• Journal of the Korean Geotechnical Society
• /
• v.21 no.2
• /
• pp.93-103
• /
• 2005

This study was performed to identify the presence of measurement distortions such as electrode polarization and to investigate the influence of soil water content on complex permittivity at low frequency. In low frequency measurement using two-terminal electrode system, electrode polarization effect was observed at frequencies less than approximately 100 HBz. The analysis for real permittivity should be performed at frequencies above 100 kHz in order to exclude electrode polarization effect in the analysis of real permittivity at low frequency measurements. For a given soil, both of real and effective imaginary permittivity of wet soil increased continuously with volumetric water content. This is evidenced by the facts that the real permittivity is proportional to the number of dipole moments per unit volume and effective imaginary permittivity is effected by the conduction due to water. However, proportional relation between real permittivity and volumetric water content is valid at upper MHz frequencies.

• Journal of the Korean Chemical Society
• /
• v.27 no.3
• /
• pp.167-177
• /
• 1983

The kinetics of 2-anthracenesulfonyl chloride in methanol-water, ethanol-water, acetone-water and acetonitrile-water has been studied by electroconductometric method. For media in which water has the same mole fraction, the rate was greater in protic solvent than in dipolar aprotic solvent and it was greater consistently in methanol-water than in ethanol-water over the whole range of solvent composition investigated, while the two rates in acetone-water and acetonitrile-water inverted at about 0.9 of mole fraction of water. Both m value, susceptibility of rate to the ionizing power and n value, solvent participation number in the transition state were much smaller in protic solvent. These values and the activation parameters show that solvolysis of 2-anthracenesulfonyl chloride proceeds by $ S_N2$ mechanism.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.08a
• /
• pp.129-129
• /
• 2010

플라즈마 처리를 통하여 수직 합성된 다중벽 탄소나노튜브가 원뿔형 다발이 될 수 있으며 원뿔형 탄소나노튜브 다발은 기존의 구조적, 기계적 성질의 향상과 더불어 향상된 전계방출 능력을 가질 것으로 기대되어 이를 X-선원, 전계방출디스플레이(FED), 유기발광다이오드(OLED) 백라이트 등의 전자빔 원으로 적용하기 위한 연구가 진행되고 있다. 원뿔형 탄소나노튜브 다발의 형상 제어를 통하여 전계방출특성을 향상시킬 수 있으며 이를 위해 원뿔형 탄소나노튜브 다발이 생성되는 메커니즘과 조사되는 플라즈마의 역할에 대해서 이해하는 것이 중요하다. 본 연구에서는 플라즈마 생성부와 조사부를 분리한 유도결합형 플라즈마 원을 사용하여 입사되는 이온의 에너지, 조사량, 입자 종을 독립적으로 제어하였고 이를 통하여 원뿔형 탄소나노튜브 다발이 형성되는 메커니즘과 플라즈마의 역할을 밝혀내었다. 알곤 및 수소 플라즈마 처리에서는 원뿔형 탄소나노튜브 다발이 형성되지 않았으나 질소 및 산소 플라즈마 처리에서는 원뿔형 탄소나노튜브 다발이 형성되었다. 특히 산소 플라즈마 처리가 원뿔형 탄소나노튜브 다발 형성에 효과적이었다. 원뿔형 탄소나노튜브 다발의 형성 메커니즘은 탄소나노튜브의 분극과 쉬스 전기장의 상호작용을 이용한 모델을 사용하여 설명하였다. 질소 및 산소 플라즈마 처리에서는 탄소나노튜브 끝단에 생성되는 C-N, C-O 결합에 의해 향상된 유도 쌍극자와 쉬스 전기장에 의해 탄소나노튜브 끝단이 모여 원뿔형 탄소나노튜브 다발이 생성됨을 밝혀내었다. 산소 플라즈마 처리에서 입사되는 이온의 에너지 조절에 의한 쉬스 전기장 조절과 조사량 조절을 독립적으로 수행하여 원뿔형 탄소나노튜브 다발의 직경 및 높이가 쉬스 전기장 및 조사량에 따라 조절 가능함을 보였다. 이로부터 입사되는 이온의 입자 종, 쉬스 전기장 및 조사량 조절 등의 플라즈마 인자 조절을 통하여 원뿔형 탄소나노튜브 다발의 형상 제어가 가능함을 보였다. 탄소나노튜브의 형상 제어와 더불어 세슘 입자 삽입을 통한 탄소나노튜브의 일함수 감소를 통하여 향상된 전계 방출 특성을 갖는 탄소나노튜브 팁의 제조 가능성을 확인하였다.

• Applied Chemistry for Engineering
• /
• v.10 no.3
• /
• pp.456-460
• /
• 1999

The YHB radial distribution functions of a linear gas molecule CO were calculated by a computer within the Stockmayer molecular potential molel, which assumed thc CO molecule as a simple dipolar molecule. To examine the validity of the obtained YHB radial distribution of CO gas molecule, the density dependent pressures of CO at several temperatures were also calculated. The calculated pressures showed a good agreement with literially known experimental CO pressure data. The temperatures examined were 273, 298, and 373 K and the densities were up to $0.013/{\AA}^3$ (maximum pressure = 1000 atm). Since the calculated pressures showed a good agreement with the experimental values, the obtained YHB radial distribution functions of CO molecule seemed good enough to obtain and predict various equilibrium physical and chemical quantities of CO molecule sensitive to density such as pressure. It was also found that in CO gas system the dipole-dipole interaction is effective up to approximately 2.5 molecular diameter.

• The Journal of Engineering Geology
• /
• v.15 no.1
• /
• pp.19-27
• /
• 2005

The Sambo mine is located in Hae-je Myeon, Moo-an Gun, Chollanamdo, which consists of host gneiss and rhyolite possessing quartzite veins with other compositions such as gold, silver, and sublimated sulfur. The ore grade estimated from the core was 0.05～10.9g/t or less in gold and 0.05～389g/t or less in silver, indicating a partial mineralization. The purpose of this paper is to understand the subsurface structures and the distribution of mineralized bodies in the Sambo mine using a combined method of Schlumberger, Wenner, and Dipole-di-pole resistivity surveys on the surface and the resistivity tomography survey in boreholes. The result of three-dimensional resistivity inversion showed that the mineralized body is extended to 240m long in the N10°～20°E direction, with 30m wide and 80 m thick from the surface. The low resistivity zones (<1,000ohm-m) determined from the resistivity image were in good agreement with the mineralized bodies and weak zones identified from the logged cores.

• Journal of Sensor Science and Technology
• /
• v.5 no.1
• /
• pp.1-8
• /
• 1996

High-sensitive pyroelectric infrared sensors have been fabricated with La-modified $PbTiO_{3}$(PLT) thin plates. The PLT thin plates have the composition of $(Pb_{0.9}La_{0.1}Ti_{0.75}O_{3})_{0.75}(PbO)_{0.25}$. Thickness of the thin plates is $100\;{\mu}m$. Top side electrodes exposed to IR are vacuum evaporated Ni-Cr, and bottom side electrodes are Ag. Each one takes the area of $1{\times}2\;mm^{2}$. The thin plates have a large resistivity of $6.41{\times}10^{10}{\Omega}{\cdot}cm$ and a relative dielectric constant of 341. They have a high figure of merit of $4.0{\times}10^{-11}\;Ccm/J$ due to its high pyroelectric coefficient of $4.45{\times}10^{-8}\;C/cm^{2}K$. The sensors show such a large voltage responsivity as 2501 V/W. That they can find practical applications like the pyroelectric infrared detectors.

• Economic and Environmental Geology
• /
• v.35 no.2
• /
• pp.155-162
• /
• 2002

There are many typical epithermal deposits scattering in the Taran of central Kalimantan. Indonesia. To get the shallow geological information, we carried out the geophysical exploration: spontaneous potential survey, in-suite magnetic susceptibility measurement and relistivity survey method in this area for a few weeks from September 30th to October 27th in 1997. SP survey (Fluke 27 multimeter)/magnetic susceptibility (EK -7 meter) measurement was carried out with a 250m$\times$10m lattice net in N45$^{\circ}$W direction. The dipole-dipole array resistivity survey was conducted with an electrode spacing of ${\alpha}$=30 m and electrode separation index n=7 at the line 5. The result shows that was the gold bearing quartz vein area can be divided into two type lone: low sulfidation type and high sulfidation type zone. The low resistivity value in the survey line 5 indicated a fracture Bone associated with the high sulfidation zone.

• Economic and Environmental Geology
• /
• v.29 no.3
• /
• pp.345-355
• /
• 1996

The effectiveness of various electrode configurations in horizontal mappings and 1-D inversions of vertical sounding data for delineating 2-D structures was studied. Apparent resistivity values of three point, dipole-dipole, Wenner, and Schlumberger mappings were simulated for such structures as vertical dyke, tabular prism, buried vertical fault, ramp and complex structure by finite difference method (FDM) and they were compared with each other. Also 2-D cross sections for three structures obtained by interpolation of 1-D inverted sounding data in terms of three layers were compared for Schlumberger and Wenner arrays. On these cross sections, horizontal and vertical resistivity interfaces of the 2-D structures are revealed relatively clearly. Apparent resistivity curves of Schlumberger mapping show vertical resistivity discontinuities very well. On the whole, Schlumberger array is superior to the other arrays in electric sounding as well as mapping. This study clearly indicates that interpretations of 2-D structures based on 1-D inversion are possible.

• Journal of the Korean Chemical Society
• /
• v.29 no.1
• /
• pp.45-51
• /
• 1985

Rate constants and activation parameters for the methanolysis of t-butyl halide (t-BuCl, t-BuBr, t-BuI) in various MeOH-DMSO mixtures were measured by conductometric method. Taft's solvatochromic parameters, such as polarity-polarizability(SPP's), ${\pi}^{\ast}$, hydrogen bond donor (HBD) acidity, ${\alpha}$, and hydrogen bond acceptor (HBA) basicity, ${\beta}$ of the solvents, were determined by the so called solvatochromic method using five indicators. The variation of methanolysis rate with the solvent composition was discussed on the basis of the activation parameters and the correlation of the rates with the solvatochromic parameters. It is concluded that the polarity-polarizability, HBD acidity and HBA basicity of the mixtures had an effect on the ionization of t-butyl halide cooperatively, also that the specific interaction between the leaving groups and the solvents, such as ion-dipole and hydrogen bond acceptor-donor interaction, is the most important factor of solvent effects on the stabilization of transition states.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2008.06a
• /
• pp.77-77
• /
• 2008

금(Au)이나 은(Ag)과 같은 귀금속 물질로 형성된 금속 나노 구조체는 표면 플라즈몬 공진(Surface Plasmon Resonance, SPR) 현상과 이의 국부 환경(local environment) 변화에 대해 민감한 의존성으로 인하여 생화학적 센서로의 응용이 주목 받고 있다. 표면 플라즈몬 공진은 광 흡수와 광 산란을 수반하는데, 두 가지 특성 모두 분광학적 신호검출방식으로 센서에 응용가능하다. 이 중 광 산란을 이용하는 방식은 광원의 배경잡음 효과가 배제되기 때문에 단일 입자 검출에 유리하다. 광 흡수와 광 산란 특성은 금속 나노 구조체는 크기, 형상, 주변 매질, 물질의 선택에 따라서 영향을 받는다. 본 연구에서는 금 나노 디스크(nanodisc)의 형상에 따라서 여기 되는 표면 플라즈몬이 광 흡수와 광 산란 특성에 미치는 영향을 가시광과 근적외선 영역에 대해서 불연속 쌍극자 근사법(Discrete Dipole Approximation, DDA)을 이용하여 전사모사(simulation) 하였다. 금 나노 디스크의 형상과 플라즈몬 특성 간의 관계는 공명 파장과 산란 양자 거둠율(scattering quantum yield, $\eta$)을 이용하여 분석하였고, 센서로서의 응용을 가늠하기 위해 주변 매질의 굴절률을 조절하여 그에 따른 민감도(sensitivity )를 비교하였다. 나노 디스크의 모양이 판상에 가까워질수록 공명 파장은 적색 편이하였고 광 산란 효율과 민감도는 증가하는 현상이 나타났다. 또한, 산란 양자 거둠율은 증가하다가 완만하게 감소하는 경향이 나타났다.