• Title/Summary/Keyword: 암모니아/물

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Anti-inflammatory Effect of Natural Plant Extracts on in vitro Rumen Fermentation and Methane Emission (천연 식물 추출물의 항염 효과가 in vitro 반추위 발효성상과 메탄 생성에 미치는 영향)

  • Lee, Shin Ja;Lee, Su Kyoung;Lim, Jung Hwa;Son, Chang Jun;Lee, Sung Sill
    • Journal of agriculture & life science
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    • v.51 no.4
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    • pp.97-109
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    • 2017
  • This study was conducted to investigate the effects of anti-inflammatory plant extracts on the in vitro rumen fermentation characteristics and methane emission. Anti-inflammatory plant extracts from Morus bombycis Koidz, Mallotus japonicus L., Morus alba L., Paulownia coreana Uyeki, Isodon japonicus Hara and Ginkgo biloba L. were used in the study. The ruminal fluid(5 mL), McDougall buffer(10 mL), timothy as a substrate(0.3 g) and each anti-inflammatory plant extract(5% of substrate) were dispensed anaerobically into 50mL serum bottle. The mixtures were incubated for 3, 9, 12, 24, 48 and 72h at $39^{\circ}C$ without shaking. Supplementation of the anti-inflammatory plant extracts did not effects characteristics(pH, digestibility of dry matter, glucose concentration, ammonia concentration, protein concentration, VFA) on rumen fermentation. Total gas was showed a different pattern depending on treatments. Carbon dioxide was significantly(p<0.05) higher in Morus alba and Isodon japonicus than in control at 48h. Methane was significantly(p<0.05) lower in treatment than in control at initial fermentation. However the more incubation time was increased, the more methane emission was higher in treatment than in control. The concentrations of polyphenol and flavonoid were higher in Ginkgo biloba. In conclusion, supplementation of the anti-inflammatory plant extracts did not effect on rumen fermentation and methane emission was decreased in initial fermentation.

Protective effect of Artemisiae Capillaris Herba water extract on liver injury induced by thioacetamide (인진호 열수 추출물이 thioacetamide에 의해 유발된 간손상에 미치는 간보호 효과)

  • Kim, Min Ju;Lee, Jin A;Shin, Mi-Rae;Park, Hae-Jin;Roh, Seong-Soo
    • Journal of Nutrition and Health
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    • v.54 no.4
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    • pp.412-421
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    • 2021
  • Purpose: Thioacetamide (TAA) produces reactive oxygen species (ROS) in the liver, and the generated ROS induces liver injury through inflammatory reactions. The current study was undertaken to investigate the hepatoprotective effect of Artemisiae Capillaris Herba water extract (AC), imparted via its antioxidant activity, in an animal model of TAA-induced liver injury. Methods: Animal experiments were conducted in 5 groups: normal, control (TAA 200 mg/kg), SM (TAA 200 mg/kg + silymarin 100 mg/kg), ACL (TAA 200 mg/kg + AC 100 mg/kg), ACH (TAA 200 mg/kg + AC 200mg/kg). TAA (intraperitoneal) and treatment compounds (per oral) were administered for 3 days. Serum levels of ammonia concentration and myeloperoxidase (MPO) activity were subsequently measured. Liver tissues were subjected to western blot analysis for measuring the oxidative stress (NADPH oxidase), anti-oxidative activity (Nrf2, heme oxygenase-1 [HO-1], superoxide dismutase [SOD], catalase, and GPx-1/2), tissue inhibitors of metalloproteinase (TIMP)-1, and matrix metalloproteinases (MMPs) protein expressions. Results: Serum ammonia levels and MPO activity were significantly increased in the TAA-induced control group, whereas groups administered AC treatment showed markedly reduced levels. Western blot analysis revealed significantly increased NOX2 and p22phox expressions, (oxidative stress-related factors) in the TAA-induced control group. These levels were determined to be significantly decreased after AC exposure. Moreover, antioxidant-related factors including Nrf2, HO-1, SOD, catalase, and GPx-1/2 were significantly decreased in the control group and increased in the AC treated groups. In addition, MMP expressions were significantly suppressed in the AC treatment group due to increased levels of TIMP-1. Conclusion: Taken together, these data indicate that exposure to AC reduces the oxidative stress by inhibiting the expression of NADPH oxidase (NOX2 and p22phox) through the Nrf2 signaling pathway. We therefore propose the potential of AC for the prevention and treatment of TAA-induced liver injury.

열 화학기상증착법을 이용한 BCN 나노시트의 합성과 전기적 특성 분석

  • Jeon, Seung-Han;Cha, Myeong-Jun;Song, U-Seok;Kim, Seong-Hwan;Jeon, Cheol-Ho;Park, Jong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.399-399
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    • 2012
  • 최근 그래핀 연구와 더불어 2차원 구조의 나노소재에 대한 관심이 급증하면서 육각형의 질화붕소(hexagonal boron nitride; h-BN) 나노시트(nanosheet)[1]나 붕소 탄화질화물(boron caronitride;BCN) 나노시트[2, 3]와 같은 2차원 구조체에 대한 연구가 활발히 진행되고 있다. 그 중 BCN은 반금속(semimetal)인 흑연(graphite)과 절연체인 h-BN이 결합된 나노시트로 원소의 구성 비율에 따라 전기적 특성을 제어할 수 있다는 장점이 있다. 따라서 다양한 나노소자로의 응용을 위한 연구가 활발히 진행되고 있다. 본 연구에서는 열 화학기상증착법(thermal chemical vapor deposition)을 이용하여 폴리스틸렌(polystyrene)과 보레인 암모니아(borane ammonia)를 사용하여 BCN 나노시트를 합성하였다. 합성된 BCN 나노시트의 구조적 특징과 화학적 조성 및 결합 상태를 주사전자현미경(scanning electron microscopy), 투과전자현미경(transmission electron microscopy), X-선 광전자 분광법(X-ray photoelectron spectroscopy), 라만 분광법(Raman spectroscopy)을 통해 조사하였고, 이온성 용액법 (ionic liquid)[4]을 이용하여 전계효과 특성을 측정하였다.

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Comparative Exergy Analysis of Kalina and Organic Rankine Cycles for Conversion of Low-Grade Heat Source (저등급 열원의 변환을 위한 칼리나 사이클과 유기 랭킨 사이클의 엑서지 성능의 비교 해석)

  • KIM, KYOUNG HOON;JUNG, YOUNG GUAN;KO, HYUNG JONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.1
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    • pp.105-111
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    • 2020
  • The organic Rankine cycle (ORC) and the Kalina cycle system (KCS) are being considered as the most feasible and promising ways to recover the low-grade finite heat sources. This paper presents a comparative exergetical performance analysis for ORC and Kalina cycle using ammonia-water mixture as the working fluid for the recovery of low-grade heat. Effects of the system parameters such as working fluid selection, turbine inlet pressure, and mass fraction of ammonia on the exergetical performance are parametrically investigated. KCS gives lower lower exergy destruction ratio at evaporator and higher second-law efficiency than ORC. The maximum exergy efficiency of ORC is higher than KCS.

Numerical Analysis on the Beat and Mass Transport in Horizontal MOCVD Reactor for the Growth of GaN Epitaxy (수평형 MOCVD에 의한 GaN 에피층 성장시 반응로내의 열 및 물질전달에 관한 수치해석 연구)

  • 신창용;윤정모;이철로;백병준
    • Journal of the Korean Vacuum Society
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    • v.10 no.3
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    • pp.341-349
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    • 2001
  • Numerical calculation has been performed to investigate the fluid flow, heat transfer and local mass fraction of chemical species in the MOCVD(metalorganic chemical vapor deposition) manufacturing process. The mixing of reactants (trimethylgallium with hydrogen gas and ammonia) was presented by the concentration of each reactant to predict the uniformity of film growth. Effects of inlet size, location, mass flow rate and susceptor/cold wall tilt angle on the concentration were reported. From the numerical calculation, the concentration of reactants could be qualitatively predicted by the Nusselt number(heat transfer) and the optimum mass flow rate, wall tilt angle and inlet condition were considered.

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Performance Analysis of a 5 RT Air-Cooled $NH_3-H_2O$ Absorption Chiller with the Variations of Heat Input and Ambient Temperature (5 RT 공랭형 $NH_3-H_2O$ 흡수식 냉동기의 발생기 입력 열량과 외기온도 변화에 따른 성능분석)

  • 윤희정;김성수;강용태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.5
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    • pp.438-443
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    • 2004
  • The objective of this paper is to study the effects of the input gas flow rate and the ambient temperature variation on the absorption cycle performance. An air-cooled NH$_3$-$H_2O$ absorption chiller is tested in the present study. The nominal cooling capacity of the single effect maching is 17.6 ㎾ (5.0 USRT). The cooling capacity, coefficient of performance, burner efficiency, and each state point are measured with the variations of the heat input and the ambient temperature. It is found that the COP and cooling capacity increase with increasing the generator exit temperature up to a certain temperature and then decrease. It is also found that the COP and the cooling capacity decrease with increasing the ambient temperature. The maximum COP of 0.51 is obtained from the present experiment.

The Synthesis of $Nb_2Zr_6O_{17-x}N_x$ : A New Visible Light Oxynitride Photocatalyst ($Nb_2Zr_6O_{17-x}N_x$의 합성 : Oxynitride계 신규 가시광 광촉매)

  • Kanade, K.G.;Baeg, Jin-Ook;Kale, B.B.;Lee, Sang-Mi;Moon, Sang-Jin;Lee, Chul-Wee;Chang, Hyun-Ju
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.1
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    • pp.55-61
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    • 2006
  • 신규 $Nb_2Zr_6O_{17-x}N_x$ 광촉매를 고상합성법처리(solid state synthesis) 후 암모니아가스($NH_3$)에 의한 기상처리법(ammonolysis)으로 합성하였다. 합성된 신규 광촉매 및 이를 다시 Pt 및 $RuO_2$를 도핑 하여 $H_2S$를 광분해하여 수소를 발생 실험을 수행하였다. 이 신규 oxynitrid계 광촉매는 가시광하에서 $H_2S$를 광분해하여 수소를 발생하는(Quantum yield = 13.5 %) 우수한 광촉매 활성을 보여주었다.

Design of a High Temperature Production Heat Pump System Using Geothermal Water at Moderate Temperature (중온 지열수를 이용한 고온제조 열펌프 시스템 해석 및 설계)

  • Kim, Min-Sung;Baik, Young-Jin;Park, Seong-Ryong;Chang, Ki-Chang;Lee, Young-Soo;Ra, Ho-Sang
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.638-641
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    • 2008
  • Geothermal water at moderate temperature in a range between 30 to $50^{\circ}C$ exists sparse in surroundings. Mostly they are utilized as heat or water source at spar zones in Korea. However, a large portion of used water is discarded due to its poor recovery quality and inferior application technologies. In this research, an innovative heat pump system based on the hybrid concept that combinate compression cycle and absorption cycle was investigated mathematically. The hybrid heat pump aims to recycle various kind of the heat sources at moderate temperature including geothermal water effectively. The prime objective of the simulation is to design a compression/absorption hybrid heat pump system which can make high temperature above the level of $90^{\circ}C$ and low temperature of $20^{\circ}C$ as well at the same using $50^{\circ}C$ geothermal heat water. As a result, primitive data was provided as a basis to design a prototype 3 RT class hybrid heat pump.

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Physical Properties and Dyeability of Cotton Fabrics Treated with Liquid Ammonia (액체암모니아 처리 면직물의 물성 및 염색성)

  • Jeon, Sung-Ki;Lee, Chang-Soo;Im, Yong-Jin;Lee, Chung;Kim, Tae-Kyung;Lee, Hye-Jung
    • Textile Coloration and Finishing
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    • v.15 no.4
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    • pp.73-79
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    • 2003
  • It is generally known that cotton treated with liquid ammonia has better soft handle, wrinkle recoveries and stability of appearance as compared with the alkali mercerized cotton. In this study, the various cotton fabrics treated with liquid ammonia$(NH_3)$, sodium hydroxide(NaOH) and sodium hydroxide(NaOH)/liquid ammonia$(NH_3)$ and untreated cotton fabric were investigated and compared in terms of physical properties and dyeing behavior. As the result, the strength of four kinds of cotton fabrics were similar. But the elongation of cotton treated with liquid ammonia increased slightly. Liquid ammonia treatment reduced the crystallinity of cotton and the crystalline structure of cotton transformed from cellulose 1 to mixed structure of celluloseIand III. In dyeing, dyeing rate decreased but equilibrium dye uptake increased by liquid ammonia treatment of cotton fabrics.

Preparation of $TiO_2$Nanocrystalline Powder at Low Temperature (저온 처리에 의한 결정형 $TiO_2$나노분말의 제조)

  • Seo, Dong-Seok;Lee, Jong-Kook;You, Hae-Geun;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.38 no.4
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    • pp.331-336
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    • 2001
  • TiOCl$_2$수용액과 암모니아수의 반응으로부터 얻은 titanium hydroxide 침전물에 대해 각각 NaOH 또한 HCl 처리를 통하여 비교적 낮은 온도에서 결정성이 우수하고, 높은 비표면적을 갖는 결정형 TiO$_2$나노분말을 제조하였다. 저온처리 조건을 변화시킴으로써 TiO$_2$분말의 결정상과 입자 모양을 제어할 수 있었는데, NaOH 처리한 다음 산처리한 분말에는 아나타제와 루틸상이 함께 형성되었으며 구형입자와 긴 스핀들 모양의 입자들로 이루어져 있었고, 비등수 처리 시에는 열처리를 통해 아나타제상의 구형 입자들을 얻을 수 있었다. Titanium hydroxide를 0.1M과 0.5M에 산처리한 분말은 모두 아나타제상을 나타내었는데, 0.1M의 분말은 구형입자로 이루어져 있었고, 0.5M의 경우는 대부분 구형입자들로 이루어져 있었지만 스핀들 모양의 입자들도 소량 관찰되었으며, 2M에 산처리한 분말은 루틸상으로서 모두 스핀들 모양의 입자들로 이루어져 있었고, 제조된 분말의 비표면적은 약 240-250$m^2$/g을 나타내었다.

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