• Title/Summary/Keyword: 알루미늄 첨가

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A study of Al-Si alloy layer with the glass frit in the aluminum paste (알루미늄 Paste의 Glass frit 첨가에 따른 Al-Si alloy 층의 변화)

  • Song, Jooyong;Park, Sungeun;Kim, Seongtak;Kim, Hyunho;Kang, Min Gu;Tark, Sung Ju;Lee, Byungchul;Kim, Donghwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.77.2-77.2
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    • 2010
  • 스크린 프린팅을 이용한 태양전지에서 전극소성 시 알루미늄 후면 전극이 실리콘으로 확산되어 후면전계(Back Surface Field)를 형성한다. 후면전계 형성시 알루미늄과 후면전계 사이에 알루미늄-실리콘 합금이 형성된다. 이 알루미늄-실리콘 합금은 알루미늄 후면전극의 전기전도도 및 휨현상, bead 형성 등에 영향을 끼친다. 본 논문은 알루미늄 페이스트에 첨가된 Glass frit이 알루미늄-실리콘 합금 형성에 끼치는 영향을 관찰하였다. 분산제, 유기바인더, 알루미늄을 섞어 1개의 페이스트를 만들었고, Glass frit을 1%, 2%, 3%, 4%, 5% 씩 첨가하여 총 6개의 알루미늄 페이스트를 만들었다. 절삭손상이 제거된 실리콘 기판의 후면에 알루미늄 페이스트를 스크린 프린팅하여 전극을 소성하였다. 주사전자 현미경(SEM)을 사용하여 시편의 단면사진으로부터 Glass frit 함량에 따른 알루미늄-실리콘 합금층의 변화를 관찰하였다. Glass frit이 첨가되지 않은 페이스트는 소성 후 알루미늄-실리콘 합금이 두껍게 형성되었으나, Glass frit이 첨가된 페이스트는 소성 후 알루미늄-실리콘 합금이 얇게 형성되는 결과를 얻었다. 또한 Glass frit을 첨가함에 따라 표면의 원형 모양의 무늬가 작아지면서 3%부터는 사라지는 것을 확인할 수 있었다.

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Effect of Electrolyte-Additives on the Performance of Al-Air Cells (전해질 첨가제가 알루미늄-공기전지의 성능에 미치는 영향)

  • Park, Gwun Pil;Chun, Hai Soo
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.52-57
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    • 1998
  • The effects of additives such as zinc compounds in 4M KOH electrolyte of Al-air cell have been studied. Zinc compounds in electrolyte increased hydrogen evolution overpotential and TPC(tripotasium citrate)/CaO formed fine film on aluminum surface, and these additives decreased hydrogen evolution rate and corrosion rate of aluminum. These additives shifted the OCP in the positive direction on high purity aluminum(purity, 99.999%) and in the negative direction on Al No 1050(purity,99.5%). Addition of two or more additives resulted in the prevention or the reduction of corrosion rate and hydrogen evolution at OCP. As the overpotential on Al electrode increased, the hydrogen evolution rate decreased and the utilization of aluminum increased. At high current density$(>100mA/cm^2)$, TPC/CaO/ZnO additives increased the utilization of high purity aluminum up to that of aluminum alloys containing indium, gallium and thallium.

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A Study on the Recovery of Aluminum from Aluminum dross (알루미늄 드로스로부터 알루미늄의 회수에 관한 연구)

  • 김홍진;김용현;이병우;이광학
    • Resources Recycling
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    • v.6 no.1
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    • pp.5-10
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    • 1997
  • The aluminum was recovered from the middle size (Q1.0-12.0 mm) aluminum drosses using NaCl and KC1 mixuture as a basic salt flux. The maximum aluminum recovery was about 76.9% when 40% basic salt flux was added to aluminum dross at 850$^{\circ}$C for two hours. Also, aluminum remvery increased with increasing fluoride (1%-5%) addition to basic salt flux. But, there was no considerable effect due ta the increasing of viscosity when the fluorides were added over 5%, respectively. E s p d y , the most aluminum recovery was about 83.5% when 5% cryolite was added to 40% basic salt flux.

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Effect of Insertion of Hf layer in Al oxide tunnel barrier on the properties of magnetic tunnel junctions (알루미늄 산화물 절연막에 하프늄의 첨가가 자기터널접합의 특성에 미치는 영향)

  • Lim, W.C.;Bae, J.Y.;Lee, T.D.;Park, B.G.
    • Journal of the Korean Magnetics Society
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    • v.14 no.1
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    • pp.13-17
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    • 2004
  • We have investigated the effect of Hf insertion in the Al oxide tunnel barrier on the properties of magnetic tunnel junctions (MTJs). MTJs with Hf inserted barrier show the higher tunnel magnetoresistance (TMR) ratio and less temperature and bias voltage dependence of TMR than MTJs with a conventional Al$_2$O$_3$ barrier. The enhancement of TMR ratio and the reduction of the temperature and bias voltage dependence might be due to the reduction of defects in the barrier. Al-Hf oxide was formed by depositing Al and Hf simultaneously, and oxidizing the compound films. The TMR ratio of 36% was almost the same value as that with Hf inserted barrier. This implies that the inserted Hf layers mixed with Al layers during deposition or oxidation, and they might form Al Hf oxide barriers. This compound Al Hf oxide formation may be responsible to reduction of defect concentration which enhanced the TMR ratio and reduced temperature and bias-voltage dependence.

A Study on the Dispersion Stability of Aluminum Slurry Fuel (알루미늄 슬러리 연료의 분산안정성 연구)

  • Cho, Min-Ho;Yang, Mun-Kyu;Jeong, Byung-Hun;Han, Jeong-Sik;Lee, Ik-Mo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.163-166
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    • 2009
  • For the preparation of Aluminum-slurry fuel, the effects of process parameters on the aluminum dispersion stability in the liquid fuel have been investigated. The dispersion stability of aluminum-slurry fuels could be monitored by measurements through Turbiscan using the scattering of the Laser. Through the application of various additives, TPAB (Tetrapropyl ammonium bromide) showed more reasonable performance than others.

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활성슬러지법에서 알루미늄 부식에 의한 인제거

  • 정경훈;최형일;정오진;이경희;강경환
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2000.05a
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    • pp.130-131
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    • 2000
  • 알루미늄판만 있는 경우보다 구리판이 첨가되었을 때 인 제거율은 높았으나 알루미늄판만 첨가하여도 수중의 인 제거가 가능하였고, 알루미늄판 표면적이 클수록 인제거 시간이 빨랐으며, 수중 전해질농도가 높을수록 인제거 시간은 단축되었고, 알루미늄판을 재 사용하였을 때는 구리판과 전해질 농도의 영향과는 상관없이 24시간만에 제거되었으며, 또한 비폭기시에는 공식이 일어나지 않아 인이 제거피지 않고 증가됨을 알 수 있었다. 또한 인이 제거되는 과정에서 COD와 질소 제거에는 영향을 주지 않음을 알 수 있었다.

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Effect of Additives on Synthesis of $\textrm{ZrB}_{2}$ By SHS Process and Its Densification (SHS법에 의한 붕화지르코늄의 합성 및 치밀화에 미치는 첨가제의 영향)

  • Lee, Yun-Bok;Gwak, Cheol-Sang;Kim, Sang-Bae;Kim, Yeong-U;Park, Hong-Chae;O, Gi-Dong
    • Korean Journal of Materials Research
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    • v.8 no.7
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    • pp.653-658
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    • 1998
  • ZrO2, B2O3 및 AI을 사용하여 SHS법에 의한 붕화지르코늄을 합성을 하고 산화철과 알루미늄 분말의 첨가가 합성물의 치밀화에 미치는 영향에 대하여 검토하였다. 합성물중에 존재하는 결정상은 대부분이 ZrB2와 $\alpha$-AI2O3상이었다. 산화붕소와 알루미늄의 몰비가 1.0:3.3이상일 때 합성물의 치밀화는 크게 증가하였고, ZrB2 입자도$\alpha$-AI2O3용융상과 더불어 조대하였다. 산화철 1목에 대하여 알루미늄을 1-3몰을 첨가한 것과 산화철 1.5몰에 대하여 알루미늄을 3몰 첨가시 $\alpha$-AI2O3를 중심으로하는 슬라그상으로부터 용융상의 분이가 가능하였고, 이들 용융상에 존재하는 결정상은 ZrB2이외에 Fe, Fe2B, Zr2Fe상이었다. 용융상의 상대밀도는 산화철 1몰에 대하여 알루미늄을 1몰 첨가시 83.2%인 반면에 그 이상의 첨가량에 대해서는 치밀화는 크게 증가하여 알루미늄을 3몰 첨가한 경우 상대밀도는 93.7%로서 최대를 나타내었다.

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Rheological Properties Investigation of Kerosene gels with Nano-Aluminum Particles (알루미늄 나노입자 첨가량에 따른 케로신 젤의 유변학적 특성 변화)

  • Kim, Sijin;Han, Seongjoo;Kim, Jinkon;Kang, Teagon;Moon, Heejang
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.469-473
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    • 2017
  • In this study, the rheological characteristics of kerosene based gel propellants were investigated. For the gelling agent, Thixatrol$^{(R)}$ has been used with 100 nm nano-sized aluminium particle addition. Three gellant contents of 2.5 wt%, 5 wt% and 7.5 wt% kerosene gels were first investigated where aluminium particles contents of 10 wt% and 20 wt% were added to 7.5 wt% gellant case. The viscosities of each sample measured by rotational rheometer show that the viscosity augments as gellant or aluminium content increases while the 20 wt% aluminum content resulted in failure of measurement due to the agglomerations of aluminum particles.

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Effects of Fe and Cu Addition on the Microstructure and Tensile Properties of Al-Si-Mg Alloy for Compound Casting (복합주조용 Al-Si-Mg합금의 미세조직 및 인장성질에 미치는 Fe 및 Cu 첨가의 영향)

  • Kim, Jeong-Min;Jung, Ki-Chae;Kim, Chae-Young;Shin, Je-sik
    • Journal of Korea Foundry Society
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    • v.41 no.1
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    • pp.3-10
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    • 2021
  • In the compound casting between the aluminum alloy and the cast iron, the iron component may be dissolved from the cast iron during the process and mixed into the aluminum melt, thereby forming various iron-containing intermetallic compounds and significantly deteriorating the tensile properties of the aluminum alloy. On the other hand, unlike Fe, which is added as an impurity, Cu is added to improve the mechanical properties of the aluminum alloy. In this study, the change in microstructure and tensile properties of aluminum alloys due to the addition of Fe and Cu was investigated. A large amount of iron-containing compounds such as coarse Al5FeSi phases were formed when the iron content was 1% or more, and the tensile properties were significantly reduced. In the case of the aluminum alloy to which Cu was added, an Al2Cu phase was additionally formed and the tensile strength was clearly improved.

Tensile and Compressive Strength Characteristics of Aluminized Paraffin Wax Fuel for Various Particle Size and Contents (파라핀/알루미늄 연료의 알루미늄 입자크기 및 함유비 변화에 따른 인장 및 압축강도 특성 연구)

  • Ryu, Sunghoon;Han, Seongjoo;Kim, Jinkon;Moon, Heejang;Kim, Junhyung;Ko, Seung Won
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.5
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    • pp.70-76
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    • 2016
  • Tensile and compressive strength tests were conducted to investigate the mechanical characteristics of aluminized paraffin wax fuel for hybrid gas generator applications. Mixtures of 0 wt%, 10 wt% and 30 wt% nano aluminum paraffin coupons as well as 5 wt%, 10 wt% and 15 wt% micro aluminum paraffin coupons were used. The average particle size of 100nm and of $8{\mu}m$ mixed each with microcrystalline paraffin wax(Sasol 0907) were chosen for the base specimens where the tensile strength test followed the ASTM-D638 specimen standard while the compressive strength test followed the ASTM D575-91. It was found that nano based specimens increased both the tensile and compressive strength enhancing the mechanical behavior of paraffin wax whereas the micro based specimens gave still less influential effect.