• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.1
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• pp.103-110
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• 2011

This study is to comparatively analyze the characteristics of pH decrease in recycled fine aggregates for embankment and landfill produced from waste concrete by using natural process and artificial process. The result was as follows In case of recycled fine aggregates left outdoor, it was found that pH level was decreased if the thickness of embankment becomes thinner, or the materials left outdoors owing to high concentration of $CO_2$ in atmosphere caused by respirations of people. When the air was permeated, pH level was decreased more effectively. It was analyzed that this phenomenon was caused by efficient supply of $CO_2$ in the recycled fine aggregates owing to high-pressure ventilators. In case of water spraying treatment, sprayed water facilitated hydration of unhydrated cement to dissolve calcium hydroxides which neutralized $CO_2$ in the atmosphere during desiccation process and decrease pH level by a considerable margin. In case of Immersed treatment, decrease of pH was not sufficient. When facilitating the supply of $CO_2$, pH level of the recycled fine aggregates was decreased by the largest margin. It was analyzed that this phenomenon was caused by efficient supply of $CO_2$. From the above results, it was analyzed that the most effective method of reducing pH level of the recycled fine aggregates from the aspects of pH reduction performance, economic efficiency and workability was repeated wet-dry cycles of spraying water to the aggregates in the proportion of 1:0.5 by weight and then treating by forcefully blowing $CO_2$ gas into the aggregates.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.3
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• pp.77-84
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• 2012

It is known that some components of wood obstruct the hydration of cement when wood is mixed with cement. In order to examine the effect of pretreatment of wood chips in hot water, this study conducted the experiments for the setting and compressive strength of mortar by sieving pine wood chips with a 2.4mm sieve, dipping them in waters of different temperatures, and then using them as a part of the fine aggregate. For the experiments, water-cement ratio of the mortar was 0.50 and the amount of the fine aggregate substituted by wood chips was set at 0%, 2%, 4%, 6%, 8%, and 10% of the mass of the fine aggregate. As a result of the test, it was found out that when wood chips were used to substitute fine aggregate for the production of mortar, more usage of wood chips postponed setting more, and the treatment of wood chips with water improved the problem of the delay in setting time. Especially, the final setting time of the mortar which used 2~6% of wood chips treated in $100^{\circ}C$ water for 30 minutes was almost the same as the final setting time of the mortar which used no wood chips. Also, the compressive strength of the mortar which used the wood chips treated with water was compared to that of the mortar which used the wood chips not treated with water. The result showed that the strength improved for age of 7 days and 28 days, while there was little change in strength for age of 3 days.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.3
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• pp.317-324
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• 2020

Plastic wastes generated from domestic waste are separated by mixed discharge with foreign substances, and the cost of the separation and screening process increases, so recycling is relatively low. In this study, as a fundamental study for recycling mixed plastic wastes generated from domestic waste into concrete aggregates, changes in concrete properties according to the plastic waste types and the substitution rate were evaluated experimentally. The mixed plastic waste aggregate(MPWA) was found to have a lower density and a higher absorption rate compared to the coarse aggregate with good particle size distribution. On the other hand, the single plastic waste aggregate(SPWA) was composed of particles of uniform size, and both the density and the absorption rate were lower than that of the fin e aggregate. It was found that the MPWA substitution concrete did not cause a material separation phenomenon due to a relatively good particle size distribution even with the largest amount of plastic waste substitution, and the amount of air flow increased little. The compressive strength and flexural strength of the PWA substitution concrete decreased as the amount of substitution of the PWA increased due to the low strength of the PWA, the suppression of the cement hydration reaction due to hydrophobicity, and the low adhesion between the PWA and the cement paste. It was found that the degree of deterioration in compressive strength and flexural strength of concrete substituted with MPWA having good particle size distribution was relatively small.

• Journal of the Korea Concrete Institute
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• v.29 no.1
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• pp.65-75
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• 2017

C-S-H phase is the most abundant reaction product, occupying about 50~60% of cement paste volume. The phase is also responsible for most of engineering properties of cement paste. This is not because it is intrinsically strong or stable, but because it forms a continuous layer that binds together the original cement particles into a cohesive whole. The binding ability of C-S-H phase arises from its nanometer-level structure. In terms of chloride penetration in concrete, C-S-H phase is known to adsorb chloride ions, however, its mechanism is very complicated and still not clear. The purpose of this study is to examine the interaction between chloride ions and C-S-H phase with various Ca/Si ratios and identify the adsorption mechanism. C-S-H phase can absorb chloride ions with 3 steps. In the C-S-H phase with low Ca/Si ratios, momentary physical adsorption could not be expected. Physical adsorption is strongly dependent on electro-kinetic interaction between surface area of C-S-H phase and chloride ions. For C-S-H phase with high Ca/Si ratio, electrical kinetic interaction was strongly activated and the amount of surface complexation increased. However, chemical adsorption could not be activated for C-S-H phase with high Ca/Si ratio. The reason can be explained in such a speculation that chloride ions cannot be penetrated and adsorbed chemically. Thus, the maximum chloride adsorption capacity was obtained from the C-S-H phase with a 1.50 Ca/Si ratio.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.31 no.5
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• pp.251-258
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• 2018

In construction site, conventional methods such as jackhammer or explosive methods(dynamite) have been often used for the demolition of structures. Use of those methods are more carefully treated in environmentally and historically sensitive area. For those reasons, use of Soundless Chemical Demolition Agent(SCDA) is getting the spotlight. The SCDA is a powder which has expansive strength when it is mixed with water. In these Characteristics, SCDA can destroy the concrete or rock as it is poured into boreholes of the concrete or rock structures. However, there is no industrial standard for the use of SCDA effectively yet. In this study, experimental study to measure the expansive pressure was conducted depending on various boundary conditions such as waterproof, length of the steel pipe, submerged of steel pipe. Furthermore, computational analysis using damage plasticity model to predict the minimum required pressure of the SCDA for the concrete demolition depending on spacing between holes(k-factor) and compressive strength of the concrete was conducted. Obtained results indicates that water heat dissipation with submerged steel pipe shows the stable pressure for measuring the SCDA and hole distance(k-factor) is the most important factor for crack initiation of concrete.

• Journal of the Korean Chemical Society
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• v.42 no.4
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• pp.422-431
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• 1998

Tridentate Schiff base ligands such as $SIPH_2,\;SIPCH_2,\;HNIPH_2,\;and\; HNIPCH_2$ were prepared by the reaction of salicylaldehyde and 2-hydroxy-l-naphthaldehyde with 2-aminophenol and 2-amino-p-cresol. The structures and properties of ligands and their Co(II) complexes were investigated by elemental analysis, $^1H$NMR, IR, UV-visible spectra, and thermogravimetric analysis. The molar ratio of Schiff base to the metal of complexes was found to be 1:1. Co(II) complexes were contemplated to be hexa-coordinated octahedral configuration containing three water molecules. The redox process of ligands and complexes in DMSO solution containing 0.1 M TBAP as a supporting electrolyte were investigated by cyclic voltammetry with glassy carbon electrode. The redox process of the tridentate Schiff base ligands was totally irreversible. The redox process of Co(II) complexes were irreversible and one electron processes by two steps in diffusion controlled reaction. The reduction potential of the Co(II) complexes was shifted to the positive direction in the order [Co(Ⅱ)$(HNIPC)(H_2O)_3$]>[Co(Ⅱ)$(HNIP)(H_2O)_3$]>[Co(II)$(SIPC)(H_2O)_3$]>[Co(Ⅱ)$(SIP)(H_2O)_3], and their dependence on ligands were not so high.

• Polymer(Korea)
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• v.36 no.2
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• pp.208-215
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• 2012

To study the effect of surface crosslinked layer on the crosslinked poly(sodium acrylate) (cPSA) absorbent, we synthesized several surface crosslinked cPSAs with 5, 10 and 20 g of ethylene glycol dimethacrylate (EGDMA) by an inverse emulsion polymerization method to delay the absorption of excess water in concrete. We measured the compressive and flexural strength of mortars having 0.5, 1.0 and 1.5 wt% cPSA-EGDMA. We observed the increase of compressive and flexural strength of the cPSA-EGDMA added cement mortars except for the 0.5 wt% cPSA-EGDMA (20 g) added cement mortar. 1.0 wt% cPSA-EGDMA (5 g) added cement mortar showed about 16% and 10% increased compressive and flexural strength than those of plain cement mortar. To study the effect of porosity on compressive and flexural strength, we used FE-SEM and porosimeter. FE-SEM analysis showed swollen cPSMAEGDMA (5 g) filled between calcium silicate hydrate (C-S-H) crystals. We observed the decreased porosity of the cPSA-EGDMA added cement mortars than that of plain cement mortar. 1.0 wt% cPSA-EGDMA (5 g) cement mortar showed the lowest porosity of 16.5%.

• Food Science and Preservation
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• v.13 no.1
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• pp.24-29
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• 2006

This study was carried out to promote aspects of preservation and convenience of red pepper paste (r.p.p.). Sample was prepared with spray drying (s.d), vacuum drying (v.d) and freeze drying (f.d) methods. The prepared powdered samples were stored for 90 days at $35^{\circ}C$ in seal condition. After powdered samples were hydrated, the samples were used for analysis such as a sensory test, texture, color and changes of component According to sensory test, quality of dried red pepper paste were better in order to f.d.r.p.p. < s.d.r.p.p. < v.d.r.p.p. Changes of pH, reducing sugar, amino nitrogen and NaCl of dried r.p.p. were not observed compared to control but viscosity decreased by about $15\%$ During the storage, acidity decreased by about $15\%$ and reducing sugar, amino nitrogen and ethanol decreased slightly. Hunter L, a and b values decreased from 24.8-27.3 to 23.6-24.4, from 10.8-12.0 to 8.3-9.3 and from 7.1-7.9 to 4.4-5.5, respectively.

• Korean Journal of Weed Science
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• v.7 no.1
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• pp.12-18
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• 1987

Seed dormancy and germination responses to light and gases were determined for Echinochloa colona (L.) Link. E. colons seeds did not require a period of after-ripening for breaking dormancy. Water movement occurred readily across the seed coat. Repeated cycles of hydration and dehydration reduced viability and thence germination. Water imbibition for 24 h increased seed moisture by 21%; seeds returned to their original weight after drying at room temperature for 13 h. Removal of seed-coats increased germination in the dark. Light stimulated germination. Germination at a daylight intensity of 51.9 $Wm^{-2}$ or less was significantly reduced. Germination of seeds which were exposed to light for 1 h each day was significantly less than that of seeds exposed for longer than 2 h a day. Seeds subjected to blue light had delayed and decreased germination compared to seeds exposed to red light. Ethylene or carbon dioxide exogenenously added in the presence of light stimulated germination. The addition of the two gases together had a synergistic effect. In the dark, however, the two gases did not increase germination.

• Journal of the Korea Concrete Institute
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• v.17 no.4 s.88
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• pp.551-558
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• 2005

The setting and hardening of concrete is accompanied with nonlinear temperature distribution caused by development of hydration heat of cement. Especially at early ages, this nonlinear distribution has a large influence on the crack evolution. As a result, in order to predict the exact temperature history in concrete structures it is required to examine thermal properties of concrete. In this study, the convection heat transfer coefficient which presents thermal transfer between surface of concrete and air, was experimentally investigated with variables such as velocity of wind, curing condition and ambient temperature. At initial stage, the convection heat transfer coefficient is overestimated by the evaporation quantity. So it is essential to modify the thermal equilibrium considered with the boiling effect. From experimental results, the convection heat transfer coefficient was calculated using equations of thermal equilibrium. Finally, the prediction model for equivalent convection heat transfer coefficient including effects of velocity of wind, curing condition, ambient temperature and boiling effects was theoretically proposed. The convection heat transfer coefficient in the proposed model increases with velocity of wind, and its dependance on wind velocity is varied with curing condition. This tendency is due to a combined heat transfer system of conduction through form and convection to air. From comparison with experimental results, the convection heat transfer coefficient by this model was well agreed with those by experimental results.