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Synthesis, Spectral and Thermal Studies of Lanthanide(III) Complexes of Phenylbutazone (Phenylbutazone의 란탄(III) 착물에 대한 합성, 스펙트럼 및 열적 연구)

  • Anoop, M.R.;Binil, P.S.;Jisha, K.R.;Suma, S.;Sudarsanakumar, M.R.
    • Journal of the Korean Chemical Society
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    • v.55 no.4
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    • pp.612-619
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    • 2011
  • Lanthanide(III) complexes of 1,2-diphenyl-4-butyl-3,5-pyrazolidinedione(phenylbutazone, PB) have been synthesized and characterized by elemental analyses, molar conductance measurements, IR, UV-Vis. and NMR spectra. The spectral data reveal that the PB acts as a bidentate and mono-ionic ligand coordinating through both the carbonyl oxygens of the pyrazolidinedione ring. The molar conductance data suggest that the complexes are non-electrolytes. The thermal behaviour of the complexes was studied by TG and DTG in air atmosphere and the results provide information about dehydration, thermal stability and thermal decomposition. The final products are found to be the corresponding metal oxides. The thermodynamic parameters and kinetic parameters were evaluated for the dehydration and decomposition stages. The negative entropy values of the decomposition stages indicate that the activated complexes have a more ordered structure than the reactants and that the reactions are slower than normal. Based on these studies, the complexes have been formulated as $[Ln(PB)_3]{\cdot}5H_2O$(Ln=La and Ce) and $[Ln(PB)_3(H_2O)_2]{\cdot}2H_2O$(Ln=Pr, Nd and Sm).

멀티미디어 정보시스템을 이용한 기업체 교육의 효과요인 도출을 위한 실증적 연구

  • 김병곤;이동만;박순창
    • Proceedings of the CALSEC Conference
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    • 1999.11a
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    • pp.280-293
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    • 1999
  • 본 연구는 경영학 관련 분야에서 멀티미디어 기술의 경영학적 측면의 응용에 관한 연구의 중요성이나 필요성을 많은 학자들이 인식하고 있음에도 불구하고 아직 멀티미디어에 관한 연구가 전무한 실정에서 시도한 초기연구라는데 연구의 의의가 있다. 이러한 시점에서 교육공학과 경영정보학을 접목시킨 멀티미디어에 관한 연구는 상당히 중요할 것으로 판단된다. 이와 같이 본 연구는 경영정보학 분야에서 멀미미디어에 관한 연구로서는 초기의 연구로서, 본 연구가 가지는 연구의 필요성이나 중요성에 대해서는 우리들이 충분히 인식할 수 있을 것이다. 지금까지 국내외적으로 멀티미디어 정보시스템을 이용한 교육의 효과에 관한 연구는 몇 편의 탐색적 논문이 발견되고 있으나, 멀티미디어를 이용한 교육의 효과를 구성하는 요인이 무엇인지를 밝히기 위한 연구는 거의 전무한 실정이다 이러한 상황에서 멀티미디어를 이용한 교육의 효과를 구성하는 요인이 무엇이며, 구성요인 중 어떤 요인이 기업이나 학습자에게 가장 큰 효과를 가져다주는지를 밝히기 위한 연구는 현실적으로 상당히 중요하며 의미 있는 연구로 받아들여진다. 본 연구는 멀티미디어 정보시스템을 이용한 기업체 교육훈련의 효과요인을 도출하기 위하여 문헌연구와 실증적 연구를 병행 수행하였다. 우선 멀티미디어 정보시스템에 관한 문헌연구를 통하여 멀티미디어를 이용한 교육의 22가지 효과항목을 도출하였다. 다음으로 멀티미디어 정보시스템을 갖추고 있는 국내 5대 재벌 그룹연수원의 멀티미디어 교육실에서 교육을 받은 517명의 기업체 사원들을 대상으로 약 2개월간 설문조사를 실시하여 자료를 수집하고, 통계분석 패키지를 이용하여 자료를 분석하였다. 방식을 결합한 하이브리드 형태이다.인터넷으로 주문처리하고, 신속 안전한 배달을 기대한다. 더불어 고객은 현재 자신의 물건이 배달되는 경로를 알고싶어 한다. 웹을 통해 물건을 주문한 고객이 자신이 물건의 배달 상황을 웹에서 모니터링 한다면 기업은 고객으로 공간적인 제약으로 인한 불신을 불식시키는 신뢰감을 주게 된다. 이러한 고객서비스 향상과 물류비용 절감은 사이버 쇼핑몰이 전국 어디서나 우리의 안방에서 자연스럽게 점할 수 있는 상황을 만들 것이다.SP가 도입되어, 설계업무를 지원하기위한 기본적인 시스템 구조를 구상하게 된다. 이와 함께 IT Model을 구성하게 되는데, 객체지향적 접근 방법으로 Model을 생성하고 UML(Unified Modeling Language)을 Tool로 사용한다. 단계 4)는 Software Engineering 관점으로 접근한다. 이는 최종산물이라고 볼 수 있는 설계업무 지원 시스템을 Design하는 과정으로, 시스템에 사용될 데이터를 Design하는 과정과, 데이터를 기반으로 한 기능을 Design하는 과정으로 나눈다. 이를 통해 생성된 Model에 따라 최종적으로 Coding을 통하여 실제 시스템을 구축하게 된다.the making. program and policy decision making, The objectives of the study are to develop the methodology of modeling the socioeconomic evaluation, and build up the practical socioeconomic evaluation model of the HAN projec

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인터넷 기반 원스톱서비스 시스템 개발에 관한 연구 -수출컨테이너화물 원스톱서비스 시스템 개발-

  • 박남규;최형림;김현수;박영재;조재형;이철우
    • Proceedings of the CALSEC Conference
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    • 1999.11a
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    • pp.159-168
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    • 1999
  • 오늘날 우리 나라가 당면한 최우선 경제과제중 하나는 물류부문의 혁신을 통한 국가경쟁력 강화라고 할 수 있으며, 이를 위해 정부도 1993년 물류체계 개선을 위한 장기구상으로 ‘화물유통체계 개선 10개년 기본계획’을 수립하여 적극 추진 중에 있다. 그러나 이러한 노력에도 불구하고 PORT-MIS사용자를 상대로 한 설문조사에서는 선박입출항 업무 관련 서류의 40%, 항만시설 사용 업무와 관련된 서류의 31%, 하역업무 관련 서류의 10%만이 EDI를 활용하고 있었다. EDI 활용이 저조한 사유로는 전송시간이 많이 걸리며, EDI 소프트웨어가 작동되지 않으며, 수신확인이 되지 않기 때문이라 응답을 하였다. 이처럼 오늘날 항만물류산업이 겪고 있는 물류 데이타 흐름의 단절적 현상은 시간이 흐를수록 해결될 기미가 보이고 있지 않다. 따라서 본 논문에서는 우리 나라가 겪고 있는 물류관련 업무를 한번의 데이터 입력으로 해결할 수 있는 원스톱 서비스 시스템개발을 목표로 우선 PORT-MIS EDI 업무를 처리할 수 있는 시스템을 구축하였다. 이는 향후 화주, 운송사, 선사, 포워더, 창고업자, 하역회사, 철도청, 화물터미널, 컨테이너 터미널, 해양수산청, 관세청, 출입국관리사무소, 검역소 사이에 서로 교환되는 적하목록, Booking List, 컨테이너 Pick up정보, 위험물 정보, COPINO 정보를 비롯하여 대 관세청 신고 등 수출컨테이너 화물업무의 전반적인 영역으로까지 쉽게 확대할 수 있을 것이다. 본 연구결과 구축된 시스템은 원천정보를 중앙의 통합데이터베이스에 저장하여 이를 사용자의 요구에 의해 인터넷을 통해 전달하는 FTP와 웹 EDI 방식을 결합한 하이브리드 형태이다.인터넷으로 주문처리하고, 신속 안전한 배달을 기대한다. 더불어 고객은 현재 자신의 물건이 배달되는 경로를 알고싶어 한다. 웹을 통해 물건을 주문한 고객이 자신이 물건의 배달 상황을 웹에서 모니터링 한다면 기업은 고객으로 공간적인 제약으로 인한 불신을 불식시키는 신뢰감을 주게 된다. 이러한 고객서비스 향상과 물류비용 절감은 사이버 쇼핑몰이 전국 어디서나 우리의 안방에서 자연스럽게 점할 수 있는 상황을 만들 것이다.SP가 도입되어, 설계업무를 지원하기위한 기본적인 시스템 구조를 구상하게 된다. 이와 함께 IT Model을 구성하게 되는데, 객체지향적 접근 방법으로 Model을 생성하고 UML(Unified Modeling Language)을 Tool로 사용한다. 단계 4)는 Software Engineering 관점으로 접근한다. 이는 최종산물이라고 볼 수 있는 설계업무 지원 시스템을 Design하는 과정으로, 시스템에 사용될 데이터를 Design하는 과정과, 데이터를 기반으로 한 기능을 Design하는 과정으로 나눈다. 이를 통해 생성된 Model에 따라 최종적으로 Coding을 통하여 실제 시스템을 구축하게 된다.the making. program and policy decision making, The objectives of the study are to develop the methodology of modeling the socioeconomic evaluation, and build up the practical socioeconomic evaluation model of the HAN projects including scientific and technologica

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Degradation Evaluation of 1Cr-0.5Mo Steel using Barkhausen Noise (바크하우젠 노이즈에 의한 1Cr-0.5Mo 강의 열화도 평가)

  • Kim, Min-Gi;Park, Jong-Seo;Lee, Yun-Hee;Kim, Cheol-Gi;Ryu, Kwon-Sang
    • Journal of the Korean Magnetics Society
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    • v.21 no.4
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    • pp.136-140
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    • 2011
  • Mechanical properties of degraded materials must be measured for evaluating the integrity of the facilities operating at high temperature. In fact it is complicated to obtain the different degraded specimens from an operating facility. Specimens of 1Cr-0.5Mo steel prepared by the isothermal heat treatment at $700^{\circ}C$ were tested, which has been widely used as tubes for heat exchangers and as plates for pressure vessels. The magnetic properties and Rockwell hardness (HRB) were measured at room temperature. The peak interval of Barkhausen noise envelope (PIBNE), coercivity, and hardness decreased with the increase of degradation. The magnetic and mechanical softening of matrix is likely to govern the properties of the specimen more than the hardening of grain boundary by carbide precipitations. The degradation of test material may be determined by the linear correlation of PIBNE and HRB. Degradation of 1Cr-0.5Mo steel could well be nondestructively evaluated by PIBNE measured with surface type probe.

A Study on the Effect of Selection Attribute of Cruise Service on Tourism Satisfaction and Behavioral Intention (크루즈 서비스 선택속성이 관광만족과 행동의도에 미치는 영향에 관한 연구)

  • Pak, Myongsop;Kang, Yongjoon;Cho, Sungwoo
    • Journal of Korea Port Economic Association
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    • v.28 no.3
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    • pp.193-214
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    • 2012
  • The interest on cruise service has been increased due to the economic development and income growth all over the world during last several decades. However, cruise industry in Korea is located in the initiating stage and the service is just focused on costal cruise service. This study investigates relationship between influencing factors of the selection attributes of cruise service on tourism satisfaction and behavioral intention. Additionally, the study aims to provide information to establish customer-oriented marketing strategies for cruise tour service. Literature review is conducted to find out the factors in order to meet the future users preference and expectations. The data was collected on-board customers of "One Night Cruise" on Panstar Line. The result of the study shows that a certain number of factors are statistically significant on the cruise tour intention of potential customers. It shows that there is significant difference related to the using purpose and the usage attitude. Managers in the cruise company are able to utilize the practical implications of the present study when the cruise service launches in Korea. This study exists limitations that samples are not sufficient and the research can not be generalized due to the inadequate samples of target company.

The Research on the effect of School Safety Management System on Accident in School -Based on study of high schools in Seoul- (학교사고에 영향을 미치는 학교안전 관리구조 실태 조사 -서울시 일부 고등학생을 대상으로-)

  • 박지은;이명선
    • Korean Journal of Health Education and Promotion
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    • v.19 no.2
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    • pp.57-72
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    • 2002
  • Students spend most of their time in school. Schools have the possibility of unanticipated accidents, however, and the rate of accidents in schools is increasing. The purpose of this study were to understand the accidents that arise in schools as well as the school safety management system and by analyzing affects that school safety management system has on accidents in schools, to come lip with a preventive plan. 906 high school sophomore students attending in Seoul were surveyed 1Tom November 12th to 23rd 2001. The results were following: 1. Students surveyed comprised of the following: Male 48.9%, Female 51.1% Public Schools 32.6%, Private Schools 67.4% Boys Schools 48.9%, Girls Schools 51.1% 2. In the past year, male students had more accidents(p〈.05) in school. 3. In examining students safety management control, 94.0% said that, there is an infirmary, there is a clear distinction between the playing fields and pathways(74.8%), and the chemicals in the labs are kept in a safe manner(77.2%). The above items were generally well maintained. However, the following recorded low scores. There are warning signs in hazardous places and facilities(30.5%), There is guiding principle to examine the safeness on a regular basis(24.9%), and There are slogans and posters preventing accidents(40.3%). 4. In examining the facilities of the schools that were surveyed, the majority answered, yes to the following. There are hazardous facilities or materials at school(62.9%), There are sharp edges in educational supplies and equipment(59.8%), There are nails or other components that are sticking out of desks and chairs(75.9%), There are slippery spots in the corridors and classrooms(69.3%), There are stones, scrap metal, broken glass, and trash on the playing fields(66.6%). Furthermore, the students surveyed said, yes to the following although in low percentages. The amount of sand on the playing fields is sufficient(49.1%), The soccer and basket goal posts are fastened (53.7%), There are safety bars on the windows of classrooms and corridors (27.4%), There are safety mats on the entrance to restrooms preventing slips (14.2%), The stairs have slip protection measures(49.1%). 5. In analyzing the affect that the school safety management system has on accidents in school, schools that had slogans and posters preventing accidents had a 50% less chance of accidents(p〈.05), schools with chemicals and equipment in the labs that were safely maintained had an 80% less probability of accidents(p〈.0l), and the schools that had sharp edges in the educational supplies and equipment had an 80% greater chance of accidents(p〈.01).

Seismic Performance of Reinforced Concrete Shear Wall Buildings with Piloti (필로티를 갖는 철근콘크리트 전단벽식 건물의 내진성능)

  • Kwon Young-Wung;Kim Min-Su
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.587-594
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    • 2005
  • The purpose of seismic design is to ensure the serviceability of buildings against earthquake, which might be occurred during the service life of buildings, and to minimize the loss of life by preventing their failure under strong earthquake. The lack resistance of walls resulting from a tendency toward high-rise apartment buildings with shear walls and use of piloti would lead to a concentration of inelastic behaviors in their weak story. In this study, the seismic performance of reinforced concrete shear wall buildings haying piloti was analyzed by using the evaluation techniques which was proposed by FEMA 273 and ATC-40. The results from comparison with these two techniques are summarized as follows.; The results of elastic analysis method for seismic performance evaluation show that the effect of piloti and building height decrease performance index. In case of shear wall building, the state of insufficient shear stress governs their overall performance and it becomes evident in the case of the buildings with more than 25 stories. For the buildings of piloti, the change of mass, weak story, as well as insufficient shear stress, decrease the performance index rapidly compared with the performance index of the buildings without piloti. The results, obtained from the nonlinear static analysis using capacity spectrum method, indicate that the performance Point increases for the structure having Piloti and high story. Also, deformation limits of buildings satisfy the allowable criteria at the life safety level, but the immediate occupancy level is exceeded in buildings which have more than 25 stories.

A Basic Study for Single Shell Support System of Railway Tunnel (철도 터널의 싱글쉘 지보시스템 적용에 관한 기초 연구)

  • Jung, Daeho;Jeong, Cahnmook
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.1
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    • pp.39-48
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    • 2016
  • In this study, it can be shortened tunnel construction work period by introducing a single-shell tunnel does not placing the secondary concrete lining, a global research trend, reduction of the cost of the lining placement and number of benefits that can ensure the safety of long-term tunnel with a single shell it was to study the tunnel method. First, we analyze the design and construction practices relating to delete lining of the domestic design and construction practices and a comprehensive analysis of the stability study found a rock in good condition interval (1~3 grades), we propose that the lining uninstalled. In the case of domestic changes on the ground floor is very heavy underfoot conditions many so tunneling method by single shell as ground conditions are good and one preferred the water points that apply in less soil, the soil health and poor sections (4~5 grades) reflecting with respect to the concrete lining that is expected reasonable.

A New Design of the Interrogating Waves for Medical Ultrasonic Imaging Based on Wavelets and Subband Filter Banks: A Simulation Study (의료용 초음파 영상시스템을 위한 Wavelet 과 Subband Filter Bank 에 기반한 새로운 탐침 파형의 설계: A Simulation Study)

  • Yang Yoon Seok
    • Journal of Biomedical Engineering Research
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    • v.25 no.6
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    • pp.431-438
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    • 2004
  • Medical ultrasonic imaging is a useful imaging facility known to be most safe and easy. It enables physicians to observe the inside structures of the bodies, blood flow, and motions of internal organs. Some physical properties of biologic tissues can also be estimated from backscattered sounds. However, the ultrasonic pulses interrogating the living organisms leave their footprints in the returning signals during imaging. Some significant details are buried in the footprints and their overlaps from adjacent particles. These distortions also decrease the quality of the images. Many research efforts have been made to enhance the image quality and to recover the acoustic information in various ways. In this study, a new interrogation method based on the wavelet and subband filter bank is proposed. It adopts the subband wavelet filters satisfying the perfect-reconstruction (PR) conditions as the interrogating pulses to restore the details useful in tissue characterization and to enhance the image quality. The proposed method was applied to two types of simulations of ultrasonic imaging. The results showed its ability to restore the detailsin the simulated interrogation of biologic tissues, and verified the improved image quality in the simulated imaging of general ultrasonic phantom compared with the conventional method.

Transmission Noise Seduction Performance of Smart Panels using Piezoelectric Shunt Damping (압전감쇠를 이용한 압전지능패널의 전달 소음저감 성능)

  • 이중근
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.1
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    • pp.49-57
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    • 2002
  • The possibility of a transmission noise reduction of piezoelectric smart panels using piezoelectric shunt damping is experimentally studied. Piezoelectric smart panel is basically a plate structure on which piezoelectric patch with shunt circuits is mounted and sound absorbing materials are bonded on the surface of the structure. Sound absorbing materials can absorb the sound transmitted at mid frequency region effectively while the use of piezoelectric shunt damping can reduce the transmission at resonance frequencies of the panel structure. To be able to reduce the sound transmission at low panel resonances, piezoelectric damping using the measured electrical impedance model is adopted. Resonant shunt circuit for piezoelectric shunt damping is composed of register and inductor in series, and they are determined by maximizing the dissipated energy throughout the circuit. The transmitted noise reduction performance of smart panels is investigated using an acoustic tunnel. The tunnel is a tube with square crosses section and a loud-speaker is mounted at one side of the tube as a sound source. Panels are mounted in the middle of the tunnel and the transmitted sound pressure across panels is measured. Noise reduction performance of a smart panels possessing absorbing material and/or air gap shows a good result at mid frequency region but little effect in the resonance frequency. By enabling the piezoelectric shunt damping, noise reduction of 10dB, 8dB is achieved at the resonance frequencise as well. Piezoelectric smart panels incorporating passive method and piezoelectric shunt damping are a promising technology for noise reduction in a broadband frequency.

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