• Title/Summary/Keyword: 수화에너지

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Effect of Temperature on the Water Uptake during Soaking of Soybeans (대두의 수화속도에 미치는 침지온도의 영향)

  • Kim, Dong-Youn;Suh, In-Sook;Rhee, Chong-Ouk
    • Applied Biological Chemistry
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    • v.31 no.1
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    • pp.46-51
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    • 1988
  • The effects of temperature on the water uptake rate of soybeans soaked in tap water and 0.5% $NaHCO_3$ solution were studied. The higher the soaking temperature, the faster the hydration rate, and among the three soybean varieties (Tanyob, Kwanggyo and Saeal), Tanyob(the smallest variety) showed faster rate than ocher varieties when soaking in tap water and 0.5% $NaHCO_3$ solution. Activation energy due to weight increase was calculated using Arrhenius equation. z-Values calculated from weight changes to reach different degrees of hydration during soaking showed the tendency to decrease with the increase of hydration degree when soaking in tap water and 0.5% $NaHCO_3$ solution.

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The characteristics of heat storage and emission of PCM in Ondol system (잠열저장재를 이용한 온돌판넬의 축열 및 방열특성에 관한 연구)

  • Cho, Soo;Yoo, Je-In;Chung, Hun-Saeng
    • Solar Energy
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    • v.10 no.2
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    • pp.38-43
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    • 1990
  • The present study was to investigate the use of a phase change material for hydronic radiant floor heating. Two identical unit test cells sized $1.8m^L{\times}1.8m^W{\times}1.8m^H$ were built and installed with specially designed $1.6cm^T{\times}9cm^W{\times}80cm^H$ aluminum Ondol-panels holding 1.25kg of calcium chloride hexahydrate(CCH) each. It was found that the Ondol-panel with CCH reduced the room temperature fluctuations and maintains the phase changing temperature for considerably long duration, $2{\sim}4$ times of heating hour, over no-CCH one.

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Rate Augmentation of Exothermic Hydration in the CaO Packed Bed (CaO 충전층의 수화발열반응 촉진)

  • Chung, Soo-Yull;Kim, Jong-Shik
    • Solar Energy
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    • v.14 no.2
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    • pp.91-101
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    • 1994
  • Heat release characteristics of a CaO packed bed reactor which is used for a chemical heat storage device has been studied. We employed Cu-plate fins to release the heat of reaction of the CaO packed bed inside the reactor fast and effectively. Two-dimensional analysis of unsteady state heat flow inside the bed was performed as a function of time and under various conditions of the Cu-plates. It is noted that the time required to release the heat of reaction with Cu fins is reduced more than twice fast compared to that without Cu fins. That was largely dependent upon the number of Cu-plate, as well.

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Effect of Freezing on Hydration Rate and Sprouting Characteristics of Soybeans (대두의 수화속도와 콩나물의 발아특성에 대한 동결처리 효과)

  • Rhim, Jong-Whan;Oh, Bong-Yun;Kim, Dong-Han;Ham, Kyung-Sik
    • Korean Journal of Food Science and Technology
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    • v.35 no.4
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    • pp.660-665
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    • 2003
  • Effect of freezing on the hydration rate and growth characteristics of bean sprout of two domestic cultivars of soybean, Eunha beans and Taegwang beans, was investigated. Freezing of the soybeans at $-80^{\circ}C$ affected characteristics of the hydration and growth of soybean sprout of the beans. Hydration rate of the frozen beans depended on the hydration temperature. It decreased up to 50% at lower than $60^{\circ}C$ of hydration temperature, but it did not decrease at higher than $60^{\circ}C$. Activation energies of frozen Eunha and Taegwang beans were 39.79 and 39.25 kJ/mol, respectively. Kinetic compensation effect between activation energy values and the pre-exponential factor for the hydration of soybeans with or without freezing was observed. Germination rate and thickness of the bean sprout increased by freezing, however, yield and weight were not affected by freezing.

Effect of Defatting on Hydration of Akibare (Japonica) and Milyang 30 (J/lndica) Rice (탈지에 따른 아끼바레 및 밀양30호 쌀의 수화속도)

  • Kim, Soon-Mi;Kim, Kwang-Ok;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.18 no.2
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    • pp.110-113
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    • 1986
  • Effect of defatting on the hydration rate of Akibare (Japonica) and Milyang 30 (J/lndica) rice was investigated. Relative crystallinity of rice starch and width of the rice grain were decreased by defatting, which was more pronounced for Milyang 30. The moisture gain at $10^{\circ}{\sim}40^{\circ}C$ for 80 min and the hydration rate of the defatted Milyang 30 rice were lower and higher than those of the defatted Akibare rice, respectively. The activation energy for hydration of rice was not affected by defatting.

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Comparison on the Energy Consumption of the Vacuum Evaporation and Hydrated-Based Technologies for Concentrating Dissolved Ions (용존 이온 농축을 위한 진공 증발 기술과 하이드레이트 기반 기술의 소모 에너지 비교)

  • Han, Kunwoo;Rhee, Chang Houn;Ahn, Chi Kyu;Lee, Man Su
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.378-386
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    • 2019
  • In the present paper we report the calculation results of operation energy consumption for dissolved ions concentration technologies using vacuum evaporation (VE) and hydrate formation. Calculations were conducted assuming the tenfold concentration of saline water (0.35 wt% NaCl solution) of 1 mol/s at room temperature and atmospheric pressure employing vacuum evaporation at $69^{\circ}C$ and 30 kPa and hydrate-based concentration using $CH_4$, $CO_2$ and $SF_6$ as guest molecules. Operation energy consumption of VE-based concentration resulted in 47 kJ/mol, whereas those of hydrate-based concentration were 43, 32, and 28 kJ/mol for $CH_4$, $CO_2$ and $SF_6$ hydrates, respectively. We observe that hydrate-based concentration can a competitive option for dissolved ions recovery from energy consumption standpoint. However, the selection of guest gas is very critical, since it accordingly determines the hydration number, the hydrate formation energy, gas compression energy, etc. The selection of guest gas, separation of concentrated brine and water phases, and the enhancement of hydrate formation rate are the key factors for the commercialization of hydrated-based technology for concentrating dissolved ions.

Numerical Analysis of Heat Transfer in Packed Bed of $Ca(OH)_2/CaO$ for Chemical Heat Pump ($Ca(OH)_2/CaO$계 화학 열펌프에 있어서 고체 반응층의 전열해석)

  • Kim, Jong-Shik
    • Solar Energy
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    • v.17 no.1
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    • pp.67-77
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    • 1997
  • To develop chemical heat pump of higher energy density and efficiency heat-release characteristics accompanied by exothermic hydration reaction in packed bed, $Ca(OH)_2/CaO$ reactor, are examined in a lab-scale unit. We have studied the enhancement effect of inserted fins in cylindical packed bed reactor. The results obtained by numerical analysis about profiles of temperature, completion time of reaction and exothermic heat amount released from the reactor read the insertion of fins in reactor can reduce the reaction completion time by half and the rate of thermochemical reaction depends on the temperature and concentration, and it is also governed by the boundary conditions and the rate of heat transfer in the particle packed bed.

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One-pot Synthesis of Hydrous MnO2 Nanowires for Selective Oxidative Transformation of Furfuryl Alcohol (Furfuryl 알코올의 선택적 산화 전환에 대한 수화 이산화망간 나노와이어의 One-pot 합성)

  • Mobina, Irshad;Choi, Bong Gill;Kim, Jung Won
    • Applied Chemistry for Engineering
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    • v.30 no.1
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    • pp.49-53
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    • 2019
  • Hydrous $MnO_2$ nanowires were easily synthesized by an one-pot synthesis with a simple hydrothermal method. As prepared hydrous $MnO_2$ nanowires were characterized with scanning emission microscopy (SEM), transmit emission microscopy (TEM), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET). They showed a good catalytic activity with the suitable nano-size of 4-5 nm and morphology. The furfuryl alcohol was selected as a substrate and the reaction was carried out in a toluene solvent at $100^{\circ}C$ under the atmospheric pressure of oxygen. The hydrous $MnO_2$ nanowire catalyst exhibited an excellent yield of furfural with the first-rate selectivity and conversion. The catalytic performance during recycle tests was also carried out and the catalyst showed a good mechanical strength with a negligible loss in the activity over five reaction cycles.

A Kinetic Study on the Hydration Process of Barley Kernels with Various Polishing Yields (도정수율별 보리의 수화공정(水和工程)에 관(關)한 속도론적(速度論的) 연구(硏究))

  • Mok, Chul-Kyoon;Lee, Hyun-Yu;Nam, Young-Jung;Min, Byong-Yong
    • Korean Journal of Food Science and Technology
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    • v.15 no.2
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    • pp.136-140
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    • 1983
  • The hydration characteristics of barley kernels with various polishing yields were investigated at temperatures of $20-60^{\circ}C$ and their sorption kinetics were studied. The moisture gain in initial stage of hydration was directly proportional to square root of hydration time and there was a break point at the moisture gain of 0.45-0.55g $H_2O/g$ solid. The hydration rate was great in order of polishing yield of 50, 70, 95, 90 and 100%, and increased with increasing hydration temperature. The diffusivity of water into barley kernels followed Arrhenius equation, and the activation energies in hydration reaction of polished barley were ranged from 6.9 to 9.5 Kcal/mole and that of non-polished one was 11.6Kcal/mole.

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