• Title/Summary/Keyword: 암모니아/물

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The Efficacy of Water Purification and Distribution of Ammonia Oxidizing Bacteria in Shihwa Constructed Wetland (시화호 인공습지의 수질정화 및 암모니아 산화균의 분포 연구)

  • Kim, Seiyoon;Kim, Misoon;Lee, Sunghee;Lim, Miyoung;Lee, Youngmin;Kim, Zhiyeol;Ko, GwangPyo
    • Journal of Korean Society on Water Environment
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    • v.26 no.1
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    • pp.10-18
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    • 2010
  • Water quality and the distribution of ammonia oxidizing bacteria were characterized in constructed wetland of Shihwa lake. Both physico-chemical parameters and fecal indicator microorganisms including total coliforms, E.coli, Enterococcus spp. were measured. In addition, denaturant gradient gel electrophoresis (DGGE) was carried out after PCR amplification of amoA gene from input, output, and wetland sites of the Banwol, Donghwa, and Samhwa stream in Shihwa lake area. Physico-chemical parameters were in proper range for typical nitrifying bacteria to grow and perform their biological activities. Average concentrations of fecal indicator microorganisms of wetland samples were lower than those of input sites. These results suggested that microbial water quality improved by the process of constructed wetland. According to phylogenetic information obtained from DGGE from study sites, distribution of nitrifying bacteria from each of input, output, and wetland were generally distinctive one another. In addition, distribution of nitrifying bacteria between Banwol and Donghwa streams showed higher similarity (52.6%) than this of Samhwa stream (15.2%). These results indicated that characteristics of ammonia oxidizing bacteria in Samhwa were unique in comparison with those of Banwol and Donghwa stream.

Effect of Water-back-flushing in Advanced Water Treatment System by Tubular Alumina Ceramic Ultrafiltration Membrane (관형 알루미나 세라믹 한외여과막에 의한 고도정수처리 시스템에서 물 역세척의 영향)

  • Park, Jin-Yong;Lee, Song-Hui
    • Membrane Journal
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    • v.19 no.3
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    • pp.194-202
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    • 2009
  • In this study periodic water-back-flushing using permeate water was performed to minimize membrane fouling and to enhance permeate flux in advanced water treatment by tubular ceramic ultrafiltration membrane for Gongji stream in Chuncheon city. The back-flushing period (FT, filtration time) 2 min with periodic water-back-flushing of 15 sec showed the highest value of dimensionless permeate flux (permeate flux vs. initial permeate flux), and the lowest value of resistance of membrane fouling. Also in the results of BT effect at fixed FT 10 min, BT (back-flushing time) 20 sec showed the lowest value of resistance of membrane fouling and the highest value of dimensionless permeate flux, and we could be obtained the highest total permeate volume of 107.3 L. Consequently FT 10 min and BT 20 sec could be the optimal condition in Gongji stream water treatment, which was the exactly same results of our previous tubular alumina microfiltration. Then the average rejection rates of pollutants by our tubular ceramic UF system were 97.0% for turbidity, 32.1 % for chemical oxygen demand by manganese method, 28.8% for ammoniac nitrogen and 54.4% for T-P.

Development of Life Cycle Inventory (LCI) Database for Production of Liquid CO2 (액체 이산화탄소의 전과정목록(LCI) DB 구축에 관한 연구)

  • Lee, Soo-Sun;Kim, Young Sil;Ahn, Joong Woo
    • Clean Technology
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    • v.21 no.1
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    • pp.33-38
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    • 2015
  • In this research, life cycle inventory database (LCI DB) was developed for liquid CO2 employing life cycle assessment (LCA) methodology. As are result of characterization and normalization process, production of liquid CO2 puts on environmental impact in the order of resource depletion, global warming, acidification, eutrophication and photochemical oxidation, and among a wide variety of input, electricity contributes in most of the impact categories. Air emission plays a key role in the acidification and eutrophication while ammonia affects most on the ozone depletion. It is anticipated that development of liquid CO2 LCI DB makes it possible for national environmental strategies to be more activated including environmental labeling scheme.

An Experimental Study on the Fundamental Properties of Zeolite Concrete (제올라이트 콘크리트의 기초 물성에 관한 실험적 연구)

  • Jo, Byung Wan;Choi, Ji Sun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.1
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    • pp.1-8
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    • 2012
  • Since the cement industry is expected to face serious setbacks in the near future associated with environmental concerns. With the advent of new technologies and increased public awareness about global environmental issues, the cement industry is actively seeking to adopt new technologies as part of an effort to diversity its resources. This study is designed to assess the fundamental properties of zeolite cement concrete which consists mainly of natural zeolite, which is known for removal of and harmful gas, ion exchange capacity removing cation contaminant including heavy metals and ammonia, absorptive capacity and molecular sieving effect together with excellent insulation capacity as a porous material, and recently draws much attention for its possibility as an alternative material to cement. The study was conducted to show the compressive strength of concrete, slump, bleeding and air volume according to the changes of natural zeolite and alkali activator(NaOH). As a result of measuring the compressive strength of natural zeolite concrete, it was almost 40MPa and displayed similar to general concrete in the tests of slump, bleeding and air volume, with which it was considered that it may be used as a future high performance, high performance construction material.

A study on the water distribution scenario for the water supply center according to the inability of water supply disaster (용수불능 재난상태에 따른 취수장 용수배분 시나리오 연구)

  • Ahn, Seung Seop;Lim, Dong Hee;Lee, Hyo Jin;Park, Ki Bum
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.368-368
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    • 2019
  • 경제의 발전과 더불어 사회가 복잡해지면서 재난의 발생은 다양한 형태로 더욱 복잡하게 발생하고 있다. 최근들어 매년 발생하는 가뭄과 기후적 특성으로 인한 유량의 변동성으로 인해 수질오염이 심해지기를 반복하고 있다. 특히, 산업단지나 화재 등 여러 가지 원인으로 인해 수질오염사고도 빈번하게 발생하고 있으며 심한 경우 취수원의 취수중단과 같은 심각한 상황을 발생하기도 한다. 최근들어 심각한 가뭄과 폭염으로 인해 취수원의 수질이 악화되는 사고들이 발생하고 있으며, 과거 수질오염사고를 살펴보면 1991년에 낙동강에서 발생한 구미 두산전자의 페놀방류에 의한 사고로 18시간 동안 대구에 취수가 중단된 적이 있으며, 1994년 대구광역시 성서공단에서 배출된 유기용제에 의해 낙동강 수계 5개 정수장이 취수가 중단된 바도 있다. 또한 2008년 김천공단 (주)코오롱 유화에서 방류된 페놀에 의해 대구의 취수원 중 두류, 매곡취수장이 5시간동안 취수가 중단된바 있으며, 2009년 다이옥산 배출, 2015년 구미공단에서 불소, 암모니아성 질소, 1.4 다이옥산 배출사고, 2018년 과불화화합물에 낙동강 수질사고, 운문댐과 가창댐 유역의 가뭄으로 인한 취수정지 상태가 발생하는 등 대구광역시 시민들의 먹는 물에 대한 불안이 끊이지 않고 있다(Peacenews, 2018). 본 연구는 대구광역시의 상수도시설이 재난상황 발생에 따라 취수가 중단되어 물을 생산하는 취수장이 불능상태가 되는 가상의 시나리오를 설정하고 각 정수장에서 용수를 공급할 수 있는 대응에 대해서 검토하였다. 대구시에서 운영하는 정수장은 총 5개이며, 전체 공급량의 60.5%를 낙동강을 수원으로 하는 매곡과 문산정수장에서 취수하고 있다. 가상의 재난상황 시나리오는 각각의 정수장이 재난발생에 따라 운영이 불가능한 경우인 Scenario 1(a)~(e)와 매곡과 문산정수장이 운영불가능한 경우인 Scenario 2를 가정하여 용수공급 대응방안에 대해 검토하였다. 그 결과 Scenario 1(a)~(e)에서는 매곡정수장이 운영이 불가능한 경우 대구광역시 전체의 용수공급 신뢰도 80.4%로 250 lpcd를 공급할 수 있으며, Scenario 2의 경우에는 낙동강 오염사고로 인해 매곡과 문산정수장이 운영이 불가능할 경우 60.4%의 신뢰도로 205 lpcd를 공급할 수 있는 것으로 검토되었다.

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Variation of the CO2 Capture Reaction by Ammonia Solution with Temperature (온도에 따른 암모니아 용액에 의한 CO2 포집 반응의 변화 양상)

  • Kim, Soo-Yeon;Choi, Ye-Seul;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.27 no.6
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    • pp.896-904
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    • 2011
  • The features of the capture reaction of $CO_2$ by ammonia solution have been investigated along with the effect of temperature on the reaction based upon computer program-utilizing calculation and thermodynamic estimation. The stable region of $CO{_3}^{2-}$ was observed to increase with temperature and the change of the stable region of $CO{_3}^{2-}$ with temperature was greater than the temperature variation of the stable region of other carbonate species. The distribution diagram for $NH_4{^+}-NH_3$ system was constructed and the rise of temperature resulted in the decrease of the stability of $NH_4{^+}$ ion, which was thought to be due to the endothermic nature of its acidic dissociation. Considering the introduction of $Ca^{2+}$ ion in the carbon capture reaction by $NH_4{^+}$, the temperature was observed to be important in the determination of the order of reaction between carbonate ion and these cations. The removal process of $CO_2$ gas by ammonia solution was presumed to occur in open system and the temperature variations of the concentration of carbonate system species along with their total concentration were calculated for the proper control and design of the real process.

Pathogenesis of Inflammation in H. pylori Infection

  • 정현채
    • 대한위암학회:학술대회논문집
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    • 2002.04a
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    • pp.9-17
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    • 2002
  • 위의 parietal cell 혹은 대식세포와 유사한 세포 내부에서 H. pylori가 발견된다는 보고가 있기는 하나 일반적으로 H. pylori는 Shigella와 같은 침습성 세균은 아닌 것으로 알려져 있다. 그럼에도 불구하고 H. pylori에 감염된 위점막에는 많은 수의 호중구를 위시한 염증세포의 침윤이 관찰되는데 H. pylori가 위상피세포에 부착 할 경우 위상피세포를 자극하여 interleukin-8을 위시한 cytokine 을 발현케하고 이에 의하여 호중구 등의 염증세포가 몰려들게 된다. 한편 고유층에 몰려든 호중구에서는 다시 interleukin-8을 위시한 일련의 호중구 활성화 chemokine을 분비하여 염증반응을 증폭해 나갈 것이다. 호중구에서 발현되는 myeloperoxidase나 활성 산소 등도 위점막의 조직 손상에 기여할 것이다. 위상피세포를 덮고 있는 점액층은 위상피세포를 보호한다고 알려져 있으나 H. pylori 감염의 경우 점액층에 의하여 H. pylori의 운동성이 증가하고 이것이 위상피세포로부터의 cytokine 발현을 자극하여 염증반응을 증폭하는데 관여할 가능성도 있다. H. pylori는 위상피세포에 대하여 apoptosis를 유도함과 동시에 고유층에 몰려든 호중구에 대하여는 apoptosis를 억제케하여 궁극적으로 염증반응을 증폭 및 지속시켜 나가는 쪽으로 작용한다. 한편 H. pylori는 위상피세포로부터 COX-2의 발현을 증가시키는데 이는 위상피세포의 apoptosis를 억제하는 방향으로 작용한다. 이외에 H. pylori의 urease에 의하여 발생한 암모니아나 H. pylori 자신이 분비하는 세포독소가 세포 손상을 유발할 가능성도 있다. 상술한 여러 독성 인자들 중 어느 하나가 단독으로 작용하기보다는 여러 인자가 같이 동시에 또는 시차를 두고 작용할 가능성이 많다고 생각된다.(\gamma-FeOOH)$, 침철광$(\alpha-FeOOH)$, 적금광$(\beta-FeOOH)$, 그리고 자철광$(Fe_3O_4)$이다. 인위적 부식에서는 전부 인철광의 부식물이 생성되었고 자연적 부식에서는 모두 침철광의 부식물이 생성되었다. 특히 철제 표면에 자연적으로 생성된 공식 녹을 XRD 분석한 결과 적금광으로 동정되었다. 이런 모든 시편들을 각 탈염방법에 따라 탈염처리한 후 XRD와 SEM-EDS으로 분석한 결과 인철광과 침철광은 어떠한 변화도 보이지 않았고, 다만 적금광으로 동정된 시편만이 잔존하지 않았다. 철기 제작별 $Cl^-$ 이온 추출량과 탈염효과에 대한 비교 실험은 이온 크로마토그래피 분석 결과와 마찬가지로 단조 철제유물이 주조 철제보다 $Cl^-$ 이온을 많이 가지고 있었으며, 탈염 처리 후에는 $Cl^-$ 이온은 전혀 발견되지 않았다. 이상의 결과 $K_2CO_3$와 Sodium 용액은 탈염처리에서 가장 적합한 탈염처리 용액으로 알수가 있었으며 특히 어떠한 탈염 용액으로 유물을 처리한다 해도 철제유물에 생성된 부식물은 제거되지 않는다는 것을 알게 되었다. 따라서 보존처리자는 유물 표면의 부식 상태만을 보고 처리하기 보다는 철기제작물로 고려하여 처리하는 것이 필요하다. 또한 금속에 부식을 야기시키는 $Cl^-$ 이온과 부식물을 완전하게 제거하여 탈염처리를 하는 것이 유물 부식을 최대한 지연시킬 수 있는 것이라 생각된다.TEX>$88\%$)였다.(P=0.063). 결론: 본 연구에서는 MTHFR C/T & T/T 유전자 다형성이 위암의 발생과 그 위치에 대해 관련이 있는 것으로 여겨지고, 흡연력, 음주력과는 관련이 없는 것으로 여겨진다.험이

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Processes and Fluxes of Uranium Removal Across the Sediment-Water Interface: A Biogeochemical Approach (해수-퇴적물 경계면을 지나는 우라늄 제거 과정과 플럭스 연구: 생지화학적 접근)

  • Kim, Kee-Hyun;Cho, Jin-Hyung;Lee, Jae-Seong
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.4 no.3
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    • pp.188-197
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    • 1999
  • In order to estimate the uranium flux from seawater to sediments, we took pore water samples and deployed benthic chambers on seafloor of Chonsu Bay, Korea. The uranium flux across the sediment-water interface was estimated from the pore water to be 0.112-0.566 mg/$m^2yr$, corresponding to a removal flux of $4.3-21.5{\times}10^7$ gU/yr for the entire Yellow Sea. Nutrient fluxes from sediment to bottom water were estimated to be 135.6 mmol/$m^2yr$ for ammonia, 228.2 mmol/$m^2yr$ for nitrate, 36.8 mmol/$m^2yr$ for phosphate and 23.9 mmol/$m^2yr$ for silicate. The redox boundary, based on the distribution of pore water nitrate and solid phase manganese, was located at 3-5 cm below the sediment surface. Phosphate flux obtained by benthic chambers was 28.S mmol/$m^2yr$. On the other hand, estimates of uranium and silicate fluxes were orders of magnitude greater than those based on pore water profiles. Flux estimates on the basis of pore water concentration is believed to have greater reliability than those obtained from benthic chamber data.

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Quality Characteristic of Saccharified Materials Manufactured from Germinated Barley (발아보리를 이용한 고추장 당화물의 품질특성)

  • Cha, Mi-Na;Yoon, Young;Jang, Seon-A;Song, Geun-Seoup;Kim, Young-Soo
    • Korean Journal of Food Science and Technology
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    • v.43 no.3
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    • pp.315-320
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    • 2011
  • Germination conditions were evaluated to obtain barley containing a high content of gamma-aminobutyric acid (GABA), and quality characteristics of saccharified materials manufactured using germinated barley were investigated. Water absorption content of barley increased but pH of the steeping solution decreased with increasing steeping time at all steeping temperatures. The changes in water absorption content and pH were highest at a steeping temperature of $25^{\circ}C$. The highest GABA content was obtained at a steeping condition of $25^{\circ}C$ for 20 h. The highest GABA content was obtained for a germination condition of $5^{\circ}C$ for 36 h after steeping, resulting in an increase of 7.4 times more GABA contents than that in raw material. The pH of saccarified materials decreased but titratable acidity, amino type nitrogen content, and ammonia type nitrogen content increased during the saccharification period. GABA content of saccarified materials increased with increasing saccharification period, resulting in the highest GABA content from saccarified materials containing germinated barley.

Isolation and Characterization of Helicobacter pylori Urease Inhibitor from Rubus coreanus Miquel (복분자(Rubus coreanus Miquel)로부터 Helicobacter pylori Urease Inhibitor의 분리 및 특성)

  • 양성우;호진녕;이유현;신동훈;홍범식;조홍연
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.5
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    • pp.769-777
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    • 2004
  • A Helicobacter pylori urease inhibitor from Rubus coreanus Miquel has been isolated and partially characterized for aiming to Prevent H. pylori growth and decrease harmful accumulation of ammonia in human gastric mucosa. We screened urease inhibitory activities in 519 extracts library prepared by solvent extraction from 173 kinds of edible plants, medicinal herbs, herbs and seaweeds using a colorimetric urease assay system. As results of primary and secondary screening, 70% acetone extract of Rubus coreanus Miquel was selected as potent candidate, showing about 24% inhibitory activity. The acetone extract was sequentially partitioned into RCE/RCWI and RCB/RCW2 layers with ethyl acetate and butanol. The major active component in RCW2, water layer from butanol fractionation was revealed to be peptidic or proteinous substance by inhibitory activity determination after pronase digestion and periodate oxidation. RCW2-IIIc a was isolated by sequential column chromatography on DEAE-Toyopearl 650C, Butrl-Toyopearl 650M and Sephadex LH-20. The isolated urease inhibitor RCW2-IIIc $\alpha$, was highly pure proteinous substance with molecular weight of 13kDa by high-performance gel permeation liquid chromatography. RCW2-IIIc$\alpha$ has about 5 times higher inhibitory activity than 70% acetone extract, showing high stability against heat treatment and peptic digestion.