• Analytical Science and Technology
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• v.26 no.1
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• pp.27-33
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• 2013

Polyalkylsilanes such as poly(dialkyl)silanes and poly(monoalkyl)silanes were synthesized by sonochemical dechlorination-condensation method from (dialkyl or monoalkyl)chlorosilanes with sodium metal. Those polyalkylsilanes were analyzed for the properties such as thermal behaviors from TGA analysis and obtained ceramic yields of 10-20% for poly(dialkyl)silanes and 40-60% for poly(monoalkyl)silanes. Ceramic composite discs were prepared by the combined mixture of polyalkylsilanes and SiC powder and were tested by TGA and analyzed by SEM and XRD for the application as binder for ceramic composite precursors.

• Membrane Journal
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• v.16 no.2
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• pp.106-114
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• 2006

This study is concerned with preparation of chlorine resistant (CR) thin layer composite (TFC) membranes. The novel method for making CR membranes from commercially available RO membranes is based on sol-gel condensation of trialkoxyalkylsilane derivatives. The silane coupling agents used in this study have different number of alkyl carbon chain group (methyltriethoxysilane; METES and octyltriethoxysilane; OCTES). The OCTES composite membranes have a significant tolerance to chlorine compared to commercial polyamide RO membrane or METES composite membranes. The surface properties of membranes were examined to explain a significant difference of chlorine tolerance between OCTES composite membrane and the other two membranes. In this study, we tried several surface analyses to explain difference of chlorine tolerance. The element composition results of surface analysis by EDX confirmed that both silane fixed on polyamide firmly, The surface roughness and contact angle results showed long chain alkyl group of OCTES enhancing hydrophobicity considerably than METES. The hydrophobicity plays an important role in chlorine resistance of membrane.

• Proceedings of the KSME Conference
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• 2007.05a
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• pp.521-526
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• 2007

Density functional calculations have been performed for the reactions of perfluoroalkylsilane and alkylsilane with silica surfaces. The (100) and (111) surfaces of ${\beta}-cristobalite$ are used as two possible models of the hydroxylated amorphous silica surface. This is the crystalline phase of silica with density and refractive index closest to those of amorphous silica. Moreover, two ${\beta}-cristobalite$ surfaces have the two types of silanol groups, namely the single silanols and the geminal silanols. We investigate the possible adsorption structure and formation energy of perfluoroalkylsilane and alkylsilane molecules with two type of silanol groups. The results will be compared with cluster and slab model.

• Journal of Conservation Science
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• v.27 no.2
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• pp.201-209
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• 2011

While consolidants based on tetraethoxysilane (TEOS) have been widely used for the consolidation of decaying stone heritages, TEOS-based consolidants suffer from practical drawbacks, such as crack formation of the gel during the drying phase due to the developed capillary force. We have prepared new TEOS-based consolidants containing flexible (3-glycidoxypropyl) trimethoxysilane (GPTMS) in order to reduce capillary force development during gel drying. In this study, we have prepared TEOS/GPTMS-based consolidants containing ETEOS in order to improve the surface hydrophobisity. The physical properties of the TEOS/GPTMS/ETEOS solution with different hydrolysis were compared with those of the commercial products Wacker OH$^{(R)}$. The contact angle of the surface increased with the addition of the ETEOS, which is higher than that of Wacker OH$^{(R)}$. The sol-gel mechanism was manipulated by the degree of hydrolysis as well as the amount of ETEOS. The properties and the applicability of the developed consolidants for the decayed Korean granites are also investigated.

• The Korean Journal of Rheology
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• v.10 no.1
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• pp.24-30
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• 1998

솔젤법을 이용하여 단분산의 실리카 입자를 제조하고 농도변화에 따른 실리카 분산 액의 유변학적 거동을 해석하였다. 단분산 실리카 입자의 제조는 솔젤법을 이용한 액상반으 으로 제조하였고 입자의 안정화를 위하여 입자표면에 실란커플링제를 코팅하여 유기용매에 서 안정성을 갖도록 하였다. 분산액의 농도에 따른 유변학적 거동을 조사하기 위하여 부피 분율( )이 0.05인 희박 분산계로부터 =0.55의 고농도 분산계를 제조하였다. 솔젤법을 통하 여 단분산 실리카 입자를 성공적으로 제조하였으며 실란커플링제인 ${\gamma}$-methacryloxypropyl triethoxysilane로 입자의 표면을 화학적 방법으로 처리하여 유기용매 상에서 알킬기의 작용 에 의한 hard-sphere'특성을 나타내도록 하였으며 동시에 분산안정성을 유지할수 있었다. 입자 분산계는 =0.25이하의 부피농도에서는 분산용매와 같은 뉴톤거동을 보여주었으며 이 이이상의 농도에서는 비뉴톤거동인 전단담화(shear thinning)현상과 high shear limiting viscosity를 나타내었다. 이결과는 Krieger-Dougherty 식을 따름이 확인되었으며 부피분율 =0.50정도까지도 이식이 잘적용됨을 확인하였다. 부피분율 =0.50 이상의 고농도 입자 분산계 는 급격한 점도의 증가와 함께 전단담화와 전단탁화(shear thickening)현상이 모두 관찰되었 다. 특히 전단탁화를 일으키는 특헝전단변형률(cr)이하의 전단변형률에서는 안정되고 빠른 점성반응(viscous response)을 보여주었으나 특성 전단변형률 부근과 이상의 전단변형률 영 역에서는 매우 불안한 거동이 보여짐을 확인하였다. 그러나 이러한 점도 거동은 가역적이며 전단변형률을 증가시킬때와 감소시킬 때의 유변학적 거동이 거의 일치하였다.

• Membrane Journal
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• v.25 no.4
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• pp.332-342
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• 2015

In this study, to solve the major problem of reverse osmosis (RO) membrane, surface of reverse osmosis membrane was modified by silane-epoxy multi layer. Octyltrimethoxysilane (OcTES) was polymerized to membrane surface via cross-linking by Sol-gel method. n = 8 alkylgroup of OcTES formed the branch structure by self assembly. And for improve fouling resistance of RO membrane, Ether group of ethylene glycol diglycidyl ether (EGDE) was given to improve hydrophilicity of RO membrane surface by ring-opening. To analyze structure of RO membrane surface with FE-TEM and AFM. Membrane surface of the ridge and valley structure and the bridge structure was confirmed due to the multi-layer surface modification of OcTES and EGDE. And through the increase of the roughness, the branch structure was formed well on membrane surface. Through the XPS analysis was identified chemical structure of membrane surface. And confirmed that the hydrophilic surface modification is given to the surface of the film through a Contact angle analysis. In optimization of EGDE surface modification condition, was suitable 0.5 wt% EGDE concentraion and $70^{\circ}C$ ring-opening temperature. In result of fouling resistance test and MFI is SUL-H10, $PA-OcTES_{1.0}$, $PA-OcTES_{1.0}-EGDE_{0.5}$ 68.7, 60.4, 5.4 ($10E-8hr/mL^2$), multi-layer surface modified membrane improved fouling resistance.

• Journal of the Korean Applied Science and Technology
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• v.29 no.3
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• pp.377-392
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• 2012

It has been known that small solid particles act as a stabilizer in pickering emulsion system. In this study, we successfully prepared stable pickering emulsion in n-hexylalcohol and water system with $TiO_2$ whose surface was treated by alkylsilane. The optimum condition to prepare pickering emulsion stabilized by $TiO_2$ particles was determined by amount of $TiO_2$ particles and ratio of water and oil phase. The type of pickering emulsion was dependent on wettability of particles for water and n-hexylalcohol. When the amount of $TiO_2$ particles increased up to 5.00 wt%, the stability of pickering emulsion was showed to be improved. The most stable pickering emulsion was prepared in the case of W/O type which has the ratio of oil and water phase (3 : 7). We tried to prepare porous $SiO_2-TiO_2$ composite pigments using a pickering emulsion as template at the optimal condition. Porous pigments were synthesized with Ludox HS-30 as an inorganic material by sol-gel process. The characteristics and shape of porous pigments were measured by optical microscope, SEM, BET, XRD and EDS.

• Journal of the Korean Chemical Society
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• v.43 no.4
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• pp.447-455
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• 1999

Allyl (5R)-(Z)- and (5R)-(E)-6-[(2S)-2,3-isopropylidenedioxypropylidene]Penicillanate(10a and 10b) were prepared from allyl (5R)-dibromopenicillanate(6) via a sequence of reactions involving condensation with 2,3-O-isopropylidene-D-glyceraldehyde, reduction with $Zn-NH_4OAc$, and Mitsunobu elimination. Deprotection of isopropylidene and allyl groups of 10a gave potassium (5R)-(Z)-6-[(2S)-2,3-dihydroxypropylidene]penicillanate(4). However, deprotection of isopropylidene group of 10b afforded ${\alpha},\;{\beta}$-unsaturated-lactone(12). Allyl (5R)-(Z)- and (5R)-(E)-6-[(2S)-2-(t-butyldimethlsilyloxy)propylidene]penicillanate(18a and 18b) were prepared from ally (5R)-dibromopenicillanate(6) via a sequence of reactions involving condensation with (2S)-2-(t-butyldimethylsilyloxy)propanal(15), reduction with $Zn-NH_4OAc$ and Mitsunobu elimination or mesylation-elimination. Deprotection of t-butyldimethylsilyl and allyl groups of 18a and 18b gave potassium (5R)-(Z)- and (5R)-(E)-6-[(2S)-2-hydroxypropylidene]penicillanate(5a and 5b), respectively.

• Journal of the Korean Applied Science and Technology
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• v.36 no.2
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• pp.498-506
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• 2019

This study is based on a coating method that provides utilization value as a micronised powder for cosmetic raw materials using natural minerals buried in Bonghwa, Gyeongsangbuk-do in Korea. The mineral powder name is called Buseok, and chemical name is pumice powder. The results of a study on the efficacy of cosmetics are reported by the development of particulate powder to assess the performance of this powder. First of all, in order to coat the surface of this powder with oil, aluminum hydroxide was coated on the particulate surface and then coated with alkylsilan. In addition, it was coated with vegetable oil to prevent condensation of the powder and increase the dispersion in the oil phase. First; the particle size of pumice powder was from 10 to 50mm having porous holes on the surface of the particles. Second; The components of this powder contained $SiO_2$, $Al_2O_3$, $Fe_2O_3$, MgO, CaO, $K_2O_2$, $Na_2O$, $TiO_2$, $TiO_2$, MnO, $Cr_2O_3$, $V_2O_5$. Third: The particles of this powder have a planetary structure and are reddish-brown with porosity through SEM and TEM analysis. Fourth; the far-infrared radiation rate of this parabolic powder was $0.924{\mu}m$, and the radiative energy was $3.72{\times}102W/m^2$ and ${\mu}m$. In addition, the anion emission is 128 ION/cc, which shows that the coating remains unchanged. Based on these results, it is expected to be widely applied to basic cosmetics such as BB cream, cushion foundation, powderfect, and other color-coordinated cosmetics, sunblock cream, wash-off massage pack as an application of cosmetics. (Small and Medium Business Administration: S2601385)