• Korean Journal of Ecology and Environment
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• v.40 no.1
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• pp.93-102
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• 2007

The runoff characteristics of organic matter in turbid water were investigated in eleven tributary streams of the Han River system, Korea. The flow-weighted event mean concentrations of organic matter ranged from 1.5 to 3.2 mg $L^{-1}$ of DOM and 2.2 of 29.1 mg $L^{-1}$ of POM, respectively. The SUVA value which reflects the proportion of humic substance in organic matters was higher during the rainfall season, meaning that the runoff of refractory form increase in this period. Stable carbon isotope ratios of both POM and DOM were different among streams, which reflect the sources of organic matter. DOM isotope ratios were less depleted of $^{13}C$ than that of POM by approximately 1 to $2%_{\circ}$ ${\delta}^{13}C$ of the several turbid streams (the Mandae Stream, the Jawoon Stream, and the Daegi stream) were heavier than those of clear streams. ${\delta}^{13}C$ values in the turbid upstream tributaries were similar to those of downstream reaches (such as the Soyang River, the Sum River, and the Seo River). From the ${\delta}^{13}C$ analysis of POM it could be calculated that $C_4$ pathway contributed approximately 15.9 to 23.6% of organic matter in several turbid upstream sites, and over 20% in the three sites of large downstream reaches. On the contrary it contributed only 9.1 to 12.8% in clear streams of forest watersheds. In the Soyang River, $C_4$ pathway organic matter contributed 8.8% of the DOM pool.

• 한국해양학회지
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• v.30 no.3
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• pp.216-226
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• 1995

Stable isotopic and elemental compositions were analyzed for well- preserved calcareous skeletons (gastropods, pectenids, brachiopods, a scaphopod, and other bivalves) of the Pleistocene Seoguipo Formation from Cheju Island, Korea. Mineralogically and texturally, aragonitic and calcitic fossils still retain their original mineralogy and microstructure. High $\delta$$\^$18/O and $\delta$$\^$13/C contents indicate that the shells have not been altered by the post-burial diagenesis. Also, this is supported by high Na and Sr contents as well as low Mn and Fe compositions of the shells. Oxygen isotopic compositions of the well preserved fossils show that the organisms had lived under the lower paleotemperature or within the isotopically enriched paleo-seawater during the deposition of the Seoguipo Formation. This result strongly implies that the Seoguipo Formation was deposited during a glacial period. The paleotemperature variation throughout the sequence during the deposition of the Sewguipo Formation was negligible.

• Journal of the Korean Society of Food Science and Nutrition
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• v.32 no.8
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• pp.1390-1393
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• 2003

Measuring in vivo rate of bone collagen synthesis has so far been technically difficult and often subject to quite large errors. In the present study, bone collagen synthesis rate was measured using a precursor-product method, based on the exchange of $^2$$H_2O$ into amino acids. Mass isotopomer abundance in hydroxyproline from bone collagen was analyzed by gas chromatography/mass spectrometry. The $^2$$H_2O$ labeling protocol consisted of an initial intraperitoneal injection of 99.9% $^2$$H_2O$, to achieve approximately 2.5% body water enrichment followed by administration of 4% $^2$$H_2O$ in drinking water for 9 weeks. Body $^2$$H_2O$ enrichments were stable at 2.7 ∼ 3.0% over labeling Period. In growing rats, the fractional synthesis rate ( $k_{s}$) of bone collagen was 0.066 $\pm$ 0.049 w $k^{-1}$ . The unique features of stable $^2$$H_2O$ pools and label incorporation allowed the precursor-product approach to be used for measuring bone collagen synthesis rate..

• Economic and Environmental Geology
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• v.40 no.5
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• pp.623-633
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• 2007

Stable isotope and biomarker analyses were carried out for the organic sediments from the exploratory wells in the Jeju Basin in order to understand the characteristics of organic matter. Organic matter in Geobuk-1, Okdom-1, JDZ VII-1 and VII-2 well is predominantly originated from land plants rather than marine algae according to carbon $({\delta}^{13}C_{org})$ and nitrogen $({\delta}^{15}N_{org})$ isotopic compositions. In the Geobuk-1, geochemical characteristics such as carbon $({\delta}^{13}C_{org})$, nitrogen ($({\delta}^{15}N_{org})$ and TOC contents are obviously changed by the depth 2,400 m, which is likely due to the change of origin of organic matter, sedimentary process or sedimentary environments. Analysis of the saturated fraction of the bitumen suggests the contribution of migrated oil to the indigenous bitumen from the samples 2,509, 2,833 and 3,163 m of the JDZ YII-1 and 3,253 m of the Geobuk-1 well. However, this characteristics can be derived from the contribution of the original organic matter. Based on the biomarker analysis, the samples from the Okdom-1 and Geobuk-1 appear to represent sedimentary organic matter of similar composition, that is rotatively immature, and which was probably deposited in the fluvio-deltaic setting with minor offshore marine influence. The samples from JDZ VII-1 appear to have been deposited in a more terrestrially dominated setting.

• The Korean Journal of Quaternary Research
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• v.7 no.1
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• pp.41-68
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• 1993

In the loess-paleosol sequences from central Great Plains, U.S.A., variation in magnetic susceptibility, FD, NRM have been proven to be excellent proxy for paleoclimate, and the standard interpretation is that climatic processes have enhanced the rock magnetic intensities. By using mineral magnetic properties, we show the magnetic signal is due to pedogenesis during the warm and possibly wet interglacials and interstadials. Other proxy records, such as stable carbon isotope and phytolith, are in good agreements with the magnetic records.

• Economic and Environmental Geology
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• v.41 no.1
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• pp.15-32
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• 2008

The hydrochemical and isotopic (stable isotopes and noble gas isotopes) analyses for hot spring waters, cold groundwaters and surface water samples from the Seokmodo hot spring area of the Ganghwa province were carried out to characterize the hydrogeochemical characteristics of thermal waters and to interpret the source of thermal water and noble gases and the geochemical evolution of hot spring waters in the Seokmodo geothermal system. The hot spring waters and groundwaters show a weakly acidic condition with the pH values ranging from 6.42 to 6.77 and 6.01 to 7.71 respectively. The outflow temperature of the Seokmodo hot spring waters ranges from $43.3^{\circ}C\;to\;68.6^{\circ}C$. Relatively high values of the electrical conductivities which fall between 60,200 and $84,300{\mu}S/cm$ indicate that the hot spring waters were mixed with seawater in the subsurface geothermal system. The chemical compositions of the Seokmodo hot spring waters are characterized by Na-Ca-Cl water type. On the other hand, cold groundwaters and surface waters can be grouped into three types such as the Na(Ca)-$HCO_3$, Na(Ca)-$SO_4$ and Ca-$HCO_3$ types. The ${\delta}^{18}O\;and\;{\delta}D$ values of hot spring waters vary from -4.41 to -4.47%o and -32.0 to -33.5%o, respectively. Cold groundwaters range from -7.07 to -8.55%o in ${\delta}^{18}O$ and from -50.24 to -59.6%o in ${\delta}D$. The oxygen and hydrogen isotopic data indicate that the hot spring waters were originated from the local meteoric water source. The enrichments of heavy isotopes ($^{18}O\;and\;^2H$) in the Seokmodo hot spring waters imply that the thermal water was derived from the diffusion Bone between fresh and salt waters. The ${\delta}^{34}S$ values ranging from 23.1 to 23.5%o of dissolved sulfate are very close to the value of sea water sulfate of ${\delta}^{34}$S=20.2%o in this area, indicating the origin of sulfate in hot springs from sea water. The $^3H/^4He$ ratio of hot spring waters varies from $1.243{\times}10^{-6}\;to\;1.299{\times}10^{-6}cm^3STP/g$, which suggests that He gas in hot spring waters was partly originated from a mantle source. Argon isotopic ratio $(^{40}Ar/^{36}Ar=298{\times}10^{-6}cm^3STP/g)$ in hot spring waters corresponds to the atmospheric value.

• Korean Journal of Heritage: History & Science
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• v.55 no.1
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• pp.305-321
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• 2022

The stone chamber tomb in Eungpyeong-ri, Buyeo, is a joint tomb that contains the bodies of two individuals. This paper investigates the relationship between the buried persons and the characteristics of the stone chamber tomb. Based on the geographical location, relics, and the excavated human bones, it was determined that the tomb was built during the Sabi Period of the Baekje Dynasty and that the buried individuals were most probably residents of high stature or government officials. To study the excavated bones, the remains were carefully collected and conservation was carried out. Before collecting samples from the human bones for the analytical research, the results of near-infrared analysis were used to collect the samples for the isotope analysis and DNA analysis. The most important issue when handling the excavation site was the reinforcing agent and the concentration of the agent used. In situations like this, Paraloid B-72 is the most suitable agent. When the shape of human bones was difficult to distinguish from the soil, conservation was performed using X-ray and CT imaging data. The same chemical used for the reinforcement of the site was used to complete a minimum level of conservation to the surface areas where the conservation treatment of removing foreign substances, the reinforcement areas, and bonded areas were carried out. The collagen yield from the sample obtained at selected position was 3.8% to 6.1%. The results of analyzing the stable isotopes of carbon and nitrogen found in the extracted collagen showed that the stable isotope ratios came out to δ¹³C -18.3‰±0.1‰, -19.0‰±0.1‰ for EBW and δ¹⁵N 10.7‰±0.5‰, 10.6‰±0.1‰ for EBE. It is believed the two individuals consumed small amounts of minor cereals, mainly from C₃ plants, and protein was obtained from eating terrestrial animals. What's more, the deviations in data obtained from the two individuals were so small that it could be inferred that the individuals ate similar foods. Considering the preservation state of the sample, amplifying DNA for the DNA analysis would have been very difficult since the amount of surviving DNA was so deficient. For DNA analysis, it is anticipated that the results could be derived by applying improved extraction methods that will be developed in the future. In this research, any association between scientific analysis(DNA and stable isotope ratio) and near-infrared spectroscopy was difficult to establish. Further research is needed on the utilization of near-infrared analysis for gathering samples from human bones.

• Ocean and Polar Research
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• v.30 no.3
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• pp.249-258
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• 2008

Oxygen isotopic composition(${\delta}^{18}O$) of walleye pollock, Theragra chalcogramma, otoliths were measured to investigate interannual and regional correlation with habitat temperature. Specimens were collected from fishermen in Korea and Japan between $1997{\sim}1999$, while seawater temperatures were obtained from Korean and Japanese Oceanographic Data Centers. Seawater temperature was generally lower off the eastern Korean Peninsula than off eastern Hokkaido(Japan). Sagittal otoliths were removed for measurement of ${\delta}^{18}O$ using a micro-drilling technique. In most cases, ${\delta}^{18}O$ and habitat temperature exhibited negative relationship in Korean and Japanese waters. Higher ${\delta}^{18}O$ was observed in Korean pollock compared to Japanese pollock. The marginal parts of otoliths exhibited higher ${\delta}^{18}O$ than cores from both regions. This is an indication that somatic growth of walleye pollock occurs in deeper and cooler waters. Interannual variation in ${\delta}^{18}O$ was also observed. Mean ${\delta}^{18}O$ values acquired from 1997 otoliths were lower(2.15%) than those of 1998(2.67%) and 1999 (2.65%) in Korean pollock. These measurements coincided with changes in observed temperature in Korean waters, in which mean seawater temperature was warmer in 1997 than in 1998 and 1999. In Japanese waters, mean seawater temperature was lowest in 1997, which coincided with highest ${\delta}^{18}O$ values in the same year.

• Economic and Environmental Geology
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• v.38 no.4 s.173
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• pp.421-434
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• 2005

Abstract Based onthe characteristics of Carlin-type gold deposit in Nevada district, a potential in Korea is evaluated to the Yemi area where is structurally controlled by folds and trust fault. The fault of high angles are combined with a more permeable rocks such as the Yemi breccia and laminated silty limestone. The pattern of enrichment factors for Tl, Sb, As, Ag, Pb, Zn, Cu, Mo and W of limestones in the southern area are geochemically similar with those reported from the Carlin-type Bold deposit. Moreover, the oxygen and carbon isotopes show a hydrothermal alteration is widely developed in this area. According to the result of geophysical interpretation, stable isotope, alteration mineralogy, geochemical study, and geological structure, this mineralized zone may be extended to the M direction, so a detailed systematic exploration is required to identify this alteration zone.

• Journal of the Korean Chemical Society
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• v.37 no.9
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• pp.800-805
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• 1993

An analytical method has been developed to determine trace elements in biological samples. The biological samples are added to a laboratory-bulit Teflon bomb together with nitric acid-hydrogen peroxide mixture and enriched stable isotopes. The samples are decomposed in a microwave oven. The decomposed sample solutions are analyzed by isotope dilution inductively coupled plasma mass spectrometry. The analytical results of the biological samples agree well with the reference values.