• Title/Summary/Keyword: 알칼리 - 실리카 반응성

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Performance Evaluation of Admixture for Durability Improvement of Shielding Materials Used Waste Glass as Fine Aggregate (폐유리를 잔골재로 사용한 차폐채움재의 내구성 개선을 위한 혼화재료의 성능평가)

  • Hwang, Byoung-Il;Kim, Hyo-Jung;Song, Yong-Soon;Yi, Seong-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.2
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    • pp.20-27
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    • 2019
  • Compared to the development and manufacturing technology of electronic goods, the development of waste glass recycling technology is relatively insufficient, leading to the acceleration of waste of resources and environmental pollution. Although waste glass recycling technology is being actively developed overseas, waste glass recycling technology is insufficient in Korea, leading to the illegal dumping or burial of waste glass. Waste glass has been confirmed to have pozzolan reaction potential when having hydration reaction with cement. Waste glass is also reported to be effective in reducing bleeding and inhibiting the development of hydration heat by improving the physical properties of concrete and the rheology properties of fresh concrete. Therefore, this paper analyzed the strength characteristics and the effect of alkalic-silica reaction on the expansion of shielding concrete that used waste glass as fine aggregate. Where, suitable admixture materials were used as a measure to suppress the expansion.

An Experimental Study on the Alkali-Silica Reaction of Crushed Stones (Part4: The Application of the JIS Rapid Test Method to the Several Domestic Reactive Aggregates) (쇄석골재의 알칼리-실리카 반응에 관한 실험적 연구 (제4보: 국내산 반응성 골재에 JIS 신속법 적용가능성))

  • 차태환;조원기;조일호;노재호;이양수;정재동;윤재환
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.447-450
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    • 1994
  • The chemical method and mortar-bar method for identification of the susceptibility to Alkali-Aggregate Reaction (AAR) was established as KS method by referencing the ASTM methods. However, the chemical method requires skilled chemical engineers and aggregates are tested in very severe condition, and on the other hand, the mortar-bar method needs a long time of 3 or 6 months. Judging from this circumstance that the use of crushed stones are increased due to the shortage of natural aggregates, the development and standardization of a new rapid test method is considered essential. The purpose of this paper is to research for the possibility to apply the rapid method, instead of the chemical method and the mortar-bar method with using the several domestic crushed stones.

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Effects of Content of Reactive Aggregate on Alkali-Silica Reaction Expansion (반응성 골재의 혼입량이 모르타르의 알칼리-실리카 반응 팽창에 미치는 영향)

  • Lee Ju Hyun;Jun Ssang Sun;Um Jang Sub;Jin Chi Sub
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.435-438
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    • 2005
  • The effect of content of reactive aggregate on alkali-silica reaction was investigated through the ASTM C 1260 method. The replacement proportions of fine aggregate by reactive aggregate were 25, 50, 75 and $100\%$, respectively. Reactive aggregate and fine aggregate(non-reactive aggregate) used are a metamorphic rock and andesite rock, respectively. The results indicate that the mortar-bar containing $25\%$ replacement of fine aggregate by reactive aggregate shows the lowest expansion but expansion in excess of $0.1\%$ at 16 days, which can distinguished between deleterious and potentially reactive. Although content of reactive aggregate is a small amount, it can cause detrimental expansion due to alkali-silica reaction.

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A Feasibility Study on the Application of Ferrosilicon By-Product in Concrete to Replace Silica Fume (콘크리트 내 실리카퓸을 대체하기 위한 페로실리콘 산업부산물의 활용 적절성에 대한 연구)

  • Kim, Hansol;Cho, Won Jung;Ann, Ki Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.413-422
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    • 2019
  • A ferrosilicon (FS) by-product was applied into a cementitious binder in concrete substituting the ordinary Portland cement (OPC). The original material characteristic of FS is very identical to silica fume (SF) regarding chemical composition and physical properties such as specific surface area and specific gravity. Therefore, the FS and SF concrete or mortal of which 10% of the material was replaced to total binder weight were fabricated to evaluate the feasibility of using F S as a binder, and the comparative information of OPC, FS and SF concrete was given. The hydration characteristic of FS concrete was analyzed using X-ray diffraction analysis. The FS concrete was beneficial in compressive strength, resistivity against chloride ingress and reducing porosity considering performance of OPC concrete but the advantage was less than using SF. A possibility of alkali-silica expansion was found out from the FS concrete due to the agglomerated size of the silica particles.

The Effect of the Residual Mortar of Recycled Concrete Aggregate on Alkali Silica Reaction (순환/재생골재의 잔류 모르타르 성분이 알칼리 실리카 반응성에 미치는 영향 평가)

  • Kim, Jeonghyun;Kim, Namho;Yang, Sungchul
    • International Journal of Highway Engineering
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    • v.17 no.4
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    • pp.19-24
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    • 2015
  • PURPOSES : The objective of this study is to evaluate the effect of the residual mortar of recycled concrete aggregate on the expansion behavior during alkali silica reaction (ASR). METHODS: In order to evaluate the net effect of residual mortar on ASR expansion behavior, two aggregate samples with the same original virgin aggregate source but different residual mortar volumes were used. ASTM C1260 test was used to evaluate the ASR expansion behavior of these two aggregates and the original virgin aggregate. RESULTS: The greater the amount of residual mortar in recycled concrete aggregates, the less is the induced ASR expansion. Depending on the amount of residual mortar in recycled concrete aggregate, the ASR expansion of recycled concrete aggregate may be less than half of that of the original virgin aggregate. CONCLUSIONS: The residual mortar of recycled concrete aggregate may lead to the under estimation of the ASR expansion behavior of the original virgin aggregate.

Application of Fly Ash Concrete in the Pavement (시험시공을 통한 플라이애쉬 콘크리트 포장 적용 특성)

  • Hong, Seung-Ho;Lee, Byung-Duk;Han, Seung-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.701-704
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    • 2008
  • The case of failure of Alkali-silica reaction (ASR) on the cement concrete pavement was reported in Korea. In the United States America, the fly ash has less than 10 percent Cao reported that prevent expansion by ASR. Most of all fly ash in Korea have less than 10 percent CaO, therefore it is similar ASTM F fly ash in the USA. Crushed aggregates of the test section had expansion behavior by potential ASR that the ASTM C 1260 test method tested expansion 0.17 percent during 14 days. The test section of concrete pavement used crushed aggregate was constructed that fly ash have 20 percent weight of cementitious materials to prevent expansion by ASR. This study was performed flexural strength test for elapsed days and durability by freeze-thaw test. It was shown that flexural strength was increased elapsed days and good performed freeze-thaw test. This study shown that fly ash concrete pavement was good performance in the test section.

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Asymmetric Catalytic Activity of Mesoporous Mordenite containing Polymeric Chiral Salen Complexes in the Mesopore System (폴리머 키랄 살렌을 함유한 메조세공 모더나이트의 비대칭 촉매 활성)

  • Guo, Xiao-Feng;Kim, Yong-Suk;Kawthekar, Rahul B.;Kim, Geon-Joong
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.279-284
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    • 2009
  • The formation of mesoporous pores in the microporous mordenite crystals was performed by controlled silica extraction on alkaline treatment. Inner tunable mesopore size could be controlled by changing the concentration of alkaline solution. The pore structure of mordenite zeolite was studied by instrumental analysis after alkaline-treatment. To obtain the cage type mesopores, Ti-coating on the ourside mordenite crystals before alkaline treatment was investigated to be the most effective. Polymeric chiral salen Co (III) complexes were successfully encapsulated in mesoporous mordenite zeolite by "ship-in-a-bottle" method. The heterogeneous catalyst could be applied in asymmetric ring opening of epichlorohydrine by water. It showed very excellent enantioselectivity with a high yield in the catalysis.

Reaction Characteristics of Kaolinite-based Additives and Alkali Salts (Kaolinite 계열의 첨가제와 알칼리염의 반응 특성)

  • Jun, HyunJi;Choi, Yujin;Shun, Dowon;Han, Keun-Hee;Bae, Dal-Hee;Rhee, Young-Woo
    • Clean Technology
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    • v.26 no.3
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    • pp.221-227
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    • 2020
  • When the waste solid fuel (SRF, Bio-SRF) is burnt in a boiler, a problem occurs in the combustion process involving the alkali components (Na, K) contained in large amounts in the fuel. The alkaline component has a low melting point, which usually forms low melting point salt in the temperature of the furnace, with the resulting low melting point salts attaching to the heat pipe to form a clinker. Various additives are used to suppress clinker generation, and the additive based on the kaolinite has alkali-aluminum-silica to inhibit the clinker. In this study, the reactivity of the additives based on the kaolinite was compared. The additives utilized were R-kaolinite, B-kaolinite, and A-kaolinite. Also silica and MgO were sourced as the comparison group. The experimental group was employed as a laboratory-scale batch horizontal reactor. The additive and alkaline salts were reacted at a weight ratio of 1 : 1, and the reaction temperature was performed at 900 ℃ for 10 hours. The first measurement of HCl occurring during the experiment was performed 30 minutes after the detection tube was used, and the process was repeated every hour after the experiment. After the reaction, solid residues were photographed for characterization analysis by means of an optical microscope. The reaction characteristics of the kaolinite were confirmed based on the analysis results.

Mineralogical and Mechanical Properties of some Rocks as Aggregates and Their Suitabulity for Concrete (골재용 암석의 광물학적 및 역학적 특성과 콘크리트용으로서의 적합성 연구)

  • 진호일;민경원;연규석
    • Magazine of the Korea Concrete Institute
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    • v.10 no.4
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    • pp.183-193
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    • 1998
  • This study was designed, firstly, to determine the mineralogical and chemical characteristics of some rock aggregates, secondly, to offer interrelationships between those and mechanical properties, and thirdly, to evaluate their suitability for concrete aggregates. Mineralogical, chemical, physical and mechanical characteristics of the studied rock aggregates indicate that granite from BJ quarry and banded gneisses from KB. HI and SK quarry, and quartzite from the Hongcheon riverside are not proper to cement concrete aggregates because of quartz's potential possibility of alkali-silica reaction, and limestone in SY quarry is proper to asphalt concrete aggregates owing to dolomite causing alkali-carbonate reaction. Augen gneiss and diorite from KB and SA quarry, respectively, are to be not suitable for concrete aggregates because of biotite contents, but augen gneiss in HI quarry and gneisses in Hongcheon riverside are proper to concrete aggregates because of mineralogical and mechanical characteristics.

Effect on Ferronickel Slag Powder in ASR (페로니켈 슬래그 미분말이 ASR에 미치는 영향)

  • Kim, Min-Seok;Seo, Woo-Ram;Rhee, Suk-Keun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.1
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    • pp.9-14
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    • 2022
  • Most of the existing research on ferronickel slag has focused on its potential as aggregate and fine aggregate, this study was conducted focusing on the potential of ferronickel slag powder as a concrete admixture. For concrete, which fly ash, blast furnace slag, and FSP were mixed with each 10 % type the reactivity was evaluated by applying ASTM C 1260 of the United States. As a result, compared with the control group, the expansion rate of fly ash decreased by 8.43 % and that of fine blast furnace slag powder decreased by 14.46 %, while the expansion rate of ferronickel slag decreased by 49.40 %. it was confirmed that ferronickel slag can sufficiently be replaced existing supplementary cementitious admixtures such as fly ash and blast furnace slag in terms of suppressing the reactivity of aggregates. However as a result of SEM analysis, ettringites were generated, and additional research about how it affects concrete is needed.