• Title/Summary/Keyword: 알루미늄(III)

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Optimization of chemical precipitation for phosphate removal from domestic wastewater (생활하수내 인 제거를 위한 화학적 침전의 최적화)

  • Lee, Sunkyung;Park, Munsik;Yeon, Seungjae;Park, Donghee
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.6
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    • pp.663-671
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    • 2016
  • Coagulation/precipitation process has been widely used for the removal of phosphate within domestic wastewater. Although Fe and Al are typical coagulants used for phosphate removal, these have some shortages such as color problem and low sedimentation velocity. In this study, both Fe and Al were used to overcome the shortages caused by using single one, and anionic polymer coagulant was additionally used to enhance sedimentation velocity of the precipitate formed. Batch experiments using a jar test were conducted with real wastewater, which was an effluent of the second sedimentation tank in domestic wastewater treatment plant. Response Surface Methodology was used to examine the responsibility of each parameter on phosphate removal as well as to optimize the dosage of the three coagulants. Economic analysis was also done on the basis of selling prices of the coagulants in the field. Phosphate removal efficiency of Fe(III) was 30% higher than those of Fe(II). Considering chemical price, optimum dosage for achieving residual phosphate concentration below 0.2 mg/L were determined to be 18.14 mg/L of Fe(III), 2.60 mg/L of Al, and 1.64 mg/L of polymer coagulant.

The Development and It′s Characteristics of New Film Dosimetry Algorithm for Personal Dosimetry (개인피폭 선량 측정을 위한 필름 배지 선량계의 새로운 알고리즘 개발 및 특성)

  • 이병용;장혜숙;봉정균;권수일
    • Progress in Medical Physics
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    • v.6 no.2
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    • pp.35-40
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    • 1995
  • Purpose: We have developed new film dosimetry algorithm for personal dosimetry and examined its characteristics. Materials and methods: Agfagaevart personal monitoring 2/10 films are used. Films which are in the film badges filtered with Cu 0.3mm, plastic 1.5mm, Aluminum 0.6mm and tin 0.8mm, were exposed by standard dosimetry laboratory. Irradiated energy categories are ANSI N13.1l Category III, and IV. Manual type film precessor and X-rite film densitometor was used. Filtered densities to energy relations and does to transformed densities relations can be obtained ofter transformation of H&D curves to linear shape by polynomal fitting. Reults : Personal dose be determined within 25% error for category m and 15% for category IV. And we are able to evaluate the exposed energy. Conclusion : New algorithm developed in this study is good for personal dosimetry within 30% error range for catergory III and IV. It is expectd to be complete personal dosimetry algorithm with further study for categrory, I, Dand II V.

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The Effect of Preform Shape for Hot-forging Process of Aluminum-alloy (예비성형체형상이 알루미늄합금의 열간단조공정에 미치는 영향)

  • Kwon, Y.M.;Lee, Y.S.;Song, J.I.;Lee, J.H.
    • Proceedings of the KSME Conference
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    • 2001.06c
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    • pp.106-110
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    • 2001
  • A effective and accurate method of hot-forging process is essential to the design of optimized dies as well as workpiece of intial shape. the former is achieved by a proper forging sequence with invokes serious problem like excessive load and die wear, die failure, underfilling and lap defects. the latter is achieved by a proper preform design of case I, case II, case III. metal forming processes of aluminum-alloy forged at an effective strain and temperature are analyzed by the finite element method. the non-isothermal analysis have been compared with optimized in terms of preform shape.

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Effects of Dual-Coagulant Performance (이중응집이 응집공정에 미치는 영향)

  • Kim, Hee-Geun;Moon, Byung-Hyun;Kim, Seung-Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.1
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    • pp.92-97
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    • 2005
  • This research is to investigate the effect of the dual coagulant using inorganic coagulants($AICl3{\cdot}6H2O$) and polymer on the coagulant process. Jar-test was conducted by using Kaolin injected raw water. PDA(Photometric Dispersion Analyzer) equipment in order to analyze the size of the particles and the characteristics of the shapes. The change in the rate of sample ores' residual deposited after coagulants were also compared. According to the result derived from this experiment, the concentration of inorganic coagulant reduced 50% and the residual was lower by using dual coagulants compared to using single coagulant. However the dual coagulant required sufficient mixing time, and affected particle characteristics, with the effect of the injection order of coagulants, the simultaneous injection of inorganic coagulant and polymer showed the most effective in the particle removal.

Molecular Orbital Study of Binding at the Pt(111)/${\gamma}-Al_2O_3$(111) Interface (Pt(111)/${\gamma}-Al_2O_3$(111) 계면간 결합에 관한 분자 궤도론적 연구)

  • Choe, Sang Joon;Park, Sang Moon;Park, Dong Ho;Huh, Do Sung
    • Journal of the Korean Chemical Society
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    • v.40 no.4
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    • pp.264-272
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    • 1996
  • Cluster models of the Υ-Al2O3(111) and the Pt(111) surfaces have been used in an atom superposition and electron delocalization molecular orbital study of interfacial bond strengths between them. The reduced extents for Al3+ are due to the ratio of oxygen to aluminum atoms. The greater the reduced extent for Al3+ is, the stronger the binding energy is to Pt atoms in a cluster. The oxygen-covered surfaces of Υ-Al2O3(111) are shown to bind more weakly to Pt atoms, while the binding to the oxygen-covered surface formed under oxidizing conditions of Pt atoms is strong. The interfacial bond of platinum-alumina may be possible by a charge-transfer mechanism from the platinum surface to the partially empty O-2p band and Al3+ dangling surface orbital.

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Determination of Aluminum Leached from Cooking Utensils by using Flow Injection Analysis (흐름주입분석법에 의한 주방용기로부터 용출된 알루미늄의 정량)

  • Choi, Yong Wook
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.281-289
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    • 2004
  • Optimal analytical conditions have been established for mixing and reaction coil length, concentrations of ECR, CTAB, and acetate, reaction temperature and pH in the determination of aluminum by using flow injection analysis(FIA). Detection limit and repeatability for this system were $3{\mu}g/L$ and better than 1% of relative standard deviation, respectively. The interference from iron(III) was suppressed up to 6mg/L of iron(III) by $0.1{\mu}M$ ascorbic acid, and the interference from fluoride could be tolerated in absorption of Al/ECR/CTAB derivative by 10mM boric acid at pH 3.5 adjusted with nitric acid. This FIA system was applied to the determination of aluminum leached from cooking utensils by distilled and tap water containing fluoride ranged from 0.5 to 2mg/L by measurement of absorbance for Al/ECR/CTAB at 585nm. The leached aluminum content was increased with increasing concentration of fluoride. The aluminum contents leached from aluminum utensils by tap water were about 9 fold higher than those leached by distilled water, whereas aluminum contents leached by distilled water containing fluoride were about 2 fold higher compared to those leached by distilled water. That represented that other dissolved substances as well as fluoride in tap water contributed to liberation of aluminum from aluminum utensils. A comparison between FIA data and ICP-AES data by correlation and paired t test showed that the FIA system could be accepted as a good alternative method for the determination of aluminum in tap water.

Survey of Physicochemical Methods and Economic Analysis of Domestic Wastewater Treatment Plant for Advanced Treatment of Phosphorus Removal (총인 수질기준강화를 위한 국내 하수종말처리장의 물리화학적처리 특성조사 및 경제성 분석)

  • Park, Hye-Young;Park, Sang-Min;Lee, Ki-Cheol;Kwon, Oh-Sang;Yu, Soon-Ju;Kim, Shin-Jo
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.3
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    • pp.212-221
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    • 2011
  • Wastewater treatment plants (WWTPs) are required to meet the reinforced discharge standards which are differentiated as 0.2, 0.3 and 0.5 mg-TP/L for the district I, II and III, respectively. Although most of WWTPs are operating advanced biological phosphorus removal system, the supplementary phosphorus treatment facility using chemical addition should be required almost at all WWTPs. Therefore, water quality data from several exemplary full-scale plants operating phosphorus treatment process were analyzed to evaluate the reliability of removal performance. Additionally, a series of jar tests were conducted to find optimal coagulants dose for phosphorus removal by chemical precipitation and to describe characteristics of the reaction and sludge production. Chemical costs and the increasing sludge volume in physicochemical phosphorus removal process were estimated based on the results of jar tests. The minimum coagulant (aluminium sulfate and poly aluminium chloride) doses to keep TP concentration below 0.5 and 0.2 mg/L were around 25 and 30 mg/L (as $Al_2O_3$), respectively, in the mixed liquor of activated sludge. In the tertiary treatment facility, relatively lower coagulant doses of 1/12~1/3 the minimum doses for activated sludge were required to achieve the same TP concentrations of 0.2~0.5 mg/L. Increase in suspended solids concentration due to chemical precipitates in mixed liquor was estimated at 10~11%, compared to the concentration without chemical addition. When coagulant was added into mixed liquor, chemical (aluminium sulfate) cost was estimated to be 4~10 times higher than in secondary effluent coagulation/separation process. Sludge production to be wasted was also 4~10 times higher than secondary effluent coagulation/separation process.

Chemical Characteristics of Soils in Cheju Island -III. Aluminum Composition of the Citrus Orchard Soils (제주도(濟州道) 토양(土壤)의 화학적(化學的) 특성(特性) 조사(調査) 연구(硏究) -III. 감귤원(柑橘園) 토양(土壤)에서의 알루미늄 특성(特性))

  • Yoo, Sun-Ho;Song, Kwan-Cheol
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.2
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    • pp.167-172
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    • 1984
  • The aluminum composition of the citrus orchard soils (volcanic ash soil) in Cheju Island was studied. The content of extractable Al was high, especially for the sub-soil. However the exchangeable Al was relatively low : it was only one-tenth of the extractable Al content. The exchangeable Al of the citrus orchard soils decreased with increasing number of years of cultivation. This has resulted from an increase in pH. The content of the extractable Al of the citrus orchard soils also decreased with the increase in number of years of cultivation. This is related to the fact that the application of phosphate fertilizers led to a reduction in Al activity. Therefore, the extractable Al showed a highly significant correlation with the available phosphorus in the top soil. However it was not significantly affected by phosphates in the sub-soil where the available phosphorus was extremely low. The extractable Al content strongly correlated with the organic matter and pH(NaF) in the sub-soil, but the correlation was less significant in the top soil. This suggests that large amounts of the extractable Al are released from the hydrous oxides of Al and that the organically complexed form in the sub-soil and non-extractable due to the reactions with phosphates applied to the top soil.

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The Lightning Effects on Aircraft and Certification (항공기에 대한 낙뢰의 영향과 감항성 인증)

  • Han,Sang-Ho;Lee,Jong-Hui
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.9
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    • pp.110-120
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    • 2003
  • As the wooden aircraft in the early times has no way to let lightning flow when lighting flash attaches during flight, the aircraft got damage, or caught fire. Though all metal airplane was developed with an advent of aluminum, a lightning accident still occurred including a fire of a fuel tanks. Eventually, NACA declared problems in 1938, and an artificial lightning test began. III succession, FAA established Airworthiness Requirements for certification. The FAA committed test measures study for the protection of an airplane from lightning to SAE. SAE presented the test current and voltage waveforms that simulating natural lightning, and it is utilized on lightning protection certification of an airplane by public. A lightning effects of an airplane through an analysis of lightning mechanism was made in this technical note. Especially, lightning direct effects on aircraft are analyzed and lightning strike zones are described.

Influences of Potassium Fluoride (KF) Addition on the Surface Characteristics in Plasma Electrolytic Oxidation of Marine Grade Al Alloy (해양환경용 알루미늄 합금의 플라즈마 전해 산화 시 표면 특성에 관한 불화칼륨(KF)의 영향)

  • Lee, Jung-Hyung;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.49 no.3
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    • pp.280-285
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    • 2016
  • In this study, we investigated the influences of potassium fluoride(KF) addition on the surface characteristics of plasma electrolytic oxidation(PEO) coating produced on Al alloy. The PEO of marine grade Al alloy(5083 grade) was conducted in KOH 1g/L solution adding different concentrations of KF(0, 1 and 2 g/L) under a galvanostatic regime. With KF addition, unusual behavior was observed on the voltage-time characteristic curves, which can be characterized by the following process: (i) initial rapid increase in voltage (ii) a short plateau after 1st breakdown (iii) gradual increase in voltage (iv) intermittent fluctuation of voltage after 2nd breakdown. The SEM observation revealed irregular surface morphology with KF addition, as compared with one formed without KF addition, which had a reticulate structure. The XRD analysis detected the formation of aluminium hydroxide fluoride hydrate($H_{4.76}Al_2F_{3.24}O_{3.76}$) on surface grown by PEO process with KF. Particularly, at very early stage of the process (~ 120 s), thin film was formed having nanoporous structure, and F element was confirmed on surface by EDS analysis. The thickness and surface roughness of the coating increased with increasing KF concentration. As a result, KF addition was found to be less beneficial influences on PEO of marine grade Al alloy, and therefore needs further research to improve its capability.