• The Korean Journal of Ecology
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• v.23 no.1
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• pp.45-49
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• 2000

Tolerances of aquatic plants (emergent plants) of cattail (Typha orientalis), water oats (Zizania latifolia), reed (Phragmites communis), and bulrush (Scirpus nipponicus) to salts and high NH₄/sup ＋/-N cone. of industrial wastewater were evaluated. Evapotranspiration of cattail and water oats plants was not affected when the wastewater containing 130 ppm NH₄/sup ＋/-N with electrical conductivity of 3.0 dS/m was supplied for 5 months. Shoot and root dry wt. of cattail and water oats were rather increased by irrigation of the wastewater while the biomass production of bulrush was greatly reduced. Storage nitrogen concentration in tissues of water oats and reed plants were higher than those in cattail and bulrush. Thus, water oats and reed plants were found to be the better aquatic plants to use in constructed wetlands for treating industrial wastewater of high salt and NH₄/sup ＋/-N.

• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.2
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• pp.71-78
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• 2013

This study examined the feasibility of phosphorus removal from dewatering centrate/filtrate in wastewater treatment by struvite formation. Since dewatering centrate/filtrate obtained after anaerobic digestion contains a high content of ammonia, magesium addition and pH adjustment could remove phosphorous. The optimum magnesium dose, reaction time, settling time, and pH value was found at 2 mol Mg/mol $PO_4^{3-}$, 10 min, 120 min, and 8.5, respectively. A bench-scale continuous operation at the optimum condition showed 80% of total phosphorus removal and 82% of phosphate removal in dewatering centrate. The elemental composition and crystal structure of the chemical precipitate was similar to the reported values of struvite.

• 한국해양학회지
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• v.26 no.2
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• pp.144-154
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• 1991

After the completion of the Nakdong River estuary barrage, environmental characteristics and phytoplankton communities in the estuary were investigated from April to December, 1989. dissolved oxygen seems to have decreased in the just lower region of the barrage off Janglim, while ammonia and phosphate concentration increased, probably due to the waste discharge from the Janglim stream and stagnation of water after the barrage construction. Concentrations of nitrate and dissolved silicate were negatively correlated with salinity, suggesting that major source is the Nakdong River discharge. In April, there was a diatom (Asterinella sp.) bloom in the upper region of the barrage, while in July, a diatom (Skeletonema costatum) bloom in the estuary mouth. The green and blue-green algae in species composition seem to have increased after the barrage construction. The relatively high concentration of chlorophyll b in the upper region of the barrage probably result from the high density of freshwater green-algae there. Among the species occurred in the study area, many were indicative of water pollution. It seems that environmental characters and phytoplankton communities are changing after the barrage construction.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.5 no.6
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• pp.558-561
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• 2004

The morphology of silica supported $MoO_{3}$ catalysts, which was prepared by impregnation of ammonium heptamolybdate(AHM) with various surface loadings up to 4 atoms $Mo/nm^{2}$, was studied using x-ray diffraction(XRD). All morphologies of silica supported $MoO_{3}$ appear to be thermodynamically driven. For high loaded catalysts there appeared three states: a sintered and well-dispersed hexagonal state at moderate temperature calcination($300^{\circ}C$), and a sintered orthorhombic state at high temperature calcination($500^{\circ}C$). Whereas the sintered orthorhombic phase is detected by XRD at loadings in excess of 1.1 atom $Mo/nm^{2}$, the well-dispersed hexagonal phase is not detected even until 4.0 $atomsMo/nm^{2}$. The higher apparent dispersion of the hexagonal phase may arise from some role of ammonia which results in a stronger $MoO_{3}-SiO_{2}$ surface interaction.

• Proceedings of the KAIS Fall Conference
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• 2006.05a
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• pp.572-576
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• 2006

본 시험은 산란계에 생균제를 급여하였을 때 산란계의 산란능력과 계분내 유해가스 감소에 미치는 영향을 규명하기 위하여 실시하였다. 산란계용 사료에 생균제를 0.2%와 0.5%를 처리한 구와 무처리의 3개 처리구를 두고 처리당 6반복, 반복당 4수씩 총 72수의 갈색 산란계(36주령)를 공시하여 6주간(42일) 사양 시험을 실시하였다. 산란계 사료에 생균제의 참가량을 증가함에 따라 산란율은 증가하였으며, 사료 섭취량은 감소하였다. 한편 계란의 품질에서는 생균제의 첨가량을 증가함에 따라 난중, 농후난백고, HU 및 난항색도가 증가하였다. 산란계의 영양소 이용율에서는 가용무질소물을 제외하고 건물, 조단백질, 조지방 및 조섬유 이용율이 생균제를 첨가함에 따라 증가하였다. 계분내 유해가스 발생량에서는 암모니아, 황하수소 및 멜캅탄 가스의 감소에 효과가 있었으며, 특히 황화수소의 감소에 효과가 있었다. 이상의 시험결과를 종합해 볼 때 산란계에 첨가한 생균제는 산란율을 증가시킬 뿐만아니라 계란의 품질 향상에 효과가 있었다. 또한 영양소 이용율을 개선하고 계분내 유해가스를 감소시키는 효과가 있었다.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.1249-1254
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• 2008

Industrial low temperature waste heat exists sparse in surroundings but its amount is huge. However, large portion of waste heat is discarded due to its poor recovery quality and inferior application technologies. The heat pump system in this research is based on the hybrid combination of compression cycle and absorption cycle in order to recycle various kind of industrial waste heat effectively. The prime objective is to design a compression absorption hybrid heat pump system which can produce high temperature above the level of $90^{\circ}C$ and low temperature of $20^{\circ}C$ at the same time using waste heat water of $50^{\circ}C$. A mathematical simulation was carried out as a basis to design a prototype 3 RT class hybrid heat pump. From the simulation results, fundamental parameters to design the system were obtained.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.24 no.1
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• pp.1-7
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• 2014

Aluminum nitride, which has outstanding properties such as high thermal conductivity and electrical resistivity, has been received a great attention as a substrate and packaging material of semiconductor devices. Since aluminum nitride has a high sintering temperature of 2173 K and its properties depends on the impurity level, it is necessary to synthesize high-purity and nano-sized aluminum nitride powders for the applications. In this research, we synthesized high purity aluminum nitride nanopowders from aluminum using RF induction thermal plasma system. Sheath gas (NH3) flow was controlled to establish the synthesis condition of high purity aluminum nitride nanopowders. The obtained aluminum nitride nanopowders were evaluated by XRD, SEM, TEM, BET, FTIR and N-O analysis.

• Journal of the Korean Chemical Society
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• v.44 no.6
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• pp.547-555
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• 2000

The surface water in the upstream and midstream of Nakdong river, which is being used as tap water and industrial water supply in Daegu city and Kyungpook province, was analyzed in its water quality. In addition, the sediments of which was analyzed in terms of heavy metal and organic substance contents. All the sampling was done in the drought season for 2 days of June 22-23 and carried out in 10 sampling sites. The sites cover the whole Kyungpook provincial region, starting from Yangsam Bridge in Chyeong Ryang Provincial Park as the upper end, to the Ko Ryung Bridge as the lower end sampling site of Nakdong river that flows through Kyungpook province. The 22 items including $NH^{+}_{4}$, $NO^{-}_{2}$ and COD were analyzed for surface water and 11 items including organic constituents(trichloroethylene, etc) and heavy metals were analyzed for sediments. The sediments samples were analyzed by elution testing method and acid dissolution method and then the results were compared with each other. All heavy metals in samples were determined by Inductively Coupled Plasma-Atomic Emission Spectroscopy(ICP-AES) and other constituents were analyzed by standard testing methods of the Korean Ministry of Environment.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.4
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• pp.382-389
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• 2012

Power generation cycle using ammonia-water mixture as working fluid has attracted much attention because of its ability to efficiently convert low-temperature heat source into useful work. If an ammonia-water power cycle is combined with a power cycle using liquefied natural gas (LNG), the conversion efficiency could be further improved owing to the cold energy of LNG at $-162^{\circ}C$. In this work parametric study is carried out on the thermodynamic performance of a power cycle consisted of an ammonia-water Rankine cycle as an upper cycle and a LNG cycle as a bottom cycle. As a driving energy the combined cycle utilizes a low-temperature heat source in the form of sensible heat. The effects on the system performance of the system parameters such as ammonia concentration ($x_b$), turbine 1 inlet pressure ($P_{H_1}$) and temperature ($T_{H_1}$), and condenser outlet temperature ($T_{L_1}$) are extensively investigated. Calculation results show that thermal efficiency increases with the increase of $P_{H_1}$, $T_{H_1}$ and the decrease of $T_{L_1}$, while its dependence on $x_b$ has a downward convex shape. The changes of net work generation with respect to $P_{H_1}$, $T_{H_1}$, $T_{L_1}$, and $x_b$ are roughly linear.

• Journal of the Korean Chemical Society
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• v.37 no.4
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• pp.408-415
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• 1993

Systematic ab initio SCF calculations have been performed on the hydrogen-bonded dimers of fluoromethanes involving $CH_4,\;CH_3F,\;CH_2F_2\;and\;CHF_3$ with ammonia and water applying basis sets of 9s5p/5s and 9s5p1d/5p1d. Various ground state properties of these stable dimeric complexes have been evaluated. We compared these with corresponding properties of isolated monomers. We report equilibrium geometries, stabilization energies, dipole moments and force constants of intermolecular bonds. The effects arising as a consequence of the non-additive behavior of hydrogen bonding in chain-like oligomers are discussed. Systematic, methodical errors due to the use of the SCF approximation and the basis set dependence of the computed results are pointed out.