• Proceedings of the Korea Concrete Institute Conference
• /
• 2005.05b
• /
• pp.177-180
• /
• 2005

Decing agent with chloride promote frost damage of concrete structure in winter period. From the safetyside, however, it is difficult to stop using chloride. Therefore, the durable concrete is required from now on. In this paper, long-term freezing and thawing test was carried out using the freezing water containing $CaCl_{2}$ to consider the concrete scaling according to the kind of binders, such as OPC, Flyash, Slag+Fa. and Slag As a result, it was found that the degree of scaling is different with containing slag being considered to prevent the penetration chloride ion and according to each binders.

• Journal of the Korean Society of Hazard Mitigation
• /
• v.8 no.6
• /
• pp.47-52
• /
• 2008

Deicer has been generally used for prevention of a road freezing in winter, and the usage amount is increasing every year. However, deicer may induce the decrease of bond strength, surface scaling, and environmental pollution. In this study, the field test was performed to investigate the deterioration of concrete road structures used for 17 years. And, the corrosion resistance characteristics were compared for the existing deicer and eco-friendly deicer. According to the field test results, the penetration depth of limit chloride amount was about 40mm, and the average concentration of chloride was $3.45kg/m^3$ at the surface of structures. On the contrary, the carbonation depth was slight. The penetration depth of eco-friendly deicer was less than the existing deicer, and the corrosion resistance of eco-friendly deicer was higher.

• Journal of the Mineralogical Society of Korea
• /
• v.23 no.1
• /
• pp.51-61
• /
• 2010

Ettringite $(Ca_6[Al(OH)_6]_2(SO_4)_3{\cdot}26H_2O)$ is a sulfate mineral that shows a complicate property in concrete. It is often called as "a cancer of concrete" because secondary ettringite formation in hardened concrete often cause expansion and cracking of concrete due to its expansive crystal structure. In the present study, we tested the possibility for crystal growth inhibition of secondary ettringite by crystallization inhibitors that are commercially used for scaling inhibitors in Korea. For the test, we developed a method of ettringite solution synthesis. Three types of crystallization inhibitors were selected and examined the effects On ettringite growth inhibition. The experimental results of ettringite solution synthesis indicated that ettringite was successfully synthesized under condition that the mass balance between calcium hydroxide saturated solution and aluminum sulfate solution was attained. Monosulfate and semisulfate were synthesized when the ratio of $Ca^{2+}$ ions to ${SO_4}^{2+}$ ions was increased. The induction time of ettringite crystallization was less than 2 min. and crystallization was almost completed within an hour. The experimental results of ettringite crystallization inhibition showed that organic PBCT (2-Phosphonobutane-1,2,4-Tricarboxylic Acid) and inorganic SHMP (Sodium Hexametaphosphate) were relatively less effective on ettringite crystallization inhibition under experimental conditions. However, organic HEDP (1-Hydoxyethylidene-1,1-Diphosphonic Acid) effectively prevented ettringite growth with producing amorphous gel phase materials up to inhibitor concentration 0.1 vol.% of aluminum sulfate solution.