• Journal of the Korea Concrete Institute
• /
• v.28 no.6
• /
• pp.665-672
• /
• 2016

This study is conducted to investigate the effect of phase change materials (PCM) on hydration heat and strength characteristics of cement mortar. Two types of Barium and Strontium-based PCMs were used in this study and the addition ratio of each PCM to the cement mortar ranged from 1% to 5% by cement weight. Flow test, semi-adiabatic temperature rise test, compressive strength and flexural strength test were carried out to examine the PCM effect on heat and mechanical properties of cement mortar. Test results indicated that PCMs used in this study were effective to control hydration heat of cement mortar, and Barium-based PCM slightly reduce flow value. The compressive and flexural strength of cement mortar with PCM decreased with increasing the adding mount of PCM. The prediction model for compressive strength of cement mortar with different addition levels of PCMs are suggested in this study.

• Journal of the Korean Ceramic Society
• /
• v.38 no.8
• /
• pp.732-739
• /
• 2001

산업부산자원으로부터 유입되는 중금속이 시멘트 수화반응에 미치는 영향에 대하여 연구하였다. 출발물질은 순수시약을 사용하여 $C_3$S와 $C_2$S 조성으로 배합하고 여기에 Zn, Cu, Cr의 중금속 산화물을 1000ppm, 2000ppm, 3000ppm 첨가하여 150$0^{\circ}C$에서 1시간 소결하여 중금속의 고용분배, 결정구조, 용출상태 그리고 수화열을 관찰하였다. 중금속중 Zn는 $C_3$S와 간극질에 집중 고용되고 Cu는 간극물질에 집중 고용되며 Cr은 $C_3$S와 $C_2$S에 집중 고용되었다. 광학현미경 및 XRD 관찰결과 중금속 함량별로 $C_3$S와 $C_2$S의 결정상에는 큰 영향이 없는 것으로 나타났다. 그리고 7일간 수화시 Zn는 40~50%, Cu와 Cr은 전량 용출되었다. Conduction calorimeter 분석결과 중금속 함량별 변화에도 $C_3$S와 $C_2$S 수화열에는 차이가 없었다.

• Cement
• /
• s.108
• /
• pp.57-60
• /
• 1987

이 논문에서는 통상의 포졸란 대신에 제올라이트 물질 즉, 화산 응회암을 적절히 분쇄한 후 혼합해서 만든 시멘트의 특성 변화에 대해 논하였다. 이러한 치환이 알칼리-골재 팽창 반응을 최소화시키고 장기강도를 향상시키는 장점이 있다는 사실도 밝혀냈다. 특히 제올라이트를 미리 열처리해서 첨가했을 때 이러한 팽창감소 효과가 현저하다는 것도 발견하였다. 강도증진 효과는 포졸란 유리상의 활성도에 비해 제올라이트 광물의 활성도가 높기 때문으로 해석되며 팽창의 감소는 비정질 수화 규산염이 먼저 알칼리와 반응을 하는 성질이 있기 때문으로 판단된다.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.33 no.4
• /
• pp.1463-1469
• /
• 2013

Portland cement used as binding material in combination of ferrous iron for reductive dechlorination of chlorinated organics is already widely studied topic by several researchers. However there is no clear evidence about the component solely responsible in cement for trichloroethylene (TCE) dechlorination. Many researchers suspect that the ettringite, monosulfate phases associated with hydration of cement are responsible active agents for TCE dechlorination. This study deals with synthesizing different pure crystalline minerals like ettringite and monosulfate phases of cement hydration and check individual phase's TCE dechlorinating capacity in combination with ferrous iron. The results indicated that the synthesized minerals showed no reduction capacity for TCE. The findings in the present study is significant as it shows that ettringite and monosulfate phases which were suspected minerals by previous researchers for TCE dechlorination are not reactive. Hence it is suspected that some other mineral or mineral form in cement phase could be responsible for TCE degradation.

• Journal of the Korea Institute of Building Construction
• /
• v.14 no.4
• /
• pp.322-328
• /
• 2014

In this study, revelation performance of concrete at early age according to types of cement, water reducing ratio of high performance superplasticizer and mixing of accelerator for early hydration was examined aiming for reduction of construction period of framework through securing strength at early age of concrete. It was observed that strength at early age, 5MPa in 12hours, 14MPa in 18hours, is secured by early strength improvement type cement and using promotion admixture for early hydration which are Sodium persulfate, Potassium hydroxide. Therefore cost reduction is expected to be possible in construction site by reducing construction period of frame work.

• Journal of the Korean Ceramic Society
• /
• v.34 no.2
• /
• pp.163-170
• /
• 1997

The retarding effects of MgSiF6.6H2O on the hydration of portland cement were studied. The setting time, flow value and compressive strength of mortar were measured and the mechanism of retardation was also studied by ion concentration in solution, SEM, BET, and X-ray diffraction. The results are as follows ; 1. Setting time was delayed by the addition of MgSiF6.6H2O. 2. The flow value of mortar decreases depending upon the amount of MgSiF6.6H2O. 3. The compressive strength was almost same or some increase on 28 days hydration. 4. The main retardation mechanism of MgSiF6 on the hydration of portland cement may be explained by the following hypothesis. MgSiF6 depressing the Ca++ and K+ ion concentration of cement paste solution be-cause of the recrystalization of K2SiF6 and CaF2 phase. The new products of K2SiF6 and CaF2 deposit on the surface of unhydrated cement powder and harzard the mass transfer through these layer. The low con-centration of Ca++, K+ ion in solution was decreasing the hydration rate of portland cement.

• Journal of the Korean GEO-environmental Society
• /
• v.13 no.2
• /
• pp.59-65
• /
• 2012

Solidification/Stabilization(S/S) is one of the remediation technologies that have been applied for treating inorganic hazardous wastes. This study investigated the reduction of arsenic concentration of arsenic-contaminated soil using by S/S. The binder plays a role in controlling the mobility and solubility of the contaminants in S/S process, so it is important to determine the optimum binder content. Therefore, this study evaluated the effectiveness of S/S using four different binders(cement, zero valent iron, and monosulfate and ettringite(cement-based synthesized materials) at the binder content ranged between 5%(wt.) and 20%(wt.). The leachability of arsenic in 1 N HCl was different depending on the types of binders: cement(71.41%) > monosulfate(47.45%) > ettringite(46.36%) > ZVI(33.08%) at the binder content of 20%. Additionally, three kinds of a mixture binder were prepared using cement and additives(monosulfate, ettringite, calcium sulfoaluminate(CSA)) and tested for arsenic reduction. The highest arsenic removal capacity was found at the mass ratio of cement to the additive, 4:1 in all experiments using a mixture binder, regardless of the additives types. A mixture binder(cement and additives) resulted in higher arsenic removal relative to the arsenic removal when cement was used alone.

• Journal of the Korean Ceramic Society
• /
• v.38 no.2
• /
• pp.183-192
• /
• 2001

산업부산물을 이용하여 3CaO.3Al$_2$O$_3$.CaSO$_4$(C$_4$A$_3$S) 클링커를 합성하였다. 이때, 원료 물질은 산업부산물로 플라이 애쉬, 고로 수쇄 및 괴재슬래그를 $Al_2$O$_3$원으로 그리고 부산석고를 SO$_3$원으로 이용하였으며, CaO원으로 천연석회석을 사용하였다. 제조된 $C_4$A$_3$S 클링커를 CaSO$_4$, CaO를 배합하여 CSA계 팽창재를 제조하였으며, 일반 포틀랜드 시멘트(OPC)에 10 wt.% 첨가하여 수화 및 물성 특성을 조사하였다. 주요 수화생성상은 에트링자이트 및 수산화칼슘이었다. 수화시 에트링자이트의 생성으로 인해 팽창 및 경화체가 치밀화되어 건조수축이 감소되었고, 강도(압출, 인장, 휨)가 향상되었다.

• Applied Chemistry for Engineering
• /
• v.16 no.2
• /
• pp.180-186
• /
• 2005

This paper discusses the development of mixtures for silica fume as a stabilization/solidification agent and a binder for industrial wastewater residue containing organic and heavy metal contaminants. The UCS (unconfined compressive strength) gradually increased to 66.7% as the silica fume content increased to 15%. The leaching of TOC (total organic carbon) and chromium decreased as more OPC (Ordinary Portland Cement) was substituted with the silica fume. When a mixture had 5% silica fume, it retained about 85% TOC, and chromium leached out 0.76 mg-Cr/g-Cr in acidic solution. Also, microstructural studies of the solidified analysis showed that the silica fume caused an inhibition to the ettringite formation which did not contrilbute to setting but coated the cement particles and retarded the setting reactions. The results indicated that the incorporation of silica fume into the cement matrix minimized the detrimental effects of organic materials on the cement hydration reaction and the contaminant leachability.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.11 no.2
• /
• pp.153-160
• /
• 2023

In this study, nano-sized C-S-H crystals were synthesized using the liquid phase reaction method and their properties were investigated. The synthesized C-S-H crystals were added to the cement composite in suspension form to determine their effect on the hydration properties of the cement. The amount of chemical admixture was varied to obtain nano-sized C-S-H crystals with optimal agglomerated morphology, and SEM photographs were analyzed. A cleaning process was added to remove harmful substances other than the synthesiz ed C-S-H crystals. It was found that the concentration of harmful substances was reduced in the case of C-S-H crystals subjected to the cleaning process. The synthesized C-S-H suspensions were prepared with and without the cleaning process, and cement composites were prepared with the cement weight content as the main variable. The effect of C-S-H crystals on the initial hydration properties of the cement was confirmed by microhydration heat analysis. In addition, mortar specimens were prepared to measure the compressive strength over time. The test results showed that the nano-sized C-S-H crystals act as nucleation sites in the cement paste to promote the early hydration of the cement and increase the early compressive strength.