내에 Cu 함량 변화를 위해 Mo 캐소드는 D.C. 1 kW로 고정하고 Cu 캐소드에 R.F. 파워를 0, 40, 60, 80 W로 변화하였다. 박막의 두께는 증착시간을 변화하면서 $1\;{\mu}m$ 이상이 되도록 하였다. Cu 캐소드에 인가된 파워의 변화에 따라 Mo-N-Cu 박막내 Cu 함유량은 10 at.%까지 변화되는 것을 EDX 분석을 통해 확인하였다. 또한 증착된 Mo-N-Cu 박막의 표면 및 단면에 대한 FE-SEM 분석을 통하여 전형적인 주상구조를 지닌 MoN 박막에서 Cu 함량이 증가할수록 Mo-N-Cu 박막의 결정성을 방해하는 것을 확인하였다. 또한 XRD 분석을 통하여 박막의 결정 구조 분석을 하였고, Nano Indentor를 통하여 30 GPa 수준의 고경도를 지닌 박막이 형성됨을 확인하였다. 박막의 내마모 특성 평가를 위해 ball-on-disk 트라이보미터를 활용하여 마찰계수 평가를 수행하였고, Cu 함유량의 변화에 따라 마찰계수가 MoN 박막의 경우 0.8에서 Cu 함량이 5 at.%에서 0.15로 급격하게 낮아짐을 확인하였다.

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$CO_2$ permeation behavior of Pebax-2533 plate membranes prepared from 1-Propanol/n-Butanol mixed solvents (1-프로판올/n-부탄올 혼합용매로부터 제조된 Pebax-2533 판형 분리막의 $CO_2$ 투과거동 연구)

  • Lee, Sang Hoon;Kim, Min Zy;Cho, Churl Hee;Han, Moon Hee
    • Membrane Journal
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    • v.23 no.5
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    • pp.367-374
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    • 2013
  • In the present study, Pebax-2533 plate membranes were prepared by drying precursor solutions which were obtained by dissolving Pebax-2533 polymer in 1-Propanol/n-Butanol mixed solvents. And then the $CO_2$ and $N_2$ permeation behaviors were tested by using a time-lag system. The prepared Pebax-2533 plate membranes showed a considerable $CO_2/N_2$ separation performance : the $CO_2$ permeability was 130 to 288 barr, and the $CO_2/N_2$ permselectivity was 5-8. The $CO_2$ permeation data obtained by varying feed pressure, permeation temperature, and solvent composition announced that not only the $CO_2$ sorption but also the $CO_2$ diffusion is equally important in the overall $CO_2$ permeation.

SCR facility design for the selective catalyst performance of mixed gas

  • Woohyeon, Hwang;Kyung-Ok, Lee
    • Journal of the Korea Society of Computer and Information
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    • v.28 no.1
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    • pp.121-127
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    • 2023
  • In this study, the design conditions and CFD analysis results are compared and reviewed in SCR that can optimally reduce nitrogen compounds. To this end, it was analyzed and compared using CFD to see if the design criteria were satisfied for the shell and tube areas of the boiler. In the SCR system, the analysis area is the gas/air heat exchanger on the shell side, and eight tubes of the gas/air heat exchanger on the tube side. Through CFD analysis, the gas velocity distribution on the primary catalyst side of the SCR system was designed to be 2.4%, and the NH3/NOx molar ratio distribution was 3.7%, which satisfied the design criteria. In addition, the uniformity of the temperature distribution was confirmed and the required condition of 260℃ or higher was satisfied. The angle of the gas entering the catalyst met the design conditions at 2.9 degrees, and the pressure loss that occurred also satisfied the design requirements. Through this CFD analysis, it was confirmed that it was designed and operated by satisfying the design conditions required for each area.

Development of Carbon Dioxide Dissolution in Water System Using Nano Bubble Technology (나노버블 기술을 이용한 수중 이산화탄소 용해 시스템 개발)

  • Byeong Chan Na;Wooseok Yeo;Deok-Hyeon Kim;Jung Jun Park;Jong Kyu Kim
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.464-464
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    • 2023
  • 최근 이산화탄소(Carbon Dioxode, CO2) 배출량 증가로 인하여 지구온난화와 같은 기후변화 문제가 심각한 사회 문제로 대두되고 있다. 이에 따라 2015년 12월 12일 프랑스 파리에서 열린 제21차 유엔기후변화협약에서 교토의정서를 대체하는 파리협정(Paris Agreement)을 채택하였으며, 국내에서는 이러한 국제사회의 기후변화 대응에 동참하고 온실가스 감축을 이행하기 위한 2050 탄소중립 정책을 추진하였다. 이산화탄소를 다량으로 발생시키는 철강·산업·건설·에너지 분야 중건설 분야에서 배출되는 이산화탄소는 전체 배출량의 19.9%로 특히 시멘트를 제조하는 과정에서 많은 양의 이산화탄소가 배출되고 있다. 기존의 건설 분야 에서는 이산화탄소를 저감하기 위해 콘크리트 배합 또는 양생과정에서 챔버 내 이산화탄소를 가스 형태로 주입하여 탄산화 반응을 통해 콘크리트 내부에 이산화탄소를 영구히 저장시키고자 하였다. 그러나 이는 챔버 사용, 양생조건 등 적용 조건이 제한적이며, 콘크리트 내 이산화탄소 흡수 효율이 높지 않아 이를 개선할 수 있는 기술이 필요하다. 이를 개선하기 위해 최근에는 콘크리트 배합수 내 이산화탄소를 용해시켜 배합과정에서 콘크리트 내부로 이산화탄소를 강제로 인입시키는 연구들이 진행되고 있다. 그러나 콘크리트 배합수로 사용되고 있는 일반물이나 지하수의 경우 가압을 하여도 약 1,400mg/L의 이산화탄소를 용해시키며, 가압을 통해 용해된 이산화탄소는 쉽게 대기 중으로 방출되는 한계점을 지니고 있어 현장에서 사용하기 어려운 문제가 있다. 이러한 한계점을 극복하기 위해서 본 연구에서는 200nm 이하의 크기를 가지는 나노버블기술을 이용해 압력을 가하지 않은 상태에서 수중에 이산화탄소를 용해시킬 수 있는 시스템을 개발하고자 한다. 나노버블기술을 이용한 수중 이산화탄소용해 시스템을 통해 수중에 이산화탄소를 용해시켜 콘크리트 배합수로 활용하기 위한 기초 연구가 될 것으로 판단된다.

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An Experimental Study on the Reinforcement Effect of Installed Micropiles in the Surround of Footing on Dense Sand (조밀한 모래지반의 기초 인접에 설치된 마이크로파일 보강효과에 관한 실험적 연구)

  • Lee Tae-Hyung;Im Jong-Chul
    • Journal of the Korean Geotechnical Society
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    • v.22 no.5
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    • pp.69-81
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    • 2006
  • The micropile, which is a kind of the in-situ manufactured pile with small diameter of $150\sim300mm$, is constructed by installing a steel bar or pipe and injecting grout into a borehole. The application fields of micropile are being gradually expanded in a limited space of down-town area, because the micropile has various advantages with low vibration and noise in method and compact size in machine, etc. Mostly, the micropile has been applied to secure the safety of structures, depending on the increment of bearing capacity and the restraint of displacement. The micropile is expected to be used in various fields due to its effectiveness and potentiality in the future. The model test, focused on the interaction between micropile and soil in this study, was carried out. The micropile is installed in a soil adjacent to footing (concept of 'soil reinforcement'). With the test results and soil deformation analysis, the reinforcement effect (relating to bearing capacity and settlement) was analysed in a qualitative and quantitative manner, respectively. Consequently, it is expected that we nay demonstrate the improvement of an efficiency and application in the design and construction of micropile.

An Experimental Study on the Reinforcement Effect of Installed Micropile under Footing on Dense Sand (조밀한 모래지반의 기초하부에 설치된 마이크로파일 보강효과에 관한 실험적 연구)

  • Lee, Tae-Hyung;Im, Jong-Chul
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.3C
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    • pp.191-200
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    • 2006
  • The micropile, which is a kind of the in-situ manufactured pile with small diameter of 100~300mm, is constructed by installing a steel bar or pipe and injecting grout into a borehole. The application fields of micropile are being gradually expanded in a limited space of down-town area, because the micropile has various advantages with low vibration and noise in method and compact size in machine, etc. Mostly, the micropile has been applied to secure the safety of structures, depending on the increment of bearing capacity and the restraint of displacement. The micropile is expected to be used in various fields due to its effectiveness and potentiality in the future. The model test, focused on the interaction between micropile and soil in this study, was carried out. The micropile is installed under footing(concept of "structure supporting"). With the test results and soil deformation analysis, the reinforcement effect(relating to bearing capacity and settlement) was analysed in a qualitative and quantitative manner, respectively. Consequently, it is hoped to demonstrate the improvement of an efficiency and application in the design and construction of micropile.

Membrane-Based Carbon Dioxide Separation Process for Blue Hydrogen Production (블루수소 생산을 위한 이산화탄소 포집용 2단 분리막 공정 최적화 연구)

  • Jin Woo Park;Joonhyub Lee;Soyeon Heo;Jeong-Gu Yeo;Jaehoon Shim;Jinhyuk Yim;Chungseop Lee;Jin Kuk Kim;Jung Hyun Lee
    • Membrane Journal
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    • v.33 no.6
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    • pp.344-351
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    • 2023
  • The membrane separation process for carbon dioxide capture from hydrogen reformer exhaust gas has been developed. Using a commercial membrane module, a multi-stage process was developed to achieve 90% of carbon dioxide purity and 90% of recovery rate for ternary mixed gas. Even if a membrane module with being well-known properties such as material selectivity and permeability, the process performance of purity and recovery widely varies depending on the stage-cut, the pressure at feed and permeate side. In this study, we verify the limits of capture efficiency at single-stage membrane process under various operating conditions and optimized the two-stage recovery process to simultaneously achieve high purity and recovery rate.

Report on Extended Leak-Off Test Conducted During Drilling Large Diameter Borehole (국내 대구경 시추공 굴진 중 Extended Leak-Off Test 수행 사례 보고)

  • Jo, Yeonguk;Song, Yoonho;Park, Sehyeok;Kim, Myung Sun;Park, In-Hwa;Lee, Changhyun
    • Tunnel and Underground Space
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    • v.32 no.5
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    • pp.285-297
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    • 2022
  • We report results of Extended Leak-Off Test (XLOT) conducted in a large diameter borehole, which is drilled for installation of deep borehole geophysical monitoring system to monitor micro-earthquakes and fault behavior of major fault zones in the southeastern Korean Peninsula. The borehole was planned to secure a final diameter of 200 mm (or more) at a depth of ~1 km, with 12" diameter wellbore to intermediate depths, and 7-7/8" (~200 mm) to the bottom hole depth. We drilled first the 12" borehole to approximately 504 m deep and installed American Petroleum Institute standard 8-5/8" casing, then annulus between the casing and bedrock was fully cemented. XLOT was carried out for several purposes such as confirming casing and cementing integrity, measuring rock stress states. To that end, we drilled additional 4 m long open hole interval to directly inject water and pressurize into the rock mass using the upper API casings. During the XLOT, flow rates and interval pressures were recorded in real time. Based on the logs we tried to analyze hydraulic conductivity of the test interval.

A Study on Pullout-Resistance Increase in Soil Nailing due to Pressurized Grouting (가압 그라우팅 쏘일네일링의 인발저항력 증가 원인에 관한 연구)

  • Jeong, Kyeong-Han;Park, Sung-Won;Choi, Hang-Seok;Lee, Chung-Won;Lee, In-Mo
    • Journal of the Korean Geotechnical Society
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    • v.24 no.4
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    • pp.101-114
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    • 2008
  • Pressurized grouting is a common technique in geotechnical engineering applications to increase the stiffness and strength of the ground mass and to fill boreholes or void space in a tunnel lining and so on. Recently, the pressurized grouting has been applied to a soil-nailing system which is widely used to improve slope stability. Because interaction between pressurized grouting paste and adjacent ground mass is complicated and difficult to analyze, the soil-nailing design has been empirically performed in most geotechnical applications. The purpose of this study is to analyze the ground behavior induced by pressurized grouting paste with the aid of laboratory model tests. The laboratory tests are carried out for four kinds of granitic residual soils. When injecting pressure is applied to grout, the pressure measured in the adjacent ground initially increases for a while, which behaves in the way of the membrane model. With the lapse of time, the pressure in the adjacent ground decreases down to a value of residual stress because a portion of water in the grouting paste seeps into the adjacent ground. The seepage can be indicated by the fact that the ratio of water/cement in the grouting paste has decreased from a initial value of 50% to around 30% during the test. The reduction of the W/C ratio should cause to harden the grouting paste and increase the stiffness of it, which restricts the rebound of out-moved ground into the original position, and thus increase the in-situ stress by approximately 20% of the injecting pressures. The measured radial deformation of the ground under pressure is in good agreement with the expansion of a cylindrical cavity estimated by the cavity expansion theory. In-situ test revealed that the pullout resistance of a soil nailing with pressurized grouting is about 36% larger than that with regular grouting, caused by grout radius increase, residual stress effect, and/or roughness increase.

Solid Flow Rate and Gas Bypassing with Operating Variables of J-valve in Multistage Annular Type Fluidized Beds (다단 환원형 유동층에서 J-valve의 운전변수에 따른 고체 흐름량 및 기체 우회)

  • Hong, Yoon-Seok;Kang, Gyung-Soo;Park, Joo-Sik;Lee, Dong-Hyun
    • Clean Technology
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    • v.17 no.1
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    • pp.62-68
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    • 2011
  • Hydrodynamic characteristics in multistage annular type fluidized bed (riser: $0.01{\times}0.025{\times}2.8m^3$, J-valve: $0.009{\times}0.015m^2$)were investigated. Glass beads ($d_p=101{\mu}m$, ${\rho}_b=1,590kg/m^3$, $U_{mf}=1.25{\times}10^{-2}m/s$, Geldart classification B) was used as a bed material. Accumulated weight by the electronic balance was measured to determine the solid flow rate in batch-type. In circulation condition, we measured the accumulated weight of particle transported from riser. At the steady state condition, solid circulation rate was calculated from time interval of the heated bed material passing between two thermocouples. Solid flow rate increased with increasing inlet gas velocity ($1.2-2.6U_{mf}$) and the static bed height (z, 0.24-0.68 m) from 2.2 to 23.4 kg/s. However, mean residence time decreased with increasing inlet gas velocity ($1.2-2.6U_{mf}$) and the static bed height (z, 0.24-0.68 m) from 1,438 to 440 s. The solid holdup in the riser was determined by measuring pressure differences according to the riser height. These results showed a similar trend to that of simple exponential decay type except for the top section of the riser. To verify the gas bypassing from top bubbling beds to middle bubbling beds, $CO_2$ gas was injected by tracer gas in constant ratio, and then was measured $CO_2$ concentration in outlet gas by gas chromatography. Gas bypassing occurred below 2.6% which is negligible value.