• Analytical Science and Technology
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• v.17 no.6
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• pp.496-513
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• 2004

This study was carried out to evaluate the performance of sampling and analytical methodology used for the measurement of toxic volatile organic compounds (VOCs) in the ambient air. VOCs were determined by the adsorbent tube sampling and automatic thermal desorption coupled with GC/MSD analysis. Target analytes were 33 compounds including major aromatic compounds such as BTEX, and halogenated compounds. The methodology was investigated with a wide range of different adsorbents which are commercially available and have been frequently adopted for the VOC measurement. A total of 10 adsorbents were tested in this study: 6 carbon-based adsorbents such as Carbotrap, Carbopack B, Carbosieve S-III, Carboxen 1000, Carbotrap C, Activated Charcoal; and 4 polymer-based adsorbents including Tenax, Porapak Q, Chromosorb 102, and Chromosorb 106. The sampling performance was evaluated with respect to the sampling capacity of VOCs with single-adsorbent and multiple-adsorbents methods for standard samples and field samples. As a result, the best adsorbents for single-adsorbent method in the sampling of toxic organic compounds (including benzene, toluene, xylenes etc.) appeared to be Carbotrap, Carbopack B and Tenax TA. On the other hand, Chromosorb 102, Chromosorb 106 and Porapak Q were found to be unsuitable adsorbents for VOC measurement based on thermal desorption method. Multi-adsorbent packings were evaluated with 4 carbon-based adsorbents, which classified by 3 combination sets of double adsorbents and 2 combination sets of triple adsorbents. The results indicated that the most suitable combination for toixc VOC measurements is Carbotrap C with Carbotrap. Multi-sorbents tubes packed with a strong adsorbent such as Carbosieve S-III or Carboxen 1000 were found to be relatively unsuitable for several compounds, not only owing to the effect of migration of adsorbed compounds from weaker adsorbent to stronger adsorbent, but to hydrophobic nature of the adsorbents. Therefore, it should be addressed that selection of a proper adsorbent (or combination of multi sorbents) is extremely important to obtain reliable data for the concentrations of toxic VOCs in indoor and outdoor environments.

• International Journal of Highway Engineering
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• v.6 no.3 s.21
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• pp.27-35
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• 2004

There are two methods in estimating the remaining life of in-service airfield concrete pavement. They are a method simply using the past accumulated traffic and a method using the theoretical mechanistic analysis. Since the former method is somewhat far from the actual condition, the latter method is widely used by most engineers and researchers. The most essential component of the latter method is the fatigue model of the concrete slab. A fatigue model for airfield concrete pavement is developed in this study by a series of fatigue tests using 30 concrete cylinder specimens obtained from a 10 year old in-service airfield concrete slab. Strengths for the stress ratio calculation were obtained from the split tensile test of the cores sliced. Fatigue test mode was repeated split tensile test. The R2 of developed fatigue model was 0.5. Specimens taken from another airport had been tested for validation of the model. The results showed a good fit to the model. It was also found that the fatigue life predicted from the model was a tittle greater when the stress ratio is greater than 80 percent than other fatigue models developed earlier in America.

• Journal of the Korean GEO-environmental Society
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• v.15 no.5
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• pp.57-65
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• 2014

For economic and technical reasons, it is difficult to obtain high quality undisturbed cohesionless samples, hence most researchers rely on preparing remolded and reconstituted representative samples of sandy soils. In this study, moist tamping, air pluviation, and dry deposition methods were applied to make remolded samples at similar relative densities. A series of isotropically consolidated drained tests were conducted with accompanied by measured elastic wave velocities in order to evaluate a difference between sample preparation methods and relative densities. For the elastic wave velocity measurements, piezoelectric elements were installed on the top and bottom cap of the triaxial device. The results showed that soil behavior relies on sample preparation methods, and that the trend of shear wave velocity was the same with volumetric strain behavior.

• Korean Journal of Agricultural and Forest Meteorology
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• v.12 no.4
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• pp.277-288
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• 2010

The multi-level $H_2O/CO_2$ profile system has been widely used to quantify the storage and advection effects on energy and mass fluxes measured by eddy covariance systems. In this study, we expanded the utility of the profile system by accommodating air sampling devices for isotope analyses of water vapor and $CO_2$. A pre-evacuated 2L glass flask was connected to the discharge of an Infrared Gas Analyzer (IRGA) of the profile system so that airs with known concentration of $H_2O$ and $CO_2$ can be sampled. To test the performance of this sampling system, we sampled airs from 8 levels (from 0.1 to 40 m) at the KoFlux tower of Gwangneung deciduous forest, Korea. Air samples in the 2L flask were separated into its component gases and pure $H_2O$ and $CO_2$ were extracted by using a vacuum extraction line. This novel technique successfully produced vertical profiles of ${\delta}D$ of $H_2O$ and ${\delta}^{13}C$ of $CO_2$ in a mature forest, and estimated ${\delta}D$ of evapotranspiration (${\delta}D_{ET}$) and ${\delta}^{13}C$ of $CO_2$ from ecosystem respiration (${\delta}^{13}C_{resp}$) by using Keeling plots. While technical improvement is still required in various aspects, our sampling system has two major advantages over other proposed techniques. First, it is cost effective since our system uses the existing structure of the profile system. Second, both $CO_2$ and $H_2O$ can be sampled simultaneously so that net ecosystem exchange of $H_2O$ and $CO_2$ can be partitioned at the same temporal resolution, which will improve our understanding of the coupling between water and carbon cycles in terrestrial ecosystems.

• Analytical Science and Technology
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• v.26 no.3
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• pp.165-173
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• 2013

To establishment of PT Program for Indoor air quality field that manufacture of confidential development PTMs (proficiency testing materials) and examined of proficiency testing evaluation included sampling process whether or not that is valid. Confirmation of homogeneity and stability of PTMs prepared. PTMs were confirmed to be homogeneous enough to be used as proficiency testing materials since withinbottle homogeneities of the RMs were lower than 0.3 times of targeted standard deviation of proficiency testing. The result of this study showed that the Robust RSD of proficiency testing for VOCs (volatile organic compounds) appeared 23~43% in concentration of 50~320 ${\mu}g/m^3$ for Method A(Distribution by adsorption in Tenax-tube of VOCs), but less 13~42% in concentration of 200~1200 ${\mu}g/m^3$, 16~31% in concentration of 100~450 ${\mu}g/m^3$ for Method B (distribution by VOCs of gas phase in 10L Tedalr bag), C (directly sampling of cylinder with high pressure) respectively. The result of this study showed that method C with sampling is most adequate to the proficiency testing for VOCs in indoor air.

• Proceedings of the Korean Society for Applied Microbiology Conference
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• 1978.10a
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• pp.205.2-205
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• 1978

우리나라 전국명지에서 약 1400여점의 토양시료를 채취하여 이 토양 시료에서 방사선균 1635균주를순수분리 배양하고, 명 균주를 배양하여 생산되는 항생물질 중 paper disk method에 의해 벼문고 병균 Pellicularia sasakii에 대한 항균력을 나타내는 균주를 선발하고, 이차선발로서 Dendroid test method와 최종적 선발방법으로 벼를 대상으로 문고병 발생에 대한 green house test에 의하여 우수한 균주를 취득하였다.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2006.10a
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• pp.129-130
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• 2006

• Economic and Environmental Geology
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• v.37 no.2
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• pp.235-244
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• 2004

The shear strength of deep-sea core sediments from the nofheast equatorial Pacific was measured in various conditions to ensure precision of results. The comparison items were 1) two different measuring systems (hand-held vane and motorized vane), 2) in different places of on-board immediately after collecting the core samples and on-land laboratories after storing these samples for three months in a cold room, 3) two different core samples from a multiple corer within a sampling station, and 4) four different measuring points (holes) from a core sample. In this experiment, the values of shear strength in deep-sea sediments show significant change with depth which increase toward the bottom of core. Also, the results of two cores recovered at the same station indicate that vertical variation of shear strength is mainly caused by the change of physical properties. They strongly support the fact that the difference of vue syrtem and/or experimental conditions are not major factor in the variation of geotechnical properties.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.11
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• pp.1123-1131
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• 2008

In this study, measurement uncertainty of instrumental neutron activation analysis was evaluated for ambient As concentration in PM2.5. Expanded uncertainties of the measurements were calculated by applying both ISO-GUM approximation and Monte Carlo Simulation(MCS). The estimate of As concentration on a specific day by the Monte Carlo Simulation differed from that of ISO-GUM approximation by less than 4%. Relative expanded uncertainties of As concentrations from a total number of 60 PM2.5 samples were also estimated to be more or less than 10% with 95% confidence level using the Monte Carlo Simulation. Sensitivity test of the measurement uncertainties showed that $\gamma$-ray counting error(62.3%), efficiency(18.5%), air volume(12.3%), neutron flux(2.3%), and absolute gamma-intensity(1.8%) are major factors of uncertainty variations.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.13 no.1
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• pp.83-88
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• 2008

Using micromill, discrete carbonate powders from the otolith of Argyrosomus argentatus were sampled along the growth band, and high-resolution stable isotope profiles were obtained. The ${\delta}^{18}O$ and ${\delta}^{13}C$ values are increasing gradually from the core to the margin. However, such increases do not seem to be attributed to the environmental property changes during the growth, but to the dominant effect of metabolic carbons during the early growth, and then, the isotopic composition seems to be equilibrium to the environmental condition. This paper allows the diverse applicability of high-resolution isotope research to the fish otoliths in the future.