• Title/Summary/Keyword: 시간경화

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A Study of the Hemodynamic Hypotheses for the Progression of Atherosclerosis

  • Lee, Byeong-Gwon;No, Hyeong-Un;Seo, Sang-Ho;Gwon, Hyeok-Mun
    • 순환기질환의공학회:학술대회논문집
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    • 2004.11a
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    • pp.11-12
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    • 2004
  • 본 연구에서는 동맥경화증의 발생에 관한 가설들을 혈류역학적 관점에서 비교/검토하였다. 혈류의 와류 현상, 분리현상 등도 역시 저전단응력 위치에서 발생하게 되며 동맥경화의 발생이 되기 시작하며 동맥내 형태학적 변화로 인해 이러한 현상이 좀더 복잡한 유동을 거치게 된다. 이로 인해 동맥내의 형태적 재형성이 일어나게 되는데 유동의 변화가 역할을 하는 것으로 생각된다. 생물학적으로 동맥경화는 질병의 성격이 만성 염증성 질환으로 알려져 있는데 이러한 생물학적 변성이 발생하는데 형태적 특성에 따른 혈류역학적 변화가 그 기전에 중요한 것임을 확인되었다. 본 연구자 등은 동맥경화가 발생하기 시작하는 곳은 혈관의 만곡부, 분지부 등에서 발생하는 것을 임상적 database를 통해 확인하였고 이 위치에서 영상을 simulation model을 동생 분석하여 전단응력의 영향과 시간에 따른 역동적 변화가 큰 것을 확인하였다.

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Study of Cure Properties in Photopolymer for Stereolithography using Various Laser Bean Size (레이저빔 직경변화에 대한 광경화성 수지의 경화특성 고찰)

  • 이은덕;김준안;백인환
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2001.04a
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    • pp.1089-1092
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    • 2001
  • In the stereolithography process, build parameters are laser power, scan velocity, scan width, bean diameter, layer thickness and so on. These values are determined according to product accuracy and build time. Build time can be reduced by improving of scan velocity, laser power, layer thickness, hatching space and so on. But variation of these parameters influence part accuracy, surface roughness, strength. This paper observed cure properties in various beam diameter. In order to examine these, relationships of scan velocity and cure depth, scan velocity and cure width according to various beam diameter in one scan line are measured. And cure thickness is measured according to beam diameter and scan velocity in scan surface of one layer. For reduction of build time, beam diameter and scan velocity is proposed in stereolithography process.

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An Experimental Study on Spontaneous Combustion Risk of M.E.K (M.E.K(경화제)의 자연발화 위험성에 관한 실험적 연구)

  • Kim, Jung-Hyun;Yoo, Yong-Ho;Kweon, Oh-Sang;Yoo, Myong-Youl
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2011.11a
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    • pp.470-473
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    • 2011
  • 본 연구에서는 산업현장에서 에폭시 강화촉진제, 도로용 첨가제 등으로 많이 사용되고 있는 경화제(M.E.K)의 혼합비에 따른 자연발화 위험성을 알아보고 산업 현장의 화재 예방을 위한 기초자료로 제공하고자 하였다. M.E.K와 에포비아 수지를 각기 다른 비율로 혼합한 상태에서 시간경과에 따른 시료의 온도변화 와 유증기 발생 및 자연발화 여부를 관찰한 결과 합성수지와 경화제의 혼합시 경화제가 5% 이상으로 혼합될 경우 혼합 수지의 내부온도가 약 $40^{\circ}C$ 이상으로 상승하면서 발포 현상과 함께 다량의 유증기가 발생하였고, 유증기가 발생된 모든 조건에 대하여 자연발화 여부는 확인할 수 없었다.

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A Study on the Development of Poly-Urea for Porcelain Restoration (폴리우레아 도자기 복원 재료의 적용)

  • Han, Won-Sik;Wi, Koang-Chul;Oh, Seung-Jun;Lee, Young-Hoon
    • Journal of Conservation Science
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    • v.34 no.1
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    • pp.23-29
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    • 2018
  • This study synthesized poly-urea and used it as a filler material for the restoration of porcelain. The synthesized poly-urea was manufactured as a resin and hardener mix that does not undergo contraction during curing, and is unfading. Given an adhesion strength of $180kg/cm^2$ and shearing strength of $200kg/cm^2$, the synthesized poly-urea exhibited the same efficacy as the epoxy putty currently sold in the market. Moreover, it also overcame the drawback of foaming encountered by urethane restoratives, which are a structurally similar type. The hardening time and pot life could also be controlled using additives. The poly-urea used for the restoration of modern artifacts presented a pot life of approximately one hour and took 12 h for complete hardening ($T_{90}$). When a $2{\times}2{\times}2cm$-sized test sample was added to xylene, poly-urea started to separate approximately two hours later and completed perfect pulverization within the solution 24 h later, demonstrating its reversibility. When directly applied to contemporary artifacts, it demonstrated the potential for restoration, as well as convenience and colorfulness.

A Study on the Cure Behavior of Epoxy Molding Compound (Epoxy Molding Compound의 경화거동에 관한 연구)

  • 윤상영;오명숙;박내정
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.837-844
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    • 2000
  • The cure behavior of commercial epoxy molding compounds (EMC) commonly used for IC package was studied at constant cure temperatures as well as at constant heating rates using differential scanning calorimetry (DSC), rheometer, and dielectric analyzer (DEA). The cure kinetics were obtained using autocatalytic reaction model according to the Ryan Dutta method after assuming m+n equal to 2. The prediction of reaction rates by the model equation corresponded well to experimental data at all temperatures except for 10$0^{\circ}C$. The phase transitions such as gelation and vitrification occurred during network formation. At each isothermal cure temperature, $T_{g}$ was measured in accordance with cure time, and the vitrification point was attained when $T_{g}$ was equal to $T_{cure}$. The temperature dependence of gel points and vitrification points showed good agreement with Arrhenius relation. DEA using parallel plate electrode was effective for the monitoring of EMC cure. we knew that if the resin systems are materials of comparable quality, $_{gel}$$T_{g}$ is constant regardless of accelerator concentration in TTT (Time-Temperature-Transformation) diagram.

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Properties of Fresh Polymer Concretes Using Mixed Waste Plastics (복합 재질 폐플라스틱을 재활용한 폴리머콘크리트의 경화 전 성질)

  • Joo, Myung-Ki;Lee, Youn-Su;Kim, Moon-Chan;Kim, Youn-Hwan
    • Journal of the Korea Concrete Institute
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    • v.18 no.1 s.91
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    • pp.117-124
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    • 2006
  • The effects of binder content and recycling mixed waste plastics(PA) content on the workability, work life and hardening shrinkage of fresh polymer concrete using mixed waste plastics are examined. As a result, the workability of the polymer concretes using mixed waste plastics tend to improve with increasing binder content, PA content and filler content. The work life of the polymer concretes using mixed waste plastics is shortened with an increase in the initiator content and curing temperature. The length change of the polymer concretes using mixed waste plastics tend to increased with Increasing binder content and PA content. The result of the present research is expected to make a contribution to the recycling of final mixed waste plastics and the continuing efforts for the development of use of the recycled products are thought to expand the horizon for the recycling of the final mixed waste plastics.

Development of quick molding composite materials and lightweight parts for automotive applications (고속성형 복합소재 및 수송용 경량부품 개발)

  • Kwon, Yong-Won;Jang, Ho-Yun;Kim, Jin-Hong;Min, Byeong-Hwan;Park, Jong-Seung
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.20-20
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    • 2012
  • 최근, 수송기기 분야는 국제 환경규제 강화에 따른 CO2 절감, 연비향상, 경량화를 위한 기술적 수요가 증대되고 있으며, 그린카, 그린선박 등 친환경 수송기기에 대한 연구가 활발히 진행되고 있다. 하지만, 기존의 금속소재가 가지는 경량화의 한계를 극복하기 위해서는 CFRP, GFRP 등 금속대체 복합소재를 적용한 수송용 경량부품 개발에 대한 필요성이 요구되고 있다. 복합소재는 섬유사이에서 응력을 전달하는 기지(Matrix)와 하중을 전달하는 섬유(Fiber)의 종류와 양 및 적층 각도에 따라 수송용 부품에 적합한 기계적 특성을 얻을 수 있고, 높은 비강도와 비강성의 값을 갖게 되어 경량화가 용이한 장점이 있다. 반면, 섬유재의 종류, 성형방법, 경화온도 등에 따라 물리적 특성에 큰 변화가 발생하며, 수지의 경화조건에 따라 성형시간이 많이 소요되는 단점을 가지고 있다. 따라서, 본 연구에서는 자동차, 선박, 항공기, 철도차량 등 각종 수송기기의 경량화를 목적으로 생산성 향상 및 성형시간 절감을 위해 열가소성 수지, 저온속경화 수지를 적용하여, 경화 시간을 단축시키고, 3D-fabric 및 다층구조 직물을 Vacuum Infusion 공법으로 성형하여, 기존의 섬유재 적층시 소요되는 작업 공정을 간소화 할 수 있도록, 고속성형 복합소재를 적용한 수송용 경량부품 개발에 관한 연구를 수행하였다.

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The Effect of Mass Transfer on the Cure Properties of the Urea Resin Moulding Compounds Under the Drying Process (건조 공정 중 요소 수지 성형재료의 경화 특성에 대한 물질전달 효과)

  • Kim, Sang Yeul;Choi, Il Gon;Kim, Byoung Chul
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.681-686
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    • 2002
  • In the industrial field, the theory of drying process is different from the practical application, and it is effective to reduce energy by recirculation of the heat of exhausting gas. But the study of this field may not be performed still. The cure properties of the urea resin moulding compounds was investigated according to drying temperature, drying time, recycle rate of exhausting gas and moulding temperature in the process of drying and moulding. We obtained the following results; water content of material decreases with increasing drying time and drying temperature, and the rate of drying also decreases with increasing recycle rate of exhausting gas. Specially, The cure fluidity of the urea resin moulding compounds decreases, with increasing drying temperature, recycle rate of exhausting gas and moulding temperature. And the correlation equations on water content and cure fluidity of the urea resin moulding material were obtained through a regression analysis of experimental data.

Preparation and Physical Properties of High-Solid Coatings by Acrylic Resins and Hexamethylene Diisocyanate-Biuret (아크릴수지와 헥사메틸렌 디이소시아네이트-뷰렛에 의한 고 고형분 도료의 제조 및 도막물성 연구)

  • 유혁재;정동진;박홍수;김성길;임완빈
    • Polymer(Korea)
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    • v.28 no.3
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    • pp.273-280
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    • 2004
  • Acrylic resins (ethyl methacrylate-2-hydroxypropyl methacrylate-n-butyl acrylate-acrylic acid EHBCs) containing 80% of solid were synthesized. Then, high-solid coatings (ethyl methacrylate-2-hydroxypropyl methacrylate-n-butyl acrylate-acrylic acid/hexamethylene diisocyanate-biuret : EHBCNs) were prepared by curing of the acrylic resin with curing agent hexamethylene diisocyanate-biuret at room temperature. The cure time of prepared coatings EHBCN-4 (EHBC-4 : $T_{g}$ = $0^{\circ}C$) and EHBCN-7 (EHBC-7 : $T_{g}$ = 3$0^{\circ}C$), measured by rigid-body pendulum method, was recorded 6.2 hours and 4.5 hours, respectively. Dynamic viscoelastic experiment revealed the glass transition temperature of EHBCN-4 and EHBCN-7 to be $14^{\circ}C$ and $39^{\circ}C$, respectively. It was found that the adhesion and flexural properties among various properties of coatings were enhanced by the incorporation of caprolactone acrylate monomer into the acrylic resins.

Analysis of Early-age Property of JPCP Slab of Incheon International Airport (인천국제공항 줄눈콘크리트 슬래브의 초기재령 특성분석)

  • Sun, Ren Juan;Jeong, Jin-Hoon;Cheon, Sung-Han;Lim, Jin-Sun
    • 한국방재학회:학술대회논문집
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    • 2007.02a
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    • pp.335-339
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    • 2007
  • A jointed plain concrete pavement(JPCP) slab was tested in Incheon International Airport construction work to study the early-age property of JPCP slab. The temperature and moisture data of the concrete slab had been collected and analyzed. The setting time of the concrete was decided by using the maturity method. The initial setting time is 2 hours 40 minutes after the placement of the slab. The investigation and analysis of the slab began from the initial setting time. The strains of different locations and different depths of the slab show different variation character.

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