• Title/Summary/Keyword: 슬래그 처리

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The Study of Plasma Torch for Solid Waste Treatment (고상 廢棄物處理를 위한 플라즈마 토치에 관한 硏究)

  • Park, Hyun-Seo
    • Resources Recycling
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    • v.14 no.1
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    • pp.39-46
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    • 2005
  • A solid-state high power torch with inter-electrode insert (IEI) was developed to treat solid waste (for example, incinerated ash), and it's operation characteristics were obtained in the plasma facility test for waste treatment. According to torch test from this study, at the non-transferred mode voltage is increased by gas volume proportionally, and at the transferred mode it is not affected to voltage change. Especially arc voltage is sustained stable at the range of 10% of total Fe in slag. In addition, Electrical conductivity is 0.05~0.25${\Omega}^{-1}cm^{-1}$, torch efficiency is 75~85% and Erosion rate is 2${\times}10^{-6}~6{\times}10^{-6}$ kg/s.

Basic Oxygen Furnace Slag as a Liming Agent for Paddy and Upland Field Soils (전로슬래그 시용의 토양개량 및 작물의 수량증대 효과)

  • 이충일
    • Resources Recycling
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    • v.7 no.1
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    • pp.50-56
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    • 1998
  • Basic oxygen furnace @OF) slag. a by-pradud of thc iron and steelmaking industry produced in largc quantities in Korea, poszs a subslantial disposal challenge. The BOF slag used in this study was if3 CaCO, in total n e u ~ ~ pnowger and application of 7-8 Mgha' was needed to bring soil pH to 6.5 horn pH 5.0-5.5 m silly clay or clay loam sod wnlained about 10% orgaoic matter. A field assay was conducted to shldg whether BOP slag could bc used as a dolomitic k i n g agent for agricullural soils. Four slag rates (0, 4, 8, 12 Mgha-')were investigated for their effcfect on soil pmperti~, mineral concentralions in leaf tissues of rice and soybean, and yield of the crops. Slag application at 8 Mgha-' rate in paddy field increased pH, Ca Mg, P, Si and Fe wntenl in sail and rice yield by 4.3-14.25 depending an the soil type. h upland field the 8 Mghaf ratc increa3ed pH, Ca and Fe wntent m soil and soybean yield by 36.6%. Thus, BOF slag appears to be a useful liming mate&\ulcornerl for corrzch~gs oil acidity on both paddy and upland ficld soils and for innwing Ca, Mg, P, Si, and Fe wncenhation in plants.

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Stabilization of mixed heavy metals in contaminated marine sediment using steel slag (제강슬래그를 이용한 해양오염퇴적물 내 혼합 중금속 안정화)

  • Shin, Woo-Seok;Kim, Young-Kee
    • Journal of Navigation and Port Research
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    • v.38 no.3
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    • pp.269-275
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    • 2014
  • In this study, the adsorption efficiency of mixed heavy metals in aqueous solution was investigated using steel slag. Moreover, heavy-metal stabilization treatment of contaminated marine sediment was achieved using steel slag as stabilizing agents. Heavy metal adsorption was characterized using Freundlich and Langmuir equations. The equilibrium adsorption data were fitted well to the Langmuir model in steel slag. The adsorption uptake of heavy metals were higher in the order of $Pb^{2+}$ > $Cd^{2+}$ > $Cu^{2+}$ > $Zn^{2+}$ > $Ni^{2+}$. The steel slage was applied for a wet-curing duration of 150 days. From the sequential extraction results, the exchangeable, carbonate, and oxides fractions of Ni, Zn, Cu, Pb, and Cd in sediment decreased by 13.0%, 6.0%, 1.3%, 17.0%, and 50.0%, respectively.

Reaction Characteristics of the CAC with Various Gypsum Type and Mixing Ratio (석고 종류 및 혼입률에 따른 CAC 반응 특성)

  • Choi, Sun-Mi;Kim, Jin-Man;Koo, Ja-Sul
    • Resources Recycling
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    • v.30 no.1
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    • pp.83-91
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    • 2021
  • Ladle furnace slag is a byproduct of the steel-making process, and it contains the mineral β-C2Sandtherapid-settingmineral (dependingonwhichreducingagenthasbeenused). Ladle furnace slag is often treated through slow cooling, which causes the slag to lose its reactivity. In this study, the properties of air-quenched CAC and pulverized ladle furnace slag containing gypsum were evaluated, and the optimal mixing ratio was determined for broadening their usage. Consequently, the properties of CAC aredemonstrated by the dissolution of gypsum after a period of three hours and the content of gypsum after a period of one day. The optimal mixing ratio of anhydrate and hemihydrate gypsum is found to be within 30% and that of dihydrate gypsum is found to be higher than 35%. Furthermore, based on the results of CAC with dihydrate gypsum, the applicability of the by-product dihydrate gypsum has been verified.

Production of solar grade silicon by using metallurgical refinement (야금학적 정련 통합 공정을 이용한 태양전지용 실리콘 제조 기술)

  • Jang, Eunsu;Park, Dongho;Moon, Byung Moon;Min, Dong Jun;Yu, Tae U
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.54.2-54.2
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    • 2011
  • 야금학적 정련 공정 중 슬래그 처리, 일방향 응고, 플라즈마-전자기유도용해 공정을 적용한 태양전지용 실리콘 제조 기술에 관한 연구를 수행하였다. 원소재인 금속급 실리콘을 제조하기 위해원재료로 규석, 코크스(Cokes), 숯, 그리고 우드칩(Wood chip)을 사용하였으며, 150kW급 DC 아크로(Arc furnace)를 이용하여 순도 99.8% 금속급 실리콘을 제조하였다. 제조된 용융 상태의 금속급 실리콘은 슬래그와 반응시켜 불순물을 제거하였다. SiO2-CaO-CaF2 계의 슬래그를 이용하였으며, 금속급 실리콘과 슬래그의 질량비 및 반응 시간에 따른 실리콘 불순물 특성을 평가하였다. 이후 고액 계면이 제어 가능한 일방향 응고 장치를 이용하여 금속불순물을 제거하였다. 고액상태의 온도 조건 및 응고 시간에 따른 불순물 농도 변화를 평가하였으며, 순도 6N급의 실리콘을 제조하였다. 마지막 공정으로 스팀 플라즈마 토치와 냉도가니가 적용된 전자기 유도 용해장치를 이용하여 붕소와 인을 제거하였다. 플라즈마 토치 가스로는 아르곤, 스팀, 수소를 이용하였다. 붕소와 인의 제거율은 각각 94%와 96%를 달성하였으며, 최종 순도 6N급의 실리콘을 제조하였다.

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Study of Polymer Rapid Setting Cement Concrete Using Electric Arc Furnace Oxidizing Slag Aggregate (전기로(電氣爐) 산화(酸化)슬래그 잔골재를 이용한 폴리머 속경성(速硬性) 시멘트 콘크리트 기초물성(基礎物性) 연구(硏究))

  • Jung, Won-Kyong;Gill, Yong-Soo;Kang, Seung-Hee
    • Resources Recycling
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    • v.21 no.1
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    • pp.30-40
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    • 2012
  • Electric arc furnace slag is made in ironworks during steel refining, it is been increasing chemical and physical resistibility using ageing method of unstable state of melting steel slag for using concrete's fine aggregates. Which is been changing stable molecular structure of aggregates, it restrains moving of ion and molecule. In Korea, KS F 4571 has been prepared for using the electric arc furnace oxidizing slag to concrete aggregates(EFS). In this study, Electric arc furnace oxidizing slag is used in the PRCC(Polymer Rapid setting Cement Concrete) which is applied a bridge pavement of rehabilitation, largely. The results showed that the increment of compressive strength development by 10- 20%. The flexural strength of EFS-Con increased greatly as the electric arc furnace oxidizing slag changed. The compressive strength and flexural strength developed enough for opening the overlayed EFS-Con to the traffic after 4 hours of EFS-Con placement. The permeability of EFS-Con was evaluated as negligible due to its very low charge passed. Thus, EFS-Con could be used at repairing or overlaying the concrete at fast-track job sites.

An Investigation of Treatment Effects of Limestone and Steel Refining Slag for Stabilization of Arsenic and Heavy Metal in the Farmland Soils nearby Abandoned Metal Mine (폐금속 광산 주변 비소 및 중금속 오염농경지의 안정화 처리를 위한 석회석과 제강슬래그의 처리효과 검토)

  • Yun, Sung-Wook;Kang, Sin-Il;Jin, Hae-Geun;Kim, Ha-Jin;Lim, Young-Cheol;Yi, Ji-Min;Yu, Chan
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.5
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    • pp.734-744
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    • 2011
  • A soil stabilization method is an effective and practical remediation alternative for arsenic (As) and heavy metal contaminated farmland soils nearby abandoned metal mine in Korea. This method is a technique whereby amendments are incorporated and mixed with a contaminated soil. Toxic metal bind to the amendments, which reduce their mobility in soil, so the successful stabilization of multi-element contaminated soil depends on the combination of critical elements in the soil and the type of amendments. The objective of this study is to investigate the treatment effects and applicability of limestone (LS) and steel refining slag (SRS) as the amendment for farmland soil contaminated with As and heavy metals, and a lab-column test was conducted for achieving this purpose. The result showed that soil treated with LS and SRS maintained pH buffer capacity and, as a result, the heavy metal leaching concentration was quite low below the water quality standard compared to untreated soil which leachate exceeding the water quality standard was observed, however, the arsenic concentration rather increased with increasing mixture ratio of SRS. This was believed to be related to phosphorus (P) contained in SRS, and dominancy in the competitive adsorption relation between As and P binding strongly to iron might be different according to soil characteristic. We suggested that LS is a effective amendment for reducing heavy metals in soil, and SRS should be used after investigating its applicability based on the adsorption selectivity of arsenic and phosphorus in selected soil.

Effect of Micro Bubble on the High-Voiume Slag Concrete Mixed with Emulsified Refined Cooking Oil (마이크로버블이 유화처리 정제유지류(ERCO)혼입 고로슬래그 다량 치환 콘크리트의 특성에 미치는 영향)

  • Kim, Min-Yoyng;Park, Young-Jun;Baek, Doo-Hwan;Baek, Byung-Hoon;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.44-45
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    • 2015
  • Although the carbonation problem of high-volume slag concrete has been solved by the mixed use of emulsified refine cooling oil as the pilot study, there was an instance of securing air quantity and frost resistance followed by the use of Expancel due to the problem of having vulnerability in frost resistance in result as the air quantity has not been secured. But due to the problem of Expancel not being economical, air quantity and frost resistance of high-volume slag concrete mixed with ERCO are attempted to be secured using micro bubble that can remain in the water for a long time as a relatively economical and very microscopic bubble.

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Feasibility Study on the Multi-functional Ceramics using Industrial By-product for Treatment of Acid Mine Drainage (산성광산배수 처리를 위한 산업부산물 소재 다기능성 세라믹의 적용 가능성 연구)

  • Lee, Yeong-Nam;Yim, Soo-Bin
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.12
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    • pp.25-36
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    • 2017
  • This research was conducted to investigate the removal characteristics of heavy metals and sulfate ion from acid mine drainage (AMD) by multi-functional zeolite-slag ceramics (ZS ceramics), in which natural zeolite and converter slag were mixed and calcined at high temperature. The batch test showed that the removal efficiency of heavy metals by pellet-type ZS ceramics increased as the mixing weight ratio of converter slag to natural zeolite increased. The optimal mixing ratio of natural zeolite to converter slag for the removal of heavy metals and sulfate ion from AMD was observed to be 1:2~1:3. The adequate calcination temperature and time of ZS ceramics for the treatment of AMD were found to be $600{\sim}800^{\circ}C$ and 2 hours, respectively. The removal test of heavy metals and sulfate ion from AMD by the ZS ceramics prepared in optimal condition exhibited very high removal efficiencies close to 100% for all heavy metals (Al, As, Cd, Cu, Fe, Mn, Pb, Zn) and 77.1% for sulfate ion. The experimental results in this study revealed that the ZS ceramics could function as an effective agent for the treatment of AMD.

Study on Mock-up Properties of Concrete using Blast Furnace Slag and Recycled Aggregate (고로슬래그와 재생골재를 사용한 콘크리트의 실물대 특성에 관한 연구)

  • Park, Hyun;Han, Da-Hee;Park, Moo-Young;Kim, Woo-Jae;Lee, Young-Do;Jung, Sang-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.789-792
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    • 2008
  • Blast furnace slag doesn't have self-hydraulicity and it needs stimulants such as alkali to hydrate. Therefore using recycled aggregates erupted calcium hydroxides and blast furnace slag acquiring alkali stimulate could make a complementarily use of a recycling architectural material possible. In this study, we have discussed about characters of blast furnace slag and recycled aggregate firstly, and make recycled aggregate mortar and concrete using blast furnace slag for the experiment. The experiment is about mortar and concrete using recycled aggregate as a substitutional material of blast furnace slag. In this experiment, I replace blast furnace slag and aggregate with recycled aggregate. Conclusions through the test results analysis are as follows. And then, we added field experiment using concrete with composited materials.

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