• Journal of the Korea Institute of Building Construction
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• v.14 no.5
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• pp.389-396
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• 2014

The set accelerator used for shotcrete at high pH environment often causes the dusting problem in practice. In this research, a slurry-type set accelerator was developed to avoid this problem and its effectiveness was investigated by applying it to shotcrete mortars. Set time, stiffening, compressive strength, and chloride ion penetration resistance were examined with different amounts of slag, used as partial replacement of cement. According to the experimental results, it was found that the earlier responses such as set time, stiffening, and 1-day compressive strength were probably affected by the amount of ettringite, formulated by the hydration between C12A7 and calcium sulfate polymorphs present in blast furnace slag. Whereas, it is believed that the result of compressive strength after 3 days was attributed to the hydration of tricalcium silicates. As for the results of a chloride ion penetration test, the partial replacement of cement with slag significantly reduced the total charge passed through the shotcrete mortar.

• International Journal of Highway Engineering
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• v.13 no.2
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• pp.159-166
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• 2011

This research was performed to evaluate physical properties of polysulfide epoxy overlay material for bridge deck as part of a review for possibility of domestic application of polymer concrete for bridge deck pavement. In order to evaluate strength characteristics, compressive strength, flexural strength and bond strength were tested, and, for durability characteristics, chloride ion penetration resistance and freeze/thaw resistance were tested along with ultraviolet rays impact evaluation. The tests showed that the results met the criteria suggested by the American Concrete Institute in terms of compressive strength, flexural strength and bond strength. However, in terms of the strengths measured at various test temperatures, it was found that the epoxy material was highly dependent on temperature, and, therefore, this should be considered at the time of domestic application of the epoxy material later. Deflection characteristics was checked through flexural strength test and it was found that bridge deck pavement using the epoxy material was excellent compared to bridge deck pavement using asphalt. Furthermore, the results of chloride ion penetration resistance test and freeze/thaw resistance test were also excellent. In the evaluation of ultraviolet rays impact on epoxy slurry mixture, reduction of strain was noticed with increased strength, but the deflection characteristics after exposure to ultraviolet rays was better than the existing acryl polymer concrete. Therefore, it is concluded from the research that the polysulfide epoxy overlay material has the physical properties that are appropriate to pavement of bridge deck.

• Clean Technology
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• v.27 no.4
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• pp.332-340
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• 2021

With the recent reinforcement of emission standards, it is necessary to make efforts to reduce NOx from air pollutant-emitting workplaces. The NOx reduction method mainly used in industrial facilities is selective catalytic reduction (SCR), and the most commercial SCR catalyst is the ceramic honeycomb catalyst. This study was carried out to reduce the NOx emitted from steel plants by applying De-NOx catalyst coated on metallic monolith. The De-NOx catalyst was synthesized through the optimized coating technique, and the coated catalyst was uniformly and strongly adhered onto the surface of the metallic monolith according to the air jet erosion and bending test. Due to the good thermal conductivity of metallic monolith, the De-NOx catalyst coated on metallic monolith showed good De-NOx efficiency at low temperatures (200 ~ 250 ℃). In addition, the optimal amount of catalyst coating on the metallic monolith surface was confirmed for the design of an economical catalyst. Based on these results, the De-NOx catalyst of commercial grade size was tested in a semi-pilot De-NOx performance facility under a simulated gas similar to the exhaust gas emitted from a steel plant. Even at a low temperature (200 ℃), it showed excellent performance satisfying the emission standard (less than 60 ppm). Therefore, the De-NOx catalyst coated metallic monolith has good physical and chemical properties and showed a good De-NOx efficiency even with the minimum amount of catalyst. Additionally, it was possible to compact and downsize the SCR reactor through the application of a high-density cell. Therefore, we suggest that the proposed De-NOx catalyst coated metallic monolith may be a good alternative De-NOx catalyst for industrial uses such as steel plants, thermal power plants, incineration plants ships, and construction machinery.

• Journal of the Korea Concrete Institute
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• v.21 no.5
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• pp.557-563
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• 2009

This study is on the properties of inorganic porous calcium silicate material made from silica powder through the autoclaving curing, the results of this study should be utilized fundamental data for the development of noise reduction porous solid material using siliceous byproduct generated by various manufacture process. For the manufacture of autoclave curing specimen, various calcareous materials used and siliceous materials used silica powder. In this study, properties in density and compressive strength according to the change of W/B and C/S ratio, microscopy for the shape of pore, SEM and XRD for the examination of hydrate after autoclave curing are carried out respectively. The test results shown that the more slurry density decrease, the more W/B increase at the fresh state, this tendency shown similar to in hardened state. Among the specimens of C/S ratio, the compressive strength of C/S ratio of 0.85 gave the highest the compressive strength. In the results of XRD, tobermorite generated by autoclaving curing was created all of specimens regardless of C/S ratio. To ascertain pore structure, we compared with existing porous calcium silicate product(ALC, organic sound absorbing porous material). The results of microscope observation, pore structure of specimen of this study was similar to that of existing inorganic sound absorbing foam concrete. therefore, we could conformed a possibility of sound absorbing porous solid material on the basis of the results.

• Journal of Korean Tunnelling and Underground Space Association
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• v.20 no.5
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• pp.773-786
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• 2018

In this paper, viscosity features of sealant (bentonite-cement slurry), which is used for umbrella arch method in tunnel, were studied. The sealant must secure optimal strength and capacity for the waterproof and stabilization of borehole as well as to satisfy groutability. In this study, the variation of viscosity was measured with different mixing processes. With an increase of initial mixing period with water and bentonite mixture, the required time for the rapid increase of viscosity of the sealant is shorten. With increase of mixing period, the possibility of swelling of bentonite will increases and this can lead increase of the viscosity of the mixture. In addition, the behaviors of sealant vary with a drastic increase of the viscosity: thixotropy and rheopexy. Furthermore, the bentonite/water mixing period influences on the bleeding features of the sealant. Further study is required to introduce the guideline, which can be applicable in the field in the aspect of required capacity of the sealants and mixing processes of the ingredients.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.6
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• pp.113-123
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• 2012

The technology developed for the decrease of applying loads and self-weight of a structure is to improve conventional Foam Cement Banking Method (FCB) by applying mixed slurry of bottom ash, cement and foams. Since the foam-mixed concrete, which is a major material of the Bottom ash-mixed Light weight concrete Banking method (BLB) developed, contains mineral admixture such as cement, the behavior shows time-dependent deformation and deterioration of durability due to environmental exposure. Thus, this study is subject to figure out the characteristics of long-termed behavior and durability of the developed method by carrying out experiments for schemed parameters, which are considered to be factors affecting mainly on concrete's characteristics from mechanical analysis. As results of tests, it was found that the developed concrete offers higher resistance than conventional foamed concrete in terms of long-termed behaviors associated with drying shrinkage and creep, and durability problems of freeze-thaw and carbonation processes, especially with addition of bottom ash.

• Journal of the Korean Geotechnical Society
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• v.21 no.5
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• pp.215-223
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• 2005

Piezo-ceramics are special materials which transform energy from mechanical to electrical forms and vice versa. Bender elements are composite materials consisting of thin piezo-ceramics and elastic shims, and are widely used as actuators and transducers in the field of electronics, robotics, autos and mechatronics utilizing the effectiveness of energy transformation capability. In geotechnical engineering, commercial bender elements are used in laboratory as source and receiver in the measurements of soil stiffness. The elements were built by using various metal shims sandwiched between piezo-ceramics and coating over the composite in the research. A pair of elements were buried in a concrete block and used as source and receiver to measure the stiffness of the concrete. The test results were verified by comparing with the resonant column testing results. In a preliminary stage of the development of an in-situ seismic testing equipment using bender elements for soft clay materials, shear waves were generated and measured by burying the elements in the barrel of kaolinite and water mixture. The measured shear wave signals were so distinct for the first-arrival pick that applicability of the elements in the field measurements could be very promising.

• Tribology and Lubricants
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• v.39 no.2
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• pp.72-75
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• 2023

Silicon carbide (SiC) is used as a substrate material for power semiconductors; however, SiC chemical mechanical polishing (CMP) requires considerable time owing to its chemical stability and high hardness. Therefore, researchers are attempting to increase the material removal rate (MRR) of SiC CMP using various methods. Mixed-abrasive CMP (MAS CMP) is one method of increasing the material removal efficiency of CMP by mixing two or more particles. The aim of this research is to study the mathematical modeling of the MRR of MAS CMP of SiC with SiO₂ and TiO₂ particles. With a total particle concentration of 32 wt, using 80-nm SiO₂ particles and 25-nm TiO₂ particles maximizes the MRR at 8 wt of the TiO₂ particle concentration. In the case of 5 nm TiO₂ particles, the MRR tends to increase with an increase in TiO₂ concentration. In the case of particle size 10-25 nm TiO₂, as the particle concentration increases, the MRR increases to a certain level and then decreases again. TiO₂ particles of 25 nm or more continuously decreased MRR as the particle concentration increased. In the model proposed in this study, the MRR of MAS CMP of SiC increases linearly with changes in pressure and relative speed, which shows the same result as the Preston's equation. These results can contribute to the future design of MAS; however, the model needs to be verified and improved in future experiments.

• Korean Journal of Materials Research
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• v.8 no.12
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• pp.1158-1164
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• 1998

Aluminium sulfate solution was prepared by sulfuric acid treatment from gibbsite. Aluminium sulfate hydrate [$Al_2(SO_4)_3$ · $nH_2O$] was precipitated from aluminium sulfate solution by adding it into ethylalcohol. From XRD analysis as-prepared $Al_2(SO_4)_3$ · $nH_2O$ was confirmed to have mixed-crystalization water(n=18, 16, 12, 6). The average water of crystalization calculated from thermogravimetry(TG) was 14.7. Aluminium sulfate hydrate [$Al_2(SO_4)_3$ · $nH_2O$] was thermally decomposed and converted to $Al_2(SO_4)_3$ at $800^{\circ}C$, $\gamma-Al_2O_3$ at $900-1000^{\circ}C$, and $\alpha-Al_2O_3$ at $1200^{\circ}C$. Ni-doped $\gamma-Al_2O_3$, was synthesized from the slurry of as-prepared $\gamma-Al_2O_3$, with the ratio of [Ni]/[Al]=0.5. The reaction conditions of synthesis were determined as initial pH 9.0 and temperature $80^{\circ}C$ The basicity(pH) of slurry was controlled by using urea and $NH_4OH$ solution. Urea was also used for deposition-precipitation. For determining termination of reaction, the data acquisition was performed by oxidation reduction potential(ORP), conductivity and pH value in the process of reaction. Termination of the reaction was decided by observing the reaction steps and rapid decrease in conductivity. On the other hand, BET(Brunauer, Emmett and Teller) and thermal diffusity of Ni- doped $\gamma-Al_2O_3$, with various content of Ni were measured and compared. Thermal stability of Ni- doped $\gamma-Al_2O_3$ at $1250^{\circ}C$ was confirmed from BET and XRD analysis. The surface state of Ni-doped $\gamma-Al_2O_3$ was investigated by X-ray photoelectron spectroscopy(XPS). The binding energy at $Ni2P_{3/2}$ increased with increasing the formation of $NiAl_2O_4$ phase.

• Journal of the Korean Geotechnical Society
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• v.16 no.4
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• pp.17-30
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• 2000

The objective of this study is to evaluate the lateral earth pressure and the stability of small scale retaining wall with waste foundry sand(WFS) mixtures as a controlled low strength materials (CLSM). Three different types of WFS, like Green WFS, Hurane WFS and Coated WFS, were used in this study, and fly ash of Class F type was adopted. To evaluate the lateral earth pressure and the stability of retaining wall, two different samll scale retaining wall tests, which are called an artificially controlled strain method and a natural strain method, were carried out. In case of an artificially controlled strain method, the coefficient of lateral earth pressure, just after backfilling of WF mixtures, was around 0.8 to 1.0, and most of earth pressure was dissipated within 12 hours. In case of a natural strain method, two steps of stage constructions were employed. The mixtures of Hurane WFS and Coated WFS showed fast decrease of earth pressure due to a relatively good drainage. Judging from the sta bility of retaining wall for overturning and sliding, two steps of stage construction for 2 days were enough to finish the backfill of 6-m height of retaining wall. Also, considering the curling effect of WFS mixtures, the stability of retaining wall increased as curling time increased.