• Title/Summary/Keyword: 알루미나 세라믹

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Feasibility of Pyrophyllite Ceramic Membrane for Wastewater Treatment and Membrane Fouling (국내산 납석기반 세라믹 멤브레인 수처리 적용 가능성 평가 및 파울링 현상관찰)

  • Park, Eunyoung;Jang, Hoseok;Choi, Nakcheol;Lee, Sungjae;Kim, Jeonghwan
    • Membrane Journal
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    • v.26 no.3
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    • pp.205-211
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    • 2016
  • Performance of pyrophyllite-based ceramic membranes newly developed were investigated. Membrane fouling caused by microbial suspensions taken from a full-scaled MBR system at domestic wastewater treatment plant was observed at different airflow rate and distance between each membrane. For the pyrophyllite support, pore size was about $1.0{\mu}m$, but surface coating with $Al_2O_3$ solution decreased the pore size with the reduction of the pure water permeability. With the MLSS taken from the full-scaled MBR system (6 g/L), the fouling rate was decreased by increasing airflow rate under $20L/m^2{\cdot}hr$ of setpoint flux. However, the effectiveness of the airflow rate on the fouling control depends strongly upon the gap between each membrane. At fixed airflow rate, the fouling rate was decreased by increasing the gap between each pyrophyllite membrane. Nevertheless, further increasing the membrane distance from 3.5 to 5.4 cm resulted in higher fouling rate. Similar result was observed with the $Al_2O_3$ coated-pyrophyllite membrane. Nevertheless, the fouling rate was lower with the coated membrane than that observed with the uncoated pyrophyllite support. Regardless of surface coating, the suspended solids were removed almost completely and the surface coating on the pyrophyllite support improved organic rejection with PEG solution (MW : 8000 kDa) tested.

Decomposition Characteristics of Aniline Treated in Fe2O3 Supported γ-Alumina Catalyst and O3 (Fe2O3γ-Al2O3 세라믹촉매와 오존을 이용한 아닐린의 분해특성)

  • Park, Byung-Ki;Suh, Jeong-Kwon;Lee, Jung-Min
    • Journal of the Korean Ceramic Society
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    • v.42 no.4
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    • pp.237-244
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    • 2005
  • We prepared the cylindrical $\gamma-alumina$ pellets of 5 mm in diameter and 10 mm in average length using amorphous alumina and pore generating agent. The pellets were immersed in an aqueous solution of the mixture of $Fe(NO_{3})_{3}{\cdot}9H_{2}O$ and $CH_{3}COOH$. They were then hydrothermally treated at $200^{\circ}C$ for 3 h in autoclave, dried and calcined. For the application as an environmental catalyst, we investigated the decomposition characteristics of aniline and the initiation characteristics of $OH^{\cdot}$ conversion action in $O_{3}$ environment with or without the $Fe_{2}O_{3}$ supported y-alumina catalyst and $O_{3}$ molecule.

Preparation of Asymmetric Ceramic Membrane by Coating-Pyrolysis Process (도포-열분해법을 이용한 비대칭 세라믹 분리막 제조)

  • Ryu, Hyun-Wook;Kim, Byung-Hoon
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1153-1157
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    • 2002
  • The fabrication of a three-layered asymmetric ceramic membrane was performed by slip casting of the porous alumina support and dip coating of the alumina intermediate layer using high purity ${\alpha}-Al_2O_3$ powders that have different particle size, followed by screen printing-pyrolysis of the $Tio_2$ layer as an ultrafilteration membrane using Ti-naphthenate solution. The bending strength, porosity and mean pore size of the alumina support were 231 kg/$cm^2$s, 30.26% and 0.19 ${mu}m$, respectively. The thickness of the intermediate layer was 30 ${mu}m$ and the mean pore size of that was 0.063 ${mu}m$. Also, the top layer was 0.5 ${mu}m$ thick and micropores with about 20 nm size were formed uniformly.

Preparation and Characterization of Alumina Thin Film by Sol-Gel Method (II); Synthesis of Alumina Sol for Coating and Preparation of Coating Films (졸겔법에 의한 알루미나 박막의 제조 및 특성(II);코팅용 알루미나 졸의 합성 및 박막 제조)

  • 이재호;최세영
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.911-919
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    • 1994
  • As the study for preparation of single-layer anti-reflective coating on glass, the conditions of synthesis of sol for coating and of reproducible coating procedure were investigated. In case of water-based sol, coating was impossible because of poor wettability of sol. The Substitution of solvent with ethanol improved the wettability of sol on the glass surface, and optimum amount of ethanol for substitution was 70 vol%. Maximum specific surface area and total pore volume of water-based sol were 268.7$m^2$/g and 0.315 cc/g, but after substitution, those values increased to 404.1 $m^2$/g and 0.376 cc/g, respectively. The upper limit withdrawl speed of coating in order to get clean coated films without aggregations or stains was 7 cm/min. In case of addition of 0.1 mol HNO3 and substitution with 70 vol% ethanol and heat-treatment at 40$0^{\circ}C$ for 1 hour, thin film with thickness of 94 nm was obtained at withdrawl speed of 4 cm/min. The thickness of thin film was independent of drying time.

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Effect of Cold Cyclic Compaction on Densification of $Al_2O_3$ Powder/SiC Whisker Composite ($Al_2O_3$분말과 SiC 휘스커 복합체의 치밀화에 미치는 상온 반복 압축의 영향)

  • 최승완;김기태
    • Journal of the Korean Ceramic Society
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    • v.34 no.3
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    • pp.296-302
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    • 1997
  • The effect of cold cyclic compaction on densification of SiC whisker/Al2O3 composite was investigated. Re-lative density of the compact increased as the number of cycle and the compaction pressure increased and the bias pressure decreased. The rate of loading and unloading and the frequency of cold cyclic compaction did not affect much on sliding and rearrangement of the particles. Fracture of SiC whisker was hardly ob-served during cold cyclic compaction and the direction of whisker was randomly oriented throughout the compact regardless of the direction of compaction. Thus, cold cyclic compaction may be an efficient method to densify SiC whisker/Al2O3 composite.

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Tool-Wear Characteristics of the Ceramic, CBN and Diamond Tools in Turning of the Presintered Low Purity Alumina (저순도 알루미나 예비소결체 선삭시의 세라믹, CBN 및 다이아몬드 공구의 마멸 특성)

  • Lee Jae-Woo
    • Journal of the Korean Society for Precision Engineering
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    • v.23 no.1 s.178
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    • pp.80-88
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    • 2006
  • In this study, unsintered and presintered low purity alumina ceramics were machined with various tools to clarify the machinability and the optimum cutting conditions. The main conclusions obtained were as fellows. Machined with ceramic tool, the ceramics presintered at the temperature range of $1000\~1100^{\circ}C$ showed the best machinability due to the adhesion formed in weared surface within a certain cutting speed range. In the above combination and conditions, the ceramic tool showed the highest productivity through all experiments. The life of CBN tool was longer in machining of the ceramics presintered at $1000^{\circ}C$ than in the case of that presintered at $600^{\circ}C$, but the diamond tool showed adverse tendency. In machining of the ceramics presintered at $1000^{\circ}C$, the ceramic tool exhibits the longest tool life in high speed, the tool lives became extremely worse in the order of CBN tool and diamond tool. However, in the case of the ceramics presintered at $600^{\circ}C$, the diamond tool shows the longest tool life, the tool lives was much worse in the order of CBN tool and ceramic tool.

A Study on the Preparation of Alumina Powders from Bauxite by Wet Acid Process and Their Utilization (III) : Effects of the Dispersion of Aluminum Hydrate Gel on the Sintering Behavior of Alumina Powder (Bauxite로부터 습식 산처리법에 의한 알루미나 분체의 제조 및 그 이용에 관한 연구(III) : Aluminum Hydrate Gel의 분산에 의한 알루미나 분체의 소결성 향상)

  • 조철구;정원도;배원태
    • Journal of the Korean Ceramic Society
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    • v.30 no.4
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    • pp.299-308
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    • 1993
  • Dispersant was used to avoid the agglomeration of aluminum hydrate precipitate and improve the sinterability of calcined alumina powder. The mean particle size of the aluminum hydrate precipitates was 0.26${\mu}{\textrm}{m}$ and 0.44${\mu}{\textrm}{m}$ when ball-milled with and without dispersant, respectively. After calcination at 110$0^{\circ}C$ for 5 hours, the size of the alumina powder without dispersant increased to 0.84${\mu}{\textrm}{m}$, while with dispersant slightly decreased to 0.22${\mu}{\textrm}{m}$. The most thermally active alumina powder was obtained from the sample calcined at 110$0^{\circ}C$ for 5 hours with the 1% dispersant concentration. Using the calcined alumina powder at the above optimized condition, the specimen showed fired density of 3.94g/㎤, 4-point MOR of 364MPa, and KIC of 3.26MPam1/2 after sintered at 155$0^{\circ}C$ for 3 hours.

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Nondestructive Evaluation of Thermal Shock Damage for Alumina Ceramics (알루미나 세라믹에 대한 열충격 손상의 비파괴적 평가)

  • Lee, Jun-Hyeon;Lee, Jin-Gyeong;Song, Sang-Heon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.8
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    • pp.1189-1196
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    • 2001
  • The objective of this paper is to investigate the applicability of acoustic emission(AE) technique to monitor the progress of the thermal shock damage on alumina ceramic. For this purpose, alumina ceramic specimen was heated in the furnace and then was quenched in the water tank. When the specimen was quenched in the water tank, complex AE signals due to the initiation of micro-cracks and boiling effect were generated by the progress of thermal shock damage. These mixed AE signals have to be classified for monitoring the degree of the thermal shock damage of alumina ceramics. In this paper, the mixed AE signals generated from both the boiling effect and the crack initiation under thermal shock test was analyzed. The characteristics of AE signals were also discussed by considering the variation of bending strength and Yongs modulus of specimens.