• Korean Chemical Engineering Research
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• 제49권6호
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• pp.857-864
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• 2011

순산소연소는 높은 연소 효율과 적은 배가스량, 낮은 질소산화물 농도를 장점으로 하고 있으며 연소온도 조절을 위한 배가스 재순환에 의해 배출되는 연소가스중의 $CO_2$ 농도를 95%까지 농축이 가능하므로 석탄 연소설비에 대한 유망한 CCS 기술로 부각되고 있다. 본 연구는 순산소연소 조건에서 배가스의 재순환을 통한 $CO_2$ 농도 증가에 기인하는 직접 황화반응이 탈황효율에 미치는 영향을 평가하고 반응온도, $CO_2$ 농도, $SO_2$ 농도상승이 $SO_2$ 제거효율에 미치는 영향과 배가스 중 수분 등이 $SO_2$ 제거효율에 미치는 영향을 실험적으로 고찰하였다. 반응온도 $1,200^{\circ}C$까지 온도 상승에 따라 $SO_2$의 제거효율은 증가하였고 Ca/S비, $CO_2$ 농도와 수분이 증가할수록 $SO_2$ 제거효율이 증가하였다. 이러한 운전변수는 영향인자 평가를 통하여 Ca/S 비>체류시간>$O_2$농도>반응온도>$SO_2$농도>$CO_2$농도>수분농도의 순으로 탈황반응에 영향을 미치는 것으로 나타났다. 또한 운전변수별 실험결과를 이용하여 로내 건식탈황에 있어서 각 운전변수별 성능 영향인자를 평가할 수 있는 반경험적 모델식을 도출하였다.

• 한국대기환경학회지
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• 제33권5호
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• pp.473-479
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• 2017

This study was designed to understand characteristics of oxy-combustion of coal, dried sewage sludge and solid refuse fuel (SRF). Thermogravimetric analysis was conducted by burning the fuels with air, 21% oxygen ($O_2$)/79% carbon dioxide ($CO_2$) and 30% $O_2/70%$ $CO_2$. Heating rates were varied as 5, 10, 25, 40 and $100^{\circ}C/min$. Complete coal combustion was found at the heating rates of 5, 10, 25 and $40^{\circ}C/min$, and different combustion behavior was found with the gas composition at the heating rates of 10, 25, 40 and $100^{\circ}C/min$. Coal combustion with 30% $O_2/70%$ $CO_2$ showed the highest while coal combustion with 21% $O_2/79%$ $CO_2$ showed the lowest combustion rate. On the other hand, the combustion of dried sewage sludge and SRF showed similar combustion behavior with respect to the combustion gas composition. This suggests that oxy-combustion of dried sewage sludge and SRF which contain a large amount of volatile matter may show similar combustion behavior to their air combustion.

• 대한기계학회논문집B
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• 제33권1호
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• pp.38-45
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• 2009

Oxy-fuel combustion of pulverized coal is one of the promising new technologies to reduce $CO_2$ and NOx from coal combustion. However, the stability of pulverized coal flame is reduced in the oxy-fuel combustion. This flame stability is concerned with the flame propagation that is affected by surrounding gas and coal characteristics, such as gas temperature, gas composition, coal volatile, coal activation energy and coal size. In this paper, a study on the influence of surrounding gas and coal characteristics on the flame propagation velocity in oxy-fuel combustion of pulverized coal was preformed. One dimensional model was used to calculate the flame propagation velocity of pulverized coal clouds. In this model, the radiation is considered to be the main source of heat exchange, and Monte Carlo method was adopted for accurate calculation of radiation heat flux. It was found that the flame propagation velocity become higher with the decrease of coal activation energy and the increase of coal volatile. Also, according to the increase of gas temperature and $O_2$ concentration, flame propagation velocity increased.