• Journal of the Korean Society of Radiology
• /
• v.5 no.5
• /
• pp.283-287
• /
• 2011

In this study, fine $Gd_2O_2S$:Tb powder was synthesized by using a low temperature solution-combustion method for a high-resolution digital x-ray imaging detector. From the fabricated phosphor power, the fine scintillator films was fabricated by particle sedimentation method and was investigated the luminescent property. From the experimental results of relative light output as a function of terbium concentration, the highest luminescent efficiency has at 5 wt% Tb concentration, and luminescent intensity decreased rapidly according to quenching effect about higher Tb concentration. Also, the relative light output of $270{\mu}m$-$Gd_2O_2S$:Tb film has 2945 pC/$cm^2$/mR. And light intensity was saturated at higher film thickness. Finally, to evaluate an image acquisition performance of fabricated phosphor, images were obtained by using commercial CMOS sensor and measured the MTF, NPS, and DQE. DQE(0 lp/mm) of fine phosphor film has 37%. But, DQE improvement of fine phosphor film is possible by resolving problem of film fabrication process and has a significant potential in the application of digital radiation imaging system later.

• Applied Chemistry for Engineering
• /
• v.21 no.6
• /
• pp.593-602
• /
• 2010

Chitosan as a natural polymer has superior physicochemical properties such as biocompatibility, biodegradability and nontoxicity, but application of chitosan for therapy of cancer and gene related-disease has been limited by poor solubility in aqueous solution. Therefore, low molecular weight water-soluble chitosan (LMWSC) with high reactivity and strong positive charge can be applied as a delivery system having function to carry in the specific tissue the bioactive material like poor solubility drug, or therapeutic gene and developed as a therapeutic system having good therapeutic efficiency. The most important factor for therapy of various diseases is to reveal the antigen or receptor expressed in specific lesion tissue and the antibody and ligand which can bind with antigen is to introduce at the biomaterials for enhancement the therapeutic efficiency. The studies for cationic synthetic polymer as drug or gene delivery have been actively performed, but it has many problems such as toxicity in the body, therapeutic efficiency. From this point of view, this article demonstrated the introduction of functional groups to target the specific tissue and therapeutic strategy using the modification of LMWSC with free-amine group. The development of these delivery system will provide a positive vision for cancer therapy.

• Journal of the Mineralogical Society of Korea
• /
• v.24 no.4
• /
• pp.289-300
• /
• 2011

Atomistic origins of carbon solubility into silicates are essential to understand the effect of carbon on the properties of silicates and evolution of the Earth system through igneous and volcanic processes. Here, we investigate the atomic structure and NMR properties of dissolved carbon in enstatite using Raman spectroscopy and quantum chemical calculations. Raman spectrum for enstatite synthesized with 2.4. wt% of amorphous carbon at 1.5 GPa and $1,400^{\circ}C$ shows vibrational modes of enstatite, but does not show any vibrational modes of $CO_2$ or ${CO_3}^{2-}$. The result indicates low solubility of carbon into enstatite at a given pressure and temperature conditions. Because $^{13}C$ NMR chemical shift is sensitive to local atomic structure around carbon and we calculated $^{13}C$ NMR chemical shielding tensors for C substituted enstatite cluster as well as molecular $CO_2$ using quantum chemical calculations to give insights into $^{13}C$ NMR chemical shifts of carbon in enstatite. The result shows that $^{13}C$ NMR chemical shift of $CO_2$ is 125 ppm, consistent with previous studies. Calculated $^{13}C$ NMR chemical shift of C is ~254 ppm. The current calculation will alllow us to assign potential $^{13}C$ NMR spectra for the enstatite dissolved with carbon and thus may be useful in exploring the atomic environment of carbon.

• Korean Chemical Engineering Research
• /
• v.49 no.5
• /
• pp.530-534
• /
• 2011

The synthesis of dimethyl carbonate by liquid phase oxidative carbonylation of methanol was studied under batch reaction system. Reaction factors such as effect on various metals, anion containing in copper catalyst, temperature, carbon monoxide and oxygen molar ratio and copper content were investigated. In particular $CuCl_2{\cdot}2H_2O$ showed the excellent of the methanol conversion 65.2%, DMC selectivity 96.6% reaction condition under 1.0 g, $150^{\circ}C$, MeOH/CO/$O_2$=0.2/0.215/0.05 (molar ratio). $CuCl_2$ led to corrosion of the reactor. Thus, a new catalyst system using supports was investigated to resolve these corrosion problem. Influence on various supports were examined and copper catalyst supported on zeolite Y showed the most excellent activity on the formation of dimethyl carbonate. The amount of Fe dissolved during the reaction using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometer) was compared with catalysts, calcined Cu/zeolite Y showed the lower value below 5% than $CuCl_2-2H_2O$.

• Journal of KIISE:Computer Systems and Theory
• /
• v.27 no.7
• /
• pp.650-664
• /
• 2000

NOW(Network of Workstations) is considered as a platform for running parallel programs by many people. One of the fundamental problems that must be addressed to achieve good performance for parallel programs on NOW is the determination of efficient job scheduling policies. Currently most research on NOW assumes that all the workstations in the NOW have the same processing power. In this paper we consider a NOW in which workstations may have different computing power. We introduce 10 classes of space sharing-based scheduling policies that can be applied to the NOW with heterogeneous computing power. We compare the performance of these scheduling policies by using the simulator which accepts synthetically generated sequential and parallel workloads and generates the response time and waiting time of parallel jobs as performance indices of various scheduling strategies. Through the experiments the case when a parallel program is partitioned heterogeneously in proportion to the computing power of workstations is shown to have better performance than when a parallel program is partitioned into parallel processes of the same size. When the owner returns to the workstation which is executing a parallel process, the policy which just lowers the priority of the parallel process shows better performance than the one which migrates the parallel process to a new idle workstation. Among the policies which use heterogeneous partitioning and process priority lowering, the adaptive policy performed best across the wide range of inter-arrival time of parallel programs but when the load imbalance among parallel processes becomes very high, the modified adaptive policy performed better.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
• /
• v.17 no.2 s.105
• /
• pp.89-94
• /
• 2006

A compact microstrip band-selective filter for ultra-wideband(UWB) radio system is proposed. The filter combines the traditional short-circuited stub highpass filter and coupled resonator band-stop filter on both sides of the mitered 50-ohm microstrip line. To realize the pseudo-highpass filtering characteristic over UWB frequency band(3.1 GHz to 10.6 GHz), a distributed highpass filter scheme is adopted. Three coupled resonators are utilized to obtain the band stop function at the desired frequency band. By meandering the coupled resonators, there is $29\;\%$ size reduction in footprint compared to the traditional band-stop filter using L-shaped resonators. The measured results show that the filter has a wide passband of $146.7\;\%$(2.1 GHz to 10.15 GHz) with low insertion loss and the stop band of $10.04\;\%$(5.2 GHz to 5.75 GHz) for 3-dB bandwidth. The measured group delay is less than 0.7 ns within the passband except the rejection band.

• Journal of The Korean Society of Grassland and Forage Science
• /
• v.26 no.1
• /
• pp.1-8
• /
• 2006

To develop a new variety of orchardgrass with improved digestibility, caffeic acid O-methyltransferase (Dgcomt), which is a methylation enzyme involved in the early stages of lignin biosynthesis, was isolated and characterized. Dgcomt was expressed not only in leaves but also in stems and roots. The expression levels of transcripts were high in stems and roots which are the most lignified tissues, and only moderate levels of transcripts were expressed in leaves. To develop transgenic orchardgrass plants by down-regulating the Dgcomt gene, an RNAi suppression vector with partial Dgcomt DNA fragment was constructed and transferred into the genome of orchardgrass via Agrobacterium-mediated gene transfer method. PCR and Southern blot analyses with genomic DNAs from putative transgenic plants revealed that the T-DNA region containing RNAi construct was successfully integrated into the genome of orchardgrass. Northern blot analysis revealed that the majority of the down-regulated transgenic lines showed significant reduction in Dgcomt gene expression. These RNAi transgenic orchardgrass will be useful for molecular breeding of new variety with improved digestibility by down-regulating lignin biosynthetic enzyme.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2005.05b
• /
• pp.1068-1072
• /
• 2005

조석이란, 해면의 완만한 주기적 승강을 말하며, 보통 그 승강은 1일 약 2회이나, 곳에 따라서는 1일 1회의 곳도 있다. 조석에 있어서는 이 밖에 수일의 주기를 갖는 약간 불규칙한 승강, 반년, 또는 1년을 주기로 하는 다소 규칙적인 승강까지 포함하여 취급한다. 그러나, 각 항만마다 갖는 특정적인 주기인 수분내지 수십분의 주기의 승강은 조석으로 취급하지 않는다. 조석은 해양의 제현상 중에서 예측가능성이 가장 큰 현장으로 이는 조석이 천체의 운행과 연관되기 때문이다. 조석이란 지구로부터 일정한 거리에서 각 고유의 속도를 가지는 적도상을 운행하는 무수의 가상천체에 기인하는 규칙적인 개개의 조석을 합성한 것이며 이 개개의 조석을 분조(Constituent)라 한다. 여기에서 사용되는 신경망 모형은 입력과 출력으로 구성되는 블랙박스 모형으로서 하나의 시스템을 병렬적으로 비선형적으로 구축할 수 있다는 장점 때문에 과거 하천유역의 강우-유출과정에서의 경우 유출현상을 해석하고 유출과정을 모형화 하기 위해 사용하였다. 본 연구에서는 기존의 조위 예측방법인 조화분석법이 아닌 인공신경망을 이용하여 조위예측을 실시하였다. 학습이라는 최적화 과정을 통해 구조와 기능이 복잡한 자연현상을 그대로 받아들여 축적시킴으로써 이를 지식으로 현상에 대한 재현능력이 뛰어나고, 또한 신경회로망의 연상기억능력에 적용하여 수학적으로 표현이 불가능한 불확실한 조위곡선에 적용하기에 유리한 장점을 가지고 있다. 본 연구의 목적은 과거 조위이론을 통해 이루었던 조위예측을 우리가 알기 쉬운 여러 기후인자(해면기압, 풍향, 풍속, 음력 등)에 따른 조위곡선을 예측하기 위해 신경망 모형을 이용하여 여수지역의 조위에 적용하여 비교 분석하고자 한다. May가 제안한 공식을 더 확장하여 적용할 수 있는 실험 공식으로 개선하였으며 다양한 조건에 대한 실험을 수행하여 보다 정밀한 공식으로 개선할 수 있었다.$10,924m^3/s$ 및 $10,075m^3/s$로서 실험 I의 $2,757m^3/s$에 비해 통수능이 많이 개선되었음을 알 수 있다.함을 알 수 있다. 상수관로 설계 기준에서는 관로내 수압을 $1.5\~4.0kg/cm^2$으로 나타내고 있는데 $6kg/cm^2$보다 과수압을 나타내는 경우가 $100\%$로 밸브를 개방하였을 때보다 $60\%,\;80\%$ 개방하였을 때가 더 빈번히 발생하고 있으므로 대상지역의 밸브 개폐는 $100\%$ 개방하는 것이 선계기준에 적합한 것으로 나타났다. 밸브 개폐에 따른 수압 변화를 모의한 결과 밸브 개폐도를 적절히 유지하여 필요수량의 확보 및 누수방지대책에 활용할 수 있을 것으로 판단된다.8R(mm)(r^2=0.84)$로 지수적으로 증가하는 경향을 나타내었다. 유거수량은 토성별로 양토를 1.0으로 기준할 때 사양토가 0.86으로 가장 작았고, 식양토 1.09, 식토 1.15로 평가되어 침투수에 비해 토성별 차이가 크게 나타났다. 이는 토성이 세립질일 수록 유거수의 저항이 작기 때문으로 생각된다. 경사에 따라서는 경사도가 증가할수록 증가하였으며 $10\% 경사일 때를 기준으로 $Ro(mm)=Ro_{10}{\times}0.797{\times}e^{-0.021s(\%)}$로 나타났다.천성 승모판 폐쇄 부전등을 초래하는 심각한 선

• Investigative Magnetic Resonance Imaging
• /
• v.15 no.1
• /
• pp.48-56
• /
• 2011

Purpose : The aim of this study is to measure the typical MR variables such as $T_1$- and $T_2$-relaxation times according to morphological characteristics of gold nanopartides as a preliminary study to perform theragnosis using local heating by gold nanopartides. Materials and Methods : Two types of gold nanoparticles were used. Spheres were synthesized by various methods and stirring speed. Rods were synthesized by adding various concentrations of sphere nanopartides. Gold nanopartides were mixed with 2% agarose gel at 1:1 ratio and then signals were acquired using a 1.5T MRI. For the measurements of $T_1$-and $T_2$-relaxation times, TR and TE were varied, respectively. The results were acquired through $T_1$ and $T_2$ curves based on the intensities of MR image using self-developed software. And Statistical analysis was performed. Results : $T_1$ times were measured 1.86 sec and 2.08 sec for sphere and rod, respectively. On the other hands, $T_2$ times were measured 57 ms and 35.45 ms for sphere and rod. Conclusion : The changes of the MR variables according to the morphological characteristics of the gold nanopartides were confirmed. Optimal MR imaging conditions can be obtained by choosing proper TR and TE according to the type of nanoparticles.

• Proceedings of the Korean Society of Dyers and Finishers Conference
• /
• 2011.03a
• /
• pp.29-29
• /
• 2011

아라미드 섬유는 열에 강한 튼튼한 방향족 폴리아마이드 섬유이다. 아마이드는 "85%이상의 아미드(CO-NH)기가 두 개의 방향족 고리에 직접 연결된 합성 폴리아미드로부터 제조된 섬유"로 정의된다. 아라미드 섬유는 크게 파라계와 메타계로 대별되는데 본 연구에서 사용한 파라계 아라미드는 인장강도, 강인성, 내열성이 뛰어나며 고강력 고탄성률을 지니고 있다. 일반적인 유기 섬유와는 다른 우수한 성질을 바탕으로 부직포, UD laminatig, staple 등의 형태로 크게 섬유보강 고무 복합재료 등의 각종 복합재료, 로프, 케이블, 방탄방호용과 같은 산업자재의 용도로 자동차, 우주항공, 정보통신, 국방, 등 다양한 관련 산업분야에서 사용이 확대되고 있는 고부가 소재이며 가격대비 성능비가 우수하기 때문에 세계적으로 산업용 섬유 및 초고성능 섬유시장에서 비중이 증가될 것으로 예상되고 있다. 본 연구에서는 Para-Aramid 필라멘트를 이용하여 ATY를 생산할 때 제조공정조건에 따른 ATY 물성을 알아보고 고강도를 요구하는 방화복, 고무 보강용 섬유 등의 소재에 맞는 ATY 사가공 최적공정조건을 도출하여 체계화된 data-base를 구축하여 생산성 향상 및 품질개선과 함께 산업자재용 직물개발에 응용하고자 한다. 아라미드를 ATY로 제조할 경우, 표면에 생기는 loop로 인하여 타소재와 접착시, 접착제 담지 성능이 향상되어 접착력이 상승되는 반면, 아라미드 ATY가 기존의 아라미드의 물성보다 저하되는 약점을 가지고 있으므로 이를 보완하기 위해 본 연구에서는 ATY 제조공정에서 중요 공정인자인 사속, heater 온도, over feed ratio를 변화시켜 시료를 제조하여 이들의 물성을 분석하여 최적의 물성을 갖는 ATY 사가공 공정을 도출함으로써 물성이 저하되는 문제를 보완 가능할 것으로 기대된다. 물성분석은 강신도, 초기탄성률을 각각 측정하여 인장특성을 확인하였으며, 습열수축률과 건열수축률을 측정하여 시료의 열수축률에 대해 측정을 하였다. 표면의 루프 발현 정도를 보기 위하여 Crimp Rigidity(CR%), 형태 불안정성(instability)등을 측정하였으며, 영상 현미경 시스템을 사용하여 ${\times}40$ 배율로 표면특성을 측정하였다.