• Journal of the Korean Applied Science and Technology
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• v.38 no.6
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• pp.1678-1686
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• 2021

In this study, we prepared phosphorous flame-retarding coating solutions by mixing triphosphate (3 phosphonate), phytic acid (6 phosphonate), or ammonium polyphosphate (10 phosphonate) with boric acid as a crosslinking agent and acryl resin binder. Prepared phosphorous flame-retarding coating solutions were coated onto non-woven fabrics, respectively, to obtain high flame-retarding effects. These prepared flame-retardant non-woven fabrics were evaluated using smoke density standard test (ASTM E662), limit oxygen index standard test (ISO E622), and vertical burning standard test (UL 94). Their flame-retarding effects were affected by the number of phosphonate groups. Regardless of natural or synthetic binder resins, their effects showed the following order: ammonium polyphosphate > phytic acid > triphosphate. Natural hydrocarbon compounds were also examined to determine the possible retardancy of binder resins. Results showed that natural hydrocarbon binder resins could be used for preparing fire-retardant nonwoven fabrics.

• Proceedings of the Korean Fiber Society Conference
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• 2001.10a
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• pp.364-367
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• 2001

lithography를 사용하여 패턴 형성에 이용되는 감광성 고분자 바인더 수지로는 통상 아크릴수지 또는 폴리이미드 수지가 사용된다. 폴리이미드 수지는 양호한 성능을 나타내지만 패턴 형성에 난점이 있다. 반면 아크릴수지는 패턴현상성은 우수하지만, 내열성능이 폴리이미드 수지보다는 낮기 때문에 고온 고습하에 기판을 장시간 방치한 경우, 화소내 도막의 변색이나 중량감소 등 여러 문제가 생길 수 있다. (중략)

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.3
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• pp.94-101
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• 2011

In this study, in order to develop organic-inorganic hybrid packaging materials(PM) of bike paths using blast furnace slag(BS) as industrial by-products, fundamental properties of organic-inorganic hybrid packaging materials were performed. Test result, the increase of Acryl emulsion polymer(AEP)/binder(B) ratios tends to delay the setting time, to increase the table flow, to decrease the strength by material segregation and to increase the length change. The optimal mix proportion of AEP decides on 40%(AEP/B) due to workability and high strength. The increase of BS replacement ratios also tends to delay the setting time, to separate AEP from B and to decrease the strength by material segregation. When BS replacement ratios were lower than 40%, they are satisfied with goal properties.

• Proceedings of the Korean Printing Society Conference
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• 2001.06a
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• pp.91-91
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• 2001

환경문제에 대해 오래 전부터 관심을 가져온 선진국은 잉크의 수성화에 주력하여 왔으며, 그 결과 이미 수용성 소재의 양산체재에 들어가 수성 원료 사업을 대형화하는 추세에 있다. 이에 한화석유화학 중앙연구소에선 스티렌/아크릴계 수용성 High Solid 수지를 개발하여, 수성 잉크용 분산제, Resin Fortified Emulsion (RFE), UV Resist 잉크, 수성코팅제, 바닥광택제 등에 적요하기 위한 응용기술을 개발하였다. 본 연구는 수성 잉크의 주요 구성 성분인 grinding vehicle. let-down vehicle로 사용되는 수용성 High Solid 수지 (SAA 수지) 및 이를 이용한 에멀젼 수지의 합성과 수성 잉크로의 응용에 대한 것이다. SAA(HCC Soluryl Resin) 수지는 구조적으로 Styrene, Alpha-methyl Styrene, crylic Acid의 삼원공중합체이며 약 70%의 소수성 물질과 30%의 친수성 물질이 Random 하게 중합되어 있으며 약 5000∼15000정도의 낮은 분자량을 가진 물질로, 고고형분에서도 낮은 점도를 유지하기 위하여 분자량과 좁은 분자량과 좁은 분자량을 가지는 수지를 연속벌크중합방법으로 합성하였다. 또한 이를 고분자 유화제로서 사용하여 수지보강 에멀젼수지 (RFE 수지, HCC Soluryl Emulsion) 를 제조하는데 사용하였으며, SAA수지 및 RFE수지를 수성잉크용 분산제, 잉크 바인더용으로 적용하였다.

• Applied Chemistry for Engineering
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• v.17 no.4
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• pp.397-402
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• 2006

We have investigated the effect of each ingredient in the light diffusing film (LDF) which was used as backlight unit (BLU) of TFT-LCD TV on physical, electrical, thermal and optical properties of LDF. In anti-blocking layer, the excellent anti-blocking ability was obtained when 0.5~1.5 wt% of acrylic bead was added, and good decay-time and water-stability were shown when 0.8 wt% of tertiary ammonium salt was added. Optimal results for adhesion strength, curing rates and flexibility on the surface of PET film have been obtained in the light diffusing layer by using acrylic polyol as a binder resin, and by addition of 30~35 wt% non-yellowing type HDI crosslinker. In addition, the highest normal luminance value was obtained by addition of 250 wt% poly-dispersive polystyrene ($20{\mu}m$ PS) and polymethylmethacrylate ($20{\mu}m$ PMMA) beads into the binder resin (100 wt%). The higher normal luminance could be got for PMMA beads than PS beads because of the transmittance difference.

• Applied Chemistry for Engineering
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• v.20 no.1
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• pp.52-61
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• 2009

In this study, TAPEH (t-amyl peroxy 2-ethyl hexanoate) was selected for the reaction initiator which is a core factor for developing acrylic polyol binder. Tone M100 (caprolactone acrylate), 4HBA (4-hydroxy butyl acrylate), and 2HEMA (2-hydroxy ethyl methacrylate) were used for hydroxy-monomers. To check the applicability of raw materials mentioned above into the binders of 2 components acrylic polyurethane paint and reduce the VOC, the reactivity and film performance by different kinds of aliphatic polyisocyanate hardeners which are already generalized were reviewed. As the Tin-based catalyst has been regulated, the comparison test of reactivity and performance between the conventional catalyst and non-toxic metal catalyst recommended as the alternative was conducted as well. As a result, we were able to obtain the basic data which are necessary for applying 2 components high solid polyurethane paint and also reached a conclusion that it can be applied for developing new paints in terms of high performance, workability and environmental care.

• Applied Chemistry for Engineering
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• v.23 no.1
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• pp.18-22
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• 2012

Photocurable binder for a transparent glass fiber composite was prepared with alicyclic methacrylate and fluorene-based diacrylate. ANOVA (analysis of variance) analysis was used to know main factors affecting the conversion of photocurable binder. It showed radiation intensity and photoinitiator (PI) concentration were main factors. The conversion of photocurable binder was simply increased with radiation intensity. Its increment however was abated with increasing PI concentration. We found that average conversion of the binder measured by FTIR-ATR was 87% when it was exposed to $5J/cm^2$ of UV dose with 5 wt% of PI. Oxime ester type PI was very effective to get a high degree of conversion, but it caused a yellowing problem. Owing to post-baking process, UV cured film showed an improved thermal stability by increase of conversion and removal of volatile organic compounds. TG% at $260^{\circ}C$ of film cured with 5 wt% of PI (TPO+MBF) and $5J/cm^2$ of UV radiation increased from 95.4 to 99.0% by post-baking at $230^{\circ}C$ for 5 min.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.481-487
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• 2017

The purpose of this study is to develop the hybrid sound-absorbing materials that is made from organic polyurethane sponge impregnated with inorganic binder solutions. The inorganic slurry which is made from ${\alpha}$-hemihydrate gypsum mixed with 60% water, and various additives including plasticizer are used as binder. The test specimens are prepared and tested for sound absorption performance by the impedance tube methods. From the test results, noise reduction coefficient(NRC) of development materials specimen bound by the inorganic binder slurry is 0.41. They are 2 times or more higher than commercial products specimens bound by organic materials only which have NRC values in the range of 0.14 to 0.28. The polyurethane sponge specimens impregnated with inorganic gypsum slurry binder have a good balance between performance and cost, and have proper properties in density, thermal conductivity, non-combustible, and absence of harmful substances as sound-absorbing internal boards for noise barrier wall. It is apparent that the good sound absorption materials can be produced according to the optimum mix design that is recommended from this study.