• Journal of the Korean Chemical Society
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• v.50 no.1
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• pp.65-78
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• 2006

study identified secondary school chemistry major teachers' perceptions of sublimation related to the drying phenomenon of frozen wash and representation of the phenomenon on phase diagram. The subjects were 53 teachers for the questionnaire developed for this study, and interviews. The two professors who majored physical chemistry and one professor who majored analytical chemistry at teacher's college were interviewed for teacher educators' perceptions of sublimation. The results showed that forty one teachers among fifty three teachers thought that the drying phenomenon was sublimation. The most teachers who thought that the phenomenon was sublimation responded as a reason that solid state changes to gas state. The teachers who thought that the phenomenon was not sublimation responded as a reason that the 1 atm of air pressure was not the condition of sublimation. Seventeen teachers thought that the drying phenomenon of frozen wash could be represented on phase diagram, but thirty four teachers thought that it could not. But most teachers confused the scientific representation of the phenomenon, and felt difficulties to teach the contents to students.

• Korean Journal of Food Science and Technology
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• v.25 no.4
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• pp.313-320
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• 1993

A sublimation model of the freeze drying process, which accounted for the removal of free water, was presented and used to study the operation conditions of freeze driers for carrot juice. It was found that the shortest drying time was obtained when the condenser temperature and chamber pressure were kept at heir lowest values and the plate temperature was controlled independently so that the scorch and melting constraints were both held throughout the drying period. The effect of sample thickness on the drying time was significant. Optimal policies were investigated experimentally in laboratory freeze dryer.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2013.05a
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• pp.171-172
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• 2013

종래의 흑연 위주 연료전지 분리판 개발되어 최근 고분자 전해질 막 연료전지가 높은 전력, 낮은 배기 가스 배출, 낮은 작동 온도로 자동차 산업에서 상당한 주목을 받고 있다. 요구사항은 높은 전기 전도도, 높은 내식성, 낮은 가스 투과성, 낮은 무게, 쉬운 가공, 낮은 제조비용이다. Thin film Cr 장비로 저항가열 furnace, sputter 등이 사용된다. 연료전지 분리판의 고전도도, 내부식성 보호막의 고속 증착을 위한 새로운 증착원으로 스퍼터 - 승화형 소스의 가능성을 유도 결합 플라즈마에 금속 봉을 직류 바이어스 함으로써 시도하였다. 유도 결합 플라즈마를 이용하여 승화증착 시스템을 사용하여 OES(SQ-2000)와 QMS (CPM-300)를 사용하여 $N_2$ flow에 따른 유도 결합 플라즈마를 이용한 스퍼터-승화 증착 시스템을 사용하여도 균일한 공정을 하는 것을 확인 하였다.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.186-186
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• 2013

종래의 흑연 위주 연료전지 분리판 개발되어 최근 고분자 전해질 막 연료전지가 높은 전력, 낮은 배기 가스 배출, 낮은 작동 온도로 자동차 산업에서 상당한 주목을 받고 있다. 요구사항은 높은 전기 전도도, 높은 내식성, 낮은 가스 투과성, 낮은 무게, 쉬운 가공, 낮은 제조비용이다. Thin film Cr 장비로 저항가열 furnace, sputter 등이 사용된다. 연료전지 분리판의 고전도도, 내부식성 보호막의 고속 증착을 위한 새로운 증착원으로 스퍼터 - 승화형 소스의 가능성을 유도 결합 플라즈마에 금속 봉을 직류 바이어스 함으로써 시도하였다. 유도 결합 플라즈마를 이용하여 승화증착 시스템을 사용하여 OES (SQ-2000)와 QMS (CPM-300)를 사용하여 $N_2$ flow에 따른 유도 결합 플라즈마를 이용한 스퍼터-승화증착 시스템을 사용 하여도 균일한 공정을 하는 것을 확인 하였다. 5 mTorr의 Ar 유도 결합 플라즈마를 2.4 MHz, 500 W로 유지하면서 직류 바이어스 전력을 30 W (900 V, 0.02 A) 인가하고, $N_2$의 유량을 0.5, 1.0, 1.5 SCCM로 변화를 주어 특성을 분석하였다. MID (Multiple Ion Detection) mode에서 유도결합 플라즈마를 이용한 스퍼터-승화 증착 장비를 사용하여 CrN thin flim 성장시켰고, deposition rate은 44.8 nm/min으로 얻을 수 있었다. 또한 $N_2$의 유량이 증가할 수록 bias voltage가 증가하는 것을 확인 할 수 있었다. OES time acquisition을 이용한 공정 분석에서는 $N_2$ 유량을 off 하였을 때 Ar, Cr의 중성 intensity peak이 상승하였고, 시간 경과에 따라 sublimation에 의한 영향이 없는 것을 확인 할 수가 있었다. XRD data에서는 질소 유량이 증가함에 따라 $Cr_2N$이 감소하고, CrN이 증가하는 것을 확인할 수가 있었다. 결정배향성과 Morphology는 다결정 재료의 경도에 영향을 주는 인자이다. CrN 결정 구조의 경우는 (200)면이 경도가 제일 높은데 (200)면에서 성장한 것을 확인 할 수 있었다. 잔류가스 분석 결과로는 일정한 Ar의 유량을 흘렸을 때 $N_2$의 변화량이 비례적인 경향이 보이는 것을 확인 할수 있었다. 또한 $N_2$가 흐르면서도 유도 결합 플라즈마를 이용한 스퍼터-승화 증착 시스템을 사용하면 일정한 공정을 하는 것을 확인 할 수 있었다. 질소의 분압이 유량에 따라서 $3.0{\times}10^{-10}$ Torr에서 $1.65{\times}10^{-9} $Torr까지 일정한 비율로 증가한다. 즉, 이 시스템으로 양산장비 설계를 하여도 가능 하다는 것을 말해준다.

• Journal of the Korean Institute of Traditional Landscape Architecture
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• v.40 no.1
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• pp.15-25
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• 2022

This study was conducted to provide useful basic data for restoration and maintenance of the Changdeokgung Palace(昌德宮)'s inner palace area in the future by exploring the background of terraced flower beds installed in the front space of Seunghwaru(承華樓) and grasping the reality before and after terraced flower beds were installed. The main results of this study can be summarized as follows. First, in the early 1900s, the front space of Seunghwaru formed a relatively higher terrain than the Nakseonjae(樂善齋) area. In addition, along the topography of high north and low south, a yard surrounded by Haenggak(行閣) and a rectangular open space connected to the West Haenggak of Nakseonjae were created. In particular, the rectangular open space was a staircase-type slope in which rectangular stone columns were arranged at regular intervals. Second, the terraced flower beds of Seunghwaru originated from the renovation of the new building of Nakseonjae West Hanggak, which was implemented in the late 1920s. This is because in order to secure enough available land for construction and auxiliary space during the renovation of the new building, the terraced flower beds for topographic treatment was created along the cutting area after cutting off the original topography of the front space of Seunghwaru. Third, after the construction of the terraced flower beds, many deformation occurred in the topographic features of the front space of Seunghwaru. The front yard of Seunghwaru was relatively higher than the Nakseonjae area, but most of them were cut off and disappeared as the terraced flower beds were created. The staircase-type also disappeared after the construction of the new building and terraced flower beds. The stylobate and front fence of Seunghwaru were newly built along the alignment of terraced flower beds and the unique style of narrow gate and auxiliary stairs were also relocated to the new fence.

• Analytical Science and Technology
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• v.28 no.3
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• pp.187-195
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• 2015

The heat of sublimation (HOS) is an essential parameter used to resolve environmental problems in the transfer of organic contaminants to the atmosphere and to assess the risk of toxic chemicals. The experimental measurement of the heat of sublimation is time-consuming, expensive, and complicated. In this study, quantitative structural property relationships (QSPR) were used to develop a simple and predictive model for measuring the heat of sublimation of organic compounds. The population-based forward selection method was applied to select an informative subset of descriptors of learning algorithms, such as by using multiple linear regression (MLR) and the support vector machine (SVM) method. Each individual model and consensus model was evaluated by internal validation using the bootstrap method and y-randomization. The predictions of the performance of the external test set were improved by considering their applicability to the domain. Based on the results of the MLR model, we showed that the heat of sublimation was related to dispersion, H-bond, electrostatic forces, and the dipole-dipole interaction between inter-molecules.

• Journal of the Korean Chemical Society
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• v.51 no.6
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• pp.577-584
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• 2007

The purpose of this study is to suggest how to use the phase diagram for water to explain the evaporation and sublimation in the atmospheric condition. In principle, the phase diagram for water represents a one component system so it cannot be applied to the water contact with the air. When the liquid or solid phase of water exists in the air, always water vapor also exists in the air. In this case, we cannot present this state as a single point on the phase diagram because the pressure of the liquid or solid is different from that of the vapor in the air. However, since the saturation vapor pressure of liquid or solid is altered by negligible amount due to the presence of air, the evaporation and sublimation in the atmospheric condition can be explained using the vapor pressure line and sublimation line on the phase diagram.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.70.3-70.3
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• 2010

CBD 방법은 저비용으로 양질의 CdS 박막을 얻을 수 있는 증착 방법으로, 고효율의 CdS/CdTe 태양전지를 얻기에도 적당하다. 투명전도 산화막(Transparent Conducting Oxide - TCO)이 입혀진 유리 기판 위에 CBD 방식으로 형성된 CdS 박막은 추후 CdTe 박막형성을 위해 근접승화법(Close Spaced Sublimation - CSS) 장치에 기판으로 사용된다. 또한 추후 열처리공정을 겪게 되는데, 이때 고온 상태에 높여지기 때문에 CdS 박막의 물성에 변화를 나타나게 된다. 이를 XRD, Raman spectrometer, SEM, EDS, 등의 분석 장치를 이용하여 특성 변화를 분석 하고자 한다.

• Analytical Science and Technology
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• v.27 no.4
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• pp.187-195
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• 2014

It is very important to minimize the damage of latent fingerprints at enhancing the contrast. This study proves the enhancement effects of cyanoacrylate-fumed latent fingerprints using p-dimethylaminobenzealdehyde (DMAB) on semi-porous surfaces and the influence factors. The latent fingerprints in experiment were developed for cyanoacrylate treatment in a vacuum chamber and used after drying at room temperature for 24 hours. For fluorescence staining, the cyanoacrylate-developed marks using DMAB were sublimated during 48 hours under the different conditions of surface area, temperature, atmospheric pressure. First experiment showed how surface area effects on the sublimation rate and fluorescence intensity by DMAB of particle size and container size. In addition, the fluorescence staining using DMAB with solvent-free contact method had the greatest fluorescence intensity after 36 hours and a low fluorescence intensity over a certain size of surface area. Second experiment showed that the evaporation of DMAB solid crystals got a satisfying result in a temperature of $20^{\circ}C$ and reduced time to get the greatest fluorescence intensity. It took a long time to get a optimum level of fluorescence intensity at $30^{\circ}C$ or more and it was less effective in fluorescence intensity. Third experiment on the pressure indicated that the fluorescence intensity of vacuum was weaker than nonvacuum but it was inapplicable to very high variations in pressure.

• Bulletin of Food Technology
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• v.7 no.1
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• pp.63-73
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• 1994