• Title/Summary/Keyword: 알칼리장석

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Applied Petrologic Study of the Daebo Biotite Granites in the mid Gyeonggi Massif (경기육괴 중부에 분포하는 대보 흑운모화강암류의 응용암석학적 연구)

  • Yun, Hyun-Soo;Hong, Sei-Sun;Park, Deok-Won;Lee, Jin-Young
    • The Journal of the Petrological Society of Korea
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    • v.21 no.2
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    • pp.263-275
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    • 2012
  • Jurassic Daebo biotite granites, known as one of the main stone resources in the country, are widely and away distributed in the Pocheon and Yangju areas of the mid Gyeonggi massif. The objects of the study are mainly to reveal the unique characteristics of grain size, rock color, mineral composition, physical property and fracture system from the above biotite granites. Biotite granites from the Pocheon area (PG) and Yangju area (YG) are represented by coarse-grained and light gray, and medium to coarse-grained and grayish to light gray, respectively. In modes, main minerals of Qz+Af+Pl (quartz+alkali feldspar+plagioclase) are more increased in the PG, and accessories of biotite are more increased in the YG, which differences can cause the PG more bright light gray than the YG. Specific gravity (SG) shows somewhat more increasing in the YG than the PG. These differences can be caused by more increasing in biotite contents of higher specific gravity compared to the major minerals in the former than the latter. Absorption ratio (AR) and porosity (PR) of the PG and YG show the same values of 0.33 % and 0.86 %, respectively. In the correlations, PR vs SG and AR vs PR show gradually negative and distinctly positive trends, respectively. Compressive strength (CS) and tensile strength (TS) show increasing in the PG (CS: 1,775 $kg/cm^2$, TS: 87 $kg/cm^2$) than the YG (CS: 1,647 $kg/cm^2$, TS: 79 $kg/cm^2$). These strength characteristics could be attributed to the inherent rock textures of them. Abrasive hardness (AH) also shows a little increasing in PG, which can be caused by increase in quartz contents having higher hardness than the other major minerals. Orientations of fracture sets from the PG and YG were compared with those of vertical rift and grain planes in Mesozoic granites of the country. From the overlapped diagram, the distribution pattern between fracture sets and above vertical planes suggests that microcrack systems developed in Mesozoic granites in Korea occur also in the Daebo biotite granite bodies of the mid Gyeonggi massif. From the relation diagram showing the characteristics of fracture patterns for the above two area, PG and YG may have more potentiality for dimension and non-dimension stone resources, respectively.

Geochemical Studies on Petrogenesis of the Cretaceous Myeongseongsan Granite in the Northwestern Gyeonggi Massif (경기육괴 북서부에 분포하는 백악기 명성산 화강암의 성인에 대한 지화학적 연구)

  • Yi, Eun Ji;Park, Ha Eun;Park, Young-Rok
    • The Journal of the Petrological Society of Korea
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    • v.26 no.4
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    • pp.327-339
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    • 2017
  • The Cretaceous Myeongseongsan Granite in the northwestern Gyeonggi Massif consists of a major pale pink-colored biotite monzogranite and a minor white-colored biotite alkaligranite. Low Sr and high Ba concentrations, negative Eu-anomalies in REE plot, negative Sr anomalies in spider diagram, a negative correlation between Sr and Rb, and positive correlations between Sr and Ba and $Eu/Eu^*$ indicate that a fractional crystallization of both plagioclase and K-feldspar played a significant role during magma evolution. The Myeongseongsan Granite is plotted in I-& S-type granites on I, S, A-type granite classification scheme. While the biotite monzogranite is plotted in unfractionated I-& S-type granite, the biotite alkaligranite is plotted in fractionated I-& S-type granite, which indicates that the biotite alkaligranite is a more differentiated product. In order to elucidate the nature of the protoliths of the peraluminous Myeongseongsan magma, we plotted in $Al_2O_3/TiO_2$ vs. $CaO/Na_2O$ and Rb/Sr vs. Rb/Ba diagrams, and they suggest that the Myeongseongsan Granite was derived from clay-poor metagreywackes and meta-psammites or their igneous counterparts. Whole-rock zircon saturation temperature indicates that the Myeongseongsan magma was melted at $740-799^{\circ}C$.

Crystal Chemistry and Paragenesis of Calc-silicate Minerals from Meta-sedimentary Rocks in Chuncheon Area: (I) Occurrence, Mineralogy, and Paragenesis (춘천 지역의 변성 퇴적암류에서 산출되는 석회 규산염 광물의 결정 화학과 생성: (I) 투각섬석의 산출상, 광물상 및 생성 관계)

  • 노진환;조현구;최진범
    • Journal of the Mineralogical Society of Korea
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    • v.8 no.2
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    • pp.57-72
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    • 1995
  • 춘천 지역 선캠브리아기의 구봉산층군 내의 백운석질 대리암에는 광역변성작용의 산물로서 조립질의 투각섬석이 주된 규산염 광물상을 이루며 산출된다. 이들은 배태 층준과 원암의 조성에 따라 두 가지 유형으로 구분된다. : (1) 투각섬석(흑회색)+방해석+백운석+활석, (2)투각섬석(백색)+금운모+백운석+방해석+K-장석, 백색의 투각섬석이 흑회색형보다 상대적으로 높은 Al과 알칼리 함유도를 보이지만, 전반적으로 모두 Mg-단종에 가까운 화학 조성을 갖는다. 투각섬석들이 격자 구조상의 결함 구조를 갖지 않는데 비해서, 금운모는 1M 구조형을 이루고 저면 격자 간격상에 녹니석 단위의 빈번한 개재에 의한 격자상의 구조적 결함이 흔히 관찰된다.방해석-백운석 지온계에 대한 연구와 TWEEQU 프로그램을 이용한 상평형도 작성을 통해서, 투각섬석들은 500~$600^{\circ}C$의 온도 범위, 8kb 정도의 압력 및 Xco2=0.2~0.5 조건에서 생성된 것으로 해석하였다. 이 지역의 투각섬석은 위와 같은 조건에서 지속적으로 평형 상태가 유지되고 상안정도가 증대되므로서, (1) 투휘석을 수반하지 않고, (2) 격자 구조상의 결합을 갖지 않는, (3) 자형의 큰 결정을 이루게 된 것으로 해석된다.

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A Study on Production Techniques of Ridge-end Roof Tile Excavated from Middle gate site in Bunhwangsa Temple (분황사 중문지 출토 치미의 제작기법 연구)

  • Yang, Hee Jae;Park, Do Hyun;Jeong, Min Ho
    • 보존과학연구
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    • s.35
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    • pp.57-71
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    • 2014
  • As results of this study about the restoration and production techniques of the ridge-end roof tiles excavated from middle gate site in Bunhwangsa Temple, the ridge-end tile was considered that can be combined with four distinguished parts such as a body with upper and lower portions, a back, a belly, and a wing. And also some patterns can be verified. The body and the wing were piled up the coil clay and the back-side was bonded. The pileup process was assumed that three types of wood tools were applied to bond the facing surfaces. After the completion of the pileup process, the entire exterior was retouched by hand. For touching the inside, bare hands or some tools like a wooden branches were used to scratch and to re-face a clay plasterwork. And also, the stamped patterns which produced by framework were bonded to the body. The results from the XRD and the TG-DTA, Tridymite which shows the phase transition in more than $867^{\circ}C$ could not be identified, and also the endothermic reaction peak at $1063^{\circ}C$ showed the result that the alkali feldspar such as the albite was changed into a different mineral at $1050^{\circ}C$. Therefore, the ridge-end tiles can be considered that the firing temperature was below $867^{\circ}C$.

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A Study on the Stone Materials from Gwanbong Seokjoyeoraejwasang and Three-storied Stone Pagoda in Seonbonsa Temple, Mt. Palgongsan, Korea (팔공산 선본사 관봉 석조여래좌상 및 삼층석탑의 석재에 대한 연구)

  • Moon, Sung Woo;Jwa, Yong-Joo
    • Journal of the Korean earth science society
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    • v.35 no.7
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    • pp.554-561
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    • 2014
  • The rock materials from the two stone heritages in the Seonbonsa temple, Gwanbong Seokjoyeoraejwasang (stone Buddha) and three-storied Stone Pagoda, show almost identical petrographic characteristics. They are greyish white porphyritic granites which mainly consist of plagioclase, alkali feldspar, quartz, biotite, hornblende, and chlorite. The rocks from the both heritages are petrographically similar to those from the outcrops of the Palgongsan granite near the temple. Modal compositions exhibit that the rocks from the stone Buddha belong to monzogranite, whereas those from the pagoda and the outcrop near the temple correspond to syeno- to monzo granite. Whole rock magnetic susceptibility data indicate that the rocks from the stone Buddha, the pagoda, and the outcrop have nearly the same susceptibility values ranging 9-16(${\times}10^{-3}\;SI$). Gamma spectrometer data obtained from these rocks also demonstrate the same value range. In conclusion the two stone heritages in the Seonbonsa temple were made of the Palgongsan granite surrounding the temple.

Analyses of Mineral Composition of Geochang Granitic Rocks for Stone Specification (거창화강석 품질기준 설정을 위한 광물조성 분석)

  • Choi, Jin-Beom;Jwa, Yong-Joo;Kim, Keon-Ki;Hwang, Gil-Chan
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.363-381
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    • 2006
  • Mineral compositions of granitic rocks from Geochang, Pocheon, Iksan, and China were obtained by the modal analysis, CIPW norm calculations, and Rietveld quantitative analysis for stone specification of the Geochang granitic rocks. The Geochang granitic rocks show grey to dark in color and medium grained porphyritic texture. They mainly consist of quartz, plagioclase, alkali feldspar, and biotite. Among three different method for determining the mineral compositions of granitic rocks, normative compositions using X-ray fluorescence data are not appropriate for representing real mineral composition. Rietveld quantitative analysis using X-ray powder diffraction data is proved better method to determine exact mineral compositions than modal analysis using microscopic observation. Q-A-P diagram shows that the Geochang granitic rocks are typical granodiorite, whereas the granitic rocks of Pocheon, Iksan, and China are monzogranite, monzogranite to granodiorite, and granodiorite, respectively. Compared to China ones, the Geochang granitic rocks are nearly close to each other in mineral composition.

Detailed Deterioration Diagnosis and Analysis of Site Environment for the Taean Dongmunri Maaesamjonbulipsang (Rock-carved Standing Triad Buddha Statue), Korea (태안 동문리 마애삼존불입상의 정밀 훼손도 진단과 위치환경 분석)

  • Lee, Sun-Myung;Jun, Byung-Kyu;Shin, Eun-Jeong;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.27 no.4
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    • pp.381-393
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    • 2011
  • This study focus on the surface deterioration diagnosis based on the material characteristics of Taean Dongmunri Maaesamjonbulipsang(rock-carved standing triad Buddha Statue) and the weathering environment analysis. Rock materials of the triad Buddha is coarse-grained biotite granite which is composed mainly of quartz, K-feldspar, plagioclase, biotite and muscovite. The triad Buddha was serious surface irregularity(13.5%), exfoliation(12.3%) and discoloration(46.6%), and the physical characteristics using ultrasonic velocity appeared fourth grade (0.59, highly weathered). Korean style wooden shelter of the triad Buddha(closed type) maintained high humidity environment (daily mean; 86.6%) than exterior environment, and appeared the possibility of deterioration by freezing-thawing because the temperature showed below zero temperatures in winter. The shelter was changed from closed-type to open-type to relieve the moisture problem recently. But the moisture problem is yet to be solved because surface water flowing along northern wayside is flowed into triad Buddha. Therefore, environmental control will need to stop inflow of water into triad Buddha.

Estimation Study of Firing Temperature for Fired Clay Brick Relics Excavated from Buddhist Temple in Karatepa Using Analytical Method of High Temperature X-ray Diffraction (고온 XRD 분석법을 이용한 카라테파 불교사원 출토 점토벽돌의 소성온도 추정연구)

  • Han, Min Su;Lee, Jang Jon;Kim, Jae Hwan
    • Journal of Conservation Science
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    • v.32 no.4
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    • pp.511-520
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    • 2016
  • The purpose of this study was to estimate the firing temperature of fired clay brick by applying high temperature X-ray diffraction(XRD) analysis. The clay bricks, which were excavated from a Buddhist temple in Karatepa, Uzbekistan were composed of quartz, plagioclase, alkali feldspar, mica, chlorite, limestone, hornblende, etc. Some clay bricks contained gypsum, which was presumed to have been used to improve the adhesive strength of the brick. Estimating the firing temperature using a geologic thermometer, the UZ-1 sample was identified as being in the quartz, plagioclase, pyroxene series, and the firing temperature was estimated to be $900-1200^{\circ}C$. On the other hand, applying the high temperature XRD method to the UZ-5 sample, it was found that the limestone was destroyed at $1000^{\circ}C$ and the diffraction peak of chlorite was weakened at $1050^{\circ}C$. Moreover, pyroxene series minerals developed at $1050^{\circ}C$ in the reproduction experiment. These results indicate that the clay bricks used in the temple were produced in a kiln that reached a temperature of more than $1000^{\circ}C$. Thus, high temperature XRD analysis can more accurately estimate firing temperatures as compared to the firing temperature mineral identification method and it can be used to determine the creation and extinction temperature range of minerals.

Late Quaternary Deposition of Ice-Rafted Detritus in the Mid-Latitude North Atlantic: Paleoceanographic Evidence on Climatic Instability over the Past 150 Kyr (북대서양 중위도 해역의 신생대 제4기발 빙하쇄설퇴적층: 15만년 전 이후의 기후변동에 대한 고해양학적 증거)

  • 박명호;류병재
    • Economic and Environmental Geology
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    • v.34 no.2
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    • pp.217-226
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    • 2001
  • Stable isotope, paleoceanographic and sedimentological analyses were carried out along the core Ml5612 from the Mid-Atlantic Ridge. Distinct negative ${\delta}^{18}O anomalies punctuate the planktonic isotope records and correlate with the Heinrich-IRD cvents. The IRD layer in the corc contains varying amounts of quartz, K-feldspar, plagioclase, calcite, dolomite and mica, in which detrital carbonate contributes between I and 13% (except H3 and H6). Anomalies are strongest in the N. pachydenna (sin.) isotope record. Systematic changes in the ${\delta}^{18}O offset of G. hul/aides and G. inJlata signify variations in mid-latitude thermocline structure. In conjunction with negative benthic ${\delta}^{13}C anomalies, the data document a stronger contribution of a ${\delta}^{13}C depleted, nutrient-rich water mass during the IRD events. The ${\delta}^{13}C amplitude of > 1 $\textperthousand$ between 25 and 57 ka indicates changes between northern source (NADW) and southern source (AABW) water masses at this site. The IRD layers in the core Ml56l2 are correlative with those from the core S075-26KL and DSDP 609. The IRD layers from the Portuguese margin arc coeval with HI, H2 and H4 of the open North Atlantic. This similarity (and/or synchronicity in both regions may have been resulted from common changes in a North Atlantic thermohaline switch.

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Origin of Fluorine Contained in Rocks within the Eulwangsan, Yongyudo (용유도 을왕산에 분포하는 암석 내 불소 기원)

  • Lee, Jong-Hwan;Jeong, Jong-Ok;Kim, Kun-Ki;Lee, Sang-Woo;Kim, Soon-Oh
    • Economic and Environmental Geology
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    • v.51 no.6
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    • pp.521-529
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    • 2018
  • This study was conducted to investigate the natural origin of fluorine contained in the rocks within the Eulwangsan area via petrological and mineralogical analyses. The main geology of the Yongyudo Eulwangsan area is Triassic biotite granite. Biotite granite and mylonite are the major rock types containing fluorine at high levels (up to 1,700 and 2,400 mg/kg for biotite granite and mylonite, respectively). In the case of the biotite granite, a high concentration of fluorine can be contributed to fluorite, and the results of microscopic analyses show that the fluorite was observed as small veinlets filling cleavages and micro-fractures within alkali-feldspars and plagioclases, or observed together with quartz in ore veins, indicating the secondary formation of fluorite by hydrothermal fluids. In mylonite, on the other hand, a high fluorine concentration is attributable to sericite. Microscopic analyses revealed that the boundary between sericite and surrounding quartz was not clear, the sericite occurred filling the micro-fractures of quartz and encapsulating small quartz cataclasts. These results indicate that the sericite was also formed as a result of hydrothermal alteration. Consequently, it is speculated that the high fluorine level in the rocks of the Eulwangsan area of Yongyudo is of natural origin due to hydrothermal processes.