• Title/Summary/Keyword: 아마이드

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Oxidation of a substrate by O2 in Fe(II) catalysis for the reversible oxidation effected by heme (헴에 의한 가역산화 때문에 철(II) 촉매에서 산소에 의한 기질의 산화)

  • Lee, Yong-Hee;Park, Bong-Jin;Suh, Myung-Gyo;Lee, Young-Sei
    • Journal of the Korean Society of Industry Convergence
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    • v.6 no.4
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    • pp.347-353
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    • 2003
  • Fe(II)하에서 분자산소에 의한 기질의 산화는 헴에 의해 나타난 가역산화반응에 의해서 대단한 생물학적 흥미가 있다. 적당한 조건하에서 산화되어진 리간드로서 염인 피리딘이나 아마이드, 그리고 두 가지 종류의 Fe(II)-acac나 Fe(II)-sal의 complex와 산화되는 기질의 성질이 비라디칼 조건하에서 안정하다는 것을 알았다.

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Acrylamide content and quality characteristics of sweet potato chips using different cultivars (품종에 따른 고구마 칩의 아크릴아마이드 함량과 품질 특성)

  • No, Junhee;Lee, Chae Eun;Huang, Mengyo;Lee, Jooree;Nam, Sangsik;Shin, Malshick
    • Korean Journal of Food Science and Technology
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    • v.50 no.3
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    • pp.308-315
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    • 2018
  • To select suitable cultivars to produce sweet potato (SP) chips instead of potato chips, ten Korean cultivars, Sinjami, Yeunjami, Sinhwangmi, Juhwangmi, Sincheonmi, Sinyulmi, Gunhwangmi, Dahomi, Daeyumi, and Pungwonmi were used. The acrylamide content, quality characteristics, and oxidation stability of SP chips were investigated. Acrylamide content was shown to be under 0.48 mg/kg in case of all cultivars except Yeunjami (1.07 mg/kg). The color values significantly differed among the cultivars and were maintained like those of raw roots. The hardness, brittleness, and fracturability of Juhwangmi and Sinhwangmi chips showed the lowest values, while those of Daeyumi were the highest. According to the sensory evaluation data, the quality characteristics of chips were influenced by not only hardness, fracturability, and crunchiness, but also the flavor taste. Pungwonmi chips showed the highest score, followed by Gunhwangmi and Dahomi chips. Therefore, Pungwonmi, Dahomi, and Gunhwangmi are suggested as suitable cultivars to make SP chips, because of their high overall quality and very low acrylamide content.

Reduction of Acrylamide Formation in Potato Chips Fermented by Bacillus sp. (Bacillus sp. 발효를 이용한 감자 칩의 아크릴아마이드 저감화)

  • Lee, Joongjae;Oh, Myeonggeun;Chang, Yoon Hyuk;Lee, Youngseung;Jin, Yong-Ik;Chang, Dong-Chil;Kim, Sung-Hwan;Jeong, Yoonhwa;Kim, Misook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.45 no.3
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    • pp.460-465
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    • 2016
  • The market for potato chips has expanded due to increased consumption of seasoned potato chips. However, the deep-frying process facilitates development of a browning color and formation of acrylamide. The objective of this work was to minimize browning color and acrylamide formation by fermentation prior to deep-frying. Potato slices were fermented by using three Bacillus strains, B. licheniformis (BL), B. methylotrophicus (BM), and B. subtilis, for 6 h at $30^{\circ}C$. In all fermentation groups, contents of total sugars in potato slices decreased. The color of fermented potato chips improved compared to the control. BM potato chips showed the best color values (76.33 in L value, 5.67 in a value, and 34.79 in b value). All fermentation processes reduced levels of acrylamide in deep-fried potato chips. Fermentation of potato slices for 2 h by BL reduced up to 96.1% acrylamide content. It was concluded that the fermentation process can positively affect color development and acrylamide formation.

TB클리닉 - 결핵 치료시 흔히 접하는 문제들

  • Kim, Hui-Jin
    • 보건세계
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    • v.56 no.6
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    • pp.19-23
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    • 2009
  • 외래에서 흔히 이용하는 결핵 진단법으로는 객담 도말과 배양검사, 엑스선 검사가 있다. 일단 활동성 결핵으로 진단되면 환자의 과거력 등을 참조하여 치료를 하게 되는데, 초치료인 경우 아이나, 리팜핀, 에탐부톨, 피라진아마이드를 이용한 6개월 단기 초치료 처방으로 치료를 한다. 4제 처방의 효과는 강력하여 규칙적으로 약을 복용한다면 대부분 완치되며, 완치 판정은 치료 중 추구 객담검사를 이용한다. 대부분의 환자들은 진단, 치료에 어려움이 없지만 실제 외래 치료시에는 진단, 치료에서 어려운 문제가 발생하기도 한다. 이에 외래에서 부닥칠 수 있는 상황과 적절한 대처법을 알아보기로 한다.

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Cyclization Reaction of 2(2',2'-Diethoxyethyl) Aminobenzamide (2(2', 2'-디에톡시에틸) 아미노벤즈아마이드의 고리화반응 (I))

  • 서명은
    • YAKHAK HOEJI
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    • v.31 no.6
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    • pp.370-375
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    • 1987
  • 1, 4-Benzodiazepin 5-one was prepared from 2-aminobenzamide derivatives by acid catalyzed intermolecular cyclization. N-Alkylation of 2-aminobenzamide with $\alpha$-bromo acetaldehyde diethylacetal to 2(2', 2'-diethoxyethyl) aminobenzamide (I) and subsequent treatment of I with acid gave 1, 4-benzdiazepin 5-one, where as the acetyl derivatives of I did not react to 1, 4-benzodiazepin 5-one but to methyl 4-quinazolone (IV).

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Preparation and Characterization of Bead Type Superabsorbent Resin (비드형 고흡수성 수지의 제조 및 특성연구)

  • Ahn, Kyo Duck;Yoon, Minjoong
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.760-766
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    • 2014
  • Bead type super-absorbent resins to be used for release-control were prepared by modification of the inverse suspension polymerization, and their physical properties were characterized. Acrylic acid and acrylamide were used as monomers, and N,N-methylenebisacrylamide was used as crosslinker, controlling the viscosity of monomer solution by adding hydroxyethylcellulose (HEC). SEM studies of the synthesized beads verified that the bead surfaces had many pores with their diameters of several tens nm. The bead sizes were in the range of $500{\sim}3000{\mu}m$, depending on the viscosity of the monomer solution. Both absorbent amount and absorbent rate of the beads were inversely proportional to the bead size, and the maximum water absorbent amount of 1 g beads was determined to be ca. 170~200 g for 5 hrs. The absorbent rate was also dependent on pH change of the aqueous solution, exhibiting the maximum rate in pH ranging from 5 to 11. The absorbent rate decreased as the concentration of salt (NaCl and $MgCl_2$) or ethanol and ethylene glycol increased. Release time of the water absorbed into the bead resins was 700 hrs, confirming the usefulness of the resin for the good release-control materials.

New Micropolymer Technologies for Increased Drainage and Retention for both Wood and Non-Wood Containing Furnishes (목질 및 비목질 함유 지료의 탈수속도와 보류향상을 위한 새로운 마이크로폴리머 기술)

  • Lewis, Christopher;Polverari, Marco
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2008.05a
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    • pp.1-46
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    • 2008
  • The ability to control filler performance and fines retention is vital in the development of both filled and non filled grades, respectively. This is very important when achieving the desired sheet structure necessary to maximize machine performance and end user demands. A narrow balance exists in attaining the desired retention and formation particularly in systems with heavier ash loads and producing paper and paper board on higher speed high shear equipment. A new generation of both cationic and anionic micropolymer technologies has been developed. These water based chemistries are volatile organic compound (VOC) and alkyphenol ethoxylate (APE) free. When these novel micropolymers are applied with linear poly-acrylamide or in conjunction with inorganic microparticle technologies (such as silica or swellable minerals), substantial increases in drainage, fibre retention and ash retention are observed. These improvements have been observed not only in high filled wood and non wood containing grades such as fine paper and super calendared sheets (SCA), but also in low filled newsprint grades. Of particular note is the drainage improvement seen with the application of the cationic micropolymers in unbleached packaging grades with poly-acrylamide.

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Reaction of Potassium Fluoride with Organic Halogen Compounds. (Part I) Reactions of Potassium Fluoride with Organic Halides, Acids, and Esters in presence of Dimethyl Formamide and their Pyrolytic Decaboxylation in presence of Potassium Fluoride (有機 할로겐 化合物과 弗化加里의 反應 (第1報) 有機 할라이드, 酸 및 에스테르와 弗化加里의 디메칠 호름아마이드 溶媒系反應 및 高溫-脫炭酸-熱分解反應)

  • You Sun Kim
    • Journal of the Korean Chemical Society
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    • v.7 no.3
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    • pp.189-196
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    • 1963
  • Reactions between potassium fluoride with organic halogen-containing carboxylic acids in dimethyl formamide solvent gave a decarboxylation reaction for the case of fluoro carboxylic acids of the type of $CF_3\;COOH,\;C_3F_7COOH,\;and\;C_2F_5COOH,$ whereas an additional partial fluorination together with dimerization reaction occurred for the chlorine containing acids of the type of $CH_2ClCOOH,\;CH_3CHClCOOH, \;CHCl_2COOH\;and\;o-Cl-C_6H_4-COOH.$ The phenyl halides showed no reactivity, but the halides with two electron attracting substituents on the benzene ring gave mainly dimerization reaction. The esters and alcohols gave an usual fluorination reaction. The same reactions in absence of the solvent at the elevated temperature increase the yield of the dimerized product and gave the cyclized product, fluorenone, in case of ο-chlorobenzoic acid. It was found that the fluorination usually precede the decarboxylation reaction by checking the stiochemical sequence of reaction. Catalytic influence of potassium fluoride were discussed and the mechanism of the reaction was considered.

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Tuning the Stiffness of Dermal Fibroblast-encapsulating Collagen Gel by Sequential Cross-linking (연속가교를 통한 피부 진피세포 담지 콜라겐 겔의 강도 제어)

  • Jung, Mun-Hee;Shin, Sung Gyu;Lim, Jun Woo;Han, Sa Ra;Kim, Hee-Jin;Jeong, Jae Hyun
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.1
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    • pp.23-29
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    • 2018
  • In this study, sequential cross-linked collagen gels were successfully prepared with collagen, which is biomaterial, and acrylamide (AAm), which is a synthetic monomer. The elastic moduli (E) of cross-linked collagen gels were increased from 1.5 to 3.0 kPa by varying of AAm concentrations. In addition, human dermal fibroblasts were encapsulated into the porous pores introduced into the gels, and cell growth and behavior were investigated. Increasing E of the gels led to decreases in cell growth rate, while the cellular glycosaminoglycan (GAG) production level was elevated. Overall, the growth and cellular activity of skin cells were influenced by the extracellular matrix properties of the collagen gels. In conclusion, these results will be highly useful for designing reconstructive skins and various tissue engineering researches.